Alkaline water electrolysis has been commercialized as the only large-scale method for a long time to produce hydrogen and the technology is superior to other methods such as photochemical, thermochemical water splitting, and thermal decomposition method in view of efficiency and related technical problem. However, such conventional electrolyzer do not have high electric efficiency and productivity to apply to large scale hydrogen production for energy or chemical feedstocks. Solid polymer electrolyte water electrolysis using a perfluorocation exchange membrane as an $H^+$ ion conductor is considered to be a promising method, because of capability for operating at high current densities and low cell voltages. So, this is a good technology for the storage of electricity generated by photovoltaic power plants, wind generators and other energy conversion systems. One of the most important R&D topics in electrolyser is how to minimize cell voltage and maximize current density in order to increase the productivity of the electrolyzer. A commercialized technology is the hot press method which the film type electrocatalyst is hot-pressed to soild polymer membrane in order to eliminate the contact resistance. Various technologies, electrocatalyst formed over Nafion membrane surface by means of nonelectrolytic plating process, porous sintered metal(titanium powder) or titanium mesh coated with electrocatalyst, have been studied for preparation of membrane-electrocatalyst composites. In this study some experiments have been conducted at a solid polymer electrolyte water electrolyzer, which consisted of single cell stack with an electrode area of $25cm^2$ in a unipolar arrangement using titanium mesh coated with electrocatalyst.
Transactions of the Korean Society of Pressure Vessels and Piping
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v.10
no.1
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pp.90-95
/
2014
Local wall thinning is a point of concern in almost all steel structures such as pipe lines covered with a thermal insulator made up of materials with low thermal conductivity(fiberglass or mineral wool); hence, Non Destructive Technique(NDT) methods that are capable of detecting the wall thinning and defects without removing the insulation are necessary. In this study we developed a Pulsed Eddy Current(PEC) system to detect the wall thinning of Ferro magnetic steel pipes covered with fiber glass thermal insulator and shielded with Aluminum plate. The developed system is capable of detecting the wall thickness change through an insulation of thickness 10cm and 0.4mm aluminum shielding. In order to confirm the thickness change due to wall thinning, two different sensors, a hall sensor and coil sensor were used as a detecting element. In both cases, the results show a very good change corresponding to the thickness change of the test specimen. During these experiments a carbon steel tube of diameter 210mm and a length of 620mm, which is covered with insulator of 95mm thickness was used. To simulate the wall thinning, the thickness of the tube is changed for a specified length such as 2.5mm, 5mm and 8 mm from the inner surface of the tube. A 0.4mm thick Aluminum plate was covered on the Test specimen to simulate the shielding of the insulated pipelines. For both hall sensor and coil detection methods Fast Fourier transform(FFT) was calculated using window approach and the results for the test specimen without Aluminum shielding were summarized which shows a clear identification of thickness change in the test specimen by comparing the magnitude spectra. The PEC system can detect the wall thinning under the 95 mm thickness insulation and 0.4 mm Al shielding, and the output signal showed linear relation with tube wall thickness.
To identify the differences on plant growth and yield of two rice cultivars among direct water-seeding methods broadcasting on flooded paddy surface(BF), drilling on flooded paddy surface(DF), and puddled-soil drill seeding(PD) under markedly different weather condition between 1995 and 1996. The mean air temperature for duration from May to June, early growth stage of rice in 1995 was lower $1{\sim}3^{\circ}C$ than that in normal or 1996. In 1995 the respiratory consumption index during panicle formation stage and early ripening stage was higher than those of in 1996 or normal year. Number of seedling stand among the methods of direct seeding rice appeared slightly higher in order of BF>DF>PD. Properly in Nonganbyeo, the number of seedling stand was much low in 1995 compared with in 1996. The leaf area index and shoot dry weight at early growth stage of rice plant and culm length at mature in 1995 were larger in direct water seeding rice than those of machanical transplanting rice, but in 1996. Faster ripening speed and shorter ripening period of rice crop appeared in 1996 compared to in 1995. It was due to higher growing degree-days, sunshine hours and solar radiation during rice growing season in 1996. Dongjinbyeo rice showed higher yield than Nonganbyeo which had lower ripened grains especially in 1995.
