• Korean Journal of Metals and Materials
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• v.49 no.1
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• pp.52-57
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• 2011

Nickel ferrite ($NiFe_2O_4$) powder was prepared through the ceramic route by calcination of a stoichiometric mixture of nickel oxide (NiO) and iron oxide ($Fe_2O_3$). The pressed pellets of $NiFe_2O_4$ were isothermally reduced in pure hydrogen at 800, 900, 1000 and $1100^{\circ}C$. Based on thermogravimetric analysis, the reduction behavior and the kinetic reaction mechanisms of the synthesized ferrite were studied. The initial ferrite powder and various reduction products were characterized by XRD, SEM, reflected light microscope and VSM to reveal the effect of hydrogen reduction on the composition, microstructure, magnetic properties and reaction kinetics of the produced Fe-Ni alloy. Complete reduction of the $NiFe_2O_4$ was achieved with synthesis of homogeneous nanocrystalline Fe-Ni alloys. Arrhenius equation with the approved mathematical formulations for a gas-solid reaction was applied for calculating the activation energy ($E_a$) values and detecting the controlling reaction mechanism.

• Journal of the Mineralogical Society of Korea
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• v.15 no.4
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• pp.283-291
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• 2002

Dry-based processes such as crushing, milling, sieving, magnetic and gravity separation were employed in order to investigate the purification characteristics of bentonite. The CECs of Gampo 13 and 35 bentonites were estimated at 88.3 and 93.3 meq/100 g and the samples contained quartz and feldspar as impurity minerals. According to the physical properties of constituent minerals of bentonite, the purification techniques were adopted to enhance the grade of montmorillonite High grade of montmorillonite could be obtained by the combination of each process. Consequently, the recovery of final products of Gampo 13 and 35 bentonite were 68.6 and 49.5%, and the CECs of them were 96.9 and 109.6 meq/100 g, respectively.

• Economic and Environmental Geology
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• v.31 no.4
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• pp.325-338
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• 1998

105 oriented samples (19 matrix samples, 86 cobble samples) were collected from the Silla Coglomerate Formation in Jinju and Goryeong areas to clarify the regional remagnetization of Cretaceous Kyongsang supergroup. Both the alternating field and thermal demagnetizations were conducted for the collected samples. The characteristic remanent magnetizations of these samples divided into three types in the Silla Conglomerate Formation: The ingredient magnetic minerals are magnetite, hematite, or both magnetite and hematite in a specimen. The characteristic remanent directions of cobble samples did not clustered to any direction. And the characteristic remanent directions of interbedded sandstones in the Silla Conglomerate Formation is $D/I=20.6^{\circ}/54.5^{\circ}$ (${\alpha}_{95}=11.1^{\circ}$, k=48.8) after tilting correction, agree with previous paleomagnetic studies on the Hayang group. These results implied that conglomerate test was passed indicating no regional remagnetization in the studied area after deposition of the Silla Conglomerate Formation.

• Journal of the Korean Magnetics Society
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• v.13 no.6
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• pp.226-230
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• 2003

In this study, we analyzed the volcanic rock and scoria samples taken from special sites of Jeju island in two ways at the room temperature. One is the analysis of the chemical composition using X-ray fluorescence spectrometer, the other is the analysis of minerals in the samples, oxidized iron's genus, valence state and magnetic properties using X-ray diffractometry and Mossbauer spectroscopy. We believe that the volcanic rock and scoria samples are chiefly made of silicate minerals, like SiO$_2$, and they also have olivine, pyroxene, ilmenite, hematite and magnetite. The major Fe fractions of the volcanic rock samples are 2+ charge state and those of the scoria samples are 3+ charge state.

