• Title/Summary/Keyword: mass variation effect

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Effect of the Deposition Time onto Structural Properties of Cu2ZnSnS4 Thin Films Deposited by Pulsed Laser Deposition (펄스 레이저 증착법으로 제작한 Cu2ZnSnS4 박막의 구조 특성 변화에 대한 증착 시간 효과)

  • Byeon, Mirang;Bae, Jong-Seong;Hong, Tae-Eun;Jeong, Euh-Duck;Kim, Shinho;Kim, Yangdo
    • Korean Journal of Materials Research
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    • v.23 no.1
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    • pp.7-12
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    • 2013
  • The $Cu_2ZnSnS_4$ (CZTS) thin film solar cell is a candidate next generation thin film solar cell. For the application of an absorption layer in solar cells, CZTS thin films were deposited by pulsed laser deposition (PLD) at substrate temperature of $300^{\circ}C$ without post annealing process. Deposition time was carefully adjusted as the main experimental variable. Regardless of deposition time, single phase CZTS thin films are obtained with no existence of secondary phases. Irregularly-shaped grains are densely formed on the surface of CZTS thin films. With increasing deposition time, the grain size increases and the thickness of the CZTS thin films increases from 0.16 to $1{\mu}m$. The variation of the surface morphology and thickness of the CZTS thin films depends on the deposition time. The stoichiometry of all CZTS thin films shows a Cu-rich and S-poor state. Sn content gradually increases as deposition time increases. Secondary ion mass spectrometry was carried out to evaluate the elemental depth distribution in CZTS thin films. The optimal deposition time to grow CZTS thin films is 150 min. In this study, we show the effect of deposition time on the structural properties of CZTS thin film deposited on soda lime glass (SLG) substrate using PLD. We present a comprehensive evaluation of CZTS thin films.

Effect of Swirl Cup Geometry on Spray Characteristics in Gas Turbine Engine (가스터빈 연소기의 스월컵 형상이 분무특성에 미치는 영향)

  • 김동준;박종훈;고현석;윤영빈
    • Journal of the Korean Society of Propulsion Engineers
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    • v.6 no.2
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    • pp.29-36
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    • 2002
  • Experiments have been performed to investigate the effect of secondary venturi tip angle on flow and spray characteristics in gas turbine combustor with a swirl cup assembly. Three variations of secondary venturi tip angle are made: converging, straight and diverging angles. It is found that the variation of venturi tip angle results in the significant changes of flow and spray characteristics in gas turbine combustors, such as the size and location of recirculation zones. drop size and mass distribution affecting combustion efficiency and NOx emissions. In diverge case, central toroidal recirculation zone(CTRZ) exists near the exit, which is known to be beneficial for flame stability. But in converge case, the finest SMD distribution and uniform mass distribution are found and CTRZ is longer than other cases. Consequently, high combustion efficiency and low pollutant emission are expected in converge case.

Experimental Study on Characteristics of Evaporation Heat Transfer and Oil Effect of $CO_2$ in Mini-channels (미세채널 내 이산화탄소의 증발 열전달 특성 및 오일의 영향에 관한 실험적 연구)

  • Lee, Sang-Jae;Kim, Dae-Hoon;Choi, Jun-Young;Lee, Jae-Heon;Kwon, Young-Chul
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.21 no.1
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    • pp.16-22
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    • 2009
  • In order to investigate $CO_2$ heat transfer coefficient and pressure drop by PAG oil concentration during $CO_2$ evaporation, the experiment on evaporation heat transfer characteristics in a mini-channels were performed. The experimental apparatus consisted of a test section, a DC power supply, a heater, a chiller, a mass flow meter, a pump and a measurement system. Experiment was conducted for various mass fluxes($300{\sim}800kg/m^{2}s$), heat fluxes($10{\sim}40kW/m^2$) saturation temperatures($-5{\sim}5^{\circ}C$), and PAG oil concentration(0, 3, 5wt%). The variation of the heat transfer coefficient was different according to the oil concentration. With the increase of the oil concentration, the evaporation heat transfer coefficient decreased and the delay of dryout by oil addition was found. Pressure drop increased with the increase of the oil concentration and heat flux, and the decrease of saturation temperature.

