• Title/Summary/Keyword: matrix application

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Fundamental study of electrolyte cathode atomic discharge for development of on-line monitoring system (On-line monitoring system 개발에 관한 음극 액상 글로우 방전의 기초 연구)

  • Kim, Kyung-Mi;Woo, Young-A;Cho, Won-Bo;Kim, Hyo-Jin
    • Analytical Science and Technology
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    • v.15 no.6
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    • pp.496-501
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    • 2002
  • The electrolyte cathode glow discharge (ELCAD) is a new optical system for direct determination of trace heavy metals in flowing water. ELCAD has been successfully developed for on-line monitoring of heavy metals in flowing water. The application of an atmospheric glow discharge between an electrolyte solution cathode and a platinum rod anode led to the development of stable discharge. The fundamental aspects of new plasma source have been investigated. The fundamental study of ELCAD system has been measured plasma temperature using Einstein-Boltzmann equation after searching Fe atomic emission lines. The spectrum of each elements such as Cu, Pb, Fe, Ni and Cr show only major elemental line and no ionic line possibly due to low temperature plasma source. The detection limits of each elements are also investigated. These informations show that this type of plasma may apply for monitoring of heavy metals in waste water which consists of complex matrix.

Sequential separation of 90Sr, 241Am, 239,240Pu and 238Pu by radioanalytical techniques (방사능 분석기술을 이용한 90Sr, 239,240Pu, 238Pu, 241Am 축차분리)

  • Lee, Myung Ho;Park, Kyoung Kyun;Kim, Jong-Yun;Park, Yeong Jae;Kim, Won Ho
    • Analytical Science and Technology
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    • v.18 no.6
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    • pp.469-474
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    • 2005
  • This paper presents a quantitative method of sequential separation of $^{90}Sr$, $^{241}Am$ and Pu radionuclides with an anion exchange resin and a Sr-Spec resin. The Pu isotopes were purified with an anion exchange resin. The americium and strontium fractions were separated from the matrix elements with an oxalate co-precipitation method. Americium fraction was separated from the strontium fraction with iron co-precipitation method and purified from lanthanides with anion exchange resin. Strontium-90 was purified from other hindrance elements with the Sr-Spec resin after oxalate co-precipitation. The measurement of Pu and Am isotopes was carried out by an ${\alpha}$-spectrometer. Strontium-90 was measured by a liquid scintillation counter. The radiochemical procedure of $^{90}Sr$, $^{241}Am$ and Pu radionuclides investigated in this study has been validated by application to IAEA-Reference soils.

A Study on the Application of Safety Design based on the Risk of Construction Process (건설공정 위험성 기반 설계안전성 활용 방안 연구)

  • Lee, Hyeon-Sung
    • Journal of the Society of Disaster Information
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    • v.15 no.4
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    • pp.493-501
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    • 2019
  • Purpose: The purpose of this study is to prevent construction safety accidents, and the design safety systems were reviewed. This paper aims to establish as an effective system by looking at the implementation procedures and contents of the design safety review system. Method: We reviewed the purpose and content of the law, accident statistics, etc. for the study. In addition, we looked at the implementation plans for actual construction sites using the 'design safety' assessment process as defined by the Act. Results: We divided it into the data review phase, the risk factor elicitation and alternative setup phase, and the design safety assessment report preparation stage. Conclusion: it is necessary to derive risk factors that take into account the diversity of construction sites. However, the effectiveness of other reports is questioned as they are often copied and written. Therefore, it is necessary to strengthen external verification procedures attended by construction safety experts.

Strain-Hardening Cementitious Composites with Low Viscosity Suitable for Grouting Application (그라우팅에 적합한 점성을 갖는 변형률 경화 시멘트 복합재료)

  • Lee, Bang Yeon
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.1
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    • pp.55-63
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    • 2012
  • This paper presents materials and processing technique to manufacture low viscous strain-hardening cementitious composite which is suitable for structures requiring low viscosity of materials. The micromechanics and fracture mechanics tools coupled with processing techniques were adopted to achieve low viscosity of composites as well as high tensile strain capacity. Optimal volume and length of fibers and interfacial properties between fibers and matrix for composites with tensile strength of 2~3MPa were determined on the basis of the micromechanical analysis and the steady-state cracking theory. Then six mixtures were determined and the experiment was carried out to evaluate the viscosity and uniaxial tensile performance of those. From the test results, it is verified that the strain-hardening cementitious composite with low viscosity suitable for grouting applications in fresh state as well as high ductility over 1.5% in hardened state can be feasible.

