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Characteristics of Wood Tar Produced as Byproduct from Two Types of The Kiln in The Manufacture of Oak Charcoal

  • Yang, Bong Suk (College of Life Science & Biotechnology, Dongguk University) ;
  • Yang, Jiwook (College of Life Science & Biotechnology, Dongguk University) ;
  • Kim, Dae-Young (College of Life Science & Biotechnology, Dongguk University) ;
  • Kim, Jin-Kyu (Gyeonggido Business & Science Accelerator) ;
  • Hwang, Won-Jung (Department of Forest Products, Korea Forest Research Institute) ;
  • Kwon, Gu-Joong (College of Life Science & Biotechnology, Dongguk University)
  • Received : 2017.09.18
  • Accepted : 2017.10.30
  • Published : 2017.11.25

Abstract

This study investigated the characteristics of wood tar, produced as a byproduct during the production of charcoal using oak wood by the modified traditional kiln and mechanical steel kiln. The wood tar was analyzed with a number of techniques, including Py-GC/MS, NMR, MALDI-TOF, FT-IR, TG and DSC. The Py-GC/MS analysis indicated that modified traditional kiln generated a higher hydrocarbon ratio in the wood tar than that of mechanical steel kiln. On the other hand, mechanical steel kiln resulted in a higher proportion of phenolic and aromatic hydrocarbon components than that of modified traditional kiln. Those results were also confirmed by NMR analysis. The MALDI-TOF analysis suggested that the wood tar produced in the mechanical steel kiln had a slightly higher molecular weight than the wood tar produced in the modified traditional kiln. In addition, the FT-IR analysis showed characteristic peak of symmetrical stretching vibration of $CH_3$ from the modified traditional kiln while characteristic peaks of the C-C and C-O stretching vibration were observed from the mechanical steel kiln. Moreover, TG and DSC analysis suggested that the mechanical steel kiln is more thermally stable than that of modified traditional kiln. Those findings clearly showed that the method of making charcoal greatly affects the properties of wood tar.

