• Transactions of the Korean Society of Machine Tool Engineers
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• v.10 no.6
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• pp.102-108
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• 2001

To prevent green house effect and destruction of an ozone layer, an ozone destruction potential(OBP) must be zero and a refrigerant for low global warming potential(GWP) is needed. HFC-l34a, in which hydrogen is mixed instead of chlorine is a refrigerant used for automobile conditioners and its destruction potential is ecologically zero. However, it is not consid- ered as a perfect substitutive refrigerant as its GWP is high. It is studied refrigerant mixtures in which HFC-l52a and $CF_3 I$ in HFC-l52a with low GWP and zero ODP are mixed by experimentally and concluded as follows: 1) With the variation of speed of compressor outside temperature and flow rate, 7he heat of evaporator and compressor and coefficient of perfor- mance was varied, and influenced the air conditioner. 2) The pressure of evaporator was decreased with increasing the speed of compressor and the pressure of evaporator with the refrigerant HFC-l52a was higher 24% than that of azotrope refrigerant mixed with $CF_3 I$

• Transactions of the Korean hydrogen and new energy society
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• v.23 no.4
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• pp.382-389
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• 2012

Power generation cycle using ammonia-water mixture as working fluid has attracted much attention because of its ability to efficiently convert low-temperature heat source into useful work. If an ammonia-water power cycle is combined with a power cycle using liquefied natural gas (LNG), the conversion efficiency could be further improved owing to the cold energy of LNG at $-162^{\circ}C$. In this work parametric study is carried out on the thermodynamic performance of a power cycle consisted of an ammonia-water Rankine cycle as an upper cycle and a LNG cycle as a bottom cycle. As a driving energy the combined cycle utilizes a low-temperature heat source in the form of sensible heat. The effects on the system performance of the system parameters such as ammonia concentration ($x_b$), turbine 1 inlet pressure ($P_{H_1}$) and temperature ($T_{H_1}$), and condenser outlet temperature ($T_{L_1}$) are extensively investigated. Calculation results show that thermal efficiency increases with the increase of $P_{H_1}$, $T_{H_1}$ and the decrease of $T_{L_1}$, while its dependence on $x_b$ has a downward convex shape. The changes of net work generation with respect to $P_{H_1}$, $T_{H_1}$, $T_{L_1}$, and $x_b$ are roughly linear.

• The Bulletin of The Korean Astronomical Society
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• v.43 no.2
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• pp.55.1-55.1
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• 2018

Theoretical models of reionization require that approximately 10% of the Lyman Continumm (LyC) photons escape from their host dark matter haloes and re-ionize neutral hydrogen in the Universe. However, observations of Lyman break galaxies (LBGs) at z~3 report much lower escape fractions of $f_{esc}{\sim}1%$. In an attempt to understand the discrepancy, we perform radiation-hydrodynamics simulations of isolated disk galaxies using RAMSES-RT with high resolution (maximum ~ 9 pc). We find that $f_{esc}$ is ~6% on average for the reference run ($Z=0.1Z{\odot}$), whereas the fraction decreases to ~1% in the case of metal-rich disk ($Z=1Z{\odot}$). This happens because dense metal-poor gas clumps are disrupted early due to strong Lya pressure and supernova explosions, while star particles are trapped for a longer period of time in the metal-rich environments. We also find that $f_{esc}$ is still significant (~4%) even when the amount of metal-poor gas is increased by a factor of 5. Our preliminary results suggest that the low escape fractions in LBGs may be better explained by (locally) metal-enriched gas near young stars than high gas fractions in galaxies.

