• 한국수소및신에너지학회논문집
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• 제28권4호
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• pp.361-368
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• 2017

Alanate-based materials, which were known to have high hydrogen storage capacity, were synthesized by mechanochemically metathesis reaction of metal chloride and sodium alanate without solvent. XRD patterns of synthesized materials showed that metathesis reaction of cations between metal chloride and sodium alanate was progressed favorably without any solvent. Magnesium alanate showed that 3.2 wt.% of hydrogen was evolved by the thermal decomposition. The addition of a small amount of Ti to the magnesium alanate greatly reduced hydrogen evolution temperature. Also, Ti doped magnesium alanate had a good regeneration property. Both the calcium and lithium-magnesium alanate showed the lower starting temperature of the two step hydrogen evolution and fast kinetics for the hydrogen evolution.

• Geomechanics and Engineering
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• 제12권5호
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• pp.803-813
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• 2017

This study discussed the possible optimization of enzyme-mediated calcite precipitation (EMCP) as a soil-improvement technique. Magnesium chloride was added to the injection solution to delay the reaction rate and to improve the homogenous distribution of precipitated minerals within soil sample. Soil specimens were prepared in 1-m PVC cylinders and treated with the obtained solutions composed of urease, urea, calcium, and magnesium chloride, and the mineral distribution within the sand specimens was examined. The effects of the precipitated minerals on the mechanical and hydraulic properties were evaluated by unconfined compressive strength (UCS) and permeability tests, respectively. The addition of magnesium was found to be effective in delaying the reaction rate by more than one hour. The uniform distribution of the precipitated minerals within a 1-m sand column was obtained when 0.1 mol/L and 0.4 mol/L of magnesium and calcium, respectively, were injected. The strength increased gradually as the mineral content was further increased. The permeability test results showed that the hydraulic conductivity was approximately constant in the presence of a 6% mineral mass. Thus, it was revealed that it is possible to control the strength of treated sand by adjusting the amount of precipitated minerals.

• 한국식품영양과학회지
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• 제32권8호
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• pp.1233-1238
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• 2003

Chloride염 및 유기산 칼슘염을 농도별로 첨가하여 배양할 때 6종의 식중독 미생물에 대한 증식 억제 효과를 Bioscreen C(600 nm)를 이 용하여 시험 하였다. E. cereus는 sodium chloride 7% 또는 potassium chloride 9% 처리시 증식이 관찰되지 않았다. Calcium chloride는 3% 농도에서 E. coli O157:H7과 S. aureus의 증식이 관찰되지 않았다. Magnesium chloride는 5% 농도에서 B. cereus, S. Typhimurium 및 S.aureus의 증식을 억제하였다. 유기산 칼슘염의 식중독 미생물에 대한 증식 억제 효과는 calcium propionate>calcium acetate>calcium lactate 순으로 나타났다. S. Typhimurium은 calcium chloride 단독 처리 할 때는 5% 이상 농도에서 증식이 관찰되지 않았으나, calcium chloride 3%와 젖산 0.01%를 병용할 때 같은 효과가 나타나 단독 사용할 때 보다 병용에 따른 상승효과가 큰 것으로 나타났다.

• 자원리싸이클링
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• 제15권2호
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• pp.32-36
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• 2006

마그네슘은 자동차 엔진 경량화재료 및 휴대폰과 노트북 PC케이스 등 기능성 경량재료로서의 용도개발과 함께 수요가 증가하고 있다. 마그네슘 제련법은 원료광의 특성에 따라 달라지는데 크게 용융염전해법과 열환원법 두가지로 구분할 수 있다. 본 연구에서는 염화마그네슘을 사용하여 용융염전해법에 의해 전해 마그네슘을 얻고자 하였다. 흑연양극의 침지깊이를 일정하게 하고 전해전압 7V로 두가지 조성의 염욕을 비교 실험하였다. $760^{\circ}C$에서 전해 실험한 결과 $KCl/NaCl/MgCl_2$ 혼합염욕이 $KCl/NaCl/CaCl_2/CaF_2/MgCl_2$ 혼합염욕보다 전류효율 면에서 더 효과적이었다. 회수된 전해 마그네슘의 순도는 98% 이상이었다. 본 연구를 통하여 용융염 전해장치를 Scale-up 하거나 상용화시 장치설계 등에 필요한 기초자료들을 축적할 수 있었다.

