• Title/Summary/Keyword: materials science

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Patterning of conducting polymer at micron- scale using a selective surface treatment

  • Lee, Kwang-Ho;Kim, Sang-Mook;Kim, Ki-Seok;Song, Sun-Sik;Kim, Eun-Uk;Jung, Hee-Soo;Kim, Jin-Ju;Jung, Gun-Young
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.834-836
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    • 2008
  • We demonstrated micro-scale conducting polymer patterning based on a selective surface treatment. A substrate with a patterned photoresist was immersed into OTS (Octadecyltrichlosilnae) solution. The protected substrate areas were hydrophilic after removing the PR resist, where a conducting polymer solution was coated selectively by spin-coating method.

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Coarsening Advantage of Twinned BaTiO3 Seed Particle

  • Jin, Hong-Ri;Jo, Wook;Hwang, Nong-Moon;Kim, Doh-Yeon
    • Journal of the Korean Ceramic Society
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    • v.42 no.9 s.280
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    • pp.599-601
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    • 2005
  • The coarsening process of two different $BaTiO_3$ single crystal seeds, one with a (111) double twin and the other without it, was investigated. Due to the presence of Twin Plane Reentrant Edge (TPRE), the coarsening rate of the twinned seed crystal was significantly higher than that without a twin. For the coarsening by the 2-dimensional nucleation and lateral growth, the energy barrier for nucleation at the TPRE was analyzed to be about a half compared with that at the terrace planes.

Control of Molecular Weight, Stereochemistry and Higher Order Structure of Siloxane-containing Polymers and Their Functional Design

  • Yusuke Kawakami;Yuning Li;Yang Liu;Makoto Seino;Chitsakon Pakjamsai;Motoi Oishi;Cho, Yeong-Bee;Ichiro Imae
    • Macromolecular Research
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    • v.12 no.2
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    • pp.156-171
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    • 2004
  • We describe the precision synthesis schemes of siloxane-containing polymers, i.e., the control of their molecular weight, stereoregularity, and higher-order structures. First, we found a new catalytic dehydrocoupling reaction of water with bis(dimethylsilyl)benzene to give poly(phenylene-disiloxane). Together with this reaction, we applied hetero-condensations to the synthesis of thermally stable poly(arylene-siloxane)s. The dehydrocoupling reaction was applied to the synthesis of syndiotactic poly(methylphenylsiloxane) and poly(silsesquioxane)s, which we also prepared by hydrolysis and deaminative condensation reactions. We discuss the tendency for loop formation to occur in the synthesis of poly(silsesquioxane) by hydrolysis, and provide comments on the design of functionality of the polymers produced. By taking advantage of the low energy barrier to rotation in the silicon-oxygen bond, we designed selective oxygen-permeable membrane materials and liquid crystalline materials. The low surface free energy of siloxane-containing systems allows surface modification of a blend film and the design of holographic grating materials.

Edge-Cracking Behavior of CoCrFeMnNi High-Entropy Alloy During Hot Rolling

  • Won, Jong Woo;Kang, Minju;Kwon, Heoun-Jun;Lim, Ka Ram;Seo, Seong Moon;Na, Young Sang
    • Metals and materials international
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    • v.24 no.6
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    • pp.1432-1437
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    • 2018
  • This work investigated edge-cracking behavior of equiatomic CoCrFeMnNi high-entropy alloy during hot rolling at rolling temperatures $500{\leq}T_R{\leq}1000^{\circ}C$. Edge cracks did not form in the material rolled at $500^{\circ}C$, but widened and deepened into the inside of plate as $T_R$ increased from $500^{\circ}C$. Edge cracks were most severe in the material rolled at $1000^{\circ}C$. Mn-Cr-O type non-metallic inclusion and oxidation were identified as major factors that caused edge cracking. The inclusions near edge region acted as preferential sites for crack formation. Connection between inclusion cracks and surface cracks induced edge cracking. Rolling at $T_R{\geq}600^{\circ}C$ generated distinct inclusion cracks whereas they were not serious at $T_R=500^{\circ}C$, so noticeable edge cracks formed at $T_R{\geq}600^{\circ}C$. At $T_R=1000^{\circ}C$, significant oxidation occurred at the crack surface. This accelerated edge crack penetration by embrittling the crack tip, so severe edge cracking occurred at $T_R=1000^{\circ}C$.

Influence of the Composition of Shell Layers on the Photoluminescence of Cu0.2InS2 Semiconductor Nanocrystals with a Core-shell Structure

  • Kim, Young-Kuk;Ahn, Si-Hyun;Cho, Young-Sang;Chung, Kookchae;Choi, Chul-Jin;Shin, Pyung-Woo
    • Korean Journal of Metals and Materials
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    • v.49 no.11
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    • pp.900-904
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    • 2011
  • We have synthesized core-shell structured nanocrystals based on chalcopyrite-type $Cu_{0.2}InS_2$. The photoluminescence of the nanocrystals shows a significant blueshift in the emission wavelength by shell capping with ZnS layers. This shift can be explained with the compressive stress to core nanocrystals applied by the formation of a ZnS shell layer with a large lattice mismatch with the core. In this study, the emission wavelength could be tuned by changing the composition of the shell layers. Nanocrystals with emission wavelength ranging from 575 nm through 630 nm were synthesized by varying the portion of cadmium compared with zinc in the shell layers.