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Development of Bifunctional Electrocatalyst for PEM URFC (고분자 전해질 막을 이용한 일체형 재생 연료전지용 촉매전극 개발)

  • Yim, Sung-Dae;Park, Gu-Gon;Sohn, Young-Jun;Yang, Tae-Hyun;Yoon, Young-Gi;Lee, Won-Yong;Kim, Chang-Soo
    • Journal of Hydrogen and New Energy
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    • v.15 no.1
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    • pp.23-31
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    • 2004
  • For the fabrication of high efficient bifunctional electrocatalyst of oxygen electrode for PEM URFC (Polymer Electrolyte Membrane Unitized Regenerative Fuel Cell), which is a promising energy storage and conversion system using hydrogen as the energy medium, several bifunctional electrocatalysts were prepared and tested in a single cell URFC system. The catalysts for oxygen electrode revealed fuel cell performance in the order of Pt black > PtIr > PtRuOx > PtRu ~ PtRuIr > PtIrOx, whereas water electrolysis performance in the order of PtIr ~ PtIrOx > PtRu > PtRuIr > PtRuOx ~ Pt black. Considering both reaction modes PtIr was the most effective elctrocatalyst for oxygen electrode of present PEM URFC system. In addition, the water electrolysis performance was significantly improved when Ir or IrOx was added to Pt black just 1 wt.% without the decrease of fuel cell performance. Based on the catalyst screening and the optimization of catalyst composition and loading, the optimum catalyst electrodes for PEM URFC were $1.0mg/cm^2$ of Pt black as hydrogen electrode and $2.0mg/cm^2$ of PtIr (99:1) as oxygen electrode.

Influence of different fatigue loads and coating thicknesses on service performance of RC beam specimens with epoxy-coated reinforcement

  • Wang, Xiao-Hui;Gao, Yang;Gao, Run-Dong;Wang, Jing;Liu, Xi-La
    • Computers and Concrete
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    • v.19 no.3
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    • pp.243-256
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    • 2017
  • Epoxy-coated reinforcing bars are widely used to protect the corrosion of the reinforcing bars in the RC elements under their in-service environments and external loads. In most field surveys, it was reported that the corrosion resistance of the epoxy-coated reinforcing bars is typically better than the uncoated bars. However, from the experimental tests conducted in the labs, it was reported that, under the same loads, the RC elements with epoxy-coated reinforcing bars had wider cracks than the elements reinforced with the ordinary bars. Although this conclusion may be true considering the bond reduction of the reinforcing bar due to the epoxy coating, the maximum service loads used in the experimental research may be a main reason. To answer these two phenomena, service performance of 15 RC beam specimens with uncoated and epoxy-coated reinforcements under different fatigue loads was experimentally studied. Influences of different coating thicknesses of the reinforcing bars, the fatigue load range and load upper limit as well as fatigue load cycles on the mechanical performance of RC test specimens are discussed. It is concluded that, for the test specimens subjected to the comparatively lower load range and load upper limit, adverse effect on the service performance of test specimens with thicker epoxy-coated reinforcing bars is negligible. With the increments of the coating thickness and the in-service loading level, i.e., fatigue load range, load upper limit and fatigue cycles, the adverse factor resulting from the thicker coating becomes noticeable.

An Experiemetal Study for Improvement of Seismic Performance of Steel Beam-to-Column Connections (철골 보-기둥 접합부의 내진성능 개선을 위한 실험적 연구)

  • 이승준;김원기;이정웅
    • Journal of the Earthquake Engineering Society of Korea
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    • v.3 no.4
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    • pp.61-70
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    • 1999
  • Cracking was observed in beam-to-column connections of many steel building frames during the 1994 Northridge and 1995 Kobe earthquakes. Thus extensive experimental researches are currently being conducted to improve the seismic performance of steel frames. A value of 0.015 radian was considered as a reasonable estimate of beam plastic rotation demand in steel moment-resisting frames subjected to severe earthquakes. The objective of this research is to develop a type of connection detail which moves the plastic hinge region in the beam away from the face of the column and can prevent cracking at the welded flange of the beam-to-column connection under seismic loading. An experimental investigation was undertaken on five beam-to-column connection specimens to study the performance of the connections with proposed details. The experiemental results showed that the flexural strength and rotational ductility of the beam connections were adequate for the seismic resistance steel frames to prevent possible cracks at the connections.

