• 제목/요약/키워드: metallic minerals

검색결과 63건 처리시간 0.02초

한국공업화과정(韓國工業化過程)에서의 광물자원(鑛物資源)의 수급구조변화(需給構造變化)와 경제성장(經濟成長)에 있어서의 역할(役割) (The Changing Patterns of Demand-Supply and Role of Mineral Resources in Economic Growth during Industrialization of the Republic of Korea)

  • 윤석규
    • 자원환경지질
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    • 제18권1호
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    • pp.65-92
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    • 1985
  • A total of 12 mineral commodities significant in domestic output, economy and/or strategy of the Republic of Korea are chosen to examine the structural changes in production and demand-supply of these minerals during the last two decades of her industrialization. These include iron and manganese ores as the raw materials for iron and steel making, copper, zinc and tungsten ores among other non-ferrous metallic minerals, limestone (cement), kaolin, talc, pyrophyllite and graphite among other non-metallic minerals, and anthracite coal as the only domestic source of fossil energy. These are reviewed historically in time-series based on the statistical data which are tabulated and graphed in terms of domestic output, export, import, apparent demand-supply, its increasing rate, and self-sufficiency rate of each commodity. The increasing rates of demand-supply (IRDS) of some more important commodities are compared with those of Gross Domestic Production (GDP) and Economic Growth Rate (EGR) to evaluate how the IRDS contributed to the GDP and EGR. The major results revealed are as follows: Among the 12 commodities, the domestic output of 8 commodities appeared to have grown with steady upward trends: they are ores of lead, zinc and tungsten, limestone (cement), kaolin, talc, pyrophyllite and anthracite coal. Two commodities, ores of iron and copper, continued with unchanging or slightly declining trends and varied fluctuations, in spite of their cardinal importance to the heavy industry and strategy of Korea. The remaining two, graphite and manganese ore, have gradualy declined in domestic output in which the former has still enough resource potential but the latter has not and virtually ceased its domestic output. Trade patterns for mineral commodities in the Republic of Korea during the last two decades have changed greatly, being marked by a shift from mineral-exporting to mineral importing, mainly because of increasing consumption of mineral raw materials for industrialization rather than beceuse of decreasing output of domestic mineral commodities in quantity. In terms of trade patterns, the 12 commodities concerned in this study can be classified into the following four groups. The 1st group - ores of lead and tungsten have only been exported without imports. The 2nd group - amorphous graphite, and pyrophyllite have mainly been exported but partly been imported. The 3rd group - kaolin, talc and crystalline graphite have equally been exported and imported, but quantity of imports have rapidly been increased with time. The 4th group - ores of iron, manganese and zinc have shifted from exports to imports during the industrialization, particularly owing to the initiation of iron and steel making by the Pohang Iron and Steel Company in the middle 1970' s and the new establishment of the Onsan Zinc Refinery in the late 1970' s. All of the 12 commodities under considerations were far above 100% in self-sufficiency rate before or in the early 1960' s. Recently, however, most of them have been declined to below 100% except for those of limestone (cement) and pyrophyllite. It is particularly serious to identify that the self-sufficiency rates of the three important metallic minerals, iron, copper and manganese ores in 1982 appeared to be 5.1%, 0.5%, and 0.01%, respectively. The average self-sufficiency rate of the total domestic minerals produced in 1982 was 14.4% (in value) for that year. Mining industry appeared to be extremely high in its intermediate demand rate whereas its intermediate input rate to be quite low indicating that mineral raw materials have been exerted strong forward linkage effects upon the other industries rather than backward linkage effects. In comparing the curves of increasing rates of demand-supply of several major minerals - iron ore, manganese ore, copper ore, limestone (cement), kaolin, and anthracite coal - with those of Gross Domestic Production and Economic Growth Rate drawn on every graph, it is clearly shown that the curves of increasing rates of demand-supply comprise around 6 to 7 periods of cycles which roughly harmonious with those of the curves of GDP and EGR, except for the curve of anthracite coal of which the configuration seems to have resulted from the (artificial) government's mineral policy rather than from economic free market mechanism. The harmonic feature of these curves well suggests that the increasing rates of demand-supply of major minerals have been significantly contributed to the GDP and EGR. In addition, the wider amplitudes of the iron, manganese and copper curves than those of the limestone (cement) and kaolin curves indicate that the contribution of the former, metallic commodities, has been greater than that of the latter, non-metallic commodities.

