• 제목/요약/키워드: metastable

검색결과 271건 처리시간 0.023초

Study of the Structure Change on Ion-Beam-Mixed CoPt Alloys.

  • Son, J.H.;Lee, Y.S.;Lim, K.Y.;Kim, T.G.;Chang, G.S.;Woo, J.J.;Whang, C.N.
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 1998년도 제14회 학술발표회 논문개요집
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    • pp.135-136
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    • 1998
  • By the ion bombardment the original discrete layered structure is damaged and a uniformly mixed layer is formed by the intermixing of the films. Immediately after this dynamic cascade mixing a structure of this mixed layer is likely to be a mixture of randomly distributed atoms. Subsequently the mixed layered structure becomes a non-equilibrium structure such as the metastable pphase because the kinetic energies of the incident ions rappidly dissippate and host atoms within the collision cascade region are quenched from a highly energetic state. The formation of the metastable transition metal alloys using ion-beam-mixing has been extensively studied for many years because of their sppecific ppropperties that differ from those of bulk materials. in ion-beam-mixing the alloy or comppound is formed due to the atomic interaction between different sppecies during ion bombardment. in this study the metastable pphase formed by ion-beam-mixing pprocess is comppared with equilibrium one by arc-melting method by GXRD and XAS. Therfore we studied the fundamental characteristics of charge redistribution uppon alloying and formation of intermetallic comppounds. The multi-layer films were depposited on a wet-oxidized Si(100) substrate by sequential electron beam evapporation at a ppressure of less than 5$\times$10-7 Torr during depposition. These compprise 4 ppairs of Co and ppt layers where thicknesses of each layer were varied in order to change the alloy compposition.

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$Al_2O_3-ZrO_2$계에서 기계적 성질에 미치는 준안정 저앙 $ZrO_2$상의 효과 (Effect of Metastable Tetragonal $ZrO_2$ Phase on the Mechanicmal Properties in $Al_2O_3-ZrO_2$ System)

  • 김진영;황규홍;김환
    • 한국세라믹학회지
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    • 제21권2호
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    • pp.149-155
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    • 1984
  • The effect of $ZrO_2$ dispersed phase on the mechanical properties in $Al_2O_3$-$ZrO_2$system has been studied. There are both metastable tetragonal phase and stable monoclinic phase of $ZrO_2$particles diespersed in Al2O3 matrix at room temperature. Metastable tetragonal $ZrO_2$ changes to the stable monoclinic structure within the stress field of the crack. And microcracks are formed by the expansion of $ZrO_2$during the tetragonal-monoclinic transformation on cooling. Therefore stress-induced phase transformation and inclusion-induced microcracking contribute to the mec-hanical properties of $Al_2O_3$-$ZrO_2$system. Sintered composites containing 10m/o $ZrO_2$ yield KiC values of 6.5MN/$m^{3/2}$ much greater than that of pure $Al_2O_3$ This increase results from microcrack extension and stress-induced phase transformation absor-bing energy by crack propagation. Flexural strength of composites is decreased considerably in comparison with pure $Al_2O_3$ This decrease results from microcrack as a crack former and higher porosity than pure $Al_2O_3$.

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LIF를 이용한 Hg-Ar의 플라즈마 밀도 측정 (Plasma Density Measurement of Hg-Ar by LIF Method)

