• Journal of the Korean Wood Science and Technology
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• v.38 no.1
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• pp.27-35
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• 2010

To evaluate the basic characteristics and adsorption properties of commercial wood charcoal, we investigated the proximate analysis, porosimetry analysis, methylene blue adsorption, removal ratios of formaldehyde, and removal ratio of ethylene gas. Fixed carbon contents of traditional black and white charcoal, and mechanical charcoal were 51.8~76.6%, 72.9~84.6%, and 48.5~80.3%, respectively. Refining degrees of the most traditional black charcoal were 9, and those of white charcoal and mechanical charcoals were zero. Specific surface area of traditional black charcoal was 0.1~13.7 $m^2/g$, which was quite lower than that of white charcoal (53.2~372.6 $m^2/g$) and mechanical charcoals (224.3~464.6 $m^2/g$). Also, amounts of methylene blue adsorption were quite lower in black charcoal (0.53~1.97 mg/g) compared with white charcoal (2.68~7.68 mg/g) and mechanical charcoal (11.63~26.10 mg/g). Removal ratios of formaldehyde of the black charcoal were 11.4~26.7%, which is quite similar to white charcoal (17.9~34.9%) and mechanical charcoal (5.5~25.8%). Removal ratios of ethylene gas for traditional black charcoal, traditional white charcoal, and mechanical charcoal were 2.2~43.5%, 21.7~39.1%, 21.7~39.1%, respectively. There was no significant difference in the removal ratios of formaldehyde and ethylene gas among traditional black charcoal, traditional white charcoal, and mechanical charcoal.

• Journal of the Korean Wood Science and Technology
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• v.38 no.6
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• pp.480-489
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• 2010

We investigated the functional characteristics of commercial wood charcoal in Korea and their application as functional raw materials. The areas of analysis were anatomical features, elementary composition, mineral composition, caloric values, anion and far-infrared ray emission, and moisture absorption capacity. Based on the analyses as above mentioned, it is considered that charcoal can be evaluated as functional raw material. In commercial wood charcoal in Korea, there were highly varied depending on manufacturing methods as black charcoal, white charcoal and mechanical charcoal and manufactures for elementary composition, mineral composition, anion emission, far infrared ray emission. Especially, black charcoal showed lower moisture absorption capacity than white charcoal and mechanical charcoal. For charcoal as functional raw material, selective usage are needed based on the analyses of anatomical features, elementary composition, mineral composition, caloric values, anion and far-infrared ray emission, and moisture absorption capacity. Specific charcoal making methods for improving specific functionality, required as functional raw material, are necessary in further research.

• Journal of the Korean Wood Science and Technology
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• v.43 no.5
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• pp.691-699
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• 2015

To evaluate the possibility of charcoal as Green Infrastructure (GI) materials, data such as moisture content, amount of adsorbed water, and amount of evaporation were collected. Some data from previous study were referenced to find out if correlations exist between results in this study and previous study. Only porosity was directly related to moisture content. Two mechanical charcoal had better abilities than traditional charcoal in all three categories. Mechanical black charcoal chips produced by National Forestry Cooperative Federation (NFCFC) adsorbed 333.3% of water in thirty minutes, 297.5% in five minutes, and evaporated around 75% water in four days. This ability is much higher than other five charcoal. Even though results of test showed various degrees and NFCFC was the best as GI materials, data of charcoal were also within acceptable range based on generally accepted characteristics of GI materials.

• Carbon letters
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• v.1 no.2
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• pp.87-90
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• 2000

Porous carbon from charcoal filled polypropylene composites were prepared and their mechanical properties were evaluated. In preparing the composites, crosslinking agent (sodium benzonate) were used in order to improve the bonding force between matrix and fillers. In this study, the effects of charcoal powder and sodium benzonate concentration on the mechanical properties and interface phenomena on the composites were evaluated. The mechanical properties of composites increased progressively with the decrease of filler loading. In the case of addition of the crosslinking agent into the composite, the mechanical properties were increased and showed maximum value at the 3 wt% concentration of sodium benzonate. According to the result of the TGA, the weight loss of composite according to crosslinking agent was not observed and initial thermal degradation temperature of composite reinforced charcoal was located at $390^{\circ}C$.

• Elastomers and Composites
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• v.54 no.1
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• pp.22-29
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• 2019

Chitosan-polyvinyl alcohol (PVA) -bamboo charcoal/silica (CS-PVA-BC/SI) hybrid fillers with compatibilized styrene-butadiene rubber (SBR) composites were fabricated by the interpenetrating polymer network (IPN) method. The structure and composition of the composite samples were characterized by scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FT-IR). The viscoelastic behaviors of the rubber composites and their vulcanizates were explored using a rubber processing analyzer (RPA) in the rheometer, strain sweep and temperature sweep modes. The storage and loss moduli of SBR increased significantly with the incorporation of different hybrid fillers, which was attributed to the formation of an interphase between the hybrid fillers and rubber matrix, and the effective dispersion of the hybrid fillers. The mechanical properties (hardness, tensile strength, oxygen transmission rate, and swelling rate) of the composite samples were characterized in detail. From the results of the mechanical test, it was found that BC-CS-PVA0SBR had the best mechanical properties. Therefore, the BC-CS-PVA hybrid filler provided the best reinforcement effects for the SBR latex in this research.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2017.11a
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• pp.120-121
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• 2017

Polyurethane coating materials are widely used in waterproofing construction because they ensure easy workability and high performance mechanical properties, and such polyurethane coating materials are in various mixture ratios. This study carried out a test to determine the basic physical property changes of polyurethane coating material based on the amount of charcoal additives to. The results showed that he tensile strength was found to be 3.1 N / ㎟ when the charcoal amount was at 2%, displaying the highest performance rate.

