• Journal of the Korean Institute of Gas
• /
• v.10 no.1 s.30
• /
• pp.38-42
• /
• 2006

In this study, a simulation technology for refrigeration cycle which can liquefy and store liquified petroleum gas (LPG) using pure propane as a refrigerant has been introduced. Cooling water as the second cooling medium was used for the liquefaction of propane. Peng-Robinson equation of state was used for the entire refrigeration cycle. A new alpha formulation proposed by Twu et al. was used for the more accurate prediction of vapor pressures of pure propane component and LPG constituents. API method for the accurate estimation of liquid densities of propane and LPG was used instead of using Peng-Robinson equation of state. PRO/II with PROVISION release 7.1, a general purpose chemical process simulator was used for the simulation of the overall refrigeration system. Through this work, we can successfully simulate the real propane refrigeration plant operating at domestic site.

• Proceedings of the Korean Society of Propulsion Engineers Conference
• /
• 2010.11a
• /
• pp.658-663
• /
• 2010

With petroleum reserves dwindling, interest has been increasing worldwide in Fischer-Tropsch synthesis (FT) as a method of producing synthetic liquid fuels and chemicals from coal, natural gas or biomass. In general, FT synthesis is operated through the gas phase fixed-bed reaction system. Recently, there are lots of study in supercritical fluid due to unique characteristics such as the quick diffusion of reactant gas, effective removal of reaction heat, and the in-situ extraction of high molecular weight hydrocarbon, such as wax. In this study, our major aim is to obtain a deeper insight into the effect of the type of support on the reaction performance over a supported cobalt catalyst in a fixed bed reactor.

• Journal of the Korean Institute of Gas
• /
• v.12 no.3
• /
• pp.7-12
• /
• 2008

In this study, a spark ignition engine operated with the DME blended LPG fuel was investigated experimentally. Performance, emissions characteristics including hydrocarbon, CO, NOx, and combustion stability of an SI engine fuelled with DME blended LPG fuel were examined at $1200{\sim}5200\;rpm$. Results showed that stable engine operation was possible for a wide range of engine loads within 20% mass content of DME fuel. Also, engine output power within 10% mass content of DME fuel was comparable to that of pure LPG fuel operation. However, engine output power was decreased and break specific fuel consumption (BSFC) was severely increased with the amount of blended fuel as the energy content of DME was much lower than that of LPG. DME blended LPG fuel is expected to be potential for enlarging DME market.

• Elastomers and Composites
• /
• v.30 no.3
• /
• pp.185-194
• /
• 1995

Membrane process has been employed to separate a specific substance from gas or liquid mixture, and treat wastewater. This is due to the fact that the substance of mixture can be permeated and separated selectively by membrane. Since Initial equipment and operation costs are not expensive, membrane process has been adopted in various fields such as petroleum Industry, chemistry, polymer, electronics, foods, biochemical industry and wastewater treatment. In this study, $CaCO_3$ particles impregnated in silicone rubber network were extracted by using supercritical carbon dioxide and pore distribution of silicone $rubber-CaCO_3$ was investigated with varying amount of extract. Silicone rubber has excellent mechanical properties such as heat-resistance, cold-resistance etc. and $CaCO_3$ has microporous structure. It is possible to make silicone $rubber-CaCO_3$ composite sheets via work-intensive kneading processes. In so doing $CaCO_3$ particles become distributed and impregnated in silicone rubber network. Supercritical carbon dioxide diffuse through composite sample, then sample is swollen. $CaCO_3$ in silicone rubber network Is dissolved in supercritical carbon dioxide, and its sites become pores. Pore distribution, pore shape and surface area are observed by SEM(scanning electron microscope) micrograph and BET surface area analyzer examination respectively. Pore characteristics of membrane suggest the possibilities that the membrane can be used for process of mixture separation and wastewater treatment.