Kim, Hyung-Tae;Han, Jung-Suk;Yang, Jae-Ho;Lee, Jai-Bong;Kim, Sung-Hun
The Journal of Advanced Prosthodontics
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v.1
no.3
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pp.113-117
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2009
STATEMENT OF PROBLEM. Recently Yttrium-stabilized tetragonal zirconia polycrystal (Y-TZP) has been introduced due to superior flexural strength and fracture toughness compared to other dental ceramic systems. Although zirconia has outstanding mechanical properties, the phenomenon of decrease in the life-time of zirconia resulted from degradation in flexural strength after low temperature aging has been reported. PURPOSE. The objective of this study was to investigate degradation of flexural strength of Y-TZP ceramics after various low temperature aging treatments and to evaluate the phase stability and micro-structural change after aging by using X-ray diffraction analysis and a scanning electron microscope (SEM). MATERIAL AND METHODS. Y-TZP blocks of Vita In-Ceram YZ (Vita Zahnfabrik, Bad $S\ddot{a}ckingen$, Germany) were prepared in 40 mm (length) $\times$ 4 mm (width) $\times$ 3 mm (height) samples. Specimens were artificially aged in distilled water by heat-treatment at a temperature of 75, 100, 125, 150, 175, 200, and $225^{\circ}C$ for 10 hours, in order to induce the phase transformation at the surface. To measure the mechanical property, the specimens were subjected to a four-point bending test using a universal testing machine (Instron model 3365; Instron, Canton, Mass, USA). In addition, X-ray diffraction analysis (DMAX 2500; Rigaku, Tokyo, Japan) and SEM (Hitachi s4700; Jeol Ltd, Tokyo, Japan) were performed to estimate the phase transformation. The statistical analysis was done using SAS 9.1.3 (SAS institute, USA). The flexural strength data of the experimental groups were analyzed by one-way analysis of variance and to detect statistically significant differences ($\alpha$= .05). RESULTS. The mean flexural strength of sintered Vita In-Ceram YZ without autoclaving was 798 MPa. When applied aging temperature at below $125^{\circ}C$ for 10 hours, the flexural strength of Vita In-Ceram YZ increased up to 1,161 MPa. However, at above $150^{\circ}C$, the flexural strength started to decrease. Although low temperature aging caused the tetragonal-to-monoclinic phase transformation related to temperature, the minimum flexural strength was above 700 MPa. CONCLUSION. The monoclinic phase started to appear after aging treatment above $100^{\circ}C$. With the higher aging temperature, the fraction of monoclinic phase increased. The ratio of monoclinic/tetragonal + monoclinic phase reached a plateau value, circa 75% above $175^{\circ}C$. The point of monoclinic concentration at which the flexural strength begins to decrease was between 12% and 54%.
Kim, Jinse;Park, Jong Woo;Park, Seokho;Choi, Dong Soo;Choi, Seung Ryul;Kim, Yong Hoon;Lee, Soo Jang;Park, Chun Wan;Han, Gui Jeung;Cho, Byoung-Kwan
Journal of Biosystems Engineering
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v.41
no.2
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pp.108-115
/
2016
Purpose: Radio frequency (RF) heating is a promising thawing method, but it frequently causes undesirable problems such as non-uniform heating. This can occur because of the food shape, component distribution, and initial temperature differences between food parts. In this study, RF heating was applied to the thawing of cylindrically shaped pork sirloin by changing the shape of electrodes and the surrounding temperature. Methods: Curved electrodes were utilized to increase the thawing uniformity of cylindrically shaped frozen meat. Pork sirloin in the shape of a half-circle column was frozen in a deep freezer at $-70^{\circ}C$ and then thawed by RF heating with flat and curved electrodes. In order to prevent fast defrosting of the food surface by heat transfer from air to the food, the temperature of the thawing chamber was varied by -5, -10, and $-20^{\circ}C$. The temperature values of the frozen pork sirloin during RF thawing were measured using fiber-optic thermo sensors. Results: After multiple applications of curved electrodes resembling the food shape, and a cooled chamber at $-20^{\circ}C$ the half-cylindrically shaped meat was thawed without surface burning, and the temperature values of each point were similarly increased. However, with the parallel electrode, the frozen meat was partially burned by RF heating and the temperature values of center were overheated. The uniform heating rate and heat transfer prevention from air to the food were crucial factors for RF thawing. In this study, these crucial factors were accomplished by using a curved electrode and lowering the chamber temperature. Conclusions: The curved shape of the electrode and the equipotential surface calculated from the modeling of the parallel capacitor showed the effect of uniform heating of cylindrically shaped frozen food. Moreover, the low chamber temperature was effective on the prevention of the surface burning during RF thawing.