Introduction to the Indian Buffet Process: Theory and Applications (인도부페 프로세스의 소개: 이론과 응용)

  • Lee, Youngseon;Lee, Kyoungjae;Lee, Kwangmin;Lee, Jaeyong;Seo, Jinwook
    • The Korean Journal of Applied Statistics
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    • v.28 no.2
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    • pp.251-267
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    • 2015
  • The Indian Buffet Process is a stochastic process on equivalence classes of binary matrices having finite rows and infinite columns. The Indian Buffet Process can be imposed as the prior distribution on the binary matrix in an infinite feature model. We describe the derivation of the Indian buffet process from a finite feature model, and briefly explain the relation between the Indian buffet process and the beta process. Using a Gaussian linear model, we describe three algorithms: Gibbs sampling algorithm, Stick-breaking algorithm and variational method, with application for finding features in image data. We also illustrate the use of the Indian Buffet Process in various type of analysis such as dyadic data analysis, network data analysis and independent component analysis.

Properties of Polymer-Modified Mortar with Styrene-Butyl Acrylate and Styrene Butadiene Rubber (S/BA와 SBR을 혼입한 폴리머 시멘트 모르타르의 특성)

  • Mun, Kyung-Ju;Song, Hae-Ryong;Hyung, Won-Gil
    • Polymer(Korea)
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    • v.32 no.6
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    • pp.555-560
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    • 2008
  • Polymer-modified mortars have been largely used as paving materials, flooring, waterproofing material, adhesives, anticorrosive linings, deck coverings, and other various materials. The various types and properties of the mixed polymer largely affect the characteristics of polymer-modified mortar that has been mixed with polymer latexes. Consequently, its application purposes are varied according to these properties. This paper investigates the typical properties of polymer-modified mortars that contain styrene and butyl acrylate latexes and styrene butadiene rubber. They are then tested to obtain air contents, water-cement ratios, flexural and compressive strengths, water absorption, and chloride-ion penetration. From the test results, the superior flexural strength of polymer-modified mortars is obtained at a S/BA-2 and a polymer-cement ratio of 20%. And, the water absorption and chloride ion penetration depth are greatly affected by the polymer-cement ratio rather than the types of polymer. In the polymer-modified mortar and concrete structures, aggregates are bound by such a co-matrix phase, resulting in the superior properties of polymer-modified mortar and concrete compared to conventional mortar and concrete.

Tungsten oxide interlayer for hole injection in inverted organic light-emitting devices

  • Kim, Yun-Hak;Park, Sun-Mi;Gwon, Sun-Nam;Kim, Jeong-Won
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.380-380
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    • 2010
  • Currently, organic light-emitting diodes (OLEDs) have been proven of their readiness for commercialization in terms of lifetime and efficiency. In accordance with emerging new technologies, enhancement of light efficiency and extension of application fields are required. Particularly inverted structures, in which electron injection occurs at bottom and hole injection on top, show crucial advantages due to their easy integration with Si-based driving circuits for active matrix OLED as well as large open area for brighter illumination. In order to get better performance and process reliability, usually a proper buffer layer for carrier injection is needed. In inverted top emission OLED, the buffer layer should protect underlying organic materials against destructive particles during the electrode deposition, in addition to increasing their efficiency by reducing carrier injection barrier. For hole injection layers, there are several requirements for the buffer layer, such as high transparency, high work function, and reasonable electrical conductivity. As a buffer material, a few kinds of transition metal oxides for inverted OLED applications have been successfully utilized aiming at efficient hole injection properties. Among them, we chose 2 nm of $WO_3$ between NPB [N,N'-bis(1-naphthyl)-N,N'-diphenyl-1,1'-biphenyl-4,4'-diamine] and Au (or Al) films. The interfacial energy-level alignment and chemical reaction as a function of film coverage have been measured by using in-situ ultraviolet and X-ray photoelectron spectroscopy. It turned out that the $WO_3$ interlayer substantially reduces the hole injection barrier irrespective of the kind of electrode metals. It also avoids direct chemical interaction between NPB and metal atoms. This observation clearly validates the use of $WO_3$ interlayer as hole injection for inverted OLED applications.

