• Title/Summary/Keyword: methyl ester

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Life Time Estimation of Biodiesel and Biodiesel Blend Fuel from the Oxidation Stability Analysis (바이오디젤 및 바이오디젤 혼합연료의 산화특성 연구에 의한 사용 수명 예측)

  • Jung, Chung-Sub;Dong, Jong-In;Lee, Young-Jae
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.579-584
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    • 2007
  • 대두유로부터 생산된 바이오디젤과 바이오디젤 혼합 연료유를 대상으로 지방산메틸에스터 함량과 화학적 분석을 통해 산화 특성과 오일의 수명 예측 연구를 수행하였다. 바이오디젤, 경유, BD5, BD20은 산화가 진행될수록 산가(Acid number), 동점도(Kinematic Viscosity) 및 밀도(Density)는 증가하였다. 산가 측정결과의 활용에 의해 임의의 온도조건에서 정확한 사용수명을 예측하기 위하여 화학속도론에 의거하여 각각의 연료에 대한 사용수명식을 도출하였다. 도출된 사용수명식으로부터 바이오디젤이 가장 빠르게 산화가 진행되었고 바이오디젤 혼합량이 증가할수록 사용수명이 단축되는 것을 확인할 수 있었다.

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Molecular Characterization of Burkholderia Strains Isolated from Rice Cultivars (Oryza sativa L.) for Species Identification and Phylogenetic Grouping

  • Madhaiyan, Munusamy;Poonguzhali, Selvaraj;Kwon, Soon-Wo;Song, Myung-Hee;Sa, Tong-Min
    • Journal of Microbiology and Biotechnology
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    • v.18 no.6
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    • pp.1005-1010
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    • 2008
  • The genus Burkholderia consists of extremely versatile bacteria that occupy diverse niches and are commonly encountered in the rhizosphere of crop plants. In this study, we characterized three plant growth promoting strains assigned as Burkholderia sp. using biochemical and molecular characterization. The Burkholderia spp. strains CBMB40, CBPB-HIM, and CBPB-HOD were characterized using biochemical tests, BIOLOG carbon substrate utilization, fatty acid methyl ester analysis, analysis of recA gene sequences, and DNA-DNA hybridization. The results from these studies indicated that the strains CBMB40, CBPB-HIM, and CBPB-HOD can be assigned under Burkholderia vietnamiensis, Burkholderia ubonensis, and Burkholderia pyrrocinia, respectively.

Oxidations product of ${\alpha}-,\;{\gamma}-tocopherol$ and ${\gamma}-tocotrienol$ (${\alpha}-,\;{\gamma}-Tocopherol$${\gamma}-tocotrienol$의 산화 생성물)

  • Lee, Hyung-Ok
    • Applied Biological Chemistry
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    • v.36 no.1
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    • pp.33-37
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    • 1993
  • Oxidations products of ${\alpha}-tocopherol$, ${\gamma}-tocopherol$ and ${\gamma}-tocotrienol$ in lipophilic reaction media were studied. ${\alpha}-Tocopherylquinone$, ${\gamma}-tocopherylquinone$ and ${\gamma}-tocotrienylquinone$ were fractionated using micro column, isolated and identified by HPLC and MS.

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Functional Characterization of Antagonistic Fluorescent Pseudomonads Associated with Rhizospheric Soil of Rice (Oryza sativa L.)

  • Ayyadurai, N.;Naik, P. Ravindra;Sakthivel, N.
    • Journal of Microbiology and Biotechnology
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    • v.17 no.6
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    • pp.919-927
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    • 2007
  • Antagonistic fluorescent pseudomonads isolated from rhizospheric soil of rice were characterized by 16S rRNA amplicon and fatty acid methyl ester (FAME) analyses. Antagonistic isolates were grown in the fermentation media, and production of antibiotics was confirmed by thin-layer chromatography (TLC) and high-performance liquid chromatography (HPLC). Production of fungal cell-wall-degrading enzymes such as protease, cellulase, pectinase, and chitinase was determined. Dendrogram based on the major and differentiating fatty acids resulted into 5 clusters, viz., cluster I (P. pseudoalcaligenes group), cluster II (P. plecoglossicida group), cluster III (P. fluorescens group), cluster IV (P. aeruginosa group), and cluster V (P. putida group). Characteristic presence of high relative proportions of cyclopropane (17:0 CYCLO w7c) was observed in antagonistic bacteria. Data revealed biodiversity among antagonistic fluorescent pseudomonads associated with the rice rhizosphere. Results presented in this study will help to identify the antagonistic isolates and to determine their mechanisms that mediate antagonism against fungal pathogens of rice.

Influence of Physical Load on the Stability of Organic Solar Cells with Polymer : Fullerene Bulk Heterojunction Nanolayers

  • Lee, Sooyong;Kim, Hwajeong;Kim, Youngkyoo
    • Current Photovoltaic Research
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    • v.4 no.2
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    • pp.48-53
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    • 2016
  • We report the effect of physical load on the stability of organic solar cells under physical loads. The active layers in organic solar cells were fabricated with bulk heterojunction films (BHJ) films of poly (3-hexylthiophene) and phenyl-$C_{61}$-butyric methyl ester. The loading time was varied up to 60 s by keeping the physical load constant. Results showed that the open circuit voltage was not influenced by the physical load but other solar cell parameters were sensitive to the loading time. The fill factor was very slightly increased at 15 s, while short circuit current density was well kept for 30 s. The power conversion efficiency was reasonably maintained for 45 s but became significantly decreased by the continuous loading for 60 s.

