• Title/Summary/Keyword: low temperature composition

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Species composition and community structure of fish by shrimp beam trawl between Sacheon Bay and coastal waters off Namhae, Korea (사천만과 남해연안에서 새우조망에 어획된 어류의 종조성 및 군집구조)

  • SONG, Se Hyun;JEONG, Jae Mook;LEE, Seung Hwan;KIM, Do Hoon
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.55 no.3
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    • pp.217-232
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    • 2019
  • It was turned out by shrimp beam trawl monthly survey from March, 2015 to February, 2016 that different species composition and abundance of the fish assemblages in Sacheon Bay and coastal waters off Namhae, Korea were compared. As a result of monthly measured sea temperature and salinity of Sacheon Bay and coastal waters off Namhae, sea temperature of both areas was changed seasonally; however, differences in sea temperature occurred during certain periods depending on the region. Salinity was generally low in Sacheon Bay affected by fresh water, and both areas was low in summer and high in winter. A total of 73 species representing 37 families were collected in Sacheon Bay. The dominant fish species in terms of numbers and biomass were Liparis tanakae, $23,077inds./km^2$, $332.1kg/km^2$. A total of 91 fish species representing 49 families were collected in coastal waters off Namhae. The dominant fish species in terms of numbers were Leiognathus nuchalis, $139,683inds./km^2$ and biomass were Chelidonichthys spinosus, $1,078.6kg/km^2$. Analysis of dendrogram of the clustering showed that Sacheon Bay and coastal waters off Namhae were distinctive featured (global R = 0.691, p = 0.017). And except of summer season (July-October), there was a distinctive feature seasonally (global R = 0.844, p = 0.001). The fish species that appeared in common in both areas, where fish species caught in Sacheon Bay, an important inner bay,were smaller than those caught in coastal waters off Namhae appeared. It presented that Sacheon Bay plays a more important role in spawning and nursery ground for fisheries resource than coastal waters off Namhae, Korea.

The Roles of Electrolyte Additives on Low-temperature Performances of Graphite Negative Electrode (전해액 첨가제가 흑연 음극의 저온특성에 미치는 영향)

  • Park, Sang-Jin;Ryu, Ji-Heon;Oh, Seung-Mo
    • Journal of the Korean Electrochemical Society
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    • v.15 no.1
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    • pp.19-26
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    • 2012
  • SEI (solid electrolyte interphase) layers are generated on a graphite negative electrode from three different electrolytes and low-temperature ($-30^{\circ}C$) charge/discharge performance of the graphite electrode is examined. The electrolytes are prepared by adding 2 wt% of vinylene carbonate (VC) and fluoroethylene carbonate (FEC) into a standard electrolyte solution. The charge-discharge capacity of graphite electrode shows the following decreasing order; FEC-added one>standard>VC-added one. The polarization during a constant-current charging shows the reverse order. These observations illustrate that the SEI film resistance and charge transfer resistance differ according to the used additives. This feature has been confirmed by analyzing the chemical composition and thickness of three SEI layers. The SEI layer generated from the standard electrolyte is composed of polymeric carbon-oxygen species and the decomposition products ($Li_xPF_yO_z$) of lithium salt. The VC-derived surface film shows the largest resistance value even if the salt decomposition is not severe due to the presence of dense film comprising C-O species. The FEC-derived SEI layer shows the lowest resistance value as the C-O species are less populated and salt decomposition is not serious. In short, the FEC-added electrolyte generates the SEI layer of the smallest resistance to give the best low-temperature performance for the graphite negative electrode.

Reaction Characteristics of Water Gas Shift Catalysts in Various Operation Conditions of Blue Hydrogen Production Using Petroleum Cokes (석유코크스 활용 블루수소생산을 위한 Water Gas Shift 촉매의 조업조건에 따른 반응특성)

  • Park, Ji Hye;Hong, Min Woo;Yi, Kwang Bok
    • Clean Technology
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    • v.28 no.1
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    • pp.1-8
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    • 2022
  • To confirm the applicability of the water gas shift reaction for the production of high purity hydrogen for petroleum cokes, an unutilized low grade resource, Cu/ZnO/MgO/Al2O3 (CZMA), catalyst was prepared using the co-precipitation method. The prepared catalyst was analyzed using BET and H2-TPR. Catalyst reactivity tests were compared and analyzed in two cases: a single LTS reaction from syngas containing a high concentration of CO, and an LTS reaction immediately after the syngas passed through a HTS reaction without condensation of steam. Reaction characteristics in accordance with steam/CO ratio, flow rate, and temperature were confirmed under both conditions. When the converted low concentration of CO and steam were immediately injected into the LTS, the CO conversion was rather low in most conditions despite the presence of large amounts of steam. In addition, because the influence of the steam/CO ratio, temperature, and flow rate was significant, additional analysis was required to determine the optimal operating conditions. Meanwhile, carbon deposition or activity degradation of the catalyst did not appear under high CO concentration, and high CO conversion was exhibited in most cases. In conclusion, it was confirmed that when the Cu/ZnO/MgO/Al2O3 catalyst and the appropriate operating conditions were applied to the syngas composition containing a high concentration of CO, the high concentration of CO could be converted in sufficient amounts into CO2 by applying a single LTS reaction.