• Bulletin of the Korean Chemical Society
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• v.34 no.2
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• pp.629-632
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• 2013

Many properties of inorganic compounds are sensitive to changes in the point-defect concentrations. In minerals, such changes are influenced by temperature, pressure, and chemical impurities. Olivines form an important class of minerals and are magnesium-rich solid solutions consisting of the orthosilicates forsterite $Mg_2SiO_4$ and the fayalite $Fe_2SiO_4$. Orthosilicates have an orthorhombic crystal structure and exhibit anisotropic electronic and ionic transport properties. We examined the anisotropy of the electrical conductivity of $Fe_2SiO_4$ under the assumption that the electronic conduction in $Fe_2SiO_4$ occurs via a small polaron hopping mechanism. The anisotropic electrical conductivity is well explained by the electron transfer integrals obtained from the spin dimer analysis based on tight-binding calculations. The latter analysis is expected to provide insight into the anisotropic electrical conductivities of other magnetic insulators of transition metal oxides.

• Journal of Conservation Science
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• v.37 no.4
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• pp.380-390
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• 2021

The purpose of this study is to scientifically analyze the rocks of the Obongsan Mountain in Boseong, Jeollanam-do, which contains the largest extant quarry of Gudlejang (flat stone for heating) in Korea, and to scientifically determine the petrological characteristics of the area and the reasons for its use as a quarry. The rocks in the quarry are composed of light-green lapilli tuff, containing various types of lithic fragments and crystalline fragments in a vitreous matrix consisting of the fine feldspar crystals. The main constituent minerals were identified as quartz, plagioclase, mica, chlorite and opaque minerals. When the major element compositions were plotted on a Na₂O+K₂O versus SiO₂ diagram, all samples were situated in the same compositional area as rhyolite. In addition, the result of magnetic susceptibility measurement also showed a similar range of values, of 1.30 ~ 4.85 (×10^-3 SI), indicating that samples were fractionated from the same magma. Both rock types showed similar apparent specific gravity values of 2.32 ~ 2.60. In particular, plate-shaped joints are well developed in the Obongsan Mountain area, and many areas exhibit talus terrain. In conclusion, the rocks of this area is interpreted to used for a site of Gudlejang quarrying, because the rocks were easily obtainable due to the terrain characteristics, and their petrological properties made them suitable for use as Gudlejang stone.

• Economic and Environmental Geology
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• v.43 no.2
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• pp.137-148
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• 2010

The Myoungbong mine located in Boseong-gun, Jellanamdo consists of Au-Ag bearing quartz veins which filled the fissures of Bulguksa granitic rocks of Cretaceous. The tailings obtained from the Myungbong mine were used to investigate the effects of various processes, such as oxidation of primary sulfides and formation(alteration) of secondary and/or tertiary minerals, on arsenic immobilization in tailings. This study was conducted via both mineralogical and chemical methods. Mineralogical methods used included gravity and magnetic separation, ultrasonic cleaning, and instrumental analyses(X-ray diffractometry, energy-dispersive spectroscopy, and electron probe microanalyzer) and aqua regia extraction technique for soils was applied to determine the elemental concentrations in the tailings. Iron (oxy)hydroxides formed as a result of oxidation of tailings were identified as three specific forms. The first form filled in rims and fissures of primary pyrites. The second one precipitated and coated the surfaces of gangue minerals and the final form was altered into yukonites. Initially, large amounts of acid-generating minerals, such as pyrite and arsenopyrite, might make the rapid progress of oxidation reactions, and lots of secondary minerals including iron (oxy)hydroxides and scorodite were formed. The rate of pH decrease in tailings diminished, in addition, as the exposure time of tailings to oxidation environments was prolonged and the acid-generating minerals were depleted. Rather, it is speculated that the pH of tailings increased, as the contribution of pH neutralization reactions by calcite contained in surrounding parental rocks became larger. The stability of secondary minerals, such as scorodite, were deteriorated due to the increase in pH, and finally arsenic might be leached out. Subsequently, calcimn and arsenic ions dissociated from calcites and scorodites were locally concentrated, and yukonite could be grown tertiarily. It is confirmed that this tertiary yukonite which is one of arsenate minerals and contains arsenic in high level plays a crucial role in immobilizing arsenic in tailings. In addition to immobilization of arsenic in yukonites, the results indicate that a huge amount of iron (oxy)hydroxides formed by weathering of pyrite which is one of typical primary minerals in tailings can strongly control arsenic behavior as well. Consequently, this study elucidates that through a sequence of various processes, arsenic which was leached out as a result of weathering of primary minerals, such as arsenopyrite, and/or redissolved from secondary minerals, such as scorodite, might be immobilized by various sorption reactions including adsorption, coprecipiation, and absorption.