Kim, Myung-Chan;Heo, Cheol-Ho;Park, Jin-Hyo;Park, Seung-Jun;Han, Jeon-Geon
Proceedings of the Korean Vacuum Society Conference
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1999.07a
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pp.122-122
/
1999
Graphite with its advantages of high thermal conductivity, low thermal expansion coefficient, and low elasticity, has been widely used as a structural material for high temperature. However, graphite can easily react with oxygen at even low temperature as 40$0^{\circ}C$, resulting in CO2 formation. In order to apply the graphite to high temperature structural material, therefore, it is necessary to improve its oxidation resistive property. Silicon Carbide (SiC) is a semiconductor material for high-temperature, radiation-resistant, and high power/high frequency electronic devices due to its excellent properties. Conventional chemical vapor deposited SiC films has also been widely used as a coating materials for structural applications because of its outstanding properties such as high thermal conductivity, high microhardness, good chemical resistant for oxidation. Therefore, SiC with similar thermal expansion coefficient as graphite is recently considered to be a g행 candidate material for protective coating operating at high temperature, corrosive, and high-wear environments. Due to large lattice mismatch (~50%), however, it was very difficult to grow thick SiC layer on graphite surface. In theis study, we have deposited thick SiC thin films on graphite substrates at temperature range of 700-85$0^{\circ}C$ using single molecular precursors by both thermal MOCVD and PEMOCVD methods for oxidation protection wear and tribological coating . Two organosilicon compounds such as diethylmethylsilane (EDMS), (Et)2SiH(CH3), and hexamethyldisilane (HMDS),(CH3)Si-Si(CH3)3, were utilized as single source precursors, and hydrogen and Ar were used as a bubbler and carrier gas. Polycrystalline cubic SiC protective layers in [110] direction were successfully grown on graphite substrates at temperature as low as 80$0^{\circ}C$ from HMDS by PEMOCVD. In the case of thermal MOCVD, on the other hand, only amorphous SiC layers were obtained with either HMDS or DMS at 85$0^{\circ}C$. We compared the difference of crystal quality and physical properties of the PEMOCVD was highly effective process in improving the characteristics of the a SiC protective layers grown by thermal MOCVD and PEMOCVD method and confirmed that PEMOCVD was highly effective process in improving the characteristics of the SiC layer properties compared to those grown by thermal MOCVD. The as-grown samples were characterized in situ with OES and RGA and ex situ with XRD, XPS, and SEM. The mechanical and oxidation-resistant properties have been checked. The optimum SiC film was obtained at 85$0^{\circ}C$ and RF power of 200W. The maximum deposition rate and microhardness are 2$mu extrm{m}$/h and 4,336kg/mm2 Hv, respectively. The hardness was strongly influenced with the stoichiometry of SiC protective layers.
Journal of the Korea institute for structural maintenance and inspection
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v.24
no.5
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pp.103-110
/
2020
In the recent seismic design code KDS 41 17 00, selection and modification procedures of ground motions which are used for nonlinear dynamic analyses were adopted. However, its practical applications are still limited due to the lack of literatures. This paper introduces case studies which used site-response analyses to select and modify ground motions for nonlinear dynamic analyses. Based on the case studies, design criterion for site-response analyses were reviewed thoroughly in the viewpoint of practical applications. It was found that design requirements related with bedrock motions are too conservative that ground motions are selected and modified in the excessive manner. It is especially true for low-rise building structures with period ranges including acceleration-sensitive regions. Even though surface motions have shown appropriate responses, such building structures have to re-select and re-modify ground motions based on pre-analysis procedures rather than post-ones according to the current seismic design code. Also, it was observed that building structures with soft soils under strong ground motions need more comprehensive investigations on soil properties and efficient analysis methods in order to perform site-response analyses. This is due to the fact that lack of reliabilities on soil properties and analysis methods could result in unstable site-responses.
