• Title/Summary/Keyword: log P 특성

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QSAR Modeling of Toxicant Concentrations(EC50) on the Use of Bioluminescence Intensity of CMC Immobilized Photobacterium Phosphoreum (CMC 고정화 Photobacterium phosphoreum 의 생체발광량을 이용한 독성농도(EC50)의 QSAR 모델)

  • 이용제;허문석;이우창;전억한
    • KSBB Journal
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    • v.15 no.3
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    • pp.299-306
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    • 2000
  • Concern for the effects of toxic chemicals on the environment leads the search for better bioassay test organisms and test procedures. Photobacterium phosphoreum was used successfully as a test organism and the luminometer detection technique was an effective and simple method for determining the concentration of toxic chemicals. With EC50 a total of 14 chlorine substituted phenols benzenes and ethanes were used for the experiments. The test results showed that the toxicity to P. phosphoreum increased in the order of phenol > benzene > ethane and the toxicity also increased with the number of chlorine substitution. Quantitative structure activity relationship (QSARO) model can be used to predict EC50 to save time and endeavor. Correlation was well established with the QSAR parameters such as log P, log S and solvatochromic parameter(Vi/100 $\pi$, ${\beta}$m and am). The QSAR modeling was used with multi-regression analysis and mono-regression analysis. These analyses resulted in the following QSAR : $log EC_{50} =2.48 + 0.914 log S(n=9 R2=85.5% RE=0.378) log EC_{50}=0.35 - 4.48 Vi/100 + 2.84 \pi^* +9.46{\beta}m-4.48am (n =14 R2=98.2% RE=0.012) log EC_{50} =2.64 -1.66 log P(n=5, R2=98.8% RE=0.16) log EC_{50}=3.44 -1.09 log P(n=9 R2= 80.8% Re=0.207)$

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Reduction Factors of Pesticides with Different Physicochemical Properties under Washing and Cooking Conditions (물리화학적 특성이 다른 농약의 세척 및 조리방법에 의한 감소계수 산출)

  • You, Young-Hwa;Lee, Young-Sun;Kwon, Hoon-Jeong
    • Korean Journal of Food Science and Technology
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    • v.43 no.5
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    • pp.537-543
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    • 2011
  • The reduction factor of pesticides is getting more crucial these days. However, most studies have focused on the relationship between pesticides and commodities. This study was conducted to examine the pesticide reduction factor based on their physicochemical properties. Five pesticides were selected among 288 insecticides by considering the presence of an ionizable group, the log P, and boiling points. The correlation coefficients between log P and removal by tap water, 5% acetic acid, 20% ethanol, and 0.15% detergent were -0.835 (p<0.001), 0.336 (p=0.221), 0.659 (p<0.01), and -0.939 (p<0.001), respectively. Removal by blanching was affected by log P as it showed a positive correlation with a log P of 0.620 (p<0.05). Removal by frying showed a strong negative correlation with a log P of -0.913 (p<0.001). The results suggest that removing pesticides was affected largely by log P and by vapor pressure during cooking, whereas during washing, the matrix of the food also contributed to the reduction.

Soil Properties Affecting C-type slope as a Parameter for Silica Sorption of Soils (토양의 규산 흡착 지표인 C-type slope에 영향을 미치는 토양 특성)

  • Lee, Sang Eun;Lim, Woo Jin;Ahn, Jae Ho;Kim, Jeong-Gyu;Lim, Soo-Kil
    • Korean Journal of Soil Science and Fertilizer
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    • v.37 no.6
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    • pp.365-370
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    • 2004
  • To invesligate the characteristics of silica sorption on soils silica sorption experiments were conducted with 9 soils at 4 pH levels (5, 6, 7, and 8). Silica sorption increased in great extent with increase of pH. At the same pH level silica sorption increased linearly with increase of equilibrium $SiO_2$ concentration. Silica sorption characteristics was C-type. The C-type slope, i.e., the slope of linear regression of silica sorption isotherm, increased exponentially with increase of pH in all soils. Log(C-type slope) increased linearly with increase of pH in all soils. The slopes of linear regression were similar in most soils from 0.29 to 0.34 except Sachon and Jonggog soil. None of the soil properties showed any correlation with the slope of linear regression of Log(C-type slope) to pH. Only $Fe_o$ (oxalate extractable Fe oxides) was significantly correlated with the Log(C-type slope) at pH 7 in simple correlation analysis, and was shown to be the principal contributor as determined by standardized multiple linear regression.