• Journal of the Korean Wood Science and Technology
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• v.45 no.6
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• pp.772-786
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• 2017

This study investigated the characteristics of wood tar, produced as a byproduct during the production of charcoal using oak wood by the modified traditional kiln and mechanical steel kiln. The wood tar was analyzed with a number of techniques, including Py-GC/MS, NMR, MALDI-TOF, FT-IR, TG and DSC. The Py-GC/MS analysis indicated that modified traditional kiln generated a higher hydrocarbon ratio in the wood tar than that of mechanical steel kiln. On the other hand, mechanical steel kiln resulted in a higher proportion of phenolic and aromatic hydrocarbon components than that of modified traditional kiln. Those results were also confirmed by NMR analysis. The MALDI-TOF analysis suggested that the wood tar produced in the mechanical steel kiln had a slightly higher molecular weight than the wood tar produced in the modified traditional kiln. In addition, the FT-IR analysis showed characteristic peak of symmetrical stretching vibration of $CH_3$ from the modified traditional kiln while characteristic peaks of the C-C and C-O stretching vibration were observed from the mechanical steel kiln. Moreover, TG and DSC analysis suggested that the mechanical steel kiln is more thermally stable than that of modified traditional kiln. Those findings clearly showed that the method of making charcoal greatly affects the properties of wood tar.

• Journal of the Korea Furniture Society
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• v.18 no.3
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• pp.205-210
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• 2007

Particleboard(PB) is one of the most commonly used wood-based composite materials, which can be prepared by utilizing any kind of low grade wooden materials like waste wood which contains formaldehyde itself. Therefore, PB have been of considerable interest, in issues regarding the formaldehyde emission problems. Wood wastes are carbonized by the carbonization kiln at $800^{\circ}C$. Charcoal has been known as a formaldehyde adsorber. Thus, in this study, we fabricated PBs with carbonized waste particles cores, to examine the possibility of developing less formaldehyde emitting boards. The physical and mechanical properties were evaluated by Korean Standard (KS F 3104). The moisture content of PBs ranged from 6.76 to 8.36%. Internal bond strengths decreased with the increase in the content of carbonized core particles. Formaldehyde emission showed minimum value at 25% of carbonized core particles, but the emission values increased when the amount of carbonized cote particles increased. When 25% of carbonized core particles was used, PBs met KS F 3104 standard properties.

• Journal of Environmental Health Sciences
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• v.37 no.1
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• pp.50-56
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• 2011

The adsorption capacity of charcoal is a function of the airborne concentration of the target chemical. To evaluate the adsorption capacity of charcoal packed in the cartridges of air purifying respirators, breakthrough tests were conducted with carbon tetrachloride for three commercial cartridges (3M models #7251, #6000 and AX) at 25, 50, 100, 250 and 500 ppm. Adsorption capacities were calculated using a mass transfer balance equation derived from the curve fitting to the breakthrough curves obtained experimentally. Carbon micropore volumes were estimated by iteration to fit the Dubinin/Radushkevich (D/R) adsorption isotherm. They were 0.6566, 0.5727 and 0.3087 g/cc for #7251, #6000 and the AX cartridge, respectively. Above 100 ppm (at high challenge concentrations), #7251 and #6000 showed higher adsorption capacities. However, as the challenge concentration decreased, the adsorption capacities of #7251 and #6000 sharply dropped. On the other hand, the adsorption capacity of the AX cartridge showed little change with the decrease of the challenge concentration. Thus, the AX showed a higher adsorption capacity than #7251 and #6000 at the 5-50 ppm level. It is concluded that service-life tests of cartridges and adsorption capacity tests of charcoal should be conducted at challenge concentration levels reflecting actual working environmental conditions. Alternatively, it is recommended to use the D/R adsorption isotherm to extrapolate adsorption capacity at low concentration levels from the high concentration levels at which breakthrough tests are conducted, at a minimum of two different concentration levels.

• Journal of the Korean Wood Science and Technology
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• v.41 no.1
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• pp.64-76
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• 2013

In this study, eco-friendly hybrid composite boards were manufactured from green tea, three kinds of charcoals and wood fiber for developing interior materials to reinforce the strength performances and the functionalities in addition to performances of the green tea-wood fiber hybrid boards. The effects for the kind and the component ratio of raw materials on mechanical properties were investigated. Bending strength performances of hybrid composite boards were highest in the hybrid composite boards composed of green tea, fine charcoal and wood fiber on average. However, the difference caused by the kind of charcoals was not large. These values were was markedly improved than those of green tea - wood fiber hybrid composite boards reported in previous researches. And it was found that the bending strength performance decreased with increasing component ratios of green tea and charcoals. The difference between urea resins used as the binder showed the higher value in hybrid composite boards using $E_1$ grade urea resin than in those using $E_0$ grade urea resin, but the difference between hybrid composite boards manufactured by both resins decreased markedly than the green tea - wood fiber hybrid composite boards reported in previous research. The internal bond strength of hybrid composite boards was in the order of hybrid composite boards with fine charcoal, activated charcoal and black charcoal, and it was found that the hybrid composite boards with fine charcoal had a similar values to control boards composed of only wood fiber.