Keywords

References

  1. Ahn, B.J., Lee, S.M. 2014. Evaluating The Fuel Characteristics of Wood Pellets Fabricated with Wood Tar and Starch as An Additive. Journal of the Korean Wood Science & Technology 42(3): 318-326. https://doi.org/10.5658/WOOD.2014.42.3.318
  2. Alen, R., Kuoppala, E., Oesch, P. 1996. Formation of the main degradation compound groups from wood and its components during pyrolysis. Journal of Analytical and Applied Pyrolysis 36(2): 137-148. https://doi.org/10.1016/0165-2370(96)00932-1
  3. Amen-Chen, C., Pakdel, H., Roy, C. 1997. Separation of phenols from Eucalyptus wood tar. Biomass and Bioenergy 13(1-2): 25-37. https://doi.org/10.1016/S0961-9534(97)00021-4
  4. Ben, H., Ragauskas, A.J. 2011. NMR characterization of pyrolysis oils from kraft lignin. Energy & Fuels 25(5): 2322-2332. https://doi.org/10.1021/ef2001162
  5. Blanco, P.H., Wu, C., Onwudili, J.A., Williams, P.T. 2012. Characterization of Tar from the Pyrolysis/Gasification of Refuse Derived Fuel: Influence of Process Parameters and Catalysis. Energy & Fuels 26(4): 2107-2115. https://doi.org/10.1021/ef300031j
  6. Brebu, M., Cazacu, G., Chirila, O. 2011. Pyrolysis of lignin - A potential method for obtaining cheminals and/or fuels. Cellulose Chemistry and Technology 45(1-2): 43-50.
  7. Brebu, M., Vasile, C. 2010. Thermal degradation of lignin - A review. Cellulose Chemistry and Technology 44(9): 353-363.
  8. De Wild, P.J., Huijgen, W.J.J., Gosselink, R.J.A. 2014. Lignin pyrolysis for profitable lignocellulosic biorefineries. Biofuels, Bioproducts and Biorefining 8(5): 645-657. https://doi.org/10.1002/bbb.1474
  9. Griessacher, T., Antrekowitsch, J., Steinlechner, S. 2012. Charcoal from agricultural residues as alternative reducing agent in metal recycling. Biomass and Bioenergy 39: 139-146. https://doi.org/10.1016/j.biombioe.2011.12.043
  10. Iatridis, B., Gavalas, G.R. 1979. Pyrolysis of a Precipitated Kraft Lignin. Industrial & Engineering Chemistry Product Research and Development 18(2): 127-130. https://doi.org/10.1021/i360070a010
  11. Jiang, X., Ellis, N., Zhong, Z. 2010. Characterization of Pyrolytic Lignin Extracted from Bio-oil. Chinese Journal of Chemical Engineering 18(6): 1018-1022. https://doi.org/10.1016/S1004-9541(09)60162-2
  12. Jung, J.Y., Lee, Y., Lee, E.Y. 2016. Value-added Utilization of Lignin Residue from Pretreatment Process of Lignocellulosic Biomass. Applied Chemistry for Engineering 27(2): 135-144. https://doi.org/10.14478/ace.2016.1016
  13. Ku, C.S., Mun, S.P. 2006. Characterization of Pyrolysis Tar Derived from Lignocellulosic Biomass. J. Ind. Eng. Chem. 12(6): 853-861.
  14. Kwon, G.J., Kwon, S.M., Cha, D.S., Kim, N.H. 2010. Characteristics of Pellet Prepared from Sawdust and Wood-tar. Journal of the Korean Wood Science & Technology 38(1): 36-42. https://doi.org/10.5658/WOOD.2010.38.1.36
  15. Kwon, G.J., Kwon, S.M., Jang, J.H., Chun, K.W., Kim, N.H. 2011. Weathering of Larch Wood treated with Wood tar and Wood vinegar. Journal of Forest and Environmental Science 27(1): 55-60.
  16. Lee, A., Deng, Y. 2015. Green polyurethane from lignin and soybean oil through non-isocyanate reactions. European Polymer Journal 63: 67-73. https://doi.org/10.1016/j.eurpolymj.2014.11.023
  17. Liu, W.J., Jiang, H., Yu, H.Q., Elhalem, S.S.A., Shen, D., Xiao, R., Zhong, M., Hashmi, A., Xu, J., Motkuri, R.K., Fernandez, C.A., Liu, J., Tucker, M.P., McGrail, P.B., Yang, B., Nune, S.K. 2015. Thermochemical conversion of lignin to functional materials: a review and future directions. Green Chemistry 17: 4888-4907. https://doi.org/10.1039/C5GC01054C
  18. Lora, J.H., Glasser, W.G. 2002. Recent Industrial Applications of Lignin: A Sustainable Alternative to Nonrenewable Materials. Journal of Polymers and the Environment 10(1-2): 39-48. https://doi.org/10.1023/A:1021070006895
  19. Mohan, D., Pittman, C.U., Steele, P.H. 2006. Pyrolysis of wood/biomass for bio-oil: A critical review. Energy and Fuels 20(3): 848-889. https://doi.org/10.1021/ef0502397
  20. Mullen, C.A., Strahan, G.D., Boateng, A.A. 2009. Characterization of various fast-pyrolysis bio-oils by NMR spectroscopy. Energy & Fuels 23(5): 2707-2718. https://doi.org/10.1021/ef801048b
  21. Mun, S., Ku, C., Park, S. 2007. Physicochemical Characterization of Pyrolyzates Produced from Carbonization of Lignocellulosic Biomass in a Batch-type Mechanical Kiln. Journal of Industrial and Engineering Chemistry 13(1): 127-132.
  22. Mun, S.P., Ku, C.S. 2010. Pyrolysis GC-MS analysis of tars formed during the aging of wood and bamboo crude vinegars. Journal of Wood Science 56(1): 47-52. https://doi.org/10.1007/s10086-009-1054-0
  23. Park, Y., Doherty, W.O.S., Halley, P.J. 2008. Developing lignin-based resin coatings and composites. Industrial Crops and Products 27(2): 163-167. https://doi.org/10.1016/j.indcrop.2007.07.021
  24. Prauchner, M.J., Nya, V., Pasa, M.D., Otani, C., Otani, S. 2001. Characterization and Thermal Polymerization of Eucalyptus Tar Pitches. Energy & Fuels 15(2): 449-454. https://doi.org/10.1021/ef000196o
  25. Rocha, J.D., Coutinho, A.R., Luengo, C.A. 2002. Biopitch produced from eucalyptus wood pyrolysis liquids as a renewable binder for carbon electrode manufacture. Brazilian Journal of Chemical Engineering 19(2): 127-132. https://doi.org/10.1590/S0104-66322002000200002
  26. Saiz-Jimenez, C., De Leeuw, J.W. 1986. Lignin pyrolysis products: Their structures and their significance as biomarkers. Organic Geochemistry 10(4-6): 869-876. https://doi.org/10.1016/S0146-6380(86)80024-9
  27. Sarohia, G.S., Ghuman, H.S., James, A.K., Thring, R.W., Plourde, G.L. 2014. Characterization of Tar From Wood Pellet Production. International Journal of Chemistry 6(4): 1-11.
  28. Scholze, B., Hanser, C., Meier, D. 2001. Characterization of the water-insoluble fraction from fast pyrolysis liquids (pyrolytic lignin). Journal of Analytical and Applied Pyrolysis 58-59(1): 387-400. https://doi.org/10.1016/S0165-2370(00)00173-X
  29. Setua, D.K., Shukla, M.K., Nigam, V., Singh, H., Mathur, G.N. 2000. Lignin reinforced rubber composites. Polymer Composite 21(6): 988-995. https://doi.org/10.1002/pc.10252
  30. Steiner, C., Teixeira, W.G., Zech, W. 2004. Slash and Char: An Alternative to Slash and Burn Practiced in the Amazon Basin, in: Glaser, B., Woods, W.I. (Eds.). Springer Berlin Heidelberg, pp. 183-193.
  31. Wenzl, H.F.J. 1970. The chemical technology of wood. Academic Press.
  32. Yatagai, M., Unrinin, G., Sugiura, G. 1986. By-products of wood carbonization. Tars from mangrove, sugi ogalite, wheat straw, and Chishima-sasa. Mokuzai Gakkaishi. 32(6): 467-471.
  33. Zhao, B., Chen, G., Liu, Y., Hu, K., Wu, R. 2001. Synthesis of lignin base epoxy resin and its characterization. Journal of Materials Science Letters 20: 859-862. https://doi.org/10.1023/A:1010975132530