• Journal of the Mineralogical Society of Korea
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• v.30 no.3
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• pp.103-112
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• 2017

In order to transform arsenopyrite into pyrrhotite and to decrease As content by less than 2,000 mg/kg, pulp sample and non-magnetic pulp sample were heated in a microwave oven at different heating times and were separated through wet-magnetic separation. As the microwave heating time increased, the phase of pyrrhotite was extended to become arsenopyrite entirely. The melting pores and micro-cracks occurred on the pyrrhotite due to hot spot phenomenon with microwave heating. The heated raw pulp sample (As content : 19,970.13 mg/kg) and non-magnetic pulp sample (As content : 19,970.13 mg/kg) which were heated in a microwave oven for 10 minutes were separated through wet-magnetic separation and magnetic fraction containing less than 2,000 mg/kg of As content was recovered only from the heated sample of magnetic separation. It was discovered that for the sulfide complex ore with As penalty imposed on, if microwave heating and wet-magnetic separation are effectively utilized, magnetic fraction. We expect to be able to obtain ore minerals with an arsenic content below the penalty charge.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.29 no.11
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• pp.821-827
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• 2018

In devices used for re-forming osteoblasts to treat osteoporosis, a magnetic field is applied from the outside of the bone, and the minerals contained in the bone are aligned in a certain direction and undergo precessional motion. When a $90^{\circ}$ RF pulse is applied by using an RF coil, protons of minerals are brought to an excited state, and phosphorus activity promoting the deposition of osteoblasts in the bone is increased, thereby reshaping the bone. Miniaturizing the RF coil that generates a signal corresponding to the harmonic of the precessional motional frequency by means of the $90^{\circ}$ RF pulse can drastically reduce the overall size of the bone reshaping system. In this study, we propose a methodology for the miniaturization of the RF coil that can be used for osteoblast re-formation using a bone reshaping system. The capacitance of the designed RF coil is 25 pF, the inductance is approximately 100 nH, and the resonance frequency is 96 MHz. The radius of the end ring of the designed RF coil is 18 cm, and the total length of the leg is $2{\times}11.6cm$. The performance of the coil is verified through post-design measurement.

• Economic and Environmental Geology
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• v.17 no.2
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• pp.141-147
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• 1984

For the discussion of palaeogeomagnetic field direction and the movement and rotation of geotectonic blocks it is prerequisite to eliminate the secondary remanent magnetization component out of the NRM vector of given rock samples. Among various techniques alternating field and thermal demagnetization methods are most easily applicable and most widely used ones. Physical principle underlying these methods is the concept of relaxation time: Either with an action of external magnetic field or with an elevated temperature relaxation time of magnetic minerals can be drastically shortened. It has been furthermore shown experimentally that the secondary remanent magnetization can be more easily demagnetized than the primary remanent magnetization. Through careful stepwise demagnetization it should also be possible to discriminate the kind of various remanent magnetizations. In addition to the introduction to the underlying physical principles and experimental results of the alternating field and thermal demagnetization this paper gives various practical tips in earring out the demagnetization experiments. Each alternating field and thermal demagnetization instrumentation which is easily adaptable to domestic palaeomagnetic laboratories is also introduced. This paper provides a compact and practical introduction to the methods in palaeomagnetism and would be of interest to present workers and to those who want to embark on research in this field.