• Title/Summary/Keyword: membrane processes

Search Result 775, Processing Time 0.025 seconds

Hydrogen Permeation Properties of $(Ni_{60}-Nb_{40})_{95}-Pd_5$ Amorphous Metallic Membrane ($(Ni_{60}-Nb_{40})_{95}-Pd_5$ 비정질 금속막의 수소투과 특성)

  • Lee, Dock-Young;Kim, Yoon-Bae
    • Journal of Hydrogen and New Energy
    • /
    • v.19 no.4
    • /
    • pp.359-366
    • /
    • 2008
  • Hydrogen as a high-quality and clean energy carrier has attracted renewed and ever-increasing attention around the world in recent years, mainly due to developments in fuel cells and environmental pressures including climate change issues. In this processes for hydrogen production from fossil fuels, separation and purification is a critical technology. $(Ni_{60}-Nb_{40})_{95}-Pd_5$ alloy ingots were prepared by arc-melting the mixture of pure metals in an Ar atmosphere. Melt-spun ribbons were produced by the single-roller melt-spinning technique in an Ar atmosphere. Amorphous structure and thermal behavior were characterized by XRD and DSC. The permeability of the $(Ni_{60}-Nb_{40})_{95}-Pd_5$ amorphous alloy membrane was characterized by hydrogen permeation experiments in the temperature range 623 to 773 K and pressure of 2 bars. The maximum hydrogen permeability was $3.54{\times}10^{-9}[mol{\cdot}m^{-1}s^{-1}{\cdot}pa^{-1/2}]$ at 773 K for the $(Ni_{60}-Nb_{40})_{95}-Pd_5$ amorphous alloy.

The Comparative Study of Different Membranes for Electrolytic Cell for the Hydrogen Peroxide Generation (과산화수소 발생을 위한 전해셀용 양성자 교환 막의 비교)

  • You, Sun-Kyung;Kim, Han-Joo;Kim, Tae-Il;Tsurtsumia, Gigla;Park, Soo-Gil
    • Journal of the Korean Electrochemical Society
    • /
    • v.10 no.4
    • /
    • pp.235-238
    • /
    • 2007
  • There is great interest in the applicability of generated hydrogen peroxide to a variety of industrial processes, usually involving oxidation of organics. Hydrogen peroxide is now employed for the bleaching as well as mechanical and chemical treatment in the pulp and paper industries. It addition, it is considered as an agent to displace the traditional alkaline treatments with chlorine-based chemicals. This paper reports a comparative study of $H_2O_2$ electogeneration on gas-diffusion electrode in divided cell with several $Nafion^{(R)}$ proton-exchange membranes, Russian cation-exchange membrane MK-40 and SPEEK membrane. The influence of different PEMs on electro-chemical cell voltage, current efficiency and energy consumption of hydrogen peroxide generation has been studied.

Comparison of CDI and MCDI applied with sulfonated and aminated polysulfone polymers

  • Kim, Ji Sun;Rhim, Ji Won
    • Membrane and Water Treatment
    • /
    • v.7 no.1
    • /
    • pp.39-53
    • /
    • 2016
  • In this study, polysufone (PSf) was used as a base polymer to synthesize sulfonated polysulfone (SPSf) and aminated polysulfone (APSf) as cation and anion exchange polymers, respectively. Then the ion exchange polymers were coated onto the surface of commercial carbon electrodes. To compare the capacitive deionization (CDI) and membrane capacitive deionization (MCDI) processes, the pristine carbon electrodes and ionic polymer coated electrodes were tested under various operating conditions such as feed flow rate, adsorption time at fixed desorption time, and feed concentration, etc., in terms of effluent concentration and salt removal efficiency. The MCDI was confirmed to be superior to the CDI process. The performance of MCDI was 2-3 times higher than that of CDI. In particular, the reverse desorption potential was a lot better than zero potential. Typically, the salt removal efficiency 100% for 100 mg/L NaCl was obtained for MCDI at feed flow rate of 15 ml/min and adsorption/desorption time of 3 min/1 min and applied voltages 1.0 V for adsorption and -0.3 V for desorption process, and for 500 mg/L, the salt removal efficiency 91% was observed.

