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Effect of LiCoO2 Cathode Density and Thickness on Electrochemical Performance of Lithium-Ion Batteries

  • Choi, Jaecheol;Son, Bongki;Ryou, Myung-Hyun;Kim, Sang Hern;Ko, Jang Myoun;Lee, Yong Min
    • Journal of Electrochemical Science and Technology
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    • v.4 no.1
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    • pp.27-33
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    • 2013
  • The consequences of electrode density and thickness for electrochemical performance of lithium-ion cells are investigated using 2032-type coin half cells. While the cathode composition is maintained by 90:5:5 (wt.%) with $LiCoO_2$ active material, Super-P electric conductor and polyvinylidene fluoride polymeric binder, its density and thickness are independently controlled to 20, 35, 50 um and 1.5, 2.0, 2.5, 3.0, 3.5 g $cm^{-3}$, respectively, which are based on commercial lithium-ion battery cathode system. As the cathode thickness is increased in all densities, the rate capability and cycle life of lithium-ion cells become significantly worse. On the other hand, even though the cathode density shows similar behavior, its effect is not as high as the thickness in our experimental range. This trend is also investigated by cross-sectional morphology, porosity and electric conductivity of cathodes with different densities and thicknesses. This work suggests that the electrode density and thickness should be chosen properly and mentioned in detail in any kinds of research works.

Structural Performance Evaluation of Buckling-Restrained Braces Made of High-Strength Steels (고강도강 비좌굴 가새의 구조성능 평가)

  • Park, Man Woo;Ju, Young Kyu;Kim, Myeong Han;Kim, Ji Young;Kim, Sang Dae
    • Journal of Korean Society of Steel Construction
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    • v.20 no.1
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    • pp.33-42
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    • 2008
  • Buckling-Restrained Braces (BRB) has been developed to inhibit buckling and exhibit stable behavior underboth tensile and compresive cycles. In this study, an experime nt has been conducted by using the strength of its members and loading protocols as parameters to evaluate the structural performance of BRB (without in-filed concrete). Specimens are composed of an inner core and an outer tube with diferent steel strengths. When high-strength steels were used as iner cores, the ductility of BRB decreased, and the requirements (Cumulative Plastic Ductility) of the AISC Seismic Provisions were not satisfied. however, when high-strength steels were used as inner cores instead of conventional strength stel cores, the maximum capacity increased significantly and displayed similar performance in total energy dissipation.

Performance of U3Si-Al dispersion fuel at HANARO full-power condition

  • Chae, Heetaek;Lee, Choong Sung;Park, Jong Man;Kim, Heemoon;Kim, Yeon Soo
    • Nuclear Engineering and Technology
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    • v.50 no.6
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    • pp.899-906
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    • 2018
  • The irradiation performance of $U_3Si$ dispersion fuel in an Al matrix, $U_3Si-Al$, under the Hi-Flux Advanced Neutron Application Reactor (HANARO) design full-power condition of 30 MW was tested for full-power qualification of the fuel. A test assembly was fabricated containing 18 fuel rods made with atomized $U_3Si$ powder manufactured at the Korea Atomic Energy Research Institute. The test assembly was irradiated for 188 full-power operation days in the HANARO subject to the normal fuel-loading scheme and achieved about 60 at% U-235 average burnup and 75 at% U-235 peak burnup. The maximum linear power of the test assembly was 98 kW/m. Nondestructive and destructive postirradiation examinations were conducted. The measured postirradiation examination data were compared with data from previous irradiations and the design criteria required for HANARO fuel. Consequently, it was concluded that in-pile performance was acceptable and fuel integrity was maintained, and the behavior satisfied the fuel design requirements.

Development of Improved PC Stair Connections Using U-Rods (U형 강봉을 사용한 PC 계단 접합부 개발)

  • Chang, Kug-Kwan;Seo, Dae-Won;Chun, Young-Soo
    • Land and Housing Review
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    • v.2 no.4
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    • pp.509-516
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    • 2011
  • Compared with the traditional RC system, precast stairs can save construction time, reduce the cost of concrete casting, etc. This paper focuses on an investigation of improved continuous longitudinal joint details for PC stair systems. The performance of the precast concrete stair connections subjected to displacement control cyclic loading is compared with that of the monolithic connection. The developed connection is composed of U-rods and clamp joint metals. This paper proposes precast stair connection with improved structural performance and experimentally evaluates the structural performance of the proposed joints in terms of maximum load, displacement ductiliy, strain, crack and failure modes.

