• Title/Summary/Keyword: loaded stream

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Site - Specific Frost Warning Based on Topoclimatic Estimation of Daily Minimum Temperature (지형기후모형에 근거한 서리경보시스템 구축)

  • Chung Uran;Seo Hee Cheol;Yun Jin I.
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.6 no.3
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    • pp.164-169
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    • 2004
  • A spatial interpolation scheme incorporating local geographic potential for cold air accumulation (TOPSIM) was used to test the feasibility of operational frost warning in Chatancheon basin in Yeoncheon County, where the introduction of new crops including temperate zone fruits is planned. Air temperature from April to June 2003 was measured at one-minute intervals at four locations within the basin. Cold-air accumulation potentials (CAP) at 4 sites were calculated for 3 different catchment scales: a rectangular area of 65 x 55 km which covers the whole county, the KOWACO (Korea Water Corporation) hydrologic unit which includes all 4 sites, and the sub-basins delineated by a stream network analysis of the digital elevation model. Daily minimum temperatures at 4 sites were calculated by interpolating the perfect prognosis (i.e., synoptic observations at KMA Dongducheon station) based on TOPSIM with 3 different CAPs. Mean error, mean absolute error, and root mean square error were calculated for 45 days with no precipitation to test the model performance. For the 3 flat locations, little difference was detected in model performance among 3 catchment areas, but the best performance was found with the CAPs calculated for sub-basins at one site (Oksan) on complex terrain. When TOPSIM loaded with sub-basin CAPs was applied to Oksan to predict frost events during the fruit flowering period in 2004, the goodness of fit was sufficient for making an operational frost warning system for mountainous areas.

Determination of Cd(II) after Preconcentration onto Microcrystalline p-Dichlorobenzene Loaded with 2-Mercaptobenzothiazole (2-Mercaptobenzothiazole이 내포된 p-Dichlorobenzene 미세결정으로 예비농축시킨 후 Cd(II) 정량)

  • Yoon, Ju-Im;Choi, Hee-Seon
    • Journal of the Korean Chemical Society
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    • v.53 no.1
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    • pp.27-33
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    • 2009
  • A sensitive technique for the determination of trace Cd(II) in various real samples after preconcentration onto microcrystalline p-dichlorobenzene loaded with 2-mercaptobenzothiazole was developed. Several experimental conditions such as the pH of the sample solution, the amount of chelating agent 2-mercaptobenzothiazole, the amount of adsorbent p-dichlorobenzene-2-MBT, and the flow rate of sample solution were optimized. The interfering effects of various concomitant ions were investigated. Cu(II) interfered with more seriously than any other ions. However, the interference by Cu(II) could be overcome sufficiently by adjusting tartrate ion concentration to be 0.01M or by controlling the amount of 2-mercaptobenzothiazole contained in 0.20 g p-dichlorobenzene to be 0.12 g. The dynamic range, the correlation coefficient ($R^2$) and the detection limit obtained by this proposed technique were $0.5{\sim}30$ ng $mL^{-1}$, 0.9962, and 0.39 ng $mL^{-1}$, respectively. Thus, good results were obtained by the use of p-dichlorobenze as adsorbent matrix. For validating this proposed technique, the aqueous samples(wastewater, stream water, and reservoir water) and the plastic sample were used. Recovery yields of $93{\sim}104$ % were obtained. By F test, these measured data were not different from ICP-MS data at 95 % confidence level. Based on the results from the experiment, it was found that this proposed technique could be applied to the preconcentration and determination of Cd(II) in various real samples.

