• Title/Summary/Keyword: longitudinal changes

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Theroetical Study of the Nonlinear Optical Properties of Thiophene, Furan, Pyrrole, (1,2,4-triazole), (1,3,4-oxadiazole), and (1,3,4-thiadiazole) Monomers and Oligomers

  • 최우성;김태원;정승우;김철주
    • Bulletin of the Korean Chemical Society
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    • v.19 no.3
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    • pp.299-307
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    • 1998
  • PM3 semiempirical calculations were carried out to study the frequency-dependent nonlinear optical properties of thiophene, furan, pyrrole, (1,2,4)-triazole, (1,3,4)-oxadiazole, and (1,3,4)-thiadiazole monomers and oligomers. The longitudinal component, αxx, is the largest of three principle components. On the other hand, the out-of-plane component, αzz, is the smallest. Moreover, the out-of-plane component (αzz) of thiophene, furan, pyrrole, (1,2,4)-triazole, (1,3,4)-oxadiazole, and (1,3,4)-thiadiazole monomers show constant changes with increasing optical frequencies. The frequency-dependent first- order polarizabilities increase in the order: thiophene > (1,2,4)-triazole > pyrrole > furan > (1,3,4)-thiadiazole > (1,3,4)-oxa-diazole monomers and oligomers. The effects of β(-2ω;ω,ω) (SHG) shows a larger dispersion compared with (-ω;ω,0) (EOPE) and β(0;-ω,ω) (OR). The second- order polarizabilities of thiophene, furan, pyrrole, (1,2,4)-triazole, (1,3,4)-thiadiazole, and (1,3,4)-oxadiazole monomers for the various second- order effects have the order: β(-2ω;ω,ω) (SHG) > β(-ω;ω,0) (EOPE) > β(0;-ω,ω) (OR) and thiophene > pyrrole > (1,2,4)-triazole > furan > 1,3,4-thiadiazole > 1,3,4-oxadiazole monomers. The third- order polarizabilities for the various third- order effects have the following order: γ(-3ω;ω',ω,ω) (THG) > γ(-2ω;0,ω,ω) (EFISHG) > γ(-ω;ω',-ω,ω) (IDRI) > γ(-ω;0,0,ω) (OKE). The effects of THG increase rapidly with increasing optical frequencies compared with the other effects. In particular, OKE effects increase most slowly with increasing optical frequencies. Also, the effects of THG for thiophene, furan, pyrrole, (1,2,4)-triazole, (1,3,4)-thiadiazole, and (1,3,4)-oxadiazole oligomers show the order thiophene > (1,2,4)-triazole > furan > pyrrole > (1,3,4)-thiadiazole > (1,3,4)-oxadiazole oligomers. In particular, the third- order polarizabilities of thiophene and (1,3,4)-thiadiazole oligomers are about four and three times larger than those of (1,3,4)-oxadiazole and (1,2,4)-triazole oligomer, respectively.

Career Maturity of Primary and Middle School Students Who are Interested in Teaching Job in Comparison to Those Who are Interested in being a Doctor (교사 희망 학생의 진로 특성: 의사 희망 학생과의 비교를 중심으로)

  • Paik, Sunhee;Hur, Eun Jung
    • Journal of Digital Convergence
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    • v.18 no.12
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    • pp.1-10
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    • 2020
  • This study examined career maturity of primary and middle school students who were interested in teaching job and compared to those who were interested in being a doctor. Using the data from the Korean Education Longitudinal Study 2013, we examined changes in the number of students (primary 5 through middle 2) who were interested in teaching as a job as well as in being a doctor. In addition, the participants' career maturity such as self-understanding, career planing, and attitudes towards job were examined and independent sample t-tests were conducted to compare two groups of students. Overall, the students who were interested in teaching showed lower level of career maturity compared to those who expected to be a doctor. Additionally, as students advanced to higher grades, the points of career maturity had been decreased regardless of which job they were interested in. Based on the findings, suggestions will be made to broaden the pool for future teachers.

