• Title/Summary/Keyword: low-oxygen

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On the Transmittances of Thin Metal Films for the Evaporating conditions (증착조건에 따른 금속박막의 광투과율)

  • 이창재;백수현
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.22 no.6
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    • pp.7-12
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    • 1985
  • The transmittances of active metal(Al), transition metals (Cr, Ti, Mn, Ni), and nobel metal(Cu) thin films were investigated. At the pressure range of $6{\times}10^{-5}$ mbr and evapora-tion rate of 0.5 -2A/sec, the metals were evaporated with $85{\AA}$ thickness or so on the slide G1ass. We found that the evaporation rates and vacuum levels strongly influence on the optical properties of thin metal films by the reaction with oxygen. Especially, the transmittances of the metals (Al, Cr, Ti, Mn, Ni) with strong oxygen affinity were able to be enhanced by the evaporating processes of low vacuum level or low evaporating rate.

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A numerical study on the effects of the asymmetric cusp magnetic field in 8 inch silicon single crystal growth by Czochralski method (초크랄스키법에 의한 8인치 실리콘 단결정 성장시 비대칭 커스프자장의 영향에 관한 연구)

  • 이승철;정형태;윤종규
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.6 no.1
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    • pp.1-10
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    • 1996
  • A numerical study was conducted on the effects of the cusp magnetic field in 8" silicon single crystal grwoth by Czochralski method. For a damping effects simulation by magnetic field, low reynolds number ${\kappa} - {\varepsilon}$ model was adopted. Symmetrci cusp magnetic field has a effect of damping streamline crystal, is lowerd with the increasing cusp magnetic field intensity. The uniformity of the oxygen concentration was improved. The asymmetirc cusp magnetic field increased the oxygen concentration however, oxygen concentration distribution in the radial direction was remained uniform. Suitable combination of symmetric and asymmetric cusp magnetic fields could give uniform and low oxygen concentration in the axial direction.tion.

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Oxidative Etching of Imprinted Nanopatterns by Combination of Vacuum Annealing and Plasma Treatment

  • Park, Dae Keun;Kang, Aeyeon;Jeong, Mira;Lee, Jae-Jong;Yun, Wan Soo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.251.1-251.1
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    • 2013
  • Combination of oxidative vacuum annealing and oxygen plasma treatment can serve as a simple and efficient method of line-width modification of imprinted nanopatterns. Since the vacuum annealing and oxygen plasma could lead mass loss of polymeric materials, either one of the process can yield a narrowed patterns. However, the vacuum annealing process usually demands quite high temperatures (${\geq}300^{\circ}C$) and extended annealing time to get appreciable line-width reduction. Although the plasma treatment may be considered as an effective low temperature rapid process for the line-width reduction, it is also suffering for the lowered controllability on application to very fine patterns. We have found that the vacuum annealing temperature can be lowered by introducing the oxygen in the vacuum process and that the combination of oxygen plasma treatment with the vacuum annealing could yield the best result in the line-with reduction of the imprinted polymeric nanopatterns. Well-defined line width reduction by more than 50% was successfully demonstrated at relatively low temperatures. Furthermore, it was verified that this process was applicable to the nanopatterns of different shapes and materials.

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The Study of Biofouling Control and Cause Material in Hybrid Process of Pure Oxygen and Submerged Membrane Bio-reactor (순산소 고율포기시스템 및 침지식 MBR융합공정에서 Biofouling 제어 및 원인물질 규명에 관한 연구)

  • Lee, Sang-Min;Kim, Mi-Hyung
    • Journal of Korean Society on Water Environment
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    • v.27 no.1
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    • pp.44-53
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    • 2011
  • Membrane bio-reactor (MBR) has several advantages over the conventional activated sludge process, including a high biomass, low sludge production, and better permeate quality. Therefore, the MBR have gained popularity for municipal and industrial wastewater treatment. However the MBR usually were used for sewage and low streng th wastewater treatment because of membrane fouling problem and limitation of oxygen transfer into biomass. In this study, the hybrid process combining MBR and pure oxygen was tested for high strength organic wastewater treatment in the COD loading range from 2 to $10kgCOD/m^3{\cdot}day$. The hybrid process, membrane coupled pure oxygen high compact reactor (MPHCR), had been operated for one year and operation parameters, the effect of COD loading, MLSS concentration and the location of membrane module were studied for membrane fouling characteristic. Also membrane resistance test and the component of foulant was analyzed to investigate what is specific foulant in the MBR.