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Photoluminescent Graphene Oxide Microarray for Multiplex Heavy Metal Ion Analysis

  • Liu, Fei;Ha, Hyun Dong;Han, Dong Ju;Park, Min Su;Seo, Tae Seok
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.281.2-281.2
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    • 2013
  • Since heavy metal ions included in water or food resources have critical effects on human health, highly sensitive, rapid and selective analysis for heavy metal detection has been extensively explored by means of electrochemical, optical and colorimetric methods. For example, quantum dots (QDs), such as semiconductor QDs, have received enormous attention due to extraordinary optical properties including high fluorescence intensity and its narrow emission peaks, and have been utilized for heavy metal ion detection. However, the semiconductor QDs have a drawback of serious toxicity derived from cadmium, lead and other lethal elements, thereby limiting its application in the environmental screening system. On the other hand, Graphene oxide (GO) has proven its superlative properties of biocompatibility, unique photoluminescence (PL), good quenching efficiency and facile surface modification. Recently, the size of GO was controlled to a few nanometers, enhancing its optical properties to be applied for biological or chemical sensors. Interestingly, the presence of various oxygenous functional groups of GO contributes to opening the band gap of graphene, resulting in a unique PL emission pattern, and the control of the sp2 domain in the sp3 matrix of GO can tune the PL intensity as well as the PL emission wavelength. Herein, we reported a photoluminescent GO array on which heavy metal ion-specific DNA aptamers were immobilized, and sensitive and multiplex heavy metal ion detection was performed utilizing fluorescence resonance energy transfer (FRET) between the photoluminescent monolayered GO and the captured metal ion.

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Calibration and Sensitivity Analysis of LRCS Rainfall-Runoff Model(II) : Application (LRCS 강우-유출 모형의 보정 및 민감도 분석(II) : 적용)

  • O, Gyu-Chang;Lee, Gil-Seong;Lee, Sang-Ho
    • Journal of Korea Water Resources Association
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    • v.32 no.6
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    • pp.665-674
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    • 1999
  • This paper confirmed the applicability of model to Korean rivers through the calibration and sensitivity analysis of LRCS rainfall runoff model for 18 storm events of Songriweon station in Nakdong river system, and achieved that LS and WLS were better than LAD by model fitting results. Diagonal element of "hat" matrix and affluence measures were used by analysis of parameter estimates, and parameter IL was the most important parameter in model output. By the results of error propagation according to parameter error, parameters IL, TP, F1 were affected by error propagation, and this is measure of sensitivity for the model output. This paper confirmed the relationship of calibration and sensitivity analysis of model through analysis of sensitivity coefficient, diagonal element $h_i$ and $D_i$._i$.

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Reconstruction and Deconvolution of X-Ray Backscatter Data Using Adaptive Filter (적응필터를 이용한 적층 복합재료에서의 역산란 X-Ray 신호처리 및 복원)

  • Kim, Noh-Yu
    • Journal of the Korean Society for Nondestructive Testing
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    • v.20 no.6
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    • pp.545-554
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    • 2000
  • Compton X-ray backscatter technique has been used to quantitatively assess the impact damage in quasi-isotropic laminated composites and to obtain a cross-sectional profile of impact-damaged laminated composites from the density variation of the cross section. An adaptive filter is applied to the Compton backscattering data for the reconstruction and noise reduction from many sources including quantum noise, especially when the SNR(signal-to-noise ratio) of the image is relatively low. A nonlinear reconstruction model is also proposed to overcome distortion of the Compton backscatter image due to attenuation effects, beam hardening, and irregular distributions of the fibers and the matrix in composites. Delaminations masked or distorted by the first few delaminations near the front surface are detected and characterized both in width and location, by application of an error minimization algorithm.

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