Factors Influencing Posttraumatic Growth in Patients with Lung Cancer (폐암 환자의 외상 후 성장에 영향을 미치는 요인)

  • Kim, Young Suk;Moon, Jin Ha;Lee, Young Suk;Kim, Yeon Woo;Heo, Gyu Rim;Oh, Soon Keum
    • Journal of Korean Clinical Nursing Research
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    • v.27 no.1
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    • pp.98-108
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    • 2021
  • Purpose: This study was conducted to identify the factors influencing the posttraumatic growth (PTG) in patients with lung cancer and to provide basic data for nursing intervention development to improve PTG and adaptation. Methods: The study included 126 non-small cell lung cancer patients initially diagnosed at the Lung Cancer Center, C University Hospital in S city, Gyeonggi-do. Patients were asked to complete a questionnaire consisting of demographic characteristics, disease characteristics, posttraumatic growth, cancer coping, social support, and resilience. Data were analyzed using t-tests, ANOVA, and Pearson's correlation and multiple regression analysis. Results: The mean score for PTG in lung cancer patients was 56.39, cancer coping was 61.31, social support was 61.09, and resilience was 92.77. Significant positive correlations were found for PTG and cancer coping (r=.75, p<.001), social support (r=.52, p<.001) and resilience (r=.63, p<.001). Factors contributing to PTG of lung cancer patients were cancer coping (β=.53 p<.001), perceived health status(β=.20, p=.002), resilience (β=.21, p=.010) and importance of religion (β=.15, p=.013). This model explained about 64.0% of variances of PTG (F=29.58, p<.001). Conclusion: It is necessary to develop new nursing intervention programs to improve PTG for patients with lung cancer based on strategies to enhance coping and resilience to recovery. Longitudinal studies examining temporal changes in PTG among patients with lung cancer are suggested for future studies in this regard.

Structural Performance Evaluation on Ended Block of Wide Flange PSC Girder for the Semi-Integral Bridges (광폭 플랜지 PSC 거더 단부 프리캐스트 블록을 활용한 반일체식교대교량의 구조성능 평가)

  • Ka, Hoon;Choi, Jin-Woo;Kim, Young-Ho;Park, Jong-Myen
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.42 no.1
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    • pp.1-9
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    • 2022
  • Semi-integral abutment bridges are a type of integral abutment bridges. These bridges eliminate expansion joints on the structure and can be used in situations not suitable for full-integral abutment bridge. Moreover, Semi-integral bridges have excellent maintenance and can be economically constructed. This study is about precast wall-type blocks at each end which provide lateral support for PSC girder, as well as acting as retaining walls to resist longitudinal movement of semi-integral abutment bridge. The end-diaphragm connection between ended blocks of PSC girders can be achieved by in-suit nonshrinkage concrete. The results show that 3-point experiment of end-diaphragm beam have an acceptable performance which is so better than results of structural design. Moreover, the effects of backfill soil on semi-integral abutment bridge constructed are analyzed the behavior according to the temperature changes.

Predicting Longitudinal Patterns of Emotional and Behavioral Problems in Early Adolescence : A Latent Class and Latent Transition Analysis (초기 청소년기 정서행동문제의 종단적 변화에 따른 잠재프로파일 분류 및 전이 영향요인 분석)

  • Kim, Bitna;Jang, Hyein;Park, Ju Hee
    • Human Ecology Research
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    • v.60 no.1
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    • pp.53-68
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    • 2022
  • Using a person-centered approach, the current study investigated latent profiles for the emotional and behavioral problems of students in sixth-grade in elementary school and second grade of middle school. The aim was to explore latent transition patterns and verify the factors affecting the transitions. The participants were 1,937 adolescents who responded to the 3rd year (6th grade of elementary school; Time 1), 4th year (1st grade of middle school), and 5th year (2nd grade of middle school; Time 2) of the Korean Children Youth Panel Study. Latent profile and latent transition analyses were performed. The results were as follows: first, the latent profile of emotional and behavioral problems changed from Time 1 to Time 2. The latent groups at Time 1 were classified into low, moderate, high, and externalizing-dominant, whereas at Time 2, five groups were identified: low, moderate, high, externalizing-dominant, and withdrawal-dominant. Second, transition analyses revealed that although 22.3-57.0% of latent groups remained unchanged, there were significant changes over time between groups, as a new group ('withdrawal-dominant') emerged in Time 2. Third, different factors influenced the latent profile transition of emotional and behavioral problems depending on the transition pattern. Higher levels of self-esteem, better relationships with peers and teachers, and lower levels of parental inconsistency meant emotional and behavioral problems had not worsened at Time 2. The results suggest that early interventions are needed during the transition from childhood to early adolescence.