Oxygen Barrier Coating with Carbon Interlayer on Polypropylene

  • Kim, Seong-Jin;Song, Eun-Gyeong;Jo, Gyeong-Sik;Yun, Tae-Gyeong;Mun, Myeong-Un;Lee, Gwang-Ryeol
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.210-210
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    • 2012
  • Gas barrier coating from dense thin film deposition has been one of the important applications such as food-packaging and organic display. Especially for food-packaging, plastic container has been widely used due to its low price and high through-put in mass production. However, the plastic container with low surface energy like polypropylene (PP) has been limited to apply gas barrier coating. That is because a gas barrier coating could not adhere to PP due to its too low surface energy and high porosity of PP. In this research, we applied carbon coating consisting of Si and O as an interlayer between silicon oxide (SiOx) and PP. A carbon layer was found to provide better adhesion, which was experimentally proved by oxygen transmission rate (OTR) and SEM images. However, we also found that there is a limitation in the maximum thickness of a carbon layer and SiOx film due to their high stress level. For this conflict, we obtain the optimal thickness of a carbon layer and SiOx film showing optimal gas barrier property.

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Superconducting properties of Bi-2223 tapes with various pre-annealing conditions (전열처리 조건에 따른 Bi-2223 초전도 선재에서의 특성 변화)

  • 하동우;하홍수;오상수;이동훈;윤진국;양주생;최정규;권영길
    • Progress in Superconductivity
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    • v.4 no.2
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    • pp.176-179
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    • 2003
  • A lot of efforts have been focused on the optimization of PIT parameters for Bi-2223/Ag wire. Bi-2223 superconducting wires with 55 filaments were fabricated by stacking, drawing process. Before rolling process, round wires were pre -annealed at 760 - 820 $^{\circ}C$ and low oxygen partial pressure. We confirmed that pre-annealing step was to transform Bi-2212 orthorhombic structure from Bi-2212 tetragonal structure and to reduce the formation of second phases. However Bi-2223 phases also were formed at higher than 76$0^{\circ}C$ of pre-annealing temperature. The engineering critical current densities (Je) of Bi-22231Ag tapes were sintered at low oxygen partial pressure were higher than t hat of the wires sintered at air. We could achieve 6500 A/${cm}^2$ of Je for the tape that was initially kept at slightly higher temperature than that of normal heat treatment.

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Survival, Oxygen Consumption and Stress Response of Parrotfish Oplegnathus fasciatus Exposed to Different Lower Temperature (돌돔(Oplegnathus fasciatus)의 생존, 산소소비 및 생리학적 반응에 미치는 저수온의 영향)

  • Shin, Yun Kyung;Choi, Young Jae;Kim, Won Jin
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.53 no.5
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    • pp.725-732
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    • 2020
  • The sudden drop of water temperature in winter is very threatening factor that affects the productivity of farmed fish and the management in aquafarm. In this study, we investigated the effect of low temperature on the survival, oxygen consumption and stress responses of parrotfish Oplegnathus fasciatus due to acute drop of water temperature. The survival rate of parrotfish Oplegnathus fasciatus was 5% at 6℃, 95% at 8℃ and 100% at 10℃ on the 4th day of exposure in each experimental temperature. Low-lethal temperature for 4days of parrotfish Oplegnathus fasciatus (4 day-LT50) was 6.99℃ (confidence limit, 6.55-7.42℃). Oxygen consumption rate was significantly decreased with decreasing water temperature. Temperature coefficient (Q10) was found to be 4.0 between 10℃ and 8℃ and 0.39 between 8℃ and 6℃. As a result of investigating the stress response according to the drop in water temperature, the concentration of SOD (Superoxide dismutase), cortisol, glucose, total Ig, AST (Aspartate) and ALT (Alanine aminotransferase) increased with decreasing of water temperature. This study would be useful for the management of temperature about cultured fish.