• Journal of ILASS-Korea
• /
• v.27 no.4
• /
• pp.195-202
• /
• 2022

Recently, the global automobile market is rapidly changing from internal combustion engine vehicles to eco-friendly vehicles including electric vehicles. Among eco-friendly vehicles, LPG vehicles are low in fine dust and are suggested as a realistic way to replace diesel vehicles. In addition, it is more economical than gasoline in its class, showing a cost-saving effect. In Korea, the business of converting gasoline into LPG is active. Research is being conducted to apply this to hybrid vehicles. In this study, the difference in energy consumption efficiency was analyzed when LPG fuel was applied by selecting a 2-liter GDI hybrid electric vehicle. The operation of the hybrid system according to various driving characteristics was confirmed by selecting the WLTC mode. As a result, it was confirmed that the BSFC was about 5% lower than that of gasoline fuel when using LPG fuel. This is due to the active operation of the motor while driving. Optimization is required as battery consumption increases from an energy perspective.

• Journal of Environmental Science International
• /
• v.15 no.1
• /
• pp.85-94
• /
• 2006

The simultaneous analysis of multi-residual pesticides was developed using a gas chromatography (GC) method. In this study, a simple and reliable methodology was improved to detect 154 kinds of pesticides in sinseng extract sample by using a liquid-liquid extraction procedure, open column chromagraphy and chromatographic analysis by CC electron capture detector (ECD) and GC nitrogen-phosphorus detector (NPD). The 154 kinds of pesticides were classified in 4 groups according to the chemical structure. The extraction of pesticides was experimented with $70\%$ acetone and dichloromethane/petroleum ether in order, and cleaned up via open column chromatography $(3\times30cm)$ packed with florisil $(30g,\;130^{\circ}C,\;12hrs)$. The final extract was concentrated in a rotator evaporator at $40^{\circ}C$ until dryness. Then the residue was redissolved to 2ml with acetone, and analyzed by GC-ECD and GC-NPD. The applied concentration of pesticides was over $1\~10{\mu}g/ml$. The recovery tests were ranged from $70.7\%$ to $115.2\%$ with standard deviations between 0.3 and $5.7\%$ of the standard spiked to the ginseng extract sample (Group $I\~IV$). The limit of detection (LOD) ranged from 0.001 to $0.099{\mu}g/ml$ (Group $I\~IV$). The 9 kinds of pesticides were not detected. The developed method was applied satisfactory to the determination of the 154 kinds of pesticides in the ginseng extract with good reproducibility and accuracy.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.18 no.6
• /
• pp.105-113
• /
• 2010

In this study, a feasibility test of liquid petroleum gas (LPG) compression ignition (CI) engine has been carried out to study the effectiveness of cetane enhancing additive: Di-tertiary-butyl peroxide (DTBP). Performance and emissions characteristics of a CI engine fuelled with DTBP blended LPG fuel were examined. Also, the effect of EGR (exhaust gas recirculation) on the combustion and emissions characteristics has been investigated. Results showed that stable engine operation over a wide range of the engine loads was possible. Exhaust emissions measurements showed that hydrocarbon were decreased with the blended fuel at enhancing cetane number. Furthermore, the combustion stability of LPG with a cetane number improver was equivalent to that of commercial Diesel fuel. Increasing the EGR rate leads to deteriorate the IMEP (indicated mean effective pressure) and increase the ignition delay. It was found that the exhaust emissions with the EGR resulted in a very large reduction in nitrogen oxides at the expense of higher THC and CO emissions. Considering the results of engine performance and exhaust emissions, LPG blended fuel of enhancing cetane number could be used as an alternative fuel for diesel in a CI engine.

