• Journal of Electrochemical Science and Technology
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• 제4권3호
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• pp.93-101
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• 2013

The electrodeposition of indium onto a copper electrode from an aqueous sulfate solution containing $In^{3+}$ was studied by means of cyclic voltammetry and chronoamperometry. Reduction and oxidation of indium on copper were investigated by using cyclic voltammograms at different negative limiting potentials and at different scan rates in cumulative cycles. Cyclic voltammograms indicated that reduction and oxidation processes of indium could involve various reactions. Chronoamperometry was carried out to analyze the nucleation mechanism of indium in the early stage of indium electrodeposition. The non-dimensional plot of the current transients at different potentials showed that the shape of the plot depended on the applied potential. The nucleation of indium at potential step of -0.6~-0.8 V was close to progressive nucleation limited by diffusion. However the non-dimensional plot of current transients for the indium nucleation showed different behaviors from theoretical curves at the potential step lower than -0.8 V.

• Design & Manufacturing
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• 제9권3호
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• pp.24-28
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• 2015

Speaking in general terms the form injection process can be described as a new process-variant of already known structural foam molding technology which roots go back to the early sixties. The most limiting factors of already know foaming processes are large cell size and the lack of uniformity of these cells as well and the inability to foam all kinds of plastic materials. In this paper, Process Study on weight change in injection rate during foaming. Experimental conditions were set as the injection speed 50,150,300 and 450 mm/s. The experiments PA, PA+GF, PP, was confirmed that the weight increase to PP+TA.

• Journal of the Korean Data and Information Science Society
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• 제28권6호
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• pp.1565-1571
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• 2017

The standard logistic map is an iterative function, which forms a discrete-time dynamic system. The chaotic logistic map is a kind of ergodic map defined over the unit interval. In this paper we study the limiting behaviors on the several processes induced by the chaotic logistic map. We derive the law of large numbers for the process induced by the chaotic logistic map. We also derive the uniform law of large numbers for this process. When deriving the uniform law of large numbers, we study the role of bracketing of the indexed class of functions associated with the process. Then we apply the idea of DeHardt (1971) associated with the bracketing method to the process induced by the logistic map. We finally illustrate an application to Monte Carlo integration.

• 전자공학회논문지S
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• 제35S권4호
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• pp.10-19
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• 1998

With the advent of high-speed networks, the increasingly stringent performance requeirements are being placed on the underlying switching systems. Under these circumstances, simulation methods for evaluating the performace of such a switch requires vast computational cost and accordingly the importance of anlytical methods increases. In general, the performance analysis of a switch architecture is also a very difficult task in that the conventional queueing system such as switching systems, which consists of a large numbe of queues which interact with each other in a fiarly complicated manner. To overcome these difficulties, most of the past research results assumed that multiple queues become decoupled as the switch size grows unboundely large, which enables the conventional queueing theory to be applied. In this apepr, w analyze a non-blocking space-division ATM swtich with input queueing, and prove analytically the pheonomenon that virtual queues formed by the head-of-line cells become decoupled as the switch size grows unboundedly large. We also establish various properties of the limiting queue size processes so obtained and compute the maximum throughput associated with ATM switches with input queueing.

• Bulletin of the Korean Chemical Society
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• 제12권1호
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• pp.97-101
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• 1991

Gas-phase pyrolyses of carbonate esters, ${\alpha}$- and ${\beta}$-hydroxy esters and ${\beta}$-hydroxy ketones have been studied theoretically by the AM1 MO method. Carbonate esters were found to decompose by two types of processes; in the reaction pathway involving an intermediate, the decomposition of the intermediate was rate-limiting, but direct pyrolyses were also possible via a six-membered cyclic transition state in which the methoxy oxygen attacks a hydrogen atom on the ${\beta}$-carbon. The hydroxy esters and ketones were found to decompose in a concerted process involving a six-membered cyclic transition state. Successive methylation on the ${\alpha}$- and ${\gamma}$-carbon led to an increase in the reactivity in agreement with experiments.

• 한국미생물·생명공학회지
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• 제38권4호
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• pp.362-372
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• 2010

다양한 하 폐수 처리공정 중 혐기성 소화공정은 이산화탄소 배출을 감소시키고 생성되는 메탄을 에너지로서 사용할 수 있는 장점을 가지고 있다. 본 논문에서는 이러한 혐기성 소화공정의 문제점과 보완점에 대해 살펴보았다. 가수분해과정은 혐기성 소화과정 중 율속단계에 해당하여 소화공정과정을 촉진시키고 바이오가스의 생산을 증가시키기 위하여 다양한 전처리 방법이 개발되어왔다. 현재 혐기성 소화공정을 위한 전처리 방법 중 열처리 방법, 초음파 처리, 기계적 처리방법, 화학적 처리방법 등이 상업적으로 이용되고 있으며, 이들 공정은 슬러지 플록 또는 세포의 파괴를 통해 세포분획물이 생물학적으로 분해될 수 있는 형태로 전환시키는 것을 목적으로 한다. 이러한 과정들 모두는 특정 상황에 따른 장점과 단점을 모두 지니고 있으므로 각 공정과정에 대한 이해와 이를 통한 적용을 통해 특정 슬러지에 적합한 최적의 전처리 공정을 도출해 낼 필요가 있다. 또한 혐기성 소화공정의 효율증대와 경제성 확대를 위한 혐기성 소화공정 개발이 필요하다고 할 수 있다.

