• Journal of Powder Materials
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• v.19 no.5
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• pp.356-361
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• 2012

The ultra-fine and less agglomerated titanium carbonitride particles were successfully synthesized by magnesiothermic reduction with low feeding rate of $TiCl_4+1/4C_2Cl_4$ solution. The sub-stoichiometric titanium carbide ($TiC_{0.5{\sim}0.6}$) particles were produced by reduction of chlorine component by liquid magnesium at $800^{\circ}C$ of gaseous $TiCl_4+1/4C_2Cl_4$ and the heat treatments in vacuum were performed for 5 hours to remove the residual magnesium and magnesium chloride mixed with produced $TiC_{{\sim}0.5}$. The final $TiC_{{\sim}0.5}N_{0{\sim}0.5}$ particle with near 100 nm in mean size and high specific surface area of $65m^2/g$ was obtained by nitrification under nitrogen gas at $1,150^{\circ}C$ for 2 hrs.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2019.05a
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• pp.184-185
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• 2019

Korea has defined fine dust as a social disaster as the problem of fine dust and air pollution becomes serious. Fine dust is classified as class one carcinogens because it is harmful to human body. When fine dusts enter the human body, they cause bronchial and skin diseases such as respiratory allergies, irritable pneumonia, asthma and atopy. As the air pollution becomes serious, the government is demanding measures to reduce fine dust. The polluted air in the outdoor is introduced into the room, thereby increasing the pollution degree of the indoor air quality. In this study, an adsorption type matrix for the improvement of indoor air quality was produced. Magnesium oxide and magnesium chloride were used as binders and diatomaceous earth was used as a adsorption material.

• Journal of Powder Materials
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• v.16 no.2
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• pp.98-103
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• 2009

The ultrafine titanium carbonitride particles ($TiC_{0.7}N_{0.3}$) below 100nm in mean size were successfully synthesized by Mg-thermal reduction process. The nanostructured sub-stoichiometric titanium carbide ($TiC_{0.7}$) particles were produced by the magnesium reduction at 1123K of gaseous $TiC_{l4}+xC_2Cl_4$ and the heat treatments in vacuum were performed for five hours to remove residual magnesium and magnesium chloride mixed with $TiC_{0.7}$. And final $TiC_{0.7}N_{0.3}$ phase was obtained by nitrification under normal $N_2$ gas at 1373K for 2 hrs. The purity of produced $TiC_{0.7}N_{0.3}$ particles was above 99.3% and the oxygen contents below 0.2 wt%. We investigated in particular the effects of the temperatures in vacuum treatment on the particle refinement of final product.

• Corrosion Science and Technology
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• v.7 no.1
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• pp.35-39
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• 2008

We have been studying application of electrochemical noise (Fluctuation) analysis for localized corrosion. Foils of Zinc, Aluminum and Magnesium were used as specimens for electrochemical cell simulating localized corrosion. These specimens were dipped in sodium chloride solutions adjusted to each exponent of Hydrogen ion concentration (pH) condition of 5.5, 10, 12 respectively. Time variations of potential and current were measured in those solutions, and simultaneously the surfaces of specimens were observed using microscope with television monitor. Two types of electrochemical cells were arranged for experiments simulated localized corrosion. The fluctuations on trendy component of short-circuited potential and short-circuited current were appeared in synchronization. It was seemed that these fluctuations result from hydrogen evolution on the aluminum active site in the crevice from the microscopic observation. In the case of zinc and magnesium, fluctuations appeared on the trendy component of the corrosion potential. Two types fluctuation were detected. First one is the fluctuation varied periodically. The second one is the random fluctuation. It was seemed that these fluctuations result from generation of corrosion products and hydrogen evolution on the active site in the crevice of zinc and magnesium from the microscopic observation.

• Journal of the Korean Home Economics Association
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• v.18 no.2
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• pp.15-21
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• 1980

Three kinds of soybean curd were prepared with three coagulants such as calcium chloride, magnesium chloride and glucono delta lactone. The mineral contents of the three soybean curds were analyzed before soaking and after various lengths of soaking(1/2 hour, 1 hour, 2 hours, and 2 hours(water changed after 1/2 hour)). Results therefrom were as follows: 1. Before the three soybean cured were soaked, their moisture contents were 79-83g/%. The ash contents were 5.04g% in the soybean curd made with CaCl_{2}4.42g/% in the soybean curd prepared with MgCl_{2} and 3.86g/% in the soybean curd coagulated by glucono delta lactone. an analysis of calcium, magnesium and phosphorous contents showed that each element had a greater concentration in the soybean curds made with divalent mineral salts than in the soybean curd made with acid. 2. Changes taking place in the mineral contents of the soybean curds according to different soaking times were examined. The mineral contents tended to decease in process of soaking time. The soybean curds showed the highest rate of mineral dissolution after one hour of soaking, and then they tended to reabsorb minerals. When the soybean curds were soaked I freshly changed water for one hour and 30 minutes, their mineral contents indicated a greater diminishing trend but no significant difference was noticed among the different kinds of soybean curd. In case coagulant has been used excessively, it is necessary to soak the bean curds for about one hour to get the coagulant dissolved.

