• 제목/요약/키워드: lower amine

검색결과 110건 처리시간 0.031초

Diethanolamine 수용액에서의 Methyl Mercaptan의 흡수 (Absorption of Methyl Mercaptan into Aqueous Diethanolamine Solutions)

  • 박문기
    • 한국환경과학회지
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    • 제14권12호
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    • pp.1177-1183
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    • 2005
  • The kinetics of the reaction of methyl mercaptan into aqueous diethanolamine were studied over a range in temperature ($20^\~60{\circ}C$) and amine concentrations (0-40 $wt\%$) using a wetted-sphere absorber. The physicochemical properties needed to interpret the data are the solubility and diffusivity of methyl mercaptan in the aqueous diethanolamine solution. The density and the viscosity were obtained and correlated in the experimental range. The Wilke Chang equation was applied to estimate the diffusion coefficient. The enhancement factor was found to be high temperature is below than low temperature. It means the absorption rate with chemical reaction is lower than the physical absorption rate.

계절별 악취물질의 배출량 분석 및 평가에 관한 연구 (Seasonal Analysis of Odorous Compounds Emitted From the Chemical Plant)

  • 최재성;김재우
    • 한국환경과학회지
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    • 제16권1호
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    • pp.27-32
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    • 2007
  • In this study, the concentrations of offensive odorous compounds seasonally emitted from the chemical plant at Chongju industrial complex in Korea were determined by the analytical methods of gas chromatography, high performance liquid chromatography and uv/vis spectroscopy. The kinds of offensive odorous compounds examined are formaldehyde, acetaldehyde, butyl aldehyde, propion aldehyde, n-valeric aldehyde, iso-valeric aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide, dimethyl disulfide, trimethyl amine and ammonia. The seasonally emission levels of all odorous compounds except dimethyl sulfide at 13 sampling points of plant were lower than those of the regulation standard levels of the industrial complex in Korea. The levels were the highest in June, and lowest in December. The propion aldehyde and iso-valeric aldehyde in June and December, butyl aldehyde in December, and n-valeric aldehyde were not detected in all the three seasons at any sampling points of the plant examined. But in June, dimethyl sulfide was emitted up to 16 times than that of the regulation level.

화학공장에서 배출되는 악취규제물질의 분석 및 평가 (Analysis of Offensive Odorous Compounds Emitted From the Chemical Plants)

  • 최재성;김재우
    • 한국환경과학회지
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    • 제16권1호
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    • pp.33-38
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    • 2007
  • The concentrations of offensive odorous compounds emitted from the two chemical plants in Chongju and Yeosu industrial complex in Korea were determined by uv/vis spectroscopy, gas chromatography, and high performance liquid chromatography. The odorous compounds examined in this study are ammonia, trimethyl amine, formaldehyde, acetaldehyde, propion aldehyde, butyl aldehyde, n-valeric aldehyde, iso-valeric aldehyde, hydrogen sulfide, methyl mercaptan, dimethyl sulfide and dimethyl disulfide. The concentrations of those were determined from the 10 sampling points of the two plants, respectively. The emission concentrations of all odorous com-pounds examined in the two plants were lower than those of the regulation standard levels of industrial complex in Korea, respectively. The propion aldehyde, n-valeric aldehyde, methyl mercaptan and dimethyl disulfide in Chongju and Yeosu plants, and butyl aldehyde and iso-valeric aldehyde in Yeosu plant were not detected at any sampling points examined.

Comparison of Coverage-Dependent Adsorption Structures of Alanine and Leucine on Ge(100): Bonding Configuration and Adsorption Stability

  • 박영찬;양세나;김정원;이한길
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2011년도 제41회 하계 정기 학술대회 초록집
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    • pp.215-215
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    • 2011
  • The bonding configuration and adsorption stability of alanine and leucine adsorbed on Ge(100)-2${\times}$1 surface were investigated and compared using core-level photoemission spectroscopy (CLPES) and density functional theory (DFT) calculations. The bonding configuration, stability, and adsorption energies were evaluated for two different coverage levels. In both cases, the C 1s, N 1s, and O 1s core-level spectra at a low coverage (0.30 ML) indicated that the carboxyl and amine groups participated in bonding with the Ge(100) surface in an "O-H dissociated-N dative bonded structure". At high coverage levels (0.60 ML), both this structure and an "O-H dissociation bonded structure" were present. As a result, we found that alanine adsorbs more easily (lower adsorption energy) than leucine on Ge(100) surfaces due to less steric hindrance of side chain.