Determination and preconcentration of Cu(II) using microcrystalline p-Dichlorobenzene loaded with salicylaldoxime (Salicylaldoxime이 내포된 p-Dichlorobenzene 미세결정을 이용한 Cu(II)의 예비농축 및 정량)

  • Lee, Ha-Na;Choi, Hee-Seon
    • Analytical Science and Technology
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    • v.23 no.3
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    • pp.240-246
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    • 2010
  • A technique for the determination of trace Cu(II) in various real samples by FAAS after the column preconcentration onto p-dichlorobenzene-SA adsorbent, which is microcrystalline p-dichlorobenzene loaded with salicylaldoxime (SA) has been developed. Several experimental conditions such as pH of the sample solution, the amount of chelating agent salicylaldoxime, the amount of adsorbent p-dichlorobenzene-SA, and flow rate of sample solution were optimized. The interfering effects of various concomitant ions were investigated. $CN^-$ interfered more seriously than any other ions. However, the interference by $1\;{\mu}g\;mL^{-1}\;CN^-$ could be overcome completely by controlling the concentration of Ni(II) to $20\;{\mu}g\;mL^{-1}$. The linear range, correlation coefficient ($R^2$) and detection limit obtained by this technique were $3.0\sim100\;ng\;mL^{-1}$, 0.9901, and $3.1\;ng\;mL^{-1}$, respectively. For validating this technique, the aqueous samples (wastewater, reservoir water and stream water) and the food samples (orange juice, fresh egg and skim milk) were used. Recovery yields of 93~104% were obtained. These measured mean values were not differents from ICP-MS data at 95% confidence level. The good results were obtained from the experiments using the rice flour certified reference material (CRM) sample. Based on the experimental results, it was found that this technique could be applied to the preconcentration and determination of Cu(II) for various real samples.

Ion Exchange of Glutamic Acid Coupled with Crystallization (결정화 반응이 결합된 글루탐산의 이온교환)

  • 이기세
    • KSBB Journal
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    • v.11 no.5
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    • pp.606-612
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    • 1996
  • A specific ammino auid in a mixture can be crystallized inside an ion exchange column when displacer concentration is high enough to concentrate the amino acid in a pure band beyond its solubility limit. Glutamic acid formpd a discrete crystal layer in a cation exchanger column by operating displacement development mode and using a high concentration of displacer NaOH. The glutamic acid crystal formed was eluded from the column with the effluent stream and collected in a fraction collector. When 1.0 M of NaOH was used as a displacer, more than 60% of the loaded glutamic acid was recovered as crystal. The continuous crystallization and dissolution of crystal occurred, resulting in apparent movement of the crystal along the column without clogging or pressure increase. NaOH was proved a better displacer than NaCl because hydroxide ions neutralized hydrogen ions released from the resin and thus reduced the number of hydrogen ion competing with sodium ion for re-adsorption. The displacement development process coupled with crystallization provided higher concentration and recovery of glutamic acrid than conventional chromatography.

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L-THIA Modification and SCE-UA Application for Spatial Analysis of Nonpoit Source Pollution at Gumho River Basin (환경부 토지피복 중분류 적용을 위한 L-THIA 모델 수정과 SCE-UA연계적용에 의한 금호강유역 비점오염 분포파악)

  • Kim, Jung-Jin;Kim, Tae Dong;Choi, Dong Hyuk;Lim, Kyoung Jae;Engel, Bernard;Jeon, Ji-Hong
    • Journal of Korean Society on Water Environment
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    • v.25 no.2
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    • pp.311-321
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    • 2009
  • Long-Term Hydrologic Impact Assessment (L-THIA) was modified to improve runoff and pollutant load prediction for Korean watersheds with changes in land use classification and event mean concentration produced from observed data in Korea. The L-THIA model was linked with SCE-UA, which is one of the global optimization techniques, to automatically calibrate direct runoff. Modified L-THIA model was applied to Gumho River Basins to analyze spatial distribution of nonpoint source pollution. The results of model calibration during 1991~2000 and validation during 1981~1990 for direct runoff represented high model efficiency of 0.76 for calibration and 0.86 for validation. As a results of spatial analysis of nonpoint source pollution, the BOD was mainly loaded from urban area but SS, TN, and TP from agricultural area which is mainly located along the stream. Modified L-THIA model improve its accuracy with minimum imput data and application efforts. From this study, we can find out the L-THIA model is very useful tool to predict direct runoff and pollutant loads from the watershed and spatial analysis of nonpoint source pollution.