Effect of Valine on facilitated O1e1in Transport Membranes (올레핀 촉진수송 분리막의 성능향상을 위한 Valine의 효과)

  • Yong Soo Kang;Sang Wook Kang;Jong Hak Kim;Jongok Won;Kookheon Char
    • Membrane Journal
    • /
    • v.13 no.2
    • /
    • pp.125-129
    • /
    • 2003
  • A remarkable separation performance of olefin/paraffin mixtures has been observed through facilitated olefin transport membranes consisting of silver ions dissolved in polymer matrices. In this research, valine, an amino acid, was introduced in poly (2-ethyl-2-oxazoline) (POZ)/$AgBF_4$ membranes to increase the separation performance. FT-IR spectra show that the cationic sites ($-NH_3^+$) of valine interact with the counter anion of the silver salt, resulting in the enhanced activity of the silver ions and consequently improved separation perfornance. Therefore, the $POZ/AgBF_4$ membranes containing valines exhibit the higher permeance as well as the higher selectivity of propylene/propane than those without valine.

EphB/ephrinB Signaling in Cell Adhesion and Migration

  • Park, Inji;Lee, Hyun-Shik
    • Molecules and Cells
    • /
    • v.38 no.1
    • /
    • pp.14-19
    • /
    • 2015
  • Eph receptors and their ligands, ephrins, represent the largest group of the receptor tyrosine kinase (RTK) family, and they mediate numerous developmental processes in a variety of organisms. Ephrins are membrane-bound proteins that are mainly divided into two classes: A class ephrins, which are linked to the membrane by a glycosylphosphatidylinositol (GPI) linkage, and B class ephrins, which are transmembrane ligands. Based on their domain structures and affinities for ligand binding, the Eph receptors are also divided into two groups. Trans-dimerization of Eph receptors with their membrane-tethered ligands regulates cell-cell interactions and initiates bidirectional signaling pathways. These pathways are intimately involved in regulating cytoskeleton dynamics, cell migration, and alterations in cellular dynamics and shapes. The EphBs and ephrinBs are specifically localized and modified to promote higher-order clustering and initiate of bidirectional signaling. In this review, we present an in-depth overview of the structure, mechanisms, cell signaling, and functions of EphB/ephrinB in cell adhesion and migration.

Expression and phosphorylation analysis of soluble proteins and membrane-localised receptor-like kinases from Arabidopsis thaliana in Escherichia coli

  • Oh, Eun-Seok;Eva, Foyjunnaher;Kim, Sang-Yun;Oh, Man-Ho
    • Journal of Plant Biotechnology
    • /
    • v.45 no.4
    • /
    • pp.315-321
    • /
    • 2018
  • Molecular and functional characterization of proteins and their levels is of great interest in understanding the mechanism of diverse cellular processes. In this study, we report on the convenient Escherichia coli-based protein expression system that allows recombinant of soluble proteins expression and cytosolic domain of membrane-localised kinases, followed by the detection of autophosphorylation activity in protein kinases. This approach is applied to regulatory proteins of Arabidopsis thaliana, including 14-3-3, calmodulin, calcium-dependent protein kinase, TERMINAL FLOWER 1(TFL1), FLOWERING LOCUS T (FT), receptor-like cytoplasmic kinase and cytoplasmic domain of leucine-rich repeat-receptor like kinase proteins. Our Western blot analysis which uses phospho-specific antibodies showed that five putative LRR-RLKs and two putative RLCKs have autophosphorylation activity in vitro on threonine and/or tyrosine residue(s), suggesting their potential role in signal transduction pathways. Our findings were also discussed in the broader context of recombinant expression and biochemical analysis of soluble and membrane-localised receptor kinases in microbial systems.