• Advances in environmental research
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• v.10 no.1
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• pp.43-57
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• 2021

Evaluation of groundwater quality is vital due to its diverse use for several purposes. In the present study, groundwater quality and suitability from the Peshawar basin, Pakistan, were evaluated for drinking and irrigation purposes. The water samples were analysed for major cations (Ca, Mg, Na and K) and anions (chloride, bicarbonate and sulphate) along with other physicochemical parameters (pH, electrical conductivity, total dissolved solids, and total hardness). About 95% of the water samples were found to be within the WHO, US-EPA and Pak-EPA permissible levels for drinking purposes. Seventy percent (70%) of the water samples belonged to the hard water category. Irrigation water quality parameters, such as, chloride, residual sodium bicarbonate, sodium adsorption ratio, percent sodium, magnesium adsorption ratio, Kelly's ration and permeability index were evaluated which demonstrated that the groundwater was highly to moderately suitable for irrigation. A correlation study was conducted to find out the mutual associations among the variables. Piper diagram indicated the overall chemical nature of the study area was calcium-magnesium bicarbonate type. Cluster analysis revealed mutual apportionment of various parameters in the groundwater of the Peshawar basin, Pakistan.

• Journal of the korean academy of Pediatric Dentistry
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• v.27 no.1
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• pp.90-97
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• 2000

There are various kinds of factors associated with the formation of dental plaque in oral cavity such as nutrient molecules and chemical agents. The factors influencing the formation of insoluble glucan by Streptococcus sobrinus and its replication were examined on orthodontic wires. The results were as follows: 1. Insoluble glucan was well produced in the media initially adjusted at pH 7.0 than pH 5.5 or pH 8.5 like bacterial replication. 2. The synthesis of insoluble glucan and bacterial replication were significantly increased in the media containing 2.5% yeast extract. The formation of insoluble glucan was inhibited by 10 folds in the media containing 20% of sucrose than 1.25%, but the replication of bacteria was increased by 20 folds. 3. Insoluble glucan was significantly formed at a concentration of 1.0mM of calcium chloride, 40mM of potassium chloride, 0.1mM of magnesium chloride, while the replication of bacteria was little influenced by them regardless their concentration. 4. The formation of insoluble glucan and bacterial replication were significant in the media containing 10mM of sodium bicarbonate, but both were completely inhibited at 100mM or above. The production of insoluble glucan and the bacterial replication were largely decreased at 10mM of Tris while insoluble glucan was formed in abundance at 100mM of Tris. 5. The synthesis of insoluble glucan and the bacterial replication were inhibited at 10mM or above of sodium phosphate and potassium phosphate.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.11 no.2
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• pp.103-109
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• 1978

The contents of chloride ion, calcium and magnesium in Nagdong River water were determined at Mul Geum where the intake station for Busan city water is located. Samples were taken in spring and neap tides of every month from March 1914 to March 1975. The range and mean values of the chloride ion and total hardness were 5.12-39.4ppm, 11.9ppm; 27.8-70.8ppm, 49.5ppm respectively from March 1974 to January 1975. The highest values were found in the period of the widest tidal range of a year, from February 9 to March 9 in 1975, such as tile ranges and means of chloride ion and total hardness were 10.8-876 ppm, 89.8ppm : 48.0-407ppm, 89.9ppm. On several days of this period those concentrations were over the criteria of drinking water, 150 ppm in chloride and 300ppm in total hardness. Chloride ion concentration was increased with increasing of water level of the Nagdong River at Mul Geum. The patterns of the variations of tide level were similar to that of water level with delay of 2.5 hours in spring tides and 3 hours in neap tides.

• Journal of Powder Materials
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• v.17 no.2
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• pp.142-147
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• 2010

The ultrafine titanium carbonitride ($TiC_xN_y$) particles below 100 nm in mean size, including various carbon and nitrogen contents (x=0.55~0.9, y=0.1~0.5), were successfully synthesized by new Mg-thermal reduction process. Nanostructured sub-stoichiometric titanium carbide ($TiC_x$) particles were initially produced by the magnesium reduction of gaseous $TiCl_4+x/2C_2Cl_4$ at $890^{\circ}C$ and post heat treatments in vacuum were performed for 2 hrs to remove residual magnesium and magnesium chloride mixed with $TiC_x$. Finally, well C/N-controled $TiC_xN_y$ phases were successfully produced by nitrification heat treatment under normal $N_2$ gas atmosphere at $1150^{\circ}C$ for 2 hrs. The values of purity, mean particle size and oxygen content of produced particles were about 99.3%, 100 nm and 0.2 wt.%, respectively.

• Corrosion Science and Technology
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• v.9 no.2
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• pp.92-97
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• 2010

Many kinds of alternative fuels such as biodiesel, ethanol, methanol, and natural gas have been developed in order to overcome the limited deposits in fossil fuels. In some cases, the alternative fuels have been reported to cause degrade materials. The corrosion rates of metals were measured by immersion test, a kind of time consuming test because low conductivity of these fuels was not allowed to employ electrochemical tests. With twin two-electrode cell newly designed for the study, however, electrochemical impedance spectroscopy (EIS) test was successfully applied to evaluation of the corrosion resistance ($R_p$) of zinc, iron, aluminum, and its alloys in an oxidized biodiesel and gasoline/ethanol solutions and the corrosion resistance from EIS was compared with the corrosion rate from immersion test. In biodiesel, $R_p$ increased in the order of zinc, iron, and aluminum, which agreed with the corrosion resistance measured from immersion test. In addition, on aluminum showing the best corrosion resistance ($R_p$), the effect of magnesium as an alloying element was evaluated in gasoline/ethanol solutions as well as the oxidized biodiesel. $R_p$ increased with addition of magnesium in gasoline/ethanol solutions containing chloride and the oxidized biodiesel. In the mean while, in gasoline/ethanol solutions containing formic acid, Al-Mg alloy added 1% magnesium had the highest $R_p$ and the further addition of magnesium decreased $R_p$. It can be explained with the fact that the addition of more than 1% magnesium increases the passive current density of Al-Mg alloys.