Nuclear Charge Distribution in Fission Products

  • Baik, Joo-Hyun;Bak, Hae-Ill
    • Nuclear Engineering and Technology
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    • v.11 no.4
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    • pp.295-301
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    • 1979
  • For thermal-neutron-induced fission of $U^{235}$, nuclear charge distribution in the light part of the primary products has been calculated by using several postulates of charge distribution in the fission fragments. By comparing these values with the experimental results, it is revealed that those models are not appropriate for predicting the nuclear charge distribution in the fission fragments. The variation in the most probable charge, $Z_{P}$, of the isobaric distribution for the fission fragments and the charge for a mass given by unchanged charge density, $Z_{UCD}$, is turned out to be small as a function of mass. The parameter, $Z_{P}$ $-Z_{UCD}$, varies from 0.45 to 0.5 in charge units. The nuclear charge dispersion, $\sigma$, shows about 0.5 charge units for the fission fragments. Neutron odd-even effect in fission products could not be revealed clearly without considering the odd-even effect of prompt neutron emission.

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Effects of Imperfect Fixing at the Active End of Spring-top Resonant Column Apparatus (주동단에 반력으프링이 부착된 공진우 시험기에서 우동단 불완전 고정의 영향)

  • 민덕기
    • Geotechnical Engineering
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    • v.6 no.1
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    • pp.7-14
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    • 1990
  • The two degree of freedom model is proposed to study the effects of imperfect fixing at the active end of spring-top resonant column apparatus. A computer program using the SYMPHONY spreadsheet is developed to calculate the dimensionless frequency, F, from which modulug can be determined. It is found that the effect of reaction mass through the parameter Tr on dimensionless frequency, F, can not be ignored if Tr$\leq$20. As To increases, the variation of F increases. But for Tr$\geq$ 20, the effect of To becomes small. It is recommended that T. be greater than 20 if single degree of freedom model is rosed to determine modulus of soil. It also is found that damping ratios of specimen and apparatus do not strongly affect the dimensionless frequency, F.

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Computer based FEM stabilization of oxygen transport model for material and energy simulation in corroding reinforced concrete

  • Hussain, Raja Rizwan
    • Computers and Concrete
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    • v.12 no.5
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    • pp.669-680
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    • 2013
  • This paper unveils a new computer based stabilization methodology for automated modeling analysis and its experimental verification for corrosion in reinforced concrete structures under the effect of varying oxygen concentration. Various corrosion cells with different concrete compositions under four different environmental conditions (air dry, submerged, 95% R.H and alternate wetting-drying) have been investigated under controlled laboratory conditions. The results of these laboratory tests were utilized with an automated computer-aided simulation model. This model based on mass and energy stabilization through the porous media for the corrosion process was coupled with modified stabilization methodology. By this coupling, it was possible to predict, maintain and transfer the influence of oxygen concentration on the corrosion rate of the reinforcement in concrete under various defined conditions satisfactorily. The variation in oxygen concentration available for corrosion reaction has been taken into account simulating the actual field conditions such as by varying concrete cover depth, relative humidity, water-cement ratio etc. The modeling task has been incorporated by the use of a computer based durability model as a finite element computational approach for stabilizing the effect of oxygen on corrosion of reinforced concrete structures.

Pressure Effect on Ultrafiltration of Used CMP Slurry (한외여과를 이용한 폐 CMP Slurry의 분리에서 압력의 영향)

  • Hong, Seongho
    • Journal of Korean Society of Water and Wastewater
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    • v.18 no.4
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    • pp.486-492
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    • 2004
  • CMP (Chemical mechanical polishing) is inevitable process to overcome $0.2{\mu}m$ wire thickness in semiconductor industry. In this study, effect of pressure to separate used CMP slurry into solid and liquid for recycle and reuse by ultrafiltration was investigated. Also, water quality after the ultrafiltration such as turbidity and TDS was evaluated. The material of membrane used in the study was PVDF. The used CMP contained 0.5% of solid content and then concentrated up to 18% by weight. The used CMP can not be concentrated higher than 18% because of viscosity and abrasion of pump. The tested feed pressures were 22.1, 29.4 and 36.8 psi. The results have shown that operating at 36.8 psi has advantages on operation time and total flux. The specific flux showed some variation at 1 to 15 of concentration factor but no difference after 15 of concentration factor. Mass balance of solid at initial stage of the operation showed some unbalance because of deposition of solid on the membrane, which was main reason to reduce flux. Turbidity was very stable at lower than 0.2NTU for 22.1 and 36.8 psi of feed pressure.