Effect of the Blade Leading Edge on the Performance of a Centrifugal Compressor

  • Chu, Leizhe;Du, Jianyi;Zhao, Xiaolu;Xu, Jianzhong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.03a
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    • pp.168-172
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    • 2008
  • Three different geometry shapes of the blade leading edge in a centrifugal compressor were investigated in this paper. Numerical simulation was done to analyze the effect of the leading edge shape on the performance of the centrifugal compressor. The result shows that compared to the blunt leading edge, the circular leading edge will raise the chocking mass flow. The pressure ratio and efficiency will increase obviously. Using elliptical leading edge will get a further improvement on the performance than circular leading edge. The analysis of the flow field shows that the leading edge often causes flow separation near the inlet; using circular leading edge and elliptical leading edge will reduce the separation. What's more, using circular and elliptical leading edge will also reduce the wake loss near the outlet of the impeller. In a centrifugal compressor, using circular or elliptical leading edge on the splitter will improve the pressure loading distribution of main blade near the position of the splitter leading, which will increase the pressure ratio.

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Effect of staircase on seismic performance of RC frame building

  • Kumbhar, Onkar G.;Kumar, Ratnesh;Adhikary, Shrabony
    • Earthquakes and Structures
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    • v.9 no.2
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    • pp.375-390
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    • 2015
  • Staircase is a vertical transportation element commonly used in every multistoried structure. Inclined flights of staircase are usually casted monolithically with RC frame. The structural configuration of stairs generally introduces discontinuities into the typical regular reinforced concrete frame composed of beams and columns. Inclined position of flight transfers both vertical as well as horizontal forces in the frame. Under lateral loading, staircase in a multistory RC frame building develops truss action creating a local stiffening effect. In case of seismic event the stiff area around staircase attracts larger force. Therefore, special attention is required while modeling and analyzing the building with staircase. However, in general design practice, designers usually ignore the staircase while modeling either due to ignorance or to avoid complexity. A numerical study has been conducted to examine the effect of ignoring staircase in modeling and design of RC frame buildings while they are really present in structure, may be at different locations. Linear dynamic analysis is performed on nine separate building models to evaluate influence of staircase on dynamic characteristics of building, followed by nonlinear static analysis on the same models to access their seismic performance. It is observed that effect of ignoring staircase in modeling is severe and leads to unsafe structure. Effect of location and orientation of staircase is also important in determining seismic performance of RC frame buildings.

Seismic performance assessment of reinforced concrete bridge piers supported by laminated rubber bearings

  • Kim, T.H.;Kim, Y.J.;Shin, H.M.
    • Structural Engineering and Mechanics
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    • v.29 no.3
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    • pp.259-278
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    • 2008
  • This paper presents a nonlinear finite element procedure accounting for the effects of geometric as well as material nonlinearities for reinforced concrete bridge piers supported by laminated rubber bearings. Reinforced concrete bridge piers supported by laminated rubber bearings and carrying a cyclic load were analyzed by using a special purpose, nonlinear finite element program, RCAHEST. For reinforced concrete, the proposed robust nonlinear material model captures the salient response characteristics of the bridge piers under cyclic loading conditions and addresses with the influence of geometric nonlinearity on post-peak response of the bridge piers by transformations between local and global systems. Seismic isolator element to predict the behaviors of laminated rubber bearings is also developed. The seismic performance of reinforced concrete bridge piers supported by laminated rubber bearings is assessed analytically. The results show good correlation between the experimental findings and numerical predictions, and demonstrate the reliability and robustness of the proposed analytical model. Additionally, the studies and discussions presented in this investigation provide an insight into the key behavioral aspects of reinforced concrete bridge piers supported by laminated rubber bearings.