• Transactions of the Korean hydrogen and new energy society
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• v.25 no.1
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• pp.19-27
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• 2014

Mg hydride has a high hydrogen capacity (7.6%), at high temperature, and is a lightweight and low cost material, thus it a promising hydrogen storage material. However, its high operation temperature and very slow reaction kinetics are obstacles to practical application. In order to overcome these disadvantages of Mg hydride, graphene powder was added to it. The addition of graphene has been shown to reduce the operating temperature of dehydrogenation. Moreover, in this report the environmental aspects of $MgH_x$-Graphene composites are investigated by means of the environmental life cycle assessment (LCA) method. $MgH_x$-Graphene mixture was prepared by hydrogen induced mechanical alloy (HIMA). The synthesized powder was characterized by XRD(X-ray Diffraction). The hydrogenation behaviors were evaluated by using a Sievert's type automatic PCT apparatus. Such evaluation of Materials also conducted in the LCA. From the result of P-C-T(Pressure-Composition-Temperature) curves, the $MgH_x$-3wt.% graphene composite was evaluated as having a 5.86wt.% maximum hydrogen storage capacity, at 523K. From absorption kinetic testing, the $MgH_x$-7wt.% graphene composite was evaluated as having a maximum 6.94wt.%/ms hydrogen absorption rate, at 573K. Environment evaluation results for the $MgH_x$-graphene composites and other materials indicated environmental impact from the electric power used and from the materials themselves.

• Journal of the Korean Society of Marine Environment & Safety
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• v.28 no.4
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• pp.610-619
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• 2022

Hydrogen is emerging as an alternative fuel for eco-friendly ships because it reacts with oxygen to produce electrical energy and only water as a by-product. However, unlike regular fossil fuels, hydrogen has a material with a high risk of explosion due to its low ignition point and high flammability range. In order to safely use hydrogen in ships, it is an essential task to study the flow characteristics of hydrogen leakage and diffusion need to be studied. In this study, a numerical analysis was performed on the effect of leakage, ventilation, etc. on ventilation performance when hydrogen leaks in an enclosed space such as inside a ship. ANSYS CFX ver 18.1, a commercial CFD software, was used for numerical analysis. The leakage rate was changed to 1 q, 2 q, and 3 q at 1 q = 1 g/s, the ventilation rate was changed to 1 Q, 2 Q and 3 Q at 1 Q = 0.91 m/s, and the ventilation method was changed to type I, type II, type III to analyze the ventilation performance was analyzed. As the amount of leakage increased from 1 q to 3 q, the HMF in the storage room was about 2.4 to 3.0 times higher. Furthermore, the amount of ventilation to reduce the risk of explosion should be at least 2 Q, and it was established that type III was the most suitable method for the formation of negative pressure inside the hydrogen tank storage room.

• Journal of the Korean Society of Marine Environment & Safety
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• v.17 no.4
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• pp.419-427
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• 2011

The characteristics for hydrogen production and the thermochemical properties of high temperature steam electrolysis(HTSE) device have been numerically analyzed in a two-dimension, steady-state with using the COMSOL $Multiphysics^{(R)}$. The main parameters for the calculation are applied voltage, ASR(Area-specific Resistance), temperature and pressure of the inlet gas flow. The results showed that thermal-neutral voltage was 1.2454 V and rather than the cell temperature increases or decreases with increasing applied voltage by thermal-neutral voltage starting this voltage the temperature in high voltage tended to rise and temperature in the low voltage tended to fall. And with, increasing the values of ASR, temperature inside the cell and the hydrogen production rate were decreased.

• Transactions of the Korean hydrogen and new energy society
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• v.15 no.3
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• pp.235-243
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• 2004

A number of potential applications of aluminum foams are being identified and renewed interest in these engineering materials is also reflected by several current research projects. One of the key issues for industrial exploitation of aluminum foams is the development of cost-effective manufacturing strategies facilitating, preferably, net shape production of foams with controlled porosity and cell size, and minimized structural imperfection. Especially, melt route to aluminum foam production based on the foaming agents offer attraction of low cost and the potential for good microstructure. The present paper is focused mainly on foaming agents of melt-foam aluminum such as $TiH_2$ or $TiH_2-Al$ mixture. For the purpose of economical manufacturing, we are proposed to hydrogen induced mechanical alloying (HIMA) process. Thermo-physical properties of particles synthesized are compared with conventional methods. Specimens synthesized are characterized by scanning electron microscopy (SEM) with energy dispersive spectroscopy (EDS), thermo- gravimetry-differential scanning calorymetry (TG-DSC), pressure-composition-isotherm. (PCI).