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비정질 Zr-V-Ti 합금분말의 결정화에 따른 게터 특성 변화 (Changes of Getter properties by Crystallization of Amorphous Zr-V-Ti alloy Powders)

  • 박제신;김원백;백진선
    • 한국분말재료학회지
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    • 제14권1호
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    • pp.50-55
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    • 2007
  • The hydrogen sorption speeds of $Zr_{57}V_{36}Ti_7$ amorphous alloy and its crystallized alloys were evaluated at room temperature. $Zr_{57}V_{36}Ti_7$ amorphous alloy was prepared by ball milling. The hydrogen sorption rate of the partially crystallized alloy was higher than that of amorphous. The enhanced sorption rate of partially crystallized alloy was explained in terms of grain refinement that has been known to promote the diffusion into metallic bulk of the gases. The grain refinement could be obtained by crystallization of amorphous phase resulting in the observed increase in sorption property.

층상형(層狀型)의 규장암질(珪長岩質) DIATREME (A Layered Felsic Diatreme near Weolseong, Kyeongsang Nam Do, Korea)

  • 박기화;김선억
    • 자원환경지질
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    • 제18권4호
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    • pp.357-368
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    • 1985
  • 경주(慶州) 남부(南部) 2.8km 지점에는 치술령 화산암층이 분포하며, 이 화산암층 보다 후기에 분출 형성된 distreme이 있다. diatreme은 지름이 1.2km의 원형의 화구로서 화산쇄설물로 충진 되어 있다. 이 화산 쇄설물은 proximal ballistic fall deposits로서 층리를 보여주며, 각 층은 상당히 두껍고 특징적으로 많은 양의 accretionary lapilli가 함유되어 있다. 이러한 특징은 시추에 의해 지표 하부 650m가지 확인되었다. 이러한 특징으로 보아 diatreme은 규장질 magma에 많은 양의 물이 유입되는 환경에서 연속인 분출 활동을 하였음을 의미하고, 화산 활동 기간 중에 연속적으로 화산쇄설물이 퇴적 및 침강 하였음을 의미한다.

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광물 소결체를 이용한 합병정화조 개발에 관한 연구 (Development of Amalgamated Septic Tank using Mineral Sintered Body)

  • 김광수;김영훈;강헌찬
    • 자원리싸이클링
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    • 제9권4호
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    • pp.56-62
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    • 2000
  • 본 연구에서는 하.폐수 처리를 효과적으로 할 수 있도록 각종 비금속 광물들을 혼합하여 부착성 및 토양 미생물의 활동을 촉진시킬 수 있게 광물 소결체를 이용한 합병정화조를 도입하여 주택용 소규모의 생활 하수를 발생원에서 바로 처리하기 위하여 단독주택 2가구를 대상으로 소규모형 무산소-호기 공정 합병정화조 실험 장치를 설치하여 실험하였다. 그 결과 COD.BOD의 방류수는 10mg/l 전후로 나타났고 총질소 (T-N)는 60~70% 정도까지 제거시킴으로 인해 외부에서 탄소원을 첨가하지 않고도 탈질을 할 수 있음을 확인 할 수 있었다. 또한 춤인(T-P)은 80%이상의 제거 효율을 나타내어 생물학적 처리 가능성을 확인할 수 있었다.

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Behaviors of Desorption Agents During Removal of Cs From Clay Minerals and Actual Soil

  • Park, Chan Woo;Kim, Ilgook;Yoon, In-Ho;Yang, Hee-Man;Seo, Bum-Kyung
    • 방사성폐기물학회지
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    • 제19권1호
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    • pp.39-49
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    • 2021
  • The behaviors of various desorption agents were investigated during the desorption of cesium (Cs) from samples of clay minerals and actual soil. Results showed that polymeric cation exchange agents (polyethyleneimine (PEI)) efficiently desorbed Cs from expandable montmorillonite, whereas acidic desorption solutions containing HCl or PEI removed considerable Cs from hydrobiotite. However, most desorption agents could desorb only 54% of Cs from illite because of Cs's specific adsorption to selective adsorption sites. Cs desorption from an actual soil sample containing Cs-selective clay mineral illite (< 200 ㎛) and extracted from near South Korea's Kori Nuclear Power Plant was also investigated. Considerable adsorbed 137Cs was expected to be located at Cs-selective sites when the 137Cs loading was much lower than the sample's cation exchange capacity. At this low 137Cs loading, the total Cs amount desorbed by repeated washing varied by desorption agent in the order HCl > PEI > NH4+, and the highest Cs desorption amount achieved using HCl was 83%. Unlike other desorption agents with only cation exchange capabilities, HCl can attack minerals and induce dissolution of metallic elements. HCl's ability to both alter minerals and induce H+/Cs+ ion exchange is expected to promote Cs desorption from actual soil samples.

