• Title/Summary/Keyword: long electrode

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Zundel- and Eigen-like Surface Hydrated Protons on Pt(111)

  • Kim, Youngsoon;Park, Youngwook;Shin, Sunghwan;Kang, Heon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.167.1-167.1
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    • 2016
  • The interaction between adsorbed water and hydrogen on metallic surfaces is important for fundamental understanding of heterogeneous catalysis and electrode surface reactions in acidic environment. Here, we explore a long-standing question of whether hydronium ion can exist or not on a Pt surface coadsorbed with atomic hydrogen and water. Studies based on mass spectrometry and infrared spectroscopy show clear evidence that hydrogen atoms are converted into hydrated protons on a Pt(111) surface. The preferential structures of hydrated protons are identified as multiply hydrated $H_5O_2{^+}$ and $H_7O_3{^+}$ species rather than as hydronium ions. The multiply hydrated protons may be regarded as two dimensional zundel ($H_5O_2{^+}$) and Eigen cation ($H_7O_3{^+}$) in water-metal interface. These surface-bound hydrated protons may be key surface intermediates of the electrochemical interconversion between adsorbed hydrogen atoms and solvated protons.

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Improved Waveform during the Addressing Period for the Improvement of the Addressing Time for AC PDPs

  • Lim, Jong-Sik;Kim, Hyun-Seok;Kim, Joon-Yub
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.511-514
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    • 2004
  • ADS(Address Display period Separation) driving method has been considered to be the most appropriate driving technique for AC PDPs. However when the ADS driving method is applied to the high-resolution AC PDP, the required long addressing time often becomes a problem. In this paper, we present a new waveform for reducing the addressing time and for the stable addressing discharge. In this new waveform, a wall charge acceleration pulse is applied to the common electrode right after 80us scan time. In this way, the charge generated by the addressing discharge is accelerated to the electrodes. Experiments using the wall charge acceleration pulse showed that we could stably address an AC PDP with the scan pulses having pulse width of 1 us

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Fabrication of MDOF IPMC Actuators to Generate Undulatory Motion (파동형 움직임이 가능한 다자유 IPMC 구동기 제작)

  • Jeon, Jin-Han;Oh, Il-Kwon
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2006.11a
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    • pp.119-123
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    • 2006
  • The ionic-polymer-metal-composite actuators have the best merit for bio-mimetic locomotion because of their large bending performance. Especially, they have the advantage for mimicking a fish-like motion because IPMCs are useful to be actuated in water. So we have developed IPMC actuators with multiple electrodes for realization of biomimetic motion. Generally, the IPMC actuator has been fabricated in electroless plating technique, while it needs very long fabrication time and shows poor repeatability in the actuation performance owing to the variables in chemical fabrication process. Therefore, the novel fabrication methods were investigated by combining electroless plating and electroplating techniques capable of patterning precisely. On the whole, two different methods were compared and analyzed with similar thickness level of Platinum electrodes. Present results show that mixing chemical reduction and electroplating can be a promising candidate for electrode patterning.

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Fabrication of 30W PAFC stack and its electrical performance (인산형 연료전지 30W급 스택제조 및 발전실험)

  • Kim, C.S.;Song, R.H.;Choi, B.W.;Han, S.O.;Choi, S.H.
    • Proceedings of the KIEE Conference
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    • 1991.07a
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    • pp.78-80
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    • 1991
  • Preliminary multiple cell stack testing was performed using three-cell stack each electrode having an active area of $100cm^2$. The stack was operated at $190^{\circ}C$, the output power was 32W at 1.8V and maximum power was 69W. It was recorded as the first stack fabricated in Korea and continuous research works on the fabrication of stack, optimization of stack performance and long run tests will be conducted.

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A study of Pulse EMM for Invar alloy (펄스 전압을 이용한 인바 합금의 미세 전해가공)

  • 김원묵;백승엽;이은상;탁용석
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.560-563
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    • 2004
  • Invar is a compound metal of Fe-Ni system and contain 36% Ni. The most distinction characteristic of Invar is the coefficient of thermal expansion is 1.0 10$^{-6}$ /$^{\circ}C$. That is a tenth of general steel material. This low thermal expansion characteristic of Invar is applied to the missile, aircraft, monitor CRT and frontier display's shadow mask such as FED and OLED. The usage of the Invar shadow mask for display is increasing due to the requirement of larger size and flatness monitor. The Invar shadow mask is machined by two ways electro-forming and laser now. However the electro-forming takes a too long time and the laser machining is accompanied with Burr. In this study, PEMM(pulse electrochemical micro machining) is conducted to machine the micro hole to the Invar and 80${\mu}{\textrm}{m}$ hole was machined.