A Development of System for Flood Runoff Forecasting using Neural Network Model (신경망 모형을 이용한 홍수유출 예측시스템의 재발)

  • Ahn, Sang-Jin;Jun, Kye-Won
    • Journal of Korea Water Resources Association
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    • v.37 no.9
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    • pp.771-780
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    • 2004
  • The purpose of this study is to test a development of system for flood runoff forecasting using neural network model. As the forecasting models for flood runoff the neural network model was tested with the observed flood data at Gongju and Buyeo stations. The neural network model consists of input layer, hidden layer, and output layer. For the flood events tested rainfall and runoff data were the input to the input layer and the flood runoff data were used in the output layer. To make a choice the forecasting model which would make up of runoff forecasting system properly, real-time runoff of river when flood periods were forecasted by using neural network model and state-space model. A comparison of the results obtained by the two forecasting models indicated the superiority and reliability of the neural network model over the state-space model. The neural network model was modified to work in the Web and developed to be the basic model of the forecasting system for the flood runoff. The neural network model developed to be used in the Web was loaded into the server and was applied to the main stream of Geum river. For the main stage gauging stations mentioned above the applicability of the selected forecasting model, the Neural Network Model, was verified in the Web.

Preparation of Branched Dextran Microspheres of Soluble Interferon-alpha and its Activity In Vitro and In Vivo

  • Hong, Hua;Jo, Jeong-Rang;Yeon, Ji-Hyeon;Hong, Jun-Tack;Jung, Kyung-Hwan;Yoo, Sun-Kyun;Jang, Byeong-Churl
    • Journal of Microbiology and Biotechnology
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    • v.21 no.2
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    • pp.176-182
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    • 2011
  • The study objective was to prepare biodegradable branched dextran microspheres encapsulated with His-tagged interferon-alpha (BDM-hIFN-${\alpha}$) and evaluate its activity in vitro and in vivo. The glycidyl methacrylate derivatized dextrans (Dex-GMA) as precursor was primarily synthesized by substituting hydroxyl groups of either the branched or linear type of dextran with GMA. Dex-GMA microspheres loaded with hIFN-${\alpha}$ was then prepared by the water-in-water emulsion technique. In vitro release and Western blotting experiments demonstrated the retained activity of hIFN-${\alpha}$ released from branched dextran microspheres at 24 h by inducing phosphorylation of signal transducer and activator transcription-1 (STAT-1), a down-stream effector of IFN-${\alpha}$, in HepG2 cells. Animal data further revealed a peak of plasma levels of IFN-${\alpha}$ in rats injected intravenously with BDM-hIFN-${\alpha}$ at 10 min post-injection, but a sharp decline at 2 h. High plasma levels of neopterin, a plasma protein induced by IFN-${\alpha}$, were also detected in rats injected with BDM-hIFN-${\alpha}$ at 10 min post-injection. Notably, plasma levels of neopterin remained high at 4 h, but largely declined thereafter.

Aerodynamic control capability of a wing-flap in hypersonic, rarefied regime: Part II

  • Zuppardi, Gennaro;Vangone, Daniele
    • Advances in aircraft and spacecraft science
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    • v.4 no.5
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    • pp.503-514
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    • 2017
  • The attitude control of an aircraft is usually fulfilled by means of thrusters at high altitudes. Therefore, the possibility of using also aerodynamic surfaces would produce the advantage of reducing the amount of fuel for the thrusters to be loaded on board. For this purpose, Zuppardi already considered some aerodynamic problems linked to the use of a wing flap in a previous paper. A NACA 0010 airfoil with a trailing edge flap of 35% of the chord, in the range of angle of attack 0-40 deg and flap deflections up to 30 deg was investigated. Computer tests were carried out in hypersonic, rarefied flow by a direct simulation Monte Carlo code at the altitudes of 65 and 85 km of Earth Atmosphere. The present work continues this subject, considering the same airfoil and free stream conditions but two flap extensions of 45% and 25% of the chord and two flap deflections of 15 and 30 deg. The main purpose is to compare the influence of the flap dimension with that of the flap deflection. The present analysis is carried out in terms of: 1) percentage variation of the global aerodynamic coefficients with respect to the no-flap configuration, 2) increment of pressure and heat flux on the airfoil lower surface due to the Shock Wave-Shock Wave Interaction (SWSWI) with respect to the same quantities with no SWSWI or in no-flap configuration, 3) flap hinge moment. Issues 2) and 3) are important for the design of the mechanical and thermal protection system and of the flap actuator, respectively. Under the above mentioned test and geometrical conditions, the flap deflection is aerodynamically more effective than the flap extension, because it involves higher variation of the aerodynamic coefficients. However, tests verify that a smaller deflection angle involves the advantage of a smaller increment of pressure and heat flux on the airfoil lower surface, due to SWSWI, as well as a smaller hinge moment.