비금속광물 분체의 기능성 건축소재화 특성 (A Preparation and Characteristics of Functional rchitecture Materials Made frm Non-metallic Minerals)

  • 김병곤;최상근;박종력;전호석
    • 한국세라믹학회지
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    • 제40권8호
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    • pp.811-817
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    • 2003
  • 최근 들어 비금속광물의 구조적 특성을 이용한 활용분야가 매우 다양해지고 있다. 특히 판상광물은 차폐(은폐)력이 매우 우수하고, 층간특성을 이용한 흡착 및 저장특성이 매우 우수하다. 본 연구에서는 이와 같은 판상광물의 기본의 특성에 또 다른 기능성 물질을 흡착시킴으로써 부가적인 새로운 기능성을 갖는 친환경성 건축소재를 개발하고자 천연산 인상흑연 및 견운모를 기능성 모소재로 사용하고 미립화 및 ABDM(Alkyl Benzyle Demethyle Ammonium Chloride)으로 흑연입자 표면을 항균처리를 하였다. 항균처리를 위한 흡착은 전위차를 이용한 1차 흡착과 ABDM 상호간의 steric 작용에 의한 2차 흡착으로 완전 이중층이 형성되어 충분한 항균효과를 나타낼 수 있었다. 제조된 기능성 재료를 모르타르로 제조하여 다양한 기능성을 측정한 결과 세균감소율 99.7% 이상과 80% 이상의 암모니아 가스 흡착(탈취) 효과 및 95% 이상의 전자파 차폐율과 5% 정도의 열저장(축열, 잠열) 효과를 갖는 것으로 나타났다.

발전소용 이중보온용 강관의 홈부식(Grooving Corrosion)에 의한 파손 분석 (The Failure Analysis of Double Pipe for Insulation Used Power Plant by Grooving Corrosion)

  • 함종오;박기덕;박성진;선일식
    • 한국신뢰성학회지:신뢰성응용연구
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    • 제15권3호
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    • pp.197-206
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    • 2015
  • Failure analysis of pre-insulated pipe (SPPS 380, 400A) transporting high temperature water ($95{\sim}110^{\circ}C$) for a plant was carried out. The damaged area (${\Phi}5mm$) of pre-insulated pipe was found only on welds. The chemical composition of damaged pipe meets specification of carbon steel pipes for pressure service (KS D 3562). As results of microstructure analysis, crack propagated from outer to inside after pitting corrosion occurred on the outside surface. The non-metallic inclusion existed on the end of crack. And the non-metallic inclusion continuously and linearly formed along with the bond line of welds. Based on SEM-EDS analysis, the nonmetallic inclusions have higher Manganese (Mn) and Oxygen (O) content but sulfur (S) was not detected. As results of water quality analysis, hydrogen ion concentration and minerals like Fe, Mg, Si were in low level. But the content of dissolved oxygen (11.2 ppm) was slightly higher than that of standard. It seems that the cause of damaged pipe is grooving corrosion due to MnO inclusion formed on bond line and corrosion took place nearby welds.

월성(月城) 다이아튜림의 층준(層準)에 따른 광화(鑛化) 현상(現狀) (The Primary Structure Controlled Mineralization in Weolseong Diatreme, Southern Korea)

  • 박기화;오민수
    • 자원환경지질
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    • 제20권1호
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    • pp.19-34
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    • 1987
  • 경주시(慶州市) 남부(南部) 28km 지점(地占)인 월성군(月城郡) 외동읍(外東邑) 녹동리(鹿洞里) 지역에 1.2km의 지름을 갖는 다이아튜림이 분포(分布)하고, 이 다이아튜림의 화구(火口) 부위(部位)로 추정(推定)되는 중앙부(中央部)에 비소-아연을 주로 하는 광상(鑛床)(녹동광산(鹿洞鑛山))이 배태되어 있다. 지표(地表)에서 광상(鑛床)의 규모(規模)는 장경(長經)이 290m이고 단경(短涇)이 180m인 타원형이다. 한국(韓國) 동력자원연구소(動力資源硏究所)에서 1982년(年)부터 1984년(年)까지 실시(實試)한 16개공(個孔) 5,551m 시추(試錐) 결과(結果) 원통형의 광체(鑛體)가 지표(地表)에서 650m 하부(下部)까지 계속(繼續)됨이 확인(確認) 되었다. 황철우(黃鐵右), 섬아연석(閃亞鉛石), 유비철석(硫砒鐵石)을 주로한 광석(鑛石) 광물(鑛物)은 배태된 양상(樣狀)에 따라 (l) 광염상(鑛染狀), (2) 화산(火山) 각력(角礫) 충진상(充鎭狀), (3) 세맥상(細脈狀)으로 분류(分類)되며, 이들 유형(類形) 간(間)에는 점이적(漸移的)인 양상(樣狀)을 보인다. 광화(鑛化)된 부분(部分)에서의 암편들은 성분(性分), 크기, 모양(模樣), 분포양상(分布樣狀) 등(等)이 광화(鑛化)되지 않은 부분(部分)의 암체에서의 양상(樣狀)과 동일(同一)하다. 광화(鑛化)된 한 층준(層準)에서 보면, 크기가 작은 암편으로 구성(構成)된 상위(上位)는 광염상(鑛染狀)의 광화현상(鑛化現狀)이 우세(優勢)하고, 하부(下部)로 가면서 암편의 크기가 커지고 광화(鑛化) 현상(現狀)은 화산(火山) 각력(角礫) 충진형(充鎭型)으로 점이적(漸移的)으로 변(變)한다. 이런 점으로 보아, 광화(鑛化) 용액(溶液)이 화구부분(火口部分)에 형성(形成)된 균열을 따라 이동(移動)하다가 높은 투수성(透水性)과 다공질(多孔質)를 갖는 다이아튜림의 특정(特定) 층준(層準)에 광석(鑛石) 광물(鑛物)을 우세(優勢)하게 배태시킨 것으로 해석(解析)된다.

