• Journal of the Korean Chemical Society
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• 제36권4호
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• pp.552-557
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• 1992

Chloramphenicol was studied by differential pulse polarography (DDP). A reduction peak which is dependent on pH of the solution appeared in the voltage range between zero and -1.50 volt vs. Ag/AgCl (sat. KCl) reference electrode. A plot of peak potentials (Ep) measured at room temperature (20$^{\circ}C$) vs. pH of the chloramphenicol solutions showed linear relationship changing slope (Ep/pH) at pH 8.9. The slope was -59.7 mV/pH in pH 2.7∼8.9 and -24.3 mV/pH in pH 8.9∼11.2, respectively. A log plot of peak currents (ip) vs. concentrations showed a linearity at the concentrations between 4.8 ${\times}$ 10$^{-7}$ M and 6.2 ${\times}$ 10$^{-5}$ M (0.16 ppm∼20 ppm) chloramphenicol in pH 8.0 ammonium buffer. Between the DPP method and the reference method measuring absorbance at 278 nm, the correlation coefficient was 0.996, which means an excellent linearity. The DPP method was able to detect degradation products of chloramphenicol in mild alkaline solution (pH = 8.0) more distinctly than the spectrophotometric method.

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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• 제4권3호
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• pp.165-171
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• 2000

Experiments were carried out to measure variations in the oxidation potential and current density using the polarization curves of polycarbonate. The results were then examined to identify the influences affecting the oxidation potential related to various conditions, such as temperature, pH, and oxydase(citrate and lipase). The lines representing the active anodic and cathodic dissolution shifted only slightly in the potential direction relative to temperature, pH, and the effect of the enzyme. The Tafel slope for the anodic and cathodic dissolution was determined such that the reversibility polarization was indicated as being effected by various conditions. The slope of the polarization curves describing the active-to-passive transition region shifted noticeably in their direction. Also, by varying the conditions, the optimum conditions for the most ready transform were identified, including temperature, pH, oxidation rate, and resistance of oxidation potential. The critical oxidation sensitivity(I(sub)r/I(sub)f) of the anodic current density peak and maximum passive current density was also determined, which is used in measuring the critical corrosion sensitivity of a polycarbonate.

• Food Science and Biotechnology
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• 제16권6호
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• pp.999-1005
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• 2007

An oil-in-water (O/W) emulsion [20 wt% com oil, 0.5-6.0 wt% fish gelatin (FG), pH 3.0] was produced by high pressure homogenization, and the influence of pH, protein concentration, and homogenization condition on the formation of FG-stabilized emulsions was assessed by measuring particle size distribution, electrical charge, creaming stability, microstructure, and free FG concentration in the emulsions. Optical microscopy indicated that there were some large droplets ($d>10\;{\mu}m$) in all FG-emulsions, nevertheless, the amount of large droplets tended to decrease with increasing FG concentration. More than 90% of FG was present free in the continuous phase of the emulsions. To facilitate droplet disruption and prevent droplet coalescence within the homogenizer, homogenization time was adjusted in O/W emulsions stabilized by 2.0 or 4.0 wt% FG. However, the increase in the number of pass rather promoted droplet coalescence. This study has shown that the FG may have some limited use as a protein emulsifier in O/W emulsions.

• Textile Coloration and Finishing
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• 제30권4호
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• pp.264-274
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• 2018

Immobilization of lysozyme on chitosan non-woven using glutaraldehyde(GA) was investigated. For this, 100 % chitosan non-woven was prepared as novel support for the enzyme immobilization. In addition, free lysozyme activity was examined depending on various pH and temperature by measuring time. Moreover, the optimum immobilization conditions depending on various pH, temperature, immobilization time and lysozyme concentration was evaluated. In addition, thermal stability and storage stability of immobilized lysozyme were measured. The characteristics of immobilized lysozyme was examined by FT-IR, surface morphology, and MTT assay. The results are follows: the optimal immobilization of lysozyme were pH 7.0, $25^{\circ}C$, lysozyme concentration 1.5 mg/ml, immobilization time 240 min. The immobilized lysozyme showed higher thermal stability than the free trypsin. The immobilized lysozyme activity was retained 80 % of its initial activity at $4^{\circ}C$ over 30 days of storage. The lysozyme was immobilized effectively on chitosan non-woven by observation of surface morphology.

• Journal of Korean Society of Environmental Engineers
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• 제32권6호
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• pp.555-562
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• 2010

For the rapid and reliable detection of toxic compounds in water, a novel toxicity detection methodology based on sulfur-oxidizing bacteria (SOB) has been developed. The methodology exploits the ability of SOB to oxidize elemental sulfur to sulfuric acid in the presence of oxygen. The reaction results in an increase in electrical conductivity (EC) and a decrease in pH. Using a synthetic stream water (EC=0.12 mS/cm and pH=7.2), the baseline steady-state EC and pH values were 0.5~1.2 mS/cm and ~2.5 over 7 days of testing at HRT 30 minutes. When nitrite compounds were added to the system, the effluent EC decreased and the pH increased due to the inhibition of the SOB. Optimum HRT was 30 min and this HRT could be decresed by using smaller sulfur particles.