Evaluation of Preconsolidation Stress Considering Small-Strain Shear Wave Velocity (미소변형 전단파 속도를 고려한 설행압밀하중 산정)

  • Yoon, Hyung-Koo;Lee, Chang-Ho;Kim, Joon-Han;Lee, Jong-Sub
    • Journal of the Korean Geotechnical Society
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    • v.25 no.5
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    • pp.5-16
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    • 2009
  • Preconsolidation stress is one of the important design parameters in soft soils because the behavior of saturated soft soils changes dramatically at the preconsolidation stress. For the estimation of preconsolidation stress, the global vertical settlement without considering micro strain behavior has been considered. The purpose of this study is to propose and verify a new method called the "shear wave velocity method" for determination of the preconsolidation stress reflecting on particle behavior at the small-strain. In this study, the undisturbed soft soils obtained at Busan, Incheon and Gwangyang in Korea were used. The oedometer cell incoporated with the bender elements is used for the consolidation tests under the $K_0$ condition. The preconsolidation stress determined by the proposed method is compared with that estimated by Casagrande (e-log p'), Sridharan (log (1+e)-log p'), and Onitsuka (In(1+e)-log p') methods. This study suggests that the shear wave velocity method may determine simply the preconsolidation stress with considering the small-strain behavior.

냉이김치의 저장시 변화 및 품질특성

  • 정외숙;임용숙;박금순
    • Proceedings of the Korean Society of Food and Cookery Science Conference
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    • 2003.10a
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    • pp.78-78
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    • 2003
  • 냉이의 품질을 유지할 수 있는 저장 방안의 하나로 raw 군과 blanched 군으로 담근 냉이 김치를 4$^{\circ}C$와 1$0^{\circ}C$에서 숙성하면서 품질 특성의 변화를 검토하였다. 김치 발효동안 4$^{\circ}C$의 경우 숙성 14일째 raw군의 젖산균수가 7.97 log CFU/ml, blanched 군은 6.4 log CFU/ml을 나타냈고, 1$0^{\circ}C$의 경우 숙성 15일째 raw 군의 젖산균수가 7.91 log CFU/ml, blanched 군은 6.4 log CFU/ml로 4$^{\circ}C$, 1$0^{\circ}C$ 모두 raw 군에 비해 blanched군이 다소 낮은 경향을 나타내었다. pH는 raw 군에 비해 blanched 군의 pH가 다소 높게 나타났으며 그 이후로도 비슷하게 나타났다. (중략)

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Effect of Addition Methods of Green Tea on Fermentation Characteristics of Kimchi (녹차의 첨가방법이 김치의 발효특성에 미치는 영향)

  • 김경희
    • Food Science and Preservation
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    • v.9 no.4
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    • pp.406-410
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    • 2002
  • This study was conducted to investigate the effect of addition methods of green tea on the fermentation characteristics of kimchi. Kimchis were prepared to 3 methods such as Chinese cabbage soaked in brine containing 1% of green tea extracts(Ⅰ), salted the cabbage soaked in water containing 1% of green tea extracts(II), salted the cabbage mixed with seasonings containing 1% of green tea extracts(Ⅲ), and fermented at l0$\^{C}$. pH of Ⅰ∼Ⅲ kimchis were higher than that of control kimchi during fermentation and its acidity showed the same tendency. Total microbe(5.40∼8.38 log cfu/mL) and the number of lactic acid bacteria(4.99∼8.07 log cfu/mL) in Ⅰ∼Ⅲ kimchis were lower than those of control kimchi(6.16∼9.29 and 4.59∼8.42 log cfu/mL). Lightness of kimchi tissue showed the order of Ⅰ<II<control<Ⅲ. Sour taste and fishy taste of Ⅰ∼Ⅲ kimchis were lower than that of control kimchi. Overall quality was best in II estimated by sensory evaluation and fermentation characteristics.