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단기간 과량의 마늘투여가 HK phenotype 진도견의 혈액상에 미치는 영향 (The Effect of Short-Term Administration of Excessive Amount of Garlic on Hematology in HK Phenotype Jindo-Dog)

  • 진태원;김홍태;장우석;오태호;송재찬;정규식;박승춘;이근우
    • 한국임상수의학회지
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    • 제18권3호
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    • pp.232-236
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    • 2001
  • It has been known that garlic, one of the essential ingredient in korean food, has a hypotensive effect. and it is reported that they lower the level of triglycerides, cholesterol and glucose in blood. Especially, the sulfur containing amine acid and the derivatives of the garlic has the counteracting effect to heavy metals. Nowadays, the garlic is known for its efficiency for the various kinds of cancer, neoplasms, hypertension, arteriosclerosis and apoplexy. But, it is reported that the intake of the excessive amount of garlic causes hemolytic anemia recently. The hemolytic anemia is more severe especially in HK phenotype dogs which has a Na-K-ATPase activity. Therefore, this study was performed to examine the effect on the blood of the HK phenotype Jindo dogs when administered the excessive amount of garlic. HK phenotype group showed the significant decrease on RBC, WBC, PCV, Hb, MCV, MCHC, GSH, Met-Hb but LK phenotype group didn't show the significant decrease.

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ON NONLINEAR ELLIPTIC EQUATIONS WITH SINGULAR LOWER ORDER TERM

  • Marah, Amine;Redwane, Hicham
    • 대한수학회보
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    • 제58권2호
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    • pp.385-401
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    • 2021
  • We prove existence and regularity results of solutions for a class of nonlinear singular elliptic problems like $$\{-div\((a(x)+{\mid}u{\mid}^q){\nabla}u\)=\frac{f}{{\mid}u{\mid}^{\gamma}}{\text{ in }}{\Omega},\\{u=0\;on\;{\partial}{\Omega},$$ where Ω is a bounded open subset of ℝℕ(N ≥ 2), a(x) is a measurable nonnegative function, q, �� > 0 and the source f is a nonnegative (not identicaly zero) function belonging to Lm(Ω) for some m ≥ 1. Our results will depend on the summability of f and on the values of q, �� > 0.

Seismic response of pipes under the effect of fluid based on exact solution

  • Liu, Yanbing;Khadimallah, Mohamed Amine;Behshad, Amir
    • Earthquakes and Structures
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    • 제22권4호
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    • pp.431-437
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    • 2022
  • One of the best choice for transportation of oil and gas at the end of rivers or seas is concrete pipelines. In this article, a concrete pipe at the end of river is assumed under the earthquake load. The Classic shell theory is applied for the modelling and the corresponding motion equations are derived by energy method. An external force induced by fluid around the pipe is asssumed in the final motion equations. For the solution of motion equations, the differential quadrature method (DQM) and Newmark method are applied for deriving the dynamic deflection of the pipe. The effects of various parameters including boundary conditions, fluid and length to thickness ratio are presented on the seismic response of the concrete pipe. The outcomes show that the clamped pipe has lower dynamic deflection with respect to simply pipe. In addition, with the effect of fluid, the dynamic defelction is increased significantly.

Seismic response of pipes under the effect of fluid based on exact solution

  • Liu, Yanbing;Khadimallah, Mohamed Amine;Behshad, Amir
    • Earthquakes and Structures
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    • 제22권5호
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    • pp.439-445
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    • 2022
  • One of the best choice for transportation of oil and gas at the end of rivers or seas is concrete pipelines. In this article, a concrete pipe at the end of river is assumed under the earthquake load. The Classic shell theory is applied for the modelling and the corresponding motion equations are derived by energy method. An external force induced by fluid around the pipe is asssumed in the final motion equations. For the solution of motion equations, the differential quadrature method (DQM) and Newmark method are applied for deriving the dynamic deflection of the pipe. The effects of various parameters including boundary conditions, fluid and length to thickness ratio are presented on the seismic response of the concrete pipe. The outcomes show that the clamped pipe has lower dynamic deflection with respect to simply pipe. In addition, with the effect of fluid, the dynamic defelction is increased significantly.