• Journal of the Korean Society of Marine Environment & Safety
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• 제12권2호
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• pp.99-106
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• 2006

The fate of chemical pollutants in the aquatic environment is generally considered to be strongly influenced by environmental factors such as pH, salinity and electrostatic charges on the surface of particles ai well as by the characteristic of chemicals. Oxolinic acid was measured by chemical analysis using HPLC to determine the effect of salinity, pH and suspended solids on chemical binding and by bioassay for measuring bioactivity. The higher contentration of suspended solids in the medium, the lower concentration of oxolinic and was detected in measurements from by both HPLC and biosssay analysis. This indicates particle may have a stronger binding or absorption effect on oxolinic acid. Bioassay analysis showed weaker bioacivity at higher salinity and pH 7.0, but this result of bioassay analysis was different from the result of HPLC.

• Journal of the Korean Institute of Telematics and Electronics D
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• 제34D권9호
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• pp.50-55
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• 1997

In order to improve the electrical performance of ITO/InP solar cells, sulfur passivation technique was employed using (N $H_{4}$)$_{2}$ $S_{x}$ solution. Passivation effects were analyzed by measuring the short circuit current density ( $J_{sc}$ ) of solar cells and photoluminescence (PL) of ITO/InP interfaces. This paper firstly reports the sulfur passivation effects by investigating the correlation between the PL intensity and the short circuit current. Generally, PL intensity and the short circuit current of sulfur passivated sampels wer eincreased, and showed the same trend. Especially, samples prepared at 60.deg. C (N $H_{4}$)$_{2}$ $S_{x}$ solution exhibited the highest $J_{sc}$ and PL intensity. These results demonstrated that the short circuit currents was influenced by the ITO/InP interface states.

• Journal of Applied Biological Chemistry
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• 제43권4호
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• pp.246-249
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• 2000

We investigated the production of chitin oligosaccharides using food grade papain. A solution of commercial food grade papain (FGP) was dialyzed for 12 h before measuring its chitinolytic activity. The effects of enzyme concentration, reaction temperature, and pH on the endochitinase and $\beta$-N-acetylglucosaminidase activities and the thermostability of these enzymes were investigated. In adddition, the reaction products were analyzed with gel filtration on a Bio-Gel P2. The endochitinase activity was twentyfold higher than that of $\beta$-N-acetylglucosaminidase. The optimal endochitinase activity was at pH 3.0, while the maximal $\beta$-N-acetylglucosaminidase activity was at pH 6.0. The reaction product consisted mainly of the dimer of N -acetylglucosamine, with a small amount of its trimer. Under the experimental conditions, $120{\mu}g$ of chitin oligomers were obtained with 1 mg of FGP protein after an incubation of 2 h.

• Journal of Animal Environmental Science
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• 제16권3호
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• pp.227-236
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• 2010

This study was conducted to develop an measuring system and method for fermentation degree of liquid swine manure by visible ray. The constituent changes of liquid swine manure were examined. pH gradually increased with time, but EC gradually decreased. Malodor strength decreased gradually with aeration treatment with time. Control needed more time to decrease malodor strength than aeration treatment. In aeration treatment, there was no germination of seeds (radish, chinese cabbage) up to 6 weeks and germination rate at 15th week was over 50%. However, in control, there was no germination up to end of experiment. Circular chromatography method showed that there was change after 10th week in aeration treatment but there was no change up to end of experiment in control. As a result, the fermentation degree of liquid swine manure would have relations among pH, EC, germination rate, malodor concentration, and reaction of circular chromatography. The simple analytical instrument for liquid swine manure consisted of a tungsten halogen and deuterium lamp for light source, a sample holder, a quartz cell, spectrometer for spectrum analyzer, a malodour measuring device, a software, etc. Results showed that the simple analytical instrument that was developed can approximately predict the fermentation degree of liquid swine manure by visible ray. Generally, the experiment proved that the simple analytical instrument was reliable, feasible and practical for analyzing the fermentation degree of liquid swine manure.

• Korean Journal of Fisheries and Aquatic Sciences
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• 제8권4호
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• pp.202-207
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• 1975

During the term of June, 7 to August 11, the noises in the maine engine room in terms of the r. p. m. of the Pung-Yang Ho (4,500 H. P.), the Chuk-Yang Ho (3,800 H. P.), the Dong-Bang Ho (3,000 H. P.), the Oh-Dae San Ho (2,690 H, P.), the Kwan-Ak-San Ho (1,000 H. P.) and the Back-Kyung Ho (850 H. P.) (Refer to Table 1) were measured with the use of sound level meter, which has measuring range 37-140 dB and the results obtained are as follows : 1. Capacity of the engine room becomes large according to the total H. P. of the main engine, but the vessels are using of a type of engine, i.e., 6 cylinder, and thus the noise, pressure has shown a tendency to become lower except Kwan-Ak-San Ho, Chuk-Yang Ho and Dong Bang Ho where the noise pressure was higher by 3 dB than curve of mean value. 2. The maximum noise pressure appeared even before the main engine reached the maximum r. p. m. and while the percentage of the r. p. m. varied depending on the vessel, the maximum noise appeared at around the $67-75\%$ of the r. p. m. 3. The maximum of noise pressure in the respective engine room ranged between 93.5-105 dB while it was between 72-81 dB at the fish process room in the stern trawl vessel where the oral communications were possible.