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시흥군(始興郡) 서면일대(西面一帶)의 광화구제구조(鑛化規制構造)와 항공사진해석결과(航空寫眞解析結果)와의 비교연구(比較硏究) (The Study of Structural Control and Relative Photogeological Interpretation on Shiheung Mine Region)

  • 지정만;류병화
    • 자원환경지질
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    • 제3권4호
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    • pp.199-222
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    • 1970
  • One of the biggest sulfide metallic (Cu, Pb, Zn) ore deposits of South Korea is located in the area of Seo-myeon, Shiheung-gun, Gyeonggi-do. Geology of the region is mostly composed of metasediments of biotite schist, graphite schist, injection gneiss, sericite schist, limesilicate and quartzite from bottom, those are applicable to so-called Yeoncheon System of Pre-Cambrian, and granodiorite, quartz porphyry, basic dykes are outcroped in a small scope as intrusives. The origin of the ore deposit is pyrometasomatic contact deposits due to hydrothermal replacement and the ore bodies are imbedded in lower bed of limesilicate formation as impregnation and ore minerals are galena, sphalerite, marmatite, chalcopyrite, bornite, chalcocite, covellite, and the later two minerals are both hypogene and supergene. Gangue minerals are mostly skarn minerals those hornblende, diopside, epidote, hedenbergite, chlorite, garnet and quartz except primary calcite and quartz. Boundary plane (NS strike) between schists and limesilicate seemed to be primary opening of ore solution and fractures bearing $N50^{\circ}{\sim}80^{\circ}W$ are secondary structural control for localization of ore minerals and the third structural controls are both irregular gashes and schistosity in small scale. Photogeological study was carried with vertical aerial photo scaled 1: 38,000 and enlarged 1 : 10,000 under stereoscope. The study on the area convinced the fact that the geologic boundaries between rocks, limesilicates and quartzites, are traced easily by their typical topographic feature and drainage, and the main fracture patterns which derived from the result of fracture traces, that photogeologic lineament observed under stereoscope, are those bearing (1) $N20^{\circ}W$, (2) $N58^{\circ}W$, (3) $N76^{\circ}W$, (4) EW, (5) $N20^{\circ}W$, (6) $N62^{\circ}W$, (7) $N77^{\circ}W$. Among the written fractures, (5) (not schistosity, in case of fault) (6) (7) are post-mineral faults and others are pre-mineral faults and others are pre-mineral structures, and (2) (3) (6) (7) are coincided with statistical figure of 208 fractures surveyed in underground. By the result of the study, mineralized zone, are presumed to extend north and southward, total length about 4km.

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전자(電子)스크랩의 미생물(微生物) 침출액(浸出液)으로부터 구리 및 주석의 회수(回收)에 관한 연구(硏究) (Recovery of Cu and Sn from the Bioleaching Solution of Electronic Scrap)

  • 안재우
    • 자원리싸이클링
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    • 제15권6호
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    • pp.41-47
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    • 2006
  • 미생물 침출과 용매추출 기술을 이용하여 전자스크랩중의 구리 및 주석의 회수에 관한 연구를 실시하였다. Asperigillus niger를 이용한 미생물 침출시 신진대사 작용에 의해 구연산(citric acid)이 생성되며 이러한 구연산에 의해 전자스크랩중의 구리, 철, 주석, 납 등의 성분이 침출된다. 이러한 침출용액으로부터 먼저 10vo1.% LIX84를 이용하여 선택적으로 구리를 추출할 수 있었고, LIX84에 의해 추출 분리된 구리는 전해채취공정을 거쳐 99.9%의 금속 구리로 회수가 가능하였다. 한편, 구리가 추출 분리된 침출여액에서 주석을 회수하기 위해서 10% Alamine336을 이용하여 철 및 주석을 추출하고, 철 및 주석이 추출된 유기상을 NaCl용액을 탈거제로 사용함으로써 순수한 철 및 주석의 혼합용액을 얻었다. 이러한 혼합용액에서 철분말을 이용한 치환법으로 주석을 금속상태의 침전물로 회수가 가능하였다.