Conversion of Vegetable Oil into Biodiesel Fuel by Continuous Process (연속공정에 의한 식물유의 바이오디젤유 전환)

  • Hyun, Young-Jin;Kim, Hae-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.19 no.4
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    • pp.327-334
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    • 2002
  • Transesterfication of vegetable oils and methanol with alkaline catalyst was carried out to produce biodiesel fuel by continuous process. The process consists of two static mixers, one tubular reactor and two coolers and gave $96{\sim}99$% of methyl ester yield from soybean oil and rapeseed oil. Experimental variables were the molar ratios of methanol to vegetable oil, alkaline catalyst contents, flow rates, mixer element number. The optimum ranges of operating variables were as follows; reaction temperature of $70^{\circ}C$, l:6 of molar ratio of methanol to oil, O.4%(w/w) sodium hydroxide based on oil, static mixer elements number of 24 and 4 min. residence time.

Antinocicepetive effects of 3,4-Dicaffeoyl Quinic Acid of Ligularia fischerivar. spiciformis, caffeic acid and its methyl ester

  • Choi, Jong-Won;Lee, Kyung-Tae;Kim, Won-Bae;Jung, Hyun-Ju;Park, Hee-Juhn
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.387.3-388
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    • 2002
  • The plant Ligularia fischerivar. spiciformis(Compositae) is a candidate for available functional foods. It has been used to treat diabetes mellitus and rheumatoid arthritis. We have reported the isolation of a new eremophilanolide named 6-oxoeremophilenolide and cytotoxic intermedeol together with the isolation of hydrophilic constituents. chlorgenic acid. 3.4-di-O-caffeoylquinic acid(1). and 5-O-[1-butyl]-3.4-di-O-caffeoylquinic acid. (omitted)

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Nanoscale Charge Transport in P3HT:PCBM:Gold Nanoparticle Composite Materials for Polymer Solar Cell Application

  • Nguyen, Thuc-Quyen;Dante, Mark;Peet, Jeffrey;Bazan, Guillermo
    • Proceedings of the Polymer Society of Korea Conference
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    • 2006.10a
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    • pp.274-274
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    • 2006
  • Recently, conjugated polymer solar cells have attracted a great deal of attention. In this work, we applied the various scanning probe techniques to characterize composite materials typically used to fabricate polymer solar cells: poly-3(hexylthiophene) (P3HT) and [6,6]-phenyl-C61-butyric acid methyl ester (PCBM) and P3HT/PCBM/Au nanoparticle (NP) samples. The latter is studied due to the idea of using the gold NP surface plasmon to enhance the optical absorption of the composite films. AFM is used to characterize the film morphology whereas conducting AFM is used to study the charge transport properties at the nanoscale. We found that there is a direct correlation between the nanoscale charge transport measurements and the device efficiencies.

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Study on Lubrication Characteristics of Lubrication for Lubricity Improver in Dimethyl Ether (디메틸에테르에 첨가된 윤활성향상제의 윤활특성에 관한 연구)

  • Park, Cheonkyu;Jang, Eunjung;Jung, Choongsub;Lee, Bonghee;Na, Byungki
    • Tribology and Lubricants
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    • v.29 no.2
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    • pp.117-123
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    • 2013
  • Dimethyl ether (DME) has a high cetane number that is suitable for diesel fuel. DME does not contain sulfur or nitrogen, and is an oxygenated fuel so it produces no particulate matter when combusted and is environmentally friendly. DME fuel for diesel engines show excellent material properties such as a lower volumetric heating value, lower boiling point, lower lubricity, and stronger solvent effect than light oil. This study experimentally examined a lubricity improver (LI) for dimethyl ether. A diesel LI based on biodiesel and fatty acid methyl ester was tested among DME LI candidates. The long-term storage stability and physical properties of the optimum LI for DME were determined.

Two New Caffeoyl Threonate Esters from the Leaves of Toxicodendron vernicifluum

  • Jang, Jae Young;Ahn, Jong Hoon;Jo, Yang Hee;Turk, Ayman;Kang, So Young;Hwang, Bang Yeon;Lee, Mi Kyeong
    • Natural Product Sciences
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    • v.25 no.4
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    • pp.354-357
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    • 2019
  • Toxicodendron vernicifluum, also called as Rhus verniciflua is a deciduous tree belonging to Anacardiaceae family. Two new caffeoyl threonate esters, rhuseols A (1) and B (2), together with 5-O-(E)-caffeoylquinic acid methyl ester (3) were isolated from the leaves of T. vernicifluum. The structures of isolated compounds were established by using 1D and 2D NMR in combination with HR-ESI-MS. Compounds 1 - 3 showed DPPH radical scavenging effects with IC50 values of 47.9, 107.8 and 15.4 μM, respectively. Taken together, these compounds might contribute to the antioxidant properties of the leaves of T. vernicifluum, which will be useful for various oxidative stress mediated diseases.