• Corrosion Science and Technology
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• 제21권6호
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• pp.454-465
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• 2022

The objective of this study was to determine effects of temperatures and pH of sodium chloride solution with MgCl₂ ions on corrosion resistance of duplex stainless-steel X2CrNiMoN22-5-3 (DSS) and Ti 6Al 2Nb1Ta1Mo (Ti). Effects of sodium chloride concentration on corrosion resistance were also studied. Corrosion behavior and pitting morphology of duplex stainless steel (DSS) and Ti alloys were evaluated through potentiodynamic polarization, electrochemical impedance spectroscopy (EIS), and scanning electron microscopy (SEM). It was found that a decrease in pH significantly reduced the corrosion resistance of both alloys. Changes in chloride concentration and temperature had more substantial impact on corrosion behavior of DSS than on Ti alloys. Pitting corrosion was formed on DSS samples under all conditions, whereas crevice corrosion was developed on Ti samples with the presence of magnesium chloride at 90 ℃. In conclusion, magnesium chloride ions in an exceedingly strong acidity solution appear to interact with re-passivation process at the surface of these alloys and influence the resulting surface topography.

• Corrosion Science and Technology
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• 제12권1호
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• pp.40-49
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• 2013

Effects of magnesium and pH on corrosion of aluminum galvanically coupled to iron have studied by using potentio- dynamic and static tests for polarization curves, Mott-Schottky test for analysis of semiconductor property, and GD-AES and XPS for film analysis. Pitting potential was sensitive to magnesium as an alloying element but not to pH, while passive current was sensitive to pH but not to magnesium. It was explained with, instead of point defect model (PDM), surface charge model describing that the ingression of chloride depends on the state of surface charge and passive film at film/solution interface is affected by pH. In addition, galvanic current of aluminum electrically coupled to iron was not affected by magnesium in pH 8.4, 0.2M citrate solution but was increased by magnesium at the solution of pH 9.1. The galvanic current at pH 9.1 increased with time at the initial stage and after the exposure of about 200 minute, decreased and stabilized. The behavior of the galvanic current was related with the concentration of magnesium at the surface. It agreed with the depletion of magnesium at the oxide surface by using glow discharge atomic emission spectroscopy (GD-AES). In addition, pitting potential of pure aluminum was reduced in neutral pH solution where chloride ion maybe are competitively adsorbed on pure aluminum. It was confirmed by the exponential decrease of pitting potential with log of [$Cl^-$] around 0.025 M of [$Cl^-$] and linear decrease of the pitting potential. From the above results, unlike magnesium, alloying elements with higher electron negativity, lowering isoelectric point (ISE), are recommended to be added to improve pitting corrosion resistance of aluminum and its alloys in neutral solutions as well as their galvanic corrosion resistance in weakly basic solutions.

• 약학회지
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• 제39권1호
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• pp.68-77
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• 1995

Aluminum magnesium silicate was synthesized by reacting the mixed solutions of sodium aluminate and magnesium chloride with sodium silicate solution in this study. The optimal synthesis conditions based on the yield of the product has been attained according to Box-Wilson experimental design. It was found that the optimal synthetic conditions of aluminum magnesium silicate were as follows: Reaction temperature=$69~81^{\circ}C$; concentration of two reactants, sodium aluminate and magnesium chloride= 13.95~14.44 w/w%; molar concentration ratio of the two reactants, [NaAlO$_{2}$]/MgCl$_{2}$]=3.63~4.00; reaction time= 12~15 min; drying temp. of the product=$70~76^{\circ}C$. Aluminum magnesium silicate synthesized under the optimal synthesis condition was dispersed in 0.75, 1.0 and 1.5w/w% aqueous solution or suspension of six dispersing agents, and the Theological properties of the dispersed systems prepared have been investigated at $15^{\circ}C$ and $25^{\circ}C$ using Brookfield LVT Type Viscometer. The acid-consuming capacity of the most excellent product was 272~278 ml of 0.1N-HCl per gram of the antacid. The flow types of 5.0 w/w% aluminum magnesium silicate suspension were dependent upon the kind and concentration of dispersing agents added. The apparent viscosity of the suspension was generally increased with concentration of dispersing agents and was not significantly changed or decreased as the temperature was raised. A dispersing agent, hydroxypropyl cellulose suspension, exhibited an unique flow behavior of antithixotropy. The flow behavior of the suspension dispersed in a given dispersing agent not always coincided with that of the dispersing agent solution or suspension itself.