• The Korean Journal of Petroleum Geology
• /
• v.11 no.1 s.12
• /
• pp.1-8
• /
• 2005

Seventeen exploratory wells have been drilled in the Block VI-1 of offshore Korea, which is located in the southern part or the Ulleung Basin. Gas show has been recognized from most of the wells, and gas and condensate have been accompanied in some wells. Commercial discovery of gas, accompanied by condensate, has been made from Gorae V well. The reservoir gases or the Dolgorae III, Gorae I, and Gorae V wells in the Ulleung Basin mainly consists of hydrocarbon gases (>93%). These gases are thermogenic wet gases which contain more than 96% of the methane and result from the cracking of petroleum or kerogen. Based on the chemistry and composition of the gases and stable isotope data, they seem to be generated from different source rocks. The condensates from the Gorae I and V wells are mostly generated from terrestrial organic matter. Lacustrine organic matter may not play an important role for the generation of these condensates. The condensates from the Gorae V wells consist predominantly of terrestrial organic matter but with minor subsidiary input from marine organic matter. The condensates from Gorse I and V wells may be generated from different source rocks. The thermal maturity level of the condensates from the Gorae V well ranges from early to middle oil generation zone and condensate from Gorae I reaches middle oil window. Correlation or the thermal maturation level of the condensates and organic matter in the sediments reveals that a depth of the generation of liquid hydrocarbons can be inferred to 3,000 m and 3,900 m for the Gorae V and I wells, respectively. Gorae V well, however, did not reach the target depth and the geochemical data of the Gorae I well were obscured due to the severe sediment caving in.

• Clean Technology
• /
• v.28 no.2
• /
• pp.174-181
• /
• 2022

Biomass is a sustainable alternative resource for production of liquid fuels and organic compounds that are currently produced from fossil fuels including petroleum, natural gas, and coal. Because the use of fossil fuels can increase the production of greenhouse gases, the use of carbon-neutral biomass can contribute to the reduction of global warming. Although biological and chemical processes have been proposed to produce petroleum-replacing chemicals and fuels from biomass feedstocks, it is difficult to replace completely fossil fuels because of the high oxygen content of biomass. Production of petroleum-like fuels and chemicals from biomass requires the removal of oxygen atoms or conversion of the oxygen functionalities present in biomass derivatives, which can be achieved by catalytic hydrodeoxygenation. Hydrodeoxygenation has been used to convert raw biomass-derived materials, such as biomass pyrolysis oils and lignocellulose-derived chemicals and lipids, into deoxygenated fuels and chemicals. Multifunctional catalysts composed of noble metals and transition metals supported on high surface area metal oxides and carbons, usually selected as supports of heterogeneous catalysts, have been used as efficient hydrodeoxygenation catalysts. In this review, the catalysts proposed in the literature are surveyed and hydrodeoxygenation reaction systems using these catalysts are discussed. Based on the hydrodeoxygenation methods reported in the literature, an insight for feasible hydrodeoxygenation process development is also presented.

• Korean Chemical Engineering Research
• /
• v.50 no.4
• /
• pp.666-671
• /
• 2012

Gas hydrates are inclusion compounds formed when small-sized guest molecules are incorporated into the well defined cages made up of hydrogen bonded water molecules. Since large masses of natural gas hydrates exist in permafrost regions or beneath deep oceans, these naturally occurring gas hydrates in the earth containing mostly $CH_4$ are regarded as future energy resources. The heat of dissociation is one of the most important thermal properties in exploiting natural gas hydrates. The accurate and direct method to measure the dissociation enthalpies of gas hydrates is to use a calorimeter. In this study, the high pressure micro DSC (Differential Scanning Calorimeter) was used to measure the dissociation enthalpies of methane, ethane, and propane hydrates. The accuracy and repeatability of the data obtained from the DSC was confirmed by measuring the dissociation enthalpy of ice. The dissociation enthalpies of methane, ethane, and propane hydrates were found to be 54.2, 73.8, and 127.7 kJ/mol-gas, respectively. For each gas hydrate, at given pressures the dissociation temperatures which were obtained in the process of enthalpy measurement were compared with three-phase (hydrate (H) - liquid water (Lw) - vapor (V)) equilibrium data in the literature and found to be in good agreement with literature values.