  • 최용성;황종선;박계춘;송민종;김형곤;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 광주전남지부
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    • pp.27-32
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    • 2006
  • In this paper, we introduced a LIF measurement method and summarized the theoretical side. When an altered wavelength of laser and electric power, lamp applied electric power, we measured the relative density of the metastable state in mercury after observing a laser induced fluorescence signal of 404.8nm and 546.2nm, and confirmed the horizontal distribution of plasma density in the discharge lamp. Due to this generation, the extinction of atoms in a metastable state occurred through collision, ionization, and excitation between plasma particles. The density and distribution of the metastable state depended on the energy and density of plasma particles, intensely. This highlights the importance of measuring density distribution in plasma electric discharge mechanism study. The results confirmed the resonance phenomenon regarding the energy level of atoms along a wavelength change, and also confirmed that the largest fluorcscent signal in 436nm, and that the density of atoms in 546.2nm ($6^3S_1{\rightarrow}6^3P_2$) were larger than 404.8nm ($6^3S_1{\rightarrow}6^3P_2$). According to the increase of lamp applied electric power, plasma density increased, too. When increased with laser electric power, the LIF signal reached a saturation state in more than 2.6mJ. When partial plasma density distribution along a horizontal axis was measured using the laser induced fluorescence method, the density decreased by recombination away from the center.

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레이저 흡수 분광법을 이용한 He-Ne-Xe 상종가스의 외부전곡 램프의 $1s_4$ 공명준위와 $1s_5$ 준안정준위의 제논 원자 밀도에 대한 연구 (Laser absorption spectroscopy of ternary gas mixture of He-Ne-Xe in External Electrode Fluorescent Lamp (EEFL))

  • 정세훈;오필용;이준호;조광섭;최은하
    • 한국진공학회지
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    • 제15권6호
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    • pp.576-580
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    • 2006
  • 본 논문에서는 수은 램프를 대체하기 위하여 제논 기체를 사용한 무수은 램프를 제작하여 제논 여기종 밀도에 대한 연구를 진행하였다. 진공자외선을 방사할 수 있는 $1s_4$ 공명준위의 제논 원자 밀도와 $1s_5$ 준안정준위의 제논 원자 밀도를 레이저 흡수 분광법을 사용하여 다양한 기체조건 및 방전전류에 따라서 측정하였다. 우리는 주어진 압력에서 방전전류에 따른 $1s_4$ 공명준위의 제논 원자 밀도와 $1s_5$ 준안정준위의 제논 원자 밀도를 측정하였으며 이러한 기본적인 방전 특성의 이해는 EEFL뿐만 아니라 플라스마 디스플레이에서도 발광 효율을 높이는데 매우 큰 기여를 할 것이다.

Midinfrared Pulse Compression in a Dispersion-decreasing and Nonlinearity-increasing Tapered As2S3 Photonic Crystal Fiber

  • Shen, Jianping;Zhang, Siwei;Wang, Wei;Li, Shuguang;Zhang, Song;Wang, Yujun
    • Current Optics and Photonics
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    • 제5권3호
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    • pp.250-260
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    • 2021
  • A tapered As2S3 photonic crystal fiber (PCF) with four layers of air holes in a hexagonal array around the core is designed in this paper. Numerical simulation shows that the dispersion D decreases and the nonlinearity coefficient γ increases from the thick to the thin end along the tapered PCF. We simulate the midinfrared pulse compression in the tapered As2S3 PCF using the adaptive split-step Fourier method. Initial Gaussian pulses of 4.4 ps and a central wavelength of 2.5 ㎛ propagating in the tapered PCF are located in the anomalous dispersion region. With an average power of assumed input pulses at 3 mW and a repetition frequency of 81.0 MHz, we theoretically obtain a pulse duration of 56 fs and a compression factor of 78 when the pulse propagates from the thick end to the thin end of the tapered PCF. When confinement loss in the tapered PCF is included in the simulation, the minimum pulse duration reaches 72 fs; correspondingly, the maximum compression factor reaches 61. The results show that in the anomalous-dispersion region, midinfrared pulses can be efficiently compressed in a dispersion-decreasing and nonlinearity-increasing tapered As2S3 PCF. Due to confinement loss in the tapered fiber, the efficiency of pulse compression is suppressed.