Investigation of the vibration of lattice composite conical shells formed by geodesic helical ribs

  • Nezamoleslami, Reza;Khadem, Siamak E.
    • Steel and Composite Structures
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    • v.24 no.2
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    • pp.249-264
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    • 2017
  • In this paper free linear vibration of lattice composite conical shells will be investigated. Lattice composite conical shell consists of composite helical ribs and thin outer skin. A smeared method is employed to obtain the variable coefficients of stiffness of conical shell. The ribs are modeled as a beam and in addition to the axial loads, endure shear loads and bending moments. Therefore, theoretical formulations are based on first-order shear deformation theory of shell. For verification of the obtained results, comparison is made with those available in open literature. Also, using FEM software the 3D finite element model of composite lattice conical shell is built and analyzed. Comparing results of analytical and numerical analyses show a good agreement between them. Some special cases as variation of geometric parameters of lattice part, effect of the boundary conditions and influence of the circumferential wave numbers on the natural frequencies of the conical shell are studied. It is concluded, when mass and the geometrical ratio of the composite lattice conical shell do not change, increment the semi vertex angle of cone leads to increase the natural frequencies. Moreover for shell thicknesses greater than a specific value, the presence of the lattice structure has not significant effect on the natural frequencies. The obtained results have novelty and can be used for further and future researches.

Lithium Chloride-Imidazolium Chloride Melts for the Coupling Reactions of Propylene Oxide and CO2

  • Nguyen, Ly Vinh;Lee, Bo-Ra;Nguyen, Dinh Quan;Kang, Min-Jung;Lee, Hyun-Joo;Ryu, Seol-Ryu;Kim, Hoon-Sik;Lee, Je-Seung
    • Bulletin of the Korean Chemical Society
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    • v.29 no.1
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    • pp.148-152
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    • 2008
  • A series of lithium chloride-imidazolium chloride (LiCl-[imidazolium]Cl) melts were prepared and their catalytic activities were evaluated for the coupling reactions of propylene oxide and CO2. At the constant mole of LiCl, the catalytic activities of LiCl-[imidazolium]Cl melts increased with increasing molar ratio of [imidazolium]Cl/LiCl up to 2, but thereafter decreased rapidly. The variation of alkyl groups on the imidazolium ring showed a negligible effect on the catalytic activity, but the number of alkyl groups present on the imidazolium cation exerts a pronounced effect. Catalysis and electrospray ionization tandem mass spectral analysis results of LiCl-[imidazolium]Cl melts imply that the activity of the melt is strongly related to the amount of LiCl2- generated from the melt.

Effect of Injection Condition on the Diesel. Fuel Atomization in a Multi-Hole Nozzle (다공 노즐에서 분사조건이 디젤 연료의 미립화 특성에 미치는 영향)

  • Sub, Hyun-Kyu;Kim, Jee-Won;Lee, Chang-Sik
    • Journal of ILASS-Korea
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    • v.14 no.1
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    • pp.8-14
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    • 2009
  • This paper present the diesel fuel spray evolution and atomization performance in a multi-hole nozzle in terms of injection rate, spray evolutions, and mean diameter and velocity of droplets in a compression ignition engine. In order to study the effect of split injection on the diesel fuel spray and atomization characteristic in a multi-hole nozzle, the test nozzle that has two-row small orifice with 0.2 mm interval was used. The time based fuel injection rate characteristics was analyzed from the pressure variation generated in a measuring tube. The spray characteristics of a multi-hole nozzle were visualized and measured by spray visualization system and phase Doppler particle analyzer (PDPA) system. It was revealed that the total injected fuel quantities of split injection are smaller than those of single injection condition. In case of injection rate characteristics, the split injection is a little lower than single injection and the peak value of second injection rate is lower than single injection. The spray velocity of split injection is also lower because of short energizing duration and small injection mass. It can not observe the improvement of droplet atomization due to the split injection, however, it enhances the droplet distributions at the early stage of fuel injection.

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