Monitoring of Moisture and Dimensional Behaviors of Nail-Laminated Timber (NLT)-Concrete Slab Exposed to Outdoor Air

  • HWANG, Sung-Wook;CHUNG, Hyunwoo;LEE, Taekyeong;AHN, Kyung-Sun;PANG, Sung-Jun;BANG, Junsik;Won, Hyo;OH, Jung-Kwon;YEO, Hwanmyeong
    • Journal of the Korean Wood Science and Technology
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    • v.50 no.5
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    • pp.301-314
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    • 2022
  • The moisture and dimensional behaviors of a nail-laminated timber (NLT)-concrete slab composed of an NLT-plywood composite and topping concrete are monitored for 385 days. The slab is developed for using as flexural elements such as floors. The humidity control of wood gently introduces significant fluctuations under the ambient relative humidity into the slab, and fluctuations in the relative humidity result in dimensional changes. The equilibrium moisture content of the slab increases from 6.7% to 15.3% during the monitoring period, resulting in a width (radial) strain of 0.58%. The length (longitudinal) strain is negligible, and the height (tangential) strain is excluded from the analysis because of abstruse signal patterns generated. Concrete pouring causes a permanent increase in the width of the NLT-plywood composite. However, the width deforms because the weight of the concrete mixture loosens the nail-laminated structure, not because of the significant amount of moisture in the mixture. The dimensional stabilization effect of the nail-laminated system is demonstrated as the composite strain is lower than the total strain of lumber and plywood, which are elements constituting the nail-laminated structure.

Changes in Clinical Practice Satisfaction of Healthcare Students Before and After COVID-19 (COVID-19 전·후의 보건계열 학생들의 임상 실습 만족도의 변화)

  • Namkoong, Seung;Ro, Hyo-Lyun
    • Journal of the Korean Society of Physical Medicine
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    • v.17 no.3
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    • pp.41-50
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    • 2022
  • PURPOSE: This study sought to investigate the change in the satisfaction levels of healthcare students regarding clinical practice before and after the coronavirus disease 19 (COVID-19) outbreak. METHODS: This was a longitudinal survey using a structured questionnaire. The first survey was conducted before the COVID-19 outbreak in April 2018, and the second survey was conducted after the outbreak from May to June 2022. The questionnaire used before and after COVID-19 had the same content and was categorized into the following six factors to determine clinical practice satisfaction: practice guidance, practice environment, practice time, practice evaluation, interpersonal relationships, and effectiveness of practice. Before the COVID-19 pandemic, a total of 153 healthcare students (average age: 22.43 ± 1.47 years old), participated from 4 departments: nursing, physical therapy, occupational therapy, and dental hygiene. After COVID-19, 84 students (average age: 22.75 ± 2.87 years old), from the physical therapy, occupational therapy, nursing, and dental hygiene departments participated in the survey. RESULTS: Clinical practice satisfaction was evaluated considering the factors of practical guidance, practice environment, practice time, interpersonal relationships, and practical effects. It was observed that the satisfaction with clinical practice increased in nursing, physical therapy, occupational therapy, and dental hygiene students after COVID-19 compared to the situation before the outbreak. There was no difference seen in the practice time and practice evaluation factors in the occupational therapy department and in the practice time factor in the dental hygiene department before and after COVID. CONCLUSION: In clinical practice under the extremely constrained circumstances imposed by the COVID-19 pandemic, it seems that the emotional internal response is greater, and the satisfaction with clinical practice appears to be relatively higher than before the outbreak.