Fe 함량에 따른 Ti-5Mo-xFe 준안정 베타 합금의 압축 변형거동 변화 (Change of Compressive Deformation Behaviors of Ti-5Mo-xFe Metastable Beta Alloy According to Fe Contents)

  • 이용재;이재관;이동근
    • 열처리공학회지
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    • 제36권5호
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    • pp.303-310
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    • 2023
  • β titanium alloys are widely used in aerospace industry due to their excellent specific strength and corrosion resistance. In particular, mechanical properties of metastable β titanium can efficiently be controlled by various deformation mechanisms such as slip, twinning, and SIM (Stress-Induced Martensite Transformation), making it an ideal material for many industrial applications. In this study, Ti-5Mo-xFe (x=1, 2, 4 wt%) alloy was designed by adding a relatively inexpensive β element to ensure price competitiveness. Additionally, microstructural analysis was conducted using OM, SEM, and XRD, while mechanical properties were evaluated through hardness and compression tests to consider the deformation mechanisms based on the Fe content. SIMT occurred in all three alloys and was influenced by the presence of βm (metastable beta) and beta stability. As the Fe content decreased, the α'' phase increased due to SIMT occurring within the βm phase, resulting in softening. Conversely, as the Fe content increased, the strength of the alloy increased due to a reduction in α'' formation and the contributions of solid solution strengthening and grain strengthening. Moreover, unlike the other alloys, shear bands were observed only in the fracture of the Ti-5Mo-4Fe alloy, which was attributed to differences in texture and microstructure.

Effects of Magnesium Catalyst on the Nitridation of Aluminum Melt in the Synthesis of Aluminum Nitride Powder

  • Kim, Hyo-Jin;Kim, Sung-Hun;Lim, Sung-Min;Seo, Jong-Hyun;Lee, Kon-Bae;Lee, Jae-Chul;Ahn, Jae-Pyoung
    • Applied Microscopy
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    • 제44권2호
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    • pp.79-82
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    • 2014
  • Aluminum nitride (AlN) powder was easily synthesized by the direct nitridation of Al melt containing ~20 wt.% Mg catalyst and the nitriding behavior was investigated by thermodynamic calculation and through observations of electron microscopy and X-ray diffraction. The addition of Mg catalyst decreased the nitriding temperature below $1,000^{\circ}C$, which is comparable to the high nitriding temperature of $1,400^{\circ}C$ required in carbothermal method. It was caused by a significant increase of the solubility of nitrogen gas due to the increase of Mg catalyst in Al melt. The dissolved nitrogen gas met Mg catalyst and was transformed into metastable $Mg_3N_2$. Finally the metastable phase reacted with Al to AlN.

프로젝션 용접 전극을 위한 시효경화성 Cu-2.0wt%Be 합금의 미세조직과 기계적성질 (Microstructures and Mechanical Properties of Age Hardenable Cu-2.0wt%Be Alloy for Projection Welding Electrode)

  • 김광수;김진용
    • 한국재료학회지
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    • 제25권9호
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    • pp.468-474
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    • 2015
  • Evaluations of the microstructure and mechanical properties of age hardenable Cu-2.0wt%Be alloy are performed in order to determine whether it can be used as a welding electrode for projection welding. The microstructure examinations, hardness measurements, and tensile tests of selective aging conditions are conducted. The results indicate that the aging treatment with the fine-grained microstructure exhibits better hardness and high tensile properties than those of the coarse-grained microstructure. The highest hardness value and high tensile strength are obtained from the aged condition of $300^{\circ}C$ for 360 min due to the presence of the metastable ${\dot{\gamma}}$ precipitates on the grain boundaries. The values of the highest hardness and tensile strength are measured as 374 Hv and 1236.2 MPa, respectively. The metastable ${\dot{\gamma}}$ precipitates are transferred to the equilibrium ${\gamma}$ precipitates due to the over-aged treatment. The presence of the ${\gamma}$ precipitates appears as nodule-like precipitates decorated around the grain boundaries. The welding electrode with the best aging treated condition exhibits better welding performance for electrodes than those of electrodes used previously.