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2005.11a
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• pp.99-100
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• 2005

We have grown carbon nanotubes (CNTs) with a microwave plasma chemical vapor deposition (MPECVD) method, which has been regard as one of the most promising candidates for the synthesis of CNTs due to the vertical alignment, the low temperature and the large area growth. We use methane ($CH_4$) and hydrogen ($H_2$) gas for the growth of CNTs. 60 nm thick Ni catalytic layer were deposited on the TiN coated glass substrate by RF magnetron sputtering method. In this work, we report the effects of pressure on the growth of CNTs. We have changed pressure of processing (10 $\sim$ 20 Torr) deposition of CNTs. SEM (Scanning electron microscopy) images show diameter, length and cross section state CNTs.

• Analytical Science and Technology
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• v.35 no.5
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• pp.205-211
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• 2022

Deuterium (D) is an isotope with one more neutron number than hydrogen (H). Heavy elements rarely change their chemical properties with little effect even if the number of neutrons increases, but low-mass elements change their vibration energy, diffusion rate, and reaction rate because the effect cannot be ignored, which is called an isotope effect. Recently, in the semiconductor and display industries, there is a trend to replace hydrogen gas (H₂) with deuterium gas (D₂) in order to improve process stability and product quality by using the isotope effect. In addition, as the demand for D₂ in industries increases, domestic gas producers are making efforts to produce and supply D₂ on their own. In the case of high purity D₂, most of them are produced by electrolysis of heavy water (D₂O), and among D₂, hydrogen deuteride (HD) molecules are present as isotope impurities. Therefore, in order to maximize the isotope effect of hydrogen in the electronic industry, HD, which is an isotope impurity of D₂ used in the process, should be small amount. To this end, purity analysis of D₂ for industrial processing is essential. In this study, HD quantitative analysis of D₂ for high purity D₂ purity analysis was established and hydrogen isotope RM (Reference material) was developed. Since hydrogen isotopes are difficult to analyze with general gas analysis instrument, they were analyzed using a high-precision mass spectrometer (Gas/MS, Finnigan MAT271). High purity HD gas was injected into Gas/MS, sensitivity was determined by a signal according to pressure, and HD concentrations in two bottles of D₂ were quantified using the corresponding sensitivity. The amount fraction of HD in each D₂ was (4518 ± 275) μmol/mol, (2282 ± 144) μmol/mol. D₂, which quantifies HD amount using the developed quantitative analysis method, will be manufactured with hydrogen isotope RM and distributed for quality management and maintenance of electronic industries and gas producers in the future.

• Transactions of the Korean hydrogen and new energy society
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• v.24 no.6
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• pp.535-542
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• 2013

To enhance the performance of SEWGS system by holding the WGS catalyst in a SEWGS reactor using bed inserts, effect of bed insert geometry on CO conversion of WGS catalyst was measured and investigated. Small scale fluidized bed reactor was used as experimental apparatus and tablet shaped WGS catalyst and sand particle were used as bed materials. The cylinder type and the spring type bed inserts were used to hold the WGS catalysts. The CO conversion of WGS catalyst with the change of steam/CO ratio was determined based on the exit gas analysis. Moreover, gas flow direction was confirmed by bed pressure drop measurement for each case. The measured CO conversion using the bed inserts showed high value comparable to previous results even though at low catalyst content. Most of input gas flowed through the bed center side when we charged tablet type catalyst into the cylinder type bed insert and this can cause low $CO_2$ capture efficiency because the possibility of contact between input gas and $CO_2$ absorbent is low in this case. However, the spring type bed insert showed good reactivity and good distribution of gas, and therefore, the spring type bed insert was selected as the best bed insert for SEWGS process.