Improvement Proposal for the Fire Suppression Systems of Open Parking Lots (개방형주차장의 소방설비 개선 제안)

  • Jeong, Keesin
    • Fire Science and Engineering
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    • v.30 no.6
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    • pp.1-8
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    • 2016
  • In cars, the amount of combustibles, such as plastics, textiles, etc., have increased dramatically to improve the fuel efficiency of cars by reducing the gross vehicle weight according to the increases in an oil price and to reduce environmental problems. One or two cars were involved in a parking lot fire prior to the mid-2000 s. On the other hand, there were many parking lot fires where the entire car was destroyed due to increasing the use of plastics. In this study, the quantity of combustibles in a car was 316.2 kg over a total weight 1935 kg. This is 16.34% of total weight and 10 times greater than that three decades earlier. When a sprinkler is installed as a parking lot fire protection system as a substitute for water spray, the water discharge of the sprinkler must maintain the original density of water spray, $20lpm/m^2$. In addition, the use of a hose reel $CO_2$ system at pilotis parking lots must be prohibited because the hose reel $CO_2$ system has no adaptability for a car fire. Instead, this study proposes foam, dry powder, loaded stream systems be used in parking lot fire suppression systems.

Determination of Cadmium(II) and Copper(II) by Flame Atomic Absorption Spectrometry after Preconcentration on Column with Pulverized Amberlite XAD-4 with Bismuthiol I

  • Park, Dong-Seok;Choi, Hee-Seon
    • Bulletin of the Korean Chemical Society
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    • v.28 no.8
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    • pp.1375-1382
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    • 2007
  • A column preconcentration method with pulverized Amberlite XAD-4 loaded with bismuthiol I (BI) has been developed for the determination of trace Cd(II) and Cu(II) in various real samples by flame atomic absorption spectrophotometry. Various experimental conditions, such as the size of XAD-4, adsorption flow rate, amount of bismuthiol I, stirring time for adsorbing bismuthiol I on XAD-4, pH of sample solution, amount of XAD-4- BI, desorption solvent, and desorption flow rate, were optimized. Also, the adsorption capacity and the adsorption rate of Cd(II) and Cu(II) on XAD-4-BI were investigated. The interfering effects of various concomitant ions were investigated, Bi(III), Sn(II) and Fe(III) were found to affect the determination. But the interference by these ions was completely eliminated by adjusting the amount of XAD-4-BI resin to 0.70 g, although the adsorption flow rate was slower. For Cd(II) our proposed technique obtained a dynamic range of 0.5-40 ng mL-1, a correlation coefficient (R2) of 0.9913, and a detection limit of 0.3 ng mL-1. For Cu(II), the corresponding values were 2.0-120 ng mL-1, 0.9921 and 1.02 ng mL-1. To validate this proposed technique, the aqueous samples (stream water, reservoir water, tap water and wastewater), the diluted brass sample and the plastic sample, as real samples, were used. Recovery yields of 91-103% were obtained. These measured data were not different from ICP-MS data at 95% confidence level. Our proposed method was also validated using rice flour CRM (normal, fortified) samples. From the results of our experiment, we found that the technique we present here can be applied to the determination of Cd(II) and Cu(II) in various real samples.