• 한국음향학회지
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• 제36권1호
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• pp.12-22
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• 2017

소나 운용에서 잔향음은 수중 표적 탐지의 제한요소이기 때문에 정확한 예측이 중요하다. 최근에는 단상태소나 연구에서 공간적으로 송수신기의 위치가 다른 양상태 소나에 대한 연구로 확장되고 있는 추세이다. 양상태 잔향음을 모의하기 위해서는 양상태 음파전달, 양상태 산란강도 및 산란단면적 등에서 단상태와 다른 복잡한 계산이 요구된다. 전 세계적으로 양상태 잔향음에 대한 연구가 활발하게 진행되고 있지만 잔향음을 예측하는데 중요한 요소인 양상태 산란단면적을 정확하게 계산하는 방법에 대한 연구는 미비하다. 본 논문에서는 거리 독립 환경의 양상태 잔향음모의에서 두 원의 교차되는 면적을 응용하는 새로운 산란단면적 계산 방법을 제안한다. 최종적으로 본 논문의 양상태 산란단면적 계산 방법으로 모의된 잔향음 준위는 기존에 제안되었던 방법들의 예측값과 비교되며 2013년 5월에 수행된 해상 실험의 측정값과 비교를 수행하였다.

• Bulletin of the Korean Chemical Society
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• 제18권12호
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• pp.1274-1280
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• 1997

The photodissociation dynamics of CH2I2 has been studied at 304 nm by state-selective photofragment translational spectroscopy. Velocity distributions, anisotropy parameters, and relative quantum yields are obtained for the ground I(2P3/2) and spin-orbit excited state I*(2P1/2) iodine atoms, which are produced from photodissociation of CH2I2 at this wavelength. These processes are found to occur via B1 ← A1 type electronic transitions. The quantum yield of I*(2P1/2) is determined to be 0.25, indicating that the formation of ground state iodine is clearly the favored dissociation channel in the 304 nm wavelength region. From the angular distribution of dissociation products, the anisotropy parameters are determined to be β(I)=0.4 for the I(2P3/2) and β(I*)=0.55 for the I*(2P1/2) which substantially differ from the limiting value of 1.13. The positive values of anisotropy parameter, however, show that the primary processes for I and I* formation channels proceed dominantly via a transition which is parallel to I-I axis. The above results are interpreted in terms of dual path formation of iodine atoms from two different excited states, i.e., a direct and an indirect dissociation via curve crossing between these states. The translational energy distributions of recoil fragments reveal that a large fraction of the available energy goes into the internal excitation of the CH2I photofragment; < Eint > /Eavl=0.80 and 0.82 for the I and I* formation channels, respectively. The quantitative analysis for the energy partitioning of available energy into the photofragments is used to compare the experimental results with the prediction of direct impulsive model for photodissociation dynamics.

• 한국물환경학회지
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• 제27권1호
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• pp.73-87
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• 2011

An abnormal mono-specific bloom of the cyanobacterium Microcystis aeruginosa had developed at a specific location (transitional zone, monitoring station of Hoenam) in Daecheong Reservoir from middle of July to early August, 2001. The maximum cell counts during the peak bloom reached 1,477,500 cells/mL, which was more than 6~10 times greater than those at other monitoring sites. The hypothesis of this study is that the timing and location of the algal bloom was highly correlated with the local environmental niche that was controled by physical processes such as hydrodynamic mixing and pollutant transport in the reservoir. A three-dimensional, coupled hydrodynamic and ecological model, ELCOM-CAEDYM, was applied to the period of development and subsequent decline of the bloom. The model was calibrated against observed water temperature profiles and water quality variables for different locations, and applied to reproduce the algal bloom event and justify the limiting factor that controled the Microcystis bloom at R3. The simulation results supported the hypothesis that the phosphorus loading induced from a contaminated tributary during several runoff events are closely related to the rapid growth of Microcystis during the period of bloom. Also the physical environments of the reservoir such as a strong thermal stratification and weak wind velocity conditions provided competitive advantage to Microcystis given its light adaptation capability. The results show how the ELCOM-CAEDYM captures the complex interactions between the hydrodynamic and biogeochemical processes, and the local environmental niche that is preferable for cyanobacterial species growth.

• 한국분말재료학회지
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• 제30권1호
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• pp.53-64
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• 2023

Atomic layer etching (ALE) is a promising technique with atomic-level thickness controllability and high selectivity based on self-limiting surface reactions. ALE is performed by sequential exposure of the film surface to reactants, which results in surface modification and release of volatile species. Among the various ALE methods, thermal ALE involves a thermally activated reaction by employing gas species to release the modified surface without using energetic species, such as accelerated ions and neutral beams. In this study, the basic principle and surface reaction mechanisms of thermal ALE?processes, including "fluorination-ligand exchange reaction", "conversion-etch reaction", "conversion-fluorination reaction", "oxidation-fluorination reaction", "oxidation-ligand exchange reaction", and "oxidation-conversion-fluorination reaction" are described. In addition, the reported thermal ALE processes for the removal of various oxides, metals, and nitrides are presented.