Homogeneous Preparation of Barium Titanate by Dimethyl Oxalate in Ethanol Solution (에탄올 용액에서 Dimethyl Oxalate에 의한 티탄산바륨의 균일한 제조)

  • Ryu, Kyoung-Youl;Lim, Myoung-Hee;Huh, Woo-Young;Lee, Chul
    • Analytical Science and Technology
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    • v.12 no.5
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    • pp.382-386
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    • 1999
  • Spherical particles of barium titanyl oxalate(BTO) were homogeneously precipitated by thermal decomposition of dimethyl oxalate in hydrochloric mixture solutions of water and ethanol. The experimental parameters such as composition of the mixture solvents. the eoncentration of hydrochloric acid and reaction temperature had the paramount effect on the size of panicles collected from the bottom of the reaction vessel at the aging time of 120 min and the composition of BTO. Stoichiometric BTO powders were obtained under certain conditions as relatively low alcohol content in the mixtures, high chloride concentration and high temperature, Monosized, submicrometer, but titanium excess particles were obtained under certain reverse conditions.

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Microstructure and Dielectric Properties in $40Pb(Mg_{1/3}Nb_{2/3})O_3-30PbTiO_3-30Pb(Mg_{1/2}W_{1/2})O}3$ Ceramics with Excess $91PbO-9WO_3$ Addition ($91PbO-9WO_3$가 과잉첨가된 $40Pb(Mg_{1/3}Nb_{2/3})O_3-30PbTiO_3-30Pb(Mg_{1/2}W_{1/2})O}3$계 세라믹스의 미세구조와 유전특성)

  • 길영배;이응상
    • Journal of the Korean Ceramic Society
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    • v.34 no.3
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    • pp.281-288
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    • 1997
  • The effects of 0 to 6 mol% excess 91PbO-9WO3 addition on the microstructure and the dielectric pro-perties in 40Pb(Mg1/3Nb2/3)O3-30PbTiO3-30Pb(Mg1/2W1/2)O3 ternary system were investigated. Excess 91PbO-9WO3 addition enhanced densification at relatively lower temperature due to the formation of liquid phase. The dielectric constant of the specimen with standard composition was 16,400 and that of specimen with 1 mol% excess additive was the maximum of 18,500. And more than 2 mol% excess addition decreased dielec-tric constant. Specimens with 2~4 mol% 91PbO-9WO3 addition showed dual peak maxima in the tem-perature dependence of dielectric constant. In the specimens which have more than 5 mol% excess addition a new phase with W-rich composition was formed at grain boundary.

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Effects of Fuel Blending Ratio and Oxygen Concentration on Auto-ignition Characteristics of n-Decane/Ethanol Blended Fuels (연료 혼합비율 및 산소농도가 노말데케인/에탄올 혼합연료의 점화특성에 미치는 영향)

  • Oh, Chae Ho;Kang, Ki Joong;Choi, Gyung Min
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.11
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    • pp.749-757
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    • 2017
  • To cope with the development of alternative fuels and international environmental regulations, this study provides a numerical analysis of the effects of composition and temperature changes of n-decane and ethanol on auto-ignition characteristics. CHEMKIN-PRO is used as the analysis program and the LLNL model is used as the reaction model. The numerical results show that the ignition delay time increases as the mole fraction of ethanol increases for temperatures below 1000 K, where low temperature reactions occur. Because of the high octane number of ethanol, the high percentage of ethanol delays the increase in the concentration of OH radicals that cause ignition. The oxygen concentration in the mixture is changed to apply the exhaust gas recirculation and a numerical analysis is then performed. As the oxygen concentration decreases, the total ignition delay time increases because the nitrogen gas acts as a thermal load in the combustion chamber.

Modern Dinoflagellate Cysts Distribution off the Eastern Part of Geoje Island, Korea

  • Shin, Hyeon-Ho;Yoon, Yang-Ho;Matsuoka, Kazumi
    • Ocean Science Journal
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    • v.42 no.1
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    • pp.31-39
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    • 2007
  • Distributional characteristics of dinoflagellate cysts in surface sediments were investigated in relation to environmental factors in the eastern part of Geoje Island, Korea. Samples were collected from 10 stations in February of 2004 and water temperature and salinity were measured in February, May, September and November of 2004. Total 30 taxa of dinoflagellate cysts were identified representing 19 genera, 28 species and 2 unidentified species. Among these dinoflagellate cysts, Brigantedinium spp. of which relative proportion in th e total dinoflagellate cysts was 23.5%, was the most abundant at all stations except St. 1, and was followed by Spiniferites bulloideus (8.6%), Lingulodinium machaerophorum (8.2%) and Diplopsalis lenticula (6.7%). In addition, ellipsoidal cysts of the genus Alexandrium (Alexandrium catenella - tamarense type) and Gymnodinium catenatum, known to be causative organisms for PSP, occurred with high concentrations. Scrippsiella trochoidea was also found; however, its cyst concentration was low. Generally, species composition in the study area was similar to these reported from Jinhae Bay and Busan Harbor and several dinoflagellate cysts reflected the eutrophic condition. Cyst distribution in th e eastern part of Geoje Island seems to be influenced by the Tsushima Warm Current flowing from the southwest. The mean water temperature was $12.0^{\circ}C$ in February, $14.7^{\circ}C$ in May, $20.9^{\circ}C$ in September and $17.2^{\circ}C$ in November, which was most favorable for Alexandrium spp. growth. The abundances of dinoflagellate cysts rang e d from 528 to 2,834 cysts/g dry sediment. Higher concentrations were recognized in sediments of west area of the Jisimdo than at other stations. The cyst composition of this area was closely related to these of Jinhae Bay and Busan Harbor from which currents flow into this area. Higher cyst concentration in the west area of Jisimdo might be due to formation of the gyre.

