• Transactions of the Korean Society of Automotive Engineers
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• v.15 no.6
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• pp.17-22
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• 2007

GTL(Gas-to-Liquids) fuel technology was converted from the natural gas, coal and biomass into the diesel or kerosene by Fisher-Tropsch synthesis. GTL fuel have very good merits on high cetane number, low density, free sulfur, lower aromatics contents and no poly-aromatic hydrocarbons as well as the autoignition characteristics. These physical properties make it valuable as a diesel fuel with lower emissions than the conventional diesel fuel. Furthermore, GTL fuel can be use not to the engine any modification. Therefore, to evaluate emissions of GTL fuel, the tested diesel vehicles were fueled on blends of GTL fuel/ultra low sulfur diesel fuel(ULSD). And then, we found out that GTL fuel reduced regulated emissions(CO, NOx, HC, PM) compare with conventional diesel fuel.

• Proceedings of the Materials Research Society of Korea Conference
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• 2011.10a
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• pp.29.1-29.1
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• 2011

The selective catalytic reduction (SCR) of $MnO_x$ with $NH_3$ is an effective method for the removal of $MnO_x$ from stationary system. The typical catalyst for this method is $V_2O_5-WO_3(MoO_3)/TiO_2$, caused by the high activity and stability. However, This catalyst is active within $300{\sim}400^{\circ}C$ and occurs the pore plugging from the deposition of ammonium sulfate salts on the catalysts surface. It needs to locate the SCR unit after the desulfurizer and electrostatic precipitator without reheating of the flue gas as well as deposition of dust on the catalyst. The manganese oxides supported on titania catalysts have attracted interest because of its high SCR activity at low temperature. The catalytic activity of $MnO_x/TiO_2$ SCR catalyst with different manganese precursors have investigated for low-temperature SCR in terms of structural, morphological, and physico-chemical analyses. The $MnO_x/TiO_2$ were prepared from three different precursors such as manganese nitrate, manganese acetate (II), and manganese acetate (III) by the sol-gel method and then it calcinated at $500^{\circ}C$ for 2 hr. The structural analysis was carried out to identify the phase transition and the change intensity of catalytic activity by various manganese precursors was analyzed by FT-IR and Raman spectroscopy. These different precursors also led to various surface Mn concentrations indicated by SEM. The Mn acetate (III) tends to be more suppressive the crystalline phase (rutile), and it has not only smaller particle size, but also better distributed than the others. It was confirmed that the catalytic activity of MA (III)-$MnO_x/TiO_2$ was the highest among them.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.15 no.6
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• pp.3370-3375
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• 2014

MILD combustion is a highly favored technology for solving the trade-off relation between high thermal efficiency and low pollutant emissions. The system has low NOx concentration in high temperature combustion by recirculating the combustion gas, as well as improving the thermal efficiency by making the internal temperature in a combustion furnace uniform. This study describes the combustion characteristics of a conical MILD combustor in a laboratory-scale furnace by adjusting the equivalence ratio with the fuel gas flow rate while maintaining a constant air flow rate of the furnace. The MILD regime in the furnace is well characterized and the in-furnace temperature and emissions were predicted, respectively, for the range of equivalence of 0.69 - 0.83. For the range of equivalence ratios, this study confirmed the existence of a stable flame region that has an approximately $300^{\circ}C$ temperature difference between the maximum flame temperature region and main reaction region.

• Clean Technology
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• v.19 no.3
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• pp.287-294
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• 2013

The $NH_3$-selective catalytic reduction (SCR) reaction of NO with excess of oxygen were systematically investigated over Cu-zeolite and Fe-zeolite catalysts. Cu-zeolite and Fe-zeolite catatysts to adapt the SCR technology for mobile diesel engines were prepared by liquid ion exchange and incipient wetness impregnation of $NH_4$-BEA and $NH_4$-ZSM-5 zeolites. The catalysts were characterized by BET, XRD, FE-TEM (field emission transmission electron microscopy) and SEM/EDS. The SCR examinations performed under stationary conditions showed that the Cu-exchanged BEA catalyst revealed pronounced performance at low temperatures of $200{\sim}250^{\circ}C$. With respect to the Fe-zeolite catalyst, the Cu-zeolite catalyst showed a higher activity in the SCR reaction at low temperatures below $250^{\circ}C$. BEA zeolite based catalyst exhibited good activity in comparison with ZSM-5 zeolite based catalyst at low temperatures below $250^{\circ}C$.

• New & Renewable Energy
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• v.5 no.2
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• pp.15-24
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• 2009

As new small scale LFG (landfill gas) energy project model which can improve economic feasibility limited due to the economy of scale, LFG-Microturbine combined heat and power system with $CO_2$ fertilization into greenhouses was proposed and investigated including basic design process prior to the system installation at Gwang-ju metro sanitary landfill. The system features $CH_4$ enrichment for stable microturbine operation, reduction of compressor power consumption and low CO emission, and $CO_2$ supplement into greenhouse for enhancement plant growth. From many other researches, high $CO_2$ concentration was found to enhance $CO_2$ assimilation (also known as photosynthesis reaction) which converts $CO_2$ and $H_2O$ to sugar using light energy. For small scale landfills which produce LFG under $3\;m^3$/min, among currently available prime movers, microturbine is the most suitable power generation system and its low electric efficiency can be improved with heat recovery. Besides, since its exhaust gas contains very low level of harmful contaminants to plant growth such as NOx, CO and SOx, microturbine exhaust gas is a suitable and economically advantageous $CO_2$ source for $CO_2$ fertilization in greenhouse. The LFG-Microturbine combined heat and power generation system with $CO_2$ fertilization into greenhouse gas to enhance plant growth is technologically and economically feasible and improves economical feasibility compared to other small scale LFG energy project model.