Background: The purpose of this study was to investigate the effect of Plank exercise on unstable support surfaces on flexibility, abdominal muscle thickness and pain in patients with chronic back pain. Design: Randomized controlled trial. Methods: This study was performed on 16 patients with chronic back pain of ◯◯ military unit. Sixteen subjects were randomly assigned into two groups, an upper extremity trainer group (group I, n=8) and a lower extremity trainer group (group II, n=8). The subjects in group I carried out Flank exercise applying the stability trainer to their upper extremities and ones in group II carried out the same exercise applying the stability trainer to their lower extremities for 4 weeks. In order to ascertain the difference between two groups, flexibility, abdominal muscle thickness and pain were measured before and after the exercise. The flexibility was measured by sit and reach test, the thickness of the abdominal muscle was measured by using ultrasonic imaging equipment, and the pain was measured by the visual analogue scale. A paired t-test was utilized to compare changes in pain, abdominal muscle thickness and flexibility before and after flank exercise on unstable support surfaces. Analysis of Covariance (ANCOVA) was performed for ascertaining the significant differences between groups. The significance level was set by α=.05. Results: 1) The flexibilities of two groups were increased after the exercise (p<0.05). 2) In both groups, the thicknesses of rectus abdominis, external oblique abdominis, internal oblique abdominis, and transverse abdominis were all increased after the exercise (p<0.05). 3) The pains in both groups were decreased after the exercise (p<0.05). 4) In the comparisons of two groups, there were no differences in the flexibility, thickness of external oblique abdominis, internal oblique abdominis and transverse abdominis and pain (p>0.05). Whereas only thickness of Rectus abdominis was larger in the group I than in the group II (p<0.05). Conclusion: Plank exercise on the unstable support surface for 4 weeks resulted in increased flexibility, abdominal muscle thickness and pain reduction in patients with chronic back pain. Therefore, it is considered that performing flank exercise on the unstable supporting surface is suitable for the reduction of the pain in patients with chronic back pain. However, in this study, it is considered that continuous and diverse studies are needed because there was not a large difference between the groups when the upper or lower limbs are provided unstable support surfaces.
Journal of the Korean Applied Science and Technology
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v.34
no.4
/
pp.727-736
/
2017
In this study, the method of evaluation of moisturizing ability of cosmetics using specimens was studied as an alternative method of clinical tests. Cosmetic spreadability, surface drying, and moisture loss rate of four specimens (Japanese cake (Maru mochi), Garaetteok, wheat flour, and agar) were evaluated. Also, the water loss rate of the specimens and the transepidermal waterloss were analyzed for 10 kinds of lip make-up products (5 kinds of lipstick, 3 kinds of lip balm, 2 kinds of lip gloss). The moisture loss rate (moisture evaporation sensitivity) of the agar specimen was highest in the order of agar> Garaetteok> Japanese cake> wheat flour. Agar specimens are the most suitable in terms of spreadability, surface crack, and raw material supply. Containers for the preparation of agar specimens are suitable for plastic materials with low heat transfer, which can produce convex, smooth surface specimens. In the evaluation of moisturizing ability of lip makeup products, there was a strong correlation between the water loss rate and the transepidermal waterloss rate measured with agar specimens. These results show that the proposed method can be used as one of the useful alternative test methods.
The amount of carbon dioxide ($CO_2$) released while producing building materials is substantial and has been targeted as a leading contributor to global climate change. One of the most typical methods of reducing $CO_2$ in building materials is the addition of slag and fly ash, like pozzolan material another method is to reduce $CO_2$ production by developing carbon negative cement. MgO-based cement from the low-temperature calcination of magnesite required less energy and emitted less $CO_2$ than the manufacturing of Portland cements. It is also believed that adding reactive MgO to Portland-pozzolan cements can improve their performance and also increase their capacity to absorb atmospheric $CO_2$. In this study, basic research on magnesia cement using $MgCO_3$ and magnesium silicate ore (serpentine) as the main starting materials, as well as blast furnace slag for the mineral admixture, was carried out for industrial waste material recycling. In order to increase the overall hydration activity, $MgCl_2$ was also added. In the case of the addition of $MgCl_2$as accelerating admixture, there was a promoting effect on the compressive strength. This was found to be due to the production of needle-like dense Mg-Cl hydrates. Mgnesia cement has a high viscosity due to its high specific surface area therefore, when the PC-based dispersing agent was added at a level of more than 1.0%, it had the effect of improving fluidity. In particular, the addition of $MgCl_2$ in magnesia cement using $MgCO_3$and magnesium silicate ore (serpentine) as main starting materials led to a lower expansion ratio and an increase in the freeze-thaw resistance finally, the addition of $MgCl_2$ as accelerating admixture led to good overall durability.
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