Preparation of $Pb(Zr,\;Ti)O_3$ thin films by MOCVD using ultrasonic spraying (초음파분무를 이용한 MOCVD법에 의한 $Pb(Zr,\;Ti)O_3$박막의 제조)

  • Kim, Dong-Young;Lee, Choon-Ho;Park, Sun-Ja
    • Korean Journal of Materials Research
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    • v.2 no.1
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    • pp.43-51
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    • 1992
  • Thin films of )$Pb(Zr, \;TiO_3$ are fabricated by MOCVD using ultrasonic spraying. The films having perovskite structure are made at low deposition temperature, $300-450^{\circ}C$. The phase and composition of the films vary with the composition of the starting solution and the deposition temperature. Dielectric constant of the films is 187 at 1MHz. Ferroelectric hysterysis loop measurements indicate a remanant polarization of $5.5{\mu}C/cm^2$, and coercive field of 65kV/cm. Resistivity of thin films is about $10^{11}{\Omega}cm$ and the breakdown electric field abort 35kV/cm.

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Short-term effects of elevated CO2 on periphyton community in an artificially constructed channel

  • Park, Hye-Jin;Kwon, Dae-Ryul;Kim, Baik-Ho;Hwang, Soon-Jin
    • Journal of Ecology and Environment
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    • v.40 no.1
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    • pp.12-19
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    • 2016
  • Background: Direct impact of inorganic carbon (i.e., carbon dioxide ($CO_2$)) on the periphyton community is important to understand how and to what extent atmospheric conditions can affect the structure and dynamics of these communities in lotic systems. We investigated the influence of elevated $CO_2$ concentration on the periphyton community in the artificially constructed channels during the winter period. The channels made of acrylic paneling were continuously supplied with surface water discharged from a small reservoir, which was supported with ground water, at a flow rate of 5 L/min, and water temperature ranging $4-5^{\circ}C$. The effects of elevated $CO_2$ concentrations (790 ppm) were evaluated in comparison with the control (395 ppm $CO_2$) by analyzing pH, water carbon content and nutrients in water, periphyton composition and biomass, chlorophyll-a, ash-free dry-matter at 2-day intervals for 10 days. Results: After the addition of $CO_2$, significant decreases of pH, $NH_3-N$, and $PO_4-P$ (p < 0.05) and increases of chlorophyll-a, ash-free dry-matter, and the cell density of periphyton (p < 0.01) were observed, whereas the species composition of periphyton and water carbon content did not change. Conclusions: These results suggest that elevated $CO_2$ in flowing water system with low temperature could facilitate the growth of periphyton resulting in biomass increase, which could further influence water quality and the consumers throughout the food web.

Evaluation on Effects of Composting and Pelleting on Nutritional Composition of Broiler Litter and Feasibility of Use of a Small-scale Pelletizer (호기발효와 펠렛 처리가 육계분의 사료영양적 성분에 미치는 영향 및 소형 펠렛기의 육계분 성형 가능성 평가)

  • 곽완섭
    • Journal of Animal Environmental Science
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    • v.8 no.3
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    • pp.191-198
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    • 2002
  • This study was conducted to determine changes in internal temperature and chemical composition during the composting of broiler litter(BL) and to evaluate the feasibility of use of a small-scale pelletizer for the pelleting of composted BL. BL was composted for 4 weeks in an wooden cell with a size of 1 m length $\times$ 1 m width $\times$ 1.2 m height. Internal temperature reached to peak(68$^{\circ}C$) at the fourth day and thereafter gradually reduced. Among chemical components in BL, composting reduced organic matter content and increased dry matter and indigestible protein(ADF-CP) contents. When BL was pelleted using an economical small-scale pelletizer, the proper die diameter was 8~18 mm and the proper moisture content of composted BL was 20~25%. Beyond these proper conditions, addition of heat and pressure or pellet aids may be necessary. Pelleting of BL resulted in nearly threefold increase of bulk density, significant moisture evaporation, and little change in chemical components except for increased indigestible protein. In conclusion, BL may be converted into a feed with low to medium nutrition by the composting and pelleting process.

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