Confirmation of The Fouling Phenomena in CDI Process and The Establishment of Its Removal Process Conditions (CDI 전극 내 파울링 현상 확인 및 제거공정 조건의 확립)

  • Kim, Tae Yeong;Rhim, Ji Won
    • Membrane Journal
    • /
    • v.29 no.5
    • /
    • pp.276-283
    • /
    • 2019
  • In this study, The experiments of the confirmation of the fouling phenomena in CDI process and the establishment of its removal process conditions were carried out. The foulant concentrations of humic acid sodium salt (HA) added to the feed solution were 5, 10, 15 mg/L, respectively. The occurrence of fouling under the certain adsorption/desorption conditions could be confirmed with an increase in adsorption and desorption concentration curve over time. Both the voltage and time in adsorption and desorption processes were changed to eliminate the fouled pollutants. Typically, the fouling removal condition was found at the adsorption condition 1.2 V/5 min and the desorption condition -3 V/2 min, respectively.

Application of the H Infinity Control Principle to the Sodium Ion Selective Gating Channel on Biological Excitable Membranes

  • Hirayama, Hirohumi
    • International Journal of Control, Automation, and Systems
    • /
    • v.2 no.1
    • /
    • pp.23-38
    • /
    • 2004
  • We proposed the infinity control principle to evaluate the Biological function. The H infinity control was applied to the Sodium (Na) ion selective gating channel on the excitable cellular membrane of the neural system. The channel opening, closing and inactivation processes were expressed by movements of three gates and one inactivation blocking particle in the channel pore. The rate constants of the channel state transition were set to be voltage dependent. The temporal changes in amounts per unit membrane area of the channel states were expressed by means of eight differential equations. The biochemical mimetic used to complete the Na ion selective channel was regarded as noise. The control inputs for ejecting the blocking particle with plugging in the channel pore were set for the active transition from inactivated states to a closed or open state. By applying the H infinity control, we computed temporal changes in the channel states, observers, control inputs and the worst case noises. The present paper will be available for evaluating the noise filtering function of the biological signal transmission system.

Computational Modelling of Droplet Dynamics Behaviour in Polymer Electrolyte Membrane Fuel Cells: A Review

  • Yong, K.W.;Ganesan, P.B.;Kazi, S.N.;Ramesh, S.;Sandaran, S.C.
    • Journal of Electrochemical Science and Technology
    • /
    • v.10 no.4
    • /
    • pp.345-360
    • /
    • 2019
  • Polymer Electrolyte Membrane Fuel Cells (PEMFC) is one of the leading advanced energy conversion technology for the use in transport. It generates water droplets through the catalytic processes and dispenses the water through the gas-flowed microchannels. The droplets in the dispensing microchannel experience g-forces from different directions during the operation in transport. Therefore, this paper reviews the computational modelling topics of droplet dynamics behaviour specifically for three categories, i.e. (i) the droplet sliding down a surface, (ii) the droplet moving in a gas-flowed microchannel, and (iii) the droplet jumping upon coalescence on superhydrophobic surface; in particular for the parameters like hydrophobicity surfaces, droplet sizes, numerical methods, channel sizes, wall conditions, popular references and boundary conditions.

The Fine Structure of Collar Cell in Tentacles of Chinese Mystery Snail, Cipangopaludina chinensis malleata Reeve (논우렁이 촉수(觸手) 칼라세포(Collar Cell)의 미세구조(微細構造)에 관한 연구(硏究))

  • Song, Yong-Jik;Kim, Woo-Kap;Kim, Chang-Whan
    • Applied Microscopy
    • /
    • v.17 no.2
    • /
    • pp.23-30
    • /
    • 1987
  • There are groups of large monopolar cells containing numerous secretory inclusions in the muscular and connective tissue. These cells contain the electron-lucent vesicles in the size of $0.5{\sim}0.9{\mu}m$, which are secreted to the exterior of the tentacle through their cytoplasmic processes projected to the epithelial layer. Secretory material can be seen accumulating in swollen portions of the granular endoplasmic reticulum. It is postulated that this material is transported to the Golgi-complex and thus the limiting membrane of the inclusions is derived from the Golgi-membrane. An electron lucent material secreted from these cells seems to be similar to fibrous electron lucent material filled in the brush border of the epidermis.

  • PDF