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Performance Predictions of Gas Foil Journal Bearing with Shim Foils (심포일을 갖는 가스 포일 저널 베어링의 성능 예측)

  • Hwang, Sung Ho;Moon, Chang Gook;Lee, Jong Sung;Kim, Tae Ho
    • Tribology and Lubricants
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    • v.34 no.3
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    • pp.107-114
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    • 2018
  • This paper presents a computational model of a gas foil journal bearing with shim foils between the top foil and bumps, and predicts its static and dynamic performance. The analysis takes the previously developed simple elastic foundation model for the top foil-bump structure and advances it by adding foil models for the "shim foil" and "outer top foil." The outer top foil is installed between the (inner) top foil and bumps, and the shim foil is installed between the inner top foil and outer top foil. Both the inner and outer top foils have an arc length of $360^{\circ}$, but the arc length of the shim foil is shorter, which causes a ramp near its leading edge in the bearing clearance profile. The Reynolds equation for isothermal and isoviscous ideal gas solves the hydrodynamic pressure that develops within the bearing clearance with preloads due to the ramp. The centerline pressure and film thickness predictions show that the shim foil mitigates the peak pressure occurring at the loading direction, and broadens the positive pressure as well as minimum film thickness zones except for the shortest shim foil arc length of $180^{\circ}$. In general, the shim foil decreases the journal eccentricity, and increases the power loss, direct stiffness, and damping coefficients. As the shim foil arc length increases, the journal eccentricity decreases while the attitude angle, minimum film thickness, and direct stiffness/damping coefficients in the horizontal direction increase.

Structural Performance of Beam-Column Connections Using 51 mm Diameter with Different Anchorage Details (51 mm 대구경 철근을 사용한 외부 보-기둥 접합부의 정착상세별 구조성능 평가)

  • Kim, Jung-Yeob;Jung, Hyung-Suk;Chun, Sung-Chul;Kim, In-Ho;Choi, Chang-Sik
    • Journal of the Korea Concrete Institute
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    • v.29 no.2
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    • pp.201-208
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    • 2017
  • In exterior beam-column joints, hooked bars are used for anchorage, but usage of high-strength and large-diameter bars increases, headed bar is preferred for solving steel congestion and difficulty in construction. To investigate the structural performance of headed bars, Six exterior beam-column joints were tested under cyclic loading. Tests parameter were the anchorage methods and concrete strength. The test results indicate that behavior of headed bar specimens shows similar performance with hooked bar specimens. All specimens failed by flexural failure of the beam. Headed bar specimens shows better performance in anchorage and joint shear. All specimens were satisfied the criteria of ACI374.1-05. Test results indicate that use of headed bar in exterior beam column joint is available.

Numerical analysis of the seismic performance of RHC-PVCT short columns

  • Xue, Jianyang;Zhao, Xiangbi;Ke, Xiaojun;Zhang, Fengliang;Ma, Linlin
    • Advances in concrete construction
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    • v.8 no.4
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    • pp.257-267
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    • 2019
  • This paper presents the results of cyclic loading tests on new high-strength concrete (HC) short columns. The seismic performance and deformation capacity of three reinforced high-strength concrete filled Polyvinyl Chloride tube (RHC-PVCT) short columns and one reinforced high-strength concrete (RHC), under pseudo-static tests (PSTs) with vertical axial force was evaluated. The main design parameters of the columns in the tests were the axial compression ratio, confinement type, concrete strength, height-diameter ratio of PVCT. The failure modes, hysteretic curves, skeleton curves of short columns were presented and analyzed. Placing PVCT in the RHC column could be remarkably improved the ultimate strength and energy dissipation of columns. However, no fiber element models have been formulated for computing the seismic responses of RHC-PVCT columns with PVT tubes filled with high-strength concrete. Nonlinear finite element method (FEM) was conducted to predict seismic behaviors. Finite element models were verified through a comparison of FEM results with experimental results. A parametric study was then performed using validated FEM models to investigate the effect of several parameters on the mechanical properties of RHC-PVCT short columns. The parameters study indicated that the concrete strength and the ratio of diameter to height affected the seismic performance of RHC-PVCT short column significantly.

SDN/NFV Based Web Cache Consistency and JavaScript Transmission Acceleration Scheme to Enhance Web Performance in Mobile Network (모바일 네트워크에서 SDN/NFV 기반의 웹 성능 향상을 위한 웹 캐시 일관성 제공과 JavaScript 전송 가속화 방안)

  • Kim, Gijeong;Lee, Sungwon
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.39B no.6
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    • pp.414-423
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    • 2014
  • The number and size of resource constituting the web page has been increasing steadily, and this circumstance leads to rapidly falling quality of web service in mobile network that offer relatively higher delay. Moreover, Improving the quality of a web services protocol is difficult to provide network function because the current network architecture has closed structure. In this paper, we suggest schemes to enhance web performance in mobile network, which are Check Coded DOM scheme and Functional JavaScript Transmission scheme, and then try to seek idea which can be provided suggested schemes as a network function using NFV(Network Function Virtualization). For the performance evaluation and analysis about the suggested schemes, we perform network simulation using SMPL library. We confirm that suggested schemes offer better performance in term of page loading time, the number of message and the amount of traffic in the network than HTTP Protocol.