전통장류유래 Bacillus spp.의 프로바이오틱스 활성과 청국장 발효 특성 (Potential probiotics activity of Bacillus spp. from traditional soybean pastes and fermentation characteristics of Cheonggukjang)

  • 류명선;양희종;김진원;정수지;정성엽;엄정선;정도연
    • 한국식품저장유통학회지
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    • 제24권8호
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    • pp.1168-1179
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    • 2017
  • 본 연구에서는 전통발효 식품에서 균주를 분리하고 상업적으로 이용 가능하며 프로바이오틱스 특성, 우수한 발효특성 및 전통발효식품에서 문제시 되고 있는 부분을 통제하여 안전성을 갖는 Bacillus 속 균주를 선발하고자 하였다. 전통발효식품 100종에서 400종의 균주를 분리 후 선택배지를 이용하여 Bacillus 속 균주 100 종을 1차 선별하였다. 분리주를 대상으로 세포외 효소, 항균활성 등 기본 균주 특성 분석을 수행하였고, biogenic amine 생성능, 용혈성 및 유해 대사산물과 효소 생성능을 조사하여 안전성을 확인하였다. 또한 독소유전자, biogenic amine 생성 관련 유전자, 항균 펩타이드 유전자에 대한 보유 여부 조사를 통해 가장 우수한 5종의 균주를 2차 선별하였다. 5종의 선별 분리주를 대상으로 프로바이오틱스 활용 가능성을 확인하기 위해 내산성 및 내담즙성, 세포표면 소수성 분석을 실시하였다. 5종의 선별 균주 중 SRCM 100730은 pH 2.0 조건에서 4.24 log CFU/mL, 0.6% oxgall 조건에서 5.81 log CFU/mL로 높은 생존율을 나타내었고, 세포 표면 소수성 분석 결과 72.2%로 가장 높은 소수성을 지니고 있어, 잠재적 프로바이오틱스 특성이 우수한 SRCM 100730을 최종 균주로 선정하였다. 최종 선발 균주는 16S rRNA 염기서열 분석을 통해 B. amyloliquefaciens로 확인되어 B. amyloliquefaciens SRCM 100730(KCCM 11966P)로 명명하였으며, 이를 이용한 청국장을 제조하여 대두를 이용한 발효 특성을 확인하였다. 제조 청국장은 B. cereus가 검출되지 않았으며, ${\gamma}$-PGA와 세포외 효소 활성이 시판 청국장과 비교해 우수함을 확인하였다. 또한 아미노태 질소 함량은 544.02 mg%, 유리 아미노산은 26종이 검출되었고, 쓴맛을 내는 leucine, isoleucine, valine, methionine, phenylalanine이 시판 제품보다 낮으며, 중추신경계에 작용하는 억제 신경전달물질인 GABA는 시판 청국장에 비해 약 3배 높은 것을 확인하였다. 연구 결과를 토대로 SRCM 100730은 세포외 효소 및 항균활성이 우수하고, 내산성 및 내담즙성 등의 프로바이오틱스 특성이 우수하며, 청국장 발효와 같은 발효식품 산업에 활용 가능성이 높은 프로바이오틱스 소재로 기대된다.

Efficiency of Hurdle Technology Applied to Raw Cured Meat (Si-Raw)Processing

  • Chen, Ming-Tsao;Lin, Young-Sun;Tsai, Hung-Tsung;Kuo, Hsiu-Lan
    • Asian-Australasian Journal of Animal Sciences
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    • 제15권11호
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    • pp.1646-1652
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    • 2002
  • Si-Raw is a raw cured meat (raw, cured meat fermented with steamed rice) produced by the aboriginal people of Taiwan. In order to prevent food poisoning or intoxication from botulism, new methods of monitoring the production base on hurdle technology were investigated. New methods investigated incorporated citric acid, sodium hypophosphite, Monascus anka mash, plum paste or lactic acid bacteria inoculum added separately to meat with steamed rice and salt to lower the Aw (water activity) and pH values of the products to control the microbial growth. Results showed that anaerobic bacterial counts, lactic acid bacterial counts and aerobic bacterial counts for the products of all treatments were less than $10^6$, $10^5$ and $10^2cfu/g$, respectively. Sodium chloride content of all products was above 5.46%, water activity was below 0.939 and pH value was below 4.27. IMP was lower and ATP and hypoxanthine were higher. ATP concentrations were higher in the samples which contained the anka mash. Result of sensory panel test indicated that most people preferred the products with added sodium hypophosphite. Except for the fact that the content of tryptamine in the sample with Monascus anka mash was higher, the amine concentrations for all treatments were lower than those of other fermented meat products. The amino acid nitrogen content was higher in the product made from raw meat treated with citric acid, but lower in the other products. Neither Clostridium botulinum nor Trichinella spiralis were detected in any of the treatments. The result may indicate that hurdle technology is effective for hygiene and safe producing Si-Raw.