A green transportation model in reverse logistics network and its comparative assessment for environmental impacts (역물류 네트워크에서의 친환경 운송 모델 개발 및 환경영향평가 비교 분석)

  • Kim, Ki Hong;Shin, Seoung-Jun;Chung, Byung Hyun
    • Journal of the Korea Safety Management & Science
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    • v.17 no.3
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    • pp.239-246
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    • 2015
  • Enforced environmental regulations call for extending the domain of manufacturers' responsibility to the entire product life cycle. To comply with the environmental regulations, manufacturers have constructed reverse logistics networks to re-collect their leftover waste for recycling consumed resources. However, the operational activities associated with storage, loading and transportation processes within the networks inevitably impose environmental burdens. Particularly, the transportation process largely influences environmental performance due to perpetual uses of transportation vehicles. Therefore, there is a need to develop an environmentally-conscious transportation model that can efficiently manage the uses of transportation vehicles. Additionally, it is vital to analyze its significances of environmental performance to compare quantitatively it with existing models. This paper proposes a transportation model for improving environmental performance in a reverse logistics network. This paper also presents a case study to perform its comparative analysis using Life Cycle Assessment that evaluates potential environmental impacts of a product system.

Evaluations of a Seismic Performance of Geosynthetic-Reinforced Embankment Supporting Piles for a Ultra Soft Ground (침하 억제를 위하여 초연약지반에 설치된 섬유보강 성토지지말뚝의 내진성능 평가)

  • Lee, Il-Wha;Kang, Tae-Ho;Lee, Su-Hyung;Lee, Sung-Jin;Bang, Eui-Seok
    • Proceedings of the KSR Conference
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    • 2008.11b
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    • pp.918-927
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    • 2008
  • The problems associated with constructing high-speed concrete track embankments over soft compressible soil has lead to the development and/or extensive use of many of the ground improvement techniques used today. Drains, surcharge loading, and geosynthetic reinforcement, have all been used to solve the settlement and embankment stability issues associated with construction on soft soils. Geosynthetic-reinforced embankment supporting piles method consist of vertical columns that are designed to transfer the load of the embankment through the soft compressible soil layer to a firm foundation and one or more layers of geosynthetic reinforcement placed between the top of the columns and the bottom of the embankment. In the paper, the evaluations of a seismic performance of geosynthetic-reinforced embankment piles for a ultra soft ground during earthquake were studied. the equivalent linear analysis was performed by SHAKE for soft ground. A seismic performance analysis of Piles was performed by GROUP PILE and PLAXIS for geosynthetic-reinforced embankment piles. Guidelines is required for pile displacement during earthquake. Conclusions of the studies come up with a idea for soil stiffness, conditions of pile cap, pile length and span.

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CONTAINMENT PERFORMANCE EVALUATION OF PRESTRESSED CONCRETE CONTAINMENT VESSELS WITH FIBER REINFORCEMENT

  • CHOUN, YOUNG-SUN;PARK, HYUNG-KUI
    • Nuclear Engineering and Technology
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    • v.47 no.7
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    • pp.884-894
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    • 2015
  • Background: Fibers in concrete resist the growth of cracks and enhance the postcracking behavior of structures. The addition of fibers into a conventional reinforced concrete can improve the structural and functional performance of safety-related concrete structures in nuclear power plants. Methods: The influence of fibers on the ultimate internal pressure capacity of a prestressed concrete containment vessel (PCCV) was investigated through a comparison of the ultimate pressure capacities between conventional and fiber-reinforced PCCVs. Steel and polyamide fibers were used. The tension behaviors of conventional concrete and fiber-reinforced concrete specimens were investigated through uniaxial tension tests and their tension-stiffening models were obtained. Results: For a PCCV reinforced with 1% volume hooked-end steel fiber, the ultimate pressure capacity increased by approximately 12% in comparison with that for a conventional PCCV. For a PCCV reinforced with 1.5% volume polyamide fiber, an increase of approximately 3% was estimated for the ultimate pressure capacity. Conclusion: The ultimate pressure capacity can be greatly improved by introducing steel and polyamide fibers in a conventional reinforced concrete. Steel fibers are more effective at enhancing the containment performance of a PCCV than polyamide fibers. The fiber reinforcementwas shown to bemore effective at a high pressure loading and a lowprestress level.