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Polymeric Humidity Sensor Using Polyelectrolyte Derived from Poly(amide-sulfone)s

  • Jeon, Young-Min;Gong, Myoung-Seon
    • Macromolecular Research
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    • v.17 no.4
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    • pp.227-231
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    • 2009
  • New polyelectrolytes derived from poly(amide-sulfone)s and 1,5-dibromopentane were simultaneously fabricated on the electrode by the crosslinking reaction. The substrate was pretreated with a bromoalkyl-containing, silane-coupling agent to anchor the humidity-sensitive membrane to the substrate through the covalent bond. When the resistance dependence on the relative humidity of the crosslinked poly(amide-sulfone)s was measured, the resistance varied by three orders of magnitude between 20%RH and 90%RH, which was the required RH range for a humidity sensor operating at ambient humidity. Their water durability, long-term stabilities under various environments, hysteresis and response and recovery times were measured and evaluated as a humidity-sensing membrane.

Study on the Stability of Organic Thin-Film Transistors Fabricated by Inserting a Polymeric Film as an Adhesion Layer

  • Hyung, Gun-Woo;Park, Il-Houng;Seo, Ji-Hoon;Seo, Ji-Hyun;Choi, Hak-Bum;Kim, Young-Kwan
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08b
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    • pp.1348-1351
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    • 2007
  • We demonstrated that the threshold voltage shift owing to a gate-bias stress is originated from the trapped charges at the interface between semiconductor layer and dielectric layer, and such drawback can be settled by applying long-term delay time to the gate electrode.

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DEVELOPMENT and THERMAL DISTRIBUTION of an RF CAPACITIVE HYPERTHERMIA SYSTEM (고주파 유전가열형 온열암치료기의 개발과 가온특성)

  • Park, Mig-Non;Lee, Sang-Bae;Park, Duk-Kyu;Chu, Sung-Sil;Jung, Mi-Hyang
    • Proceedings of the KIEE Conference
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    • 1987.07b
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    • pp.1309-1312
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    • 1987
  • Hyperthermia for the treatment of cancer has been introduced for a long time and the biological effect for the use of hyperthermia to malignant tumors has been well established and encouraging clinical results has been observed. Unfortunately, the engineering or technical aspects of hyperthermia for the deep seated tumors has not been satisfactory. We have researched and developed the radiofrequency capacitive hyperthermia system (GHT- RF8). It was composed with 8-9 MHZ RF generator, capacitive electrode, matching system, cooling system, temperature measuring system and control computer. The thermal profile was investigated in agar phantom, animals and in human tumors, which was heated with capacitive RF device.

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Study of Electromagnetic Characteristics for Air discharge using Ultra - wideband Antenna (광대역 안테나를 이용한 기중방전현상에 대한 전자기적 특성에 관한 연구)

  • Lee K. W.;Yoon S. C.;Kim M. Y.;Baik K. S.
    • Proceedings of the KSR Conference
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    • 2004.06a
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    • pp.1489-1491
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    • 2004
  • PD in air is accompanied by light, sound and electromagnetic wave. Light and sound can be prevented from blocking between PD sources and sensor but electromagnetic wave can be transferred to long distance without any interference an captured by antenna. This paper investigated the wideband antenna is appropriate for sensing Partial discharge in air. PD was generated from simulated PD source which consist of needle and flat electrode with small gap. Signals obtained from wideband antenna were diminished in both time and frequence region with the distance between PD source and antenna.

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Fabrication and Its Biomedical Application of the pH-ISFET Microprobe (pH-ISFET 마이크로프로브의 製作과 그 生醫學的 應用)

  • Lee, Kwang-Man;Sohn, Byung-Ki
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.25 no.11
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    • pp.1335-1341
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    • 1988
  • A pH-ISEFET microprobe for in vivo measurements has been fabricated by combining ISFET (SL-IIS) chip and capillary thin film reference electrode. A two-step TCE oxidation for the gate oxide layer and multilayer encapsulation using silicone rubber and epoxy were specially used for the improvement of the stability and temperature dependence of the ISFET's. The measured sensitivit, response time and temperature dependence of the pH-ISFET microprobes are 50 mV/pH, less than one second, and - 0.01 pH/$^{\circ}$ , respectively. By operating continuously more than 40 days, a long term stability of 0.016 pH/day is obtained. The result of pH monitoring of femoral arterial blood in a rabbit is fairly good agreement with the value of blood gas analysis.

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