• Corrosion Science and Technology
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• 제18권6호
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• pp.243-252
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• 2019

The pitting corrosion and inhibition studies of AZ31B magnesium alloy were investigated in the alkaline solution (pH12) with chloride and inhibitors. The corrosion behavior of passive film with/without Cl^- in the alkaline electrolyte were conducted by polarization curve and immersion tests in the presence of various additives (inhibitors) to clarify the inhibition efficiency of pitting corrosion at higher potential region. Critical concentration of pitting corrosion for Mg alloy was evaluated with 0.005 M NaCl in 0.01 M NaOH on the anodic polarization behavior. Critical pitting of AZ31B Mg alloy in 0.01 M NaOH is a function of chlorides; E_pit = - 1.36 - 0.2 log [Cl^-]. When the Sodium Benzoate (SB) was only used as an inhibitor, a few metastable pits developed on the Mg surface by an immersion test despite no pitting corrosion on the polarization curve meaning that adsorption of SB on the surface is insufficient protection from pitting corrosion in the presence of chloride. The role of SB and Sodium Dodecylbenzenesulfonate (SDBS) inhibitors for the Mg alloy surface in the presence of chloride was suppressed from pitting corrosion to co-adsorb on the Mg alloy surface with strong formation of passive film preventing pitting corrosion.

• 한국건축시공학회지
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• 제17권4호
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• pp.341-348
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• 2017

콘크리트 포장도로는 동절기 제설제에 의한 내구성 저하가 심각한 위협으로 거론되고 있고 그 보수에도 많은 비용이 소요되고 있다. 따라서 이러한 콘크리트 포장재에 대한 적절한 보수 대책의 마련과 이에 활용될 우수한 성능의 보수 재료가 요구되고 있는 상황인데, 본 연구에서는 국내에서 개발된 인산마그네슘 세라믹(Magnesium phosphate ceramics)을 대상으로 압축강도 특성 및 염소이온 침투 저항성, 길이변화 특성을 평가하여 국내 콘크리트 포장 도로의 보수 재료로 적용 가능성을 검토하였다. 평가 결과 모르타르의 유동성은 190mm의 평범한 수준을 나타내었으나 다소 점성이 높고 재료 자체의 흐름성은 크지 않았다. 응결 시간은 12분으로 매우 빠른 경화가 이루어졌으며 이에 따라 신속한 작업이 요구되었다. 모르타르의 압축강도 성능은 2시간에 38.4MPa, 24시간에 73.8MPa, 28일에 111.0MPa로 재령 초기부터 높은 수준을 나타내었다. 염소이온 침투 저항성 시험 결과 모르타르의 경우 143 Coulombs, 콘크리트의 경우 173 Coulombs으로 매우 우수한 수준을 나타내었다. 콘크리트의 길이변화 시험 결과는 재령 40일까지 $60{\times}10^{-6}$ 이하로 완만하게 감소하였으며, 보통의 시멘트 콘크리트의 길이변화 수준과 비교할 때 1/10 이하의 수준으로 우수한 체적안정성을 확보하고 있었다. 이상과 같이 인산마그네슘 세라믹은 우수한 강도 성능과 염소이온 침투 저항성, 체적 안정성을 보유하고 있음을 확인하였고, 향후 작업 시간이나 작업성에 대한 개선이 요구되며, 현장 적용시에는 이러한 부분에 대한 주의가 필요하다.

• 한국지반공학회:학술대회논문집
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• 한국지반공학회 2003년도 봄 학술발표회 논문집
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• pp.593-596
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• 2003

The special amendment agent used in this study is mainly composed of inorganic metal salts such as sodium chloride, magnesium chloride, potassium chloride, calcium chloride, thus is friendly to the environment, and has a function of soil-cement-agent solidification. In this study, a series of laboratory and field experiments including unconfined compressive strength, permeability, pH test, constituent analysis, leaching test were carried out to analyse engineering and environmental characteristics of solidified sludge. The results of this research showed that the solidified sludge could be efficiently used in covering, filling, and planting materials.