A Study on the ACC Safety Evaluation Method Using Dual Cameras (듀얼카메라를 활용한 ACC 안전성 평가 방법에 관한 연구)

  • Kim, Bong-Ju;Lee, Seon-Bong
    • Journal of Auto-vehicle Safety Association
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    • v.14 no.2
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    • pp.57-69
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    • 2022
  • Recently, as interest in self-driving cars has increased worldwide, research and development on the Advanced Driver Assist System is actively underway. Among them, the purpose of Adaptive Cruise Control (ACC) is to minimize the driver's driving fatigue through the control of the vehicle's longitudinal speed and relative distance. In this study, for the research of the ACC test in the real environment, the real-road test was conducted based on domestic-road test scenario proposed in preceding study, considering ISO 15622 test method. In this case, the distance measurement method using the dual camera was verified by comparing and analyzing the result of using the dual camera and the result of using the measurement equipment. As a result of the comparison, two results could be derived. First, the relative distance after stabilizing the ACC was compared. As a result of the comparison, it was found that the minimum error rate was 0.251% in the first test of scenario 8 and the maximum error rate was 4.202% in the third test of scenario 9. Second, the result of the same time was compared. As a result of the comparison, it was found that the minimum error rate was 0.000% in the second test of scenario 10 and the maximum error rate was 9.945% in the second test of scenario 1. However, the average error rate for all scenarios was within 3%. It was determined that the representative cause of the maximum error occurred in the dual camera installed in the test vehicle. There were problems such as shaking caused by road surface vibration and air resistance during driving, changes in ambient brightness, and the process of focusing the video. Accordingly, it was determined that the result of calculating the distance to the preceding vehicle in the image where the problem occurred was incorrect. In the development stage of ADAS such as ACC, it is judged that only dual cameras can reduce the cost burden according to the above derivation of test results.

Numerical simulations of turbulent flow on the pool and weir type fishway and analysis of ascending possibility of fishes (계단식 어도의 난류흐름 수치해석 및 어류 소상 가능성 분석)

  • Kwon, Yong-Joon;Ryu, Yonguk;Kim, Hyung Suk
    • Journal of Korea Water Resources Association
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    • v.56 no.spc1
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    • pp.1037-1048
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    • 2023
  • Fishways are constructed to ensure the fish migration because river-crossing structures such as dams and weirs cut off the stream longitudinal connectivity and influence on aquatic ecosystems. However, the passage efficiency of fishes varies depending on flow characteristics in the fishway and fish species. In this study, three-dimensional numerical simulations are carried out using a RANS model and the volume of fluid method for resolving free surface fluctuations to calculate the turbulent flow in the pool and weir type fishway. The Flow velocity and turbulent kinetic energy in the pool of fishway are analyzed according to variation of the upstream water level and the length of pool. The present numerical simulations reasonably well reproduce the stream flow and plunging flow characteristics in the pool. The simulation results show that the stream flow changes to the plunging flow as the length of the pool increases. When the upstream level increases, the stream flow becomes more evident. Key parameters related to the fish migration within the fishway such as the flow velocity and the turbulent kinetic energy are examined to assess the ascending possibility of fishes.

Effects of die cooling on change of extrusion characteristics of Al-Mn-based thin-walled flat multi-port tube (금형 냉각이 Al-Mn계 다중압출 평판관의 압출 특성 변화에 미치는 영향)

  • Young-Chul Shin;Seong-Ho Ha;Tae-Hoon Kang;Kee-Ahn Lee;Seung-Chul Lee
    • Design & Manufacturing
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    • v.17 no.4
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    • pp.63-71
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    • 2023
  • In order to increase the extrusion production speed of aluminum, extrusion die cooling technology using liquid nitrogen has recently attracted a lot of attention. Increasing the extrusion speed increases the temperature of the bearing area of extrusion dies and the extrusion profile, which may cause defects on the surface of extruded profile. Extrusion die cooling technology is to directly inject liquid nitrogen through a cooling channel formed between the die and the backer inside the die-set. The liquid nitrogen removes heat from the die-set, and gaseous nitrogen at the exit of the channel, covers the extrusion profile of an inert atmosphere reducing the oxidation and the profile temperature. The aim of this study is to evaluate the cooling capacity by applying die cooling to extrusion of Al-Mn-based aluminum alloy flat tubes, and to investigate the effects of die cooling on the change in extrusion characteristics of flat tubes. Cooling capacity was confirmed by observing the temperature change of the extrusion profile depending on whether or not die cooling is applied. To observe changes in material characteristics due to die cooling, surface observation is conducted and microstructure and precipitate analysis are performed by FE-SEM on the surface and longitudinal cross section of the extruded flat tubes.