Quality Characteristics of the Simple Preprocessed Food Julienne White Radish and Pear during Storage and Development of a Standard Recipe (단순 가공 식품재료 활용을 위한 혼합무배생채의 저장기간에 따른 품질특성 및 레시피 기준 설정)

  • Park, Ji-Hyun;Baek, Ok-Hee
    • Journal of the East Asian Society of Dietary Life
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    • v.21 no.5
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    • pp.706-712
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    • 2011
  • This study was carried out to investigate the quality characteristics and microbiology of the simple preprocessed food julienne white radish and pear during storage at $4^{\circ}C$ and fordevelopment of a standard recipe. Total aerobic bacteria level were $3.20{\pm}0.08$ log CFU/g in julienne white radish and pear, and $3.00{\pm}0.14$ log CFU/g in julienne white radish (control). Coliform counts were $3.20{\pm}0.08$ log CFU/g in julienne white radish and pear and $1.84{\pm}0.17$ log CFU/g in julienne white radish. Low levels of coliform and total aerobic bacteria were detected. pH values of julienne white radish and pear increased significantly after 3days, whereas that of control increased significantly after 1day. Lightness and redness decreased during storage, whereas yellowness increased significantly during storage. During storage, hardness of julienne white radish and pear decreased after 3days, whereas that of julienne white radish decreased after 5days. According to sensory evaluation, 70% julienne white radish and 30% julienne pear showed higher score in term of taste, harmony of ingredient, harmony of sauce and overall preference. Consequently, 70% julienne white radish and 30% julienne pear was determined to the best formula and a maximum storage period of 3 days was showned to be optimal.

The study for compressibility of reconsititued Busan clay (부산점토 재성형 시료의 압축특성에 관한 연구)

  • Hong, Sung-Jin;Lee, Moon-Joo;Choi, Young-Min;Kim, Min-Tae;Lee, Woo-Jin
    • Proceedings of the Korean Geotechical Society Conference
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    • 2009.09a
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    • pp.1141-1146
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    • 2009
  • The compressibility of clay has been expressed e-log p' graph. In natural clay, e-log p' graph are changed by deposition condition and chemical cementation as well as Atterberg limits, whereas in reconstituted clay, it is generally known that e-log p’ curve is varied with Atterberg limits. However, e-log p' graph is possible to change according to the reconstituting methods and test conditions. In this study, consolidation tests are performed as various test condition for reconstituted Busan clay. Test results show that the relationship e/$e_L$ and log p' is almost constant with $e_L$. And the compression index obtained from slurry method sample is larger than one obtained from kneading method sample. Intrinsic compression line (ICL) of Busan clay is identical with ICL suggested by Burland.

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Long-term (2002~2017) Eutropication Characteristics, Empirical Model Analysis in Hapcheon Reservoir, and the Spatio-temporal Variabilities Depending on the Intensity of the Monsoon (합천호의 장기간 (2002~2017) 부영양화 특성, 경험적 모델 분석 및 몬순강도에 따른 시공간적 이화학적 수질 변이)

  • Kang, Yu-Jin;Lee, Sang- Jae;An, Kwang-Guk
    • Korean Journal of Environment and Ecology
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    • v.33 no.5
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    • pp.605-619
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    • 2019
  • The objective of this study was to analyze eutrophication characteristics, empirical model analysis, and variation of water quality according to monsoon intensity in Hapcheon Reservoir for 16 years from 2002 to 2017. Long-term annual water quality analysis showed that Hapcheon Reservoir was in a meso-nutrition to eutrophic condition, and the eutrophic state intensified after the summer monsoon. Annual rainfall volume (high vs. low rainfall) and the seasonal intensity in each year were the key factors that regulate the long-term water quality variation provided that there is no significant change of the point- and non-point source in the watershed. Dry years and wet years showed significant differences in the concentrations of TP, TN, BOD, and conductivity, indicating that precipitation had the most direct influence on nutrients and organic matter dynamics. Nutrient indicators (TP, TN), organic pollution indicators (BOD, COD), total suspended solids, and chlorophyll-a (Chl-a), which was an estimator of primary productivity, had significant positive relations (p<0.05) with precipitation. The Chl-a concentration, which is an indicator of green algae, was highly correlated with TP, TN, and BOD, which differed from other lakes that showed the lower Chl-a concentration when nutrients increased excessively. Empirical model analysis of log-transformed TN, TP, and Chl-a indicated that the Chl-a concentration was linearly regulated by phosphorus concentration, but not by nitrogen concentration. Spatial regression analysis of the riverine, transition, and lacustrine zones of $log_{10}TN$, $log_{10}TP$, and $log_{10}CHL$ showed that TN and Chl-a had significant relations (p<0.005) while TN and Chl-a had p > 0.05, indicating that phosphorus had a key role in the algal growth. Moreover, the higher correlation of both $log_{10}TP$ and $log_{10}TN$ to $log_{10}CHL$ in the riverine zone than the lacustrine zone indicated that there was little impact of inorganic suspended solids on the light limitation in the riverine zone.