Binder-Free Synthesis of NiCo2S4 Nanowires Grown on Ni Foam as an Efficient Electrocatalyst for Oxygen Evolution Reaction

  • Patil, Komal;Babar, Pravin;Kim, Jin Hyeok
    • Korean Journal of Materials Research
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    • v.30 no.5
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    • pp.217-222
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    • 2020
  • The design and fabrication of catalysts with low-cost and high electrocatalytic activity for the oxygen evolution reaction (OER) have remained challenging because of the sluggish kinetics of this reaction. The key to the pursuit of efficient electrocatalysts is to design them with high surface area and more active sites. In this work, we have successfully synthesized a highly stable and active NiCo2S4 nanowire array on a Ni-foam substrate (NiCo2S4 NW/NF) via a two-step hydrothermal synthesis approach. This NiCo2S4 NW/NF exhibits overpotential as low as 275 mV, delivering a current density of 20 mA cm-2 (versus reversible hydrogen electrode) with a low Tafel slope of 89 mV dec-1 and superior long-term stability for 20 h in 1 M KOH electrolyte. The outstanding performance is ascribed to the inherent activity of the binder-free deposited, vertically aligned nanowire structure, which provides a large number of electrochemically active surface sites, accelerating electron transfer, and simultaneously enhancing the diffusion of electrolyte.

Gas Separation Membranes Containing $Re_6Se_8(MeCN)_6^{2+}$ Cluster-Supported Cobalt-Porphyrin Complexes

  • Park Su Mi;Won Jongok;Lee Myung-Jin;Kang Yong Soo;Kim Se-Hye;Kim Youngmee;Kim Sung-Jin
    • Macromolecular Research
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    • v.12 no.6
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    • pp.598-603
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    • 2004
  • Cellulose nitrate (CN) composite membranes, containing cobalt porphyrin (CoP) complexes self-assembled within nanometer-sized rhenium clusters (ReCoP), have been prepared and their oxygen and nitrogen gas perme­abilities were analyzed. The solubility of ReCoP and the characteristics of the corresponding composite membranes were analyzed using a Cahn microbalance, FT-IR spectroscopy, wide-angle X-ray scattering, and differential scanning calorimetry. The nitrogen permeability through the CN composite membranes decreased upon addition of ReCoP and CoP, which implies that the presence of these oxygen carrier complexes affects the structure of the polymer matrix. The oxygen permeability through the composite membranes containing small quantities of ReCoP decreased, but it increased upon increasing the concentration. The oxygen gas transport was affected by the matrix at low ReCoP concentrations, but higher concentrations of ReCoP increased the oxygen permeability as a result of its reversible and specific interactions with oxygen, effectively realizing ReCoP carrier-mediated oxygen transport.

Electrical Conductivity of a $TiO_2$ Thin Film Deposited on $Al_2O_3$ Substrates by CVD

  • Hwang, Cheol-Seong;Kim, Hyeong-Joon
    • The Korean Journal of Ceramics
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    • v.1 no.1
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    • pp.21-28
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    • 1995
  • Electrical conductivity of $TiO_2$ thin films, deposited on $Al_2O_3$ substrates by metal organic chemical vapor deposition (MOCVD), was measured by four-point probe method in a temperature range from $800^{\circ}C$ to $1025^{\circ}C$ and an oxygen partial pressure range from $2.7{\times}10^{-5}$ atm to 1 atm. In the low oxygen partial pressure region n-type conduction was dominant, but in the high oxygen partial pressure region p-type conduction behavior appeared due to substitution of Ti ions by Al ions, which were diffused from the substrate during post deposition annealing process. Electrical conductivity of the film decreases in the n-type region and increases in the p-type region as the oxygen partial pressure increases. The transition points, which show the minimum conductivity, shifted to the higher oxygen partial pressure region as the measuring temperature increased, but it shifted to lower oxygen partial pressure region with an increase in the post annealing temperature. The results were also discussed with the possible defect models.

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