Evaluation of Warm Mix Asphalt Mixtures with Foaming Technology and Additives Using New Simple Performance Testing Equipment (새로운 Simple Performance Testing 장비를 이용한 중온형 폼드 아스팔트 혼합물의 공용성 평가)

  • Kim, Yong-Joo;Im, Soo-Hyok;Lee, David;Hwang, Sung-Do
    • International Journal of Highway Engineering
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    • v.10 no.4
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    • pp.19-29
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    • 2008
  • To produce asphalt mixtures at temperature significantly below $135^{\circ}C$, called "Warm Mix Asphalt (WMA)", new technologies are currently being developed worldwide. To produce WMA mixtures in this research, foaming technology is adopted to effectively disperse asphalt binder at lower temperature than hot mix asphalt (HMA) in the field. The main objectives of this study are to develop WMA process using foaming technology (WMA-foam) and evaluate its performance characteristics under various temperatures and loading conditions. WMA-foam mixtures were produced by injecting PO 64-22 foamed asphalt into warm aggregates whereas WMA mixtures were produced by adding PO 64-22 asphalt (without foaming) in the warm aggregates. Both dynamic modulus and flow number of WMA-foam mixtures were higher than those of WMA mixtures. Based on the limited dynamic modulus and repeated load test results, it is concluded that the WMA-foam mixtures using warm aggregates at $100^{\circ}C$ are more resistant to fatigue cracking and rutting than WMA mixtures.

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Performance Analysis of Friction Damper Considering the Change of the Vertical Force (수직력의 변화를 고려한 마찰댐퍼의 거동 분석)

  • Cho, Sung Gook;Park, Woong Ki;Yi, Seong-Tae
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.21 no.1
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    • pp.59-66
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    • 2017
  • In this paper, to protect the piping in nuclear power plants and various plant facilities, we have developed a damper using the friction method and carried out a study to analyze the performance. Friction typed damper means a device for attenuating vibration by generating a frictional force to the bearing and the shaft by applying a compressive force to the MER-Spring. In order to analyze the performance of the damper, the properties of MER-Spring and friction materials were analyzed, a study on the effects of friction was carried out, and the behavior of this equation was established. And, to determine whether deformation of the material and to examine the reliability of the behavior equation established, prototypes was produced and, through a performance test and finite element analysis of a damper made of specimens, they were analyzed. As a result, it is noted that the reliability of the material was confirmed, the coefficient of friction have to be adjusted according to the velocity, cyclic loading test and finite element analysis results show exhibits excellent results. In addition, a review of the dynamic loads in the future shall be performed for the usage in more broad fields.

Performance Analysis with Various Amounts of Electrolyte in a Molten Carbonate Fuel Cell

  • Kim, Yu-Jeong;Kim, Tae-Kyun;Lee, Ki-Jeong;Lee, Choong-Gon
    • Journal of Electrochemical Science and Technology
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    • v.7 no.3
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    • pp.234-240
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    • 2016
  • The effect of initial electrolyte loading (IEL) on cell performance in a coin-type molten carbonate fuel cell (MCFC) was investigated in this work. Since the material of MCFC depends on the manufacturer, optimisation requires experimental investigation. In total, four IEL values, 1.5, 2.0, 3.0, and 4.0 g, were used, corresponding to a pore filling ratio (PFR) of 38, 51, 77, and 102%, respectively. The cell performance with respect to the PFR was analysed via steady-state polarisation, step-chronopotentiomtery, and impedance methods. The electrochemical analyses revealed that internal resistance and overpotential of the cell decreased with increasing PFR, and a large overpotential was observed when the PFR was 102%, probably due to the flooding phenomenon. After operation, cross-section of the cell was analysed via surface analysis of SEM and EDS methods, and the remaining electrolyte was estimated by dissolution of the cell in 10 wt% acetic acid. A linear relationship between IEL and the weight reduction ratio by dissolution was obtained. Thus, the remaining amount of electrolyte could be measured after operation. The results of SEM and EDS showed that a PFR of 38 and 102% showed a lack and flooding of electrolytes at the cell, respectively, which led to a large overpotential. This work reports that MCFC performance is allowed only in the narrow range of PFR.