• Transactions of the Korean Society of Automotive Engineers
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• v.22 no.2
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• pp.156-165
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• 2014

This paper is the first investigation on the effect of flow control methods on the part load performance in a spark ignition engine. For comparison of the methods, two control devices, port throttling and masking, were applied to a conventional engine without any design change of the intake port. Steady flow evaluation shows that steady flow rates per unit opening area and swirl ratio are very low compared with the port throttling and saturated from mid-stage valve lift, however, swirl increases slightly as the lift is higher in case of 1/4 masking control. In the part load performance, the effect of simple port throttling on lean misfire limit expansion is limited and insufficient; on the other hand a masking improves the limit considerably without any port modification for increasing swirl. Also the results show that the intake flow control improves the combustion with following two mechanisms: stratification induced by the combination of the flow pattern and the fuel injection timing attribute to ignition ability and the intensified flow ensure fast burn. In addition fuel consumption reduces under the flow controls and the reduction rate is different according to the operation conditions and control methods. At the Stoichiometric and/or low speed and low load the throttling method is more advantageous; however vice versa at lean and high load condition. Finally, the throttling is more efficient for HC reduction than masking, on the other side the NOx emissions increase under the masking and decrease under the port throttling compared with conventional port scheme.

• Applied Chemistry for Engineering
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• v.23 no.2
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• pp.190-194
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• 2012

10 wt% Mn supported on various commercial $TiO_2$ catalysts were prepared by wet-impregnation method for the low temperature selective catalytic reduction (SCR) of NO with $NH_3$. A combination of various physico-chemical techniques such as BET, XRD, XPS and TPR were used to characterize these catalysts. MnOx surface densities on MnOx/$TiO_2$ catalyst were related to surface area. As MnOx surface density lowered with high dispersion, the SCR activity for low temperature was increased and the reduction temperature ($MnO_2$ ${\rightarrow}$ $Mn_2O_3$) of surface MnOx was lower. For a high SCR, MnOx could be supported on a high surface area of $TiO_2$ and should be existed a high dispersion of non-crystalline species.

• Applied Chemistry for Engineering
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• v.33 no.1
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• pp.64-70
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• 2022

In this study, an experiment was performed by adding Sb during NH3-selective catalytic reduction (NH₃-SCR) while varying calcination temperatures from 400 to 700 ℃ to improve the low temperature denitrification efficiency of VWTi catalyst. As a result, VWSbTi(500) and VWSbTi(600) catalysts corresponding to Sb calcination temperatures of 500~600 ℃ showed the best denitrification performance at low temperatures below 300 ℃. BET, XRD, Raman, XPS, H₂-TPR, and NH₃-TPD analyses were performed In order to confirm physicochemical properties according to the calcination temperature. In the case of VWSbTi(500) and VWSbTi(600), an acid site increased with the generation of W=O species, and superb activity at low temperatures was exhibited due to the excellent redox characteristics and increase in electron density of tungsten. Furthermore, in the case of VWSbTi(700), as the crystalline V₂O₅ structure was formed, the denitrification efficiency decreased. Thus the optimum calcination temperature during Sb addition process was confirmed.

• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.2
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• pp.355-362
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• 2021

To facilitate low-pressure selective catalyst reduction (L.P SCR), a high exhaust-gas temperature of a four-stroke diesel engine for a ship's generator is required. This study aimed at reducing the exhaust-gas temperature by adjusting the valve open-close timing and fuel injection timing to satisfy the operating conditions of L.P SCR and prevent accidents associated with the generator engine due to high temperature. To lower exhaust-gas temperature, the angle of the camshaft was adjusted and the shim of the fuel injection pump was added. As a result, the maximum explosion pressure increased and the average of the turbocharger outlet temperature dropped. Considering the heat loss from the turbocharger outlet to the SCR inlet, the operation condition for L.P SCR was satisfied with 290 ℃. The study demonstrates that safe operation of a diesel generator can be achieved by lowering the exhaust-gas temperature.

• Journal of ILASS-Korea
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• v.29 no.2
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• pp.53-59
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• 2024

Cars are one of the main causes of air pollution in large cities, and 34.6% of domestic air pollution emissions come from mobile sources, of which cars account for 69.6%. In particular, the importance of nitrogen oxides (NOx) and particulate matter (PM), which are major pollutants in diesel vehicles, is increasing due to their high contribution to emissions. Therefore, in this study, the problem of natural regeneration caused by low exhaust gas temperature during low speed and low load operation was solved by applying a complex regeneration DPF that is not affected by temperature conditions to large diesel vehicles with higher driving time and engine displacement than small and medium-sized vehicles. And the feasibility of application to large diesel vehicles was reviewed by measuring the emission reduction efficiency. As a result of the reduction efficiency test on the actual vehicle durability product, PM showed a reduction efficiency of 84% to 86%, and the reduction efficiency of gaseous substances showed a high reduction efficiency of over 90%. The actual vehicle applicability test was completed with three driving patterns: village bus vehicle, police car, and road-going construction equipment vehicle, and no device problems occurred until the end of the test. Both load and no-load smoke measurement results showed a smoke reduction efficiency of over 96%.