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Comparison of Characteristics and Performance of Membrane in Proton Exchange Membrane Fuel Cells (고분자전해질 연료전지 고분자막의 특성 및 성능 비교)

  • Lee, Daewoong;Lim, Daehyun;Oh, Sohyeong;Chung, Hoi-Bum;Yoo, Seung-Eul;Ku, Young-Mo;Park, Kwonpil
    • Korean Chemical Engineering Research
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    • v.58 no.2
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    • pp.171-175
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    • 2020
  • In the proton exchange membrane fuel cells (PEMFC), the development of a reinforced membrane with improved durability by a support is actively in progress in Korea. In this study, the initial performance and characteristics of four types of reinforced membranes were compared. Reinforced membranes with higher amounts of C-F chains in the polymer membrane showed lower water diffusion coefficients due to the hydrophobicity of the C-F chains. The thicker the polymer membrane, the more the hydrogen permeability decreased and the higher the OCV. Membrane with short resistance below 1.5 Ωcm2 showed OCV below 0.9 V and the lowest performance, so short resistance should be above 3.0 Ωcm2. Compared with the current standard membrane, there was a similar domestic membrane, which could confirm the possibility of localization of PEMFC polymer membrane.

Quantitative Determination of Five Phenolic Peroxynitrite-scavengers in Nine Korean Native Compositae herbs

  • Nugroho, Agung;Lim, Sang-Cheol;Karki, Subash;Choi, Jae Sue;Park, Hee-Juhn
    • Natural Product Sciences
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    • v.21 no.3
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    • pp.155-161
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    • 2015
  • Peroxynitrite (ONOO)-scavenging activities of nine Compositae herbs consisting of three Ixeris, two Youngia, two Cirsium and one of each Lactuca and Taraxacum species were evaluated. The contents of their ONOO scavengers in the extracts were also determined on a HPLC using seven standard compounds, chlorogenic acid (CGA), chicoric acid (CA), luteolin 7-glucoside (luteolin-7-glc), luteolin 7-glucuronide (luteolin-7-glcU), luteolin, linarin and pectolinarin. Five of those compounds exhibited potent ONOO-scavenging activities: IC50, CA (0.76 μM), CGA (1.34 μM), luteolin (0.81 μM), luteolin-7-glc (0.86 μM) and luteolin-7-glcU (3.13 μM). Both CA and luteolin-7-glc were highly contained in I. dentata (19.71 mg/g and 13.58 mg/g, respectively), I. dentata var. albiflora (17.58 mg/g and 23.83 mg/g, respectively) and I. sonchifolia (65.71 mg/g and 6.99 mg/g, respectively). Among the nine herbs, those three Ixeris species had very low IC50 values over the range of 0.48 - 1.74 μg/mL, suggesting that they could be potential therapeutic vegetables, particularly for preventing diabetic complications or obesity, which can be caused by an excess production of ONOO.

The Effects of Curl-up Exercise using XCO on Trunk Muscle Activation in Healthy Adults

  • Lim, Jae-Heon;Cho, Woon-Su
    • The Journal of Korean Physical Therapy
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    • v.32 no.4
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    • pp.210-216
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    • 2020
  • Purpose: This study examined the effects of curl-up using XCO® on trunk muscle activation in healthy adults. Methods: This study design was a single-blind randomized controlled trial. Twelve participants were enrolled in this study. The subjects were instructed to perform curl-up exercise in STCU (straight curl-up), LTCU (left twist curl-up), RTCU (right twist curl-up), TWCU (twist curl-up), and PPCU (power push curl-up). Electromyography was used to assess the percent maximal voluntary isometric contraction (%MVIC) of the rectus abdominis (RA), external oblique (EO), internal oblique (IO), and erector spinae (ES) muscles. The data were analyzed using two-way ANOVA with a repeated measure. The statistical significance level was set to α=0.05 Results: The IO showed significant differences in the main effect of the group and the interactions between the group and exercise (p<0.05). In particular, the IO represented the interactions between group and exercise in the RTCU and PPCU (p<0.05). The RA, EO, and ES did not show significant interactions between the group and exercise (p>0.05). The RA, IO, and EO showed significant differences in the main effect of the group (p<0.05). The EO showed a significant difference in the main effect of exercise (p<0.05). Conclusion: These findings suggest that XCO® can be used to increase the muscle activation of the internal oblique, which is the lumbar stabilizing muscle, when XCO® is combined in the curl-up exercise with rotation. In the future, research on the intensity, frequency, and duration of XCO® exercise will be needed according to the individual characteristics and preferences.

Optical Properties of Y3Al5O12;Ce3+,Pr3+ Transparent Ceramic Phosphor for High Power White Lighting (고출력 백색 광원용 Y3Al5O12;Ce3+,Pr3+ 투명 세라믹 형광체의 광학특성)

  • Kang, Taewook;Lim, Seokgyu;Kim, Jongsu;Jeong, Yongseok
    • Korean Journal of Materials Research
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    • v.29 no.2
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    • pp.116-120
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    • 2019
  • We prepared $Y_3Al_5O_{12};Ce^{3+},Pr3^{+}$ transparent ceramic phosphor using a solid state reaction method. By XRD pattern analysis and SEM measurement, our phosphors reveal an Ia-3d(230) space group of cubic structure, and the transparent ceramic phosphor has a polycrystal state with some internal cracks and pores. In the Raman scattering measurement with an increasing temperature, lattice vibrations of the transparent ceramic phosphor decrease due to its more perfect crystal structure and symmetry. Thus, low phonon generation is possible at high temperature. Optical properties of the transparent ceramic phosphor have broader excitation spectra due to a large internal reflection. There is a wide emission band from the green to yellow region, and the red color emission between 610 nm and 640 nm is also observed. The red-yellow phosphor optical characteristics enable a high Color Rendering Index (CRI) in combination with blue emitting LED or LD. Due to its good thermal properties of low phonon generation at high temperature and a wide emission range for high CRI characteristics, the transparent ceramic phosphor is shown to be a good candidate for high power solid state white lighting.

Inventory Estimation of 36Cl and 41Ca in Concrete of Kori Unit 1 (고리 1호기의 콘크리트 내 36Cl 및 41Ca의 방사화재고량 평가)

  • Jang, Mee;Lim, Jong Myoung;Kim, Hyun Chul;Kim, Chang-Jong
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.17 no.1
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    • pp.121-126
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    • 2019
  • The radionuclide inventory prediction of a nuclear power plant can help establish decommissioning plan by providing information of radiation environment. Accumulated radionuclides in reactors and related facilities after reactor shutdown can be divided into neutron activated materials and contaminated materials. Among the neutron activated radionuclides, $^{36}Cl$ and $^{41}Ca$ are important from the viewpoint of disposal because of its long half-life and physiochemical characteristics. In this research, we calculated the radionuclides of $^{36}Cl$ and $^{41}Ca$ in bioshielding concrete by estimating the neutron flux and cross section using the MCNPX. And we evaluated the inventories of $^{36}Cl$ and $^{41}Ca$ using the activation calculation code ORIGEN2.

Synthesis of Carboxylate-Based Anionic surfactant from Coconut Oil Source and Characterization of Interfacial Properties (코코넛 오일로부터 유래된 카르복실레이트계 음이온 계면활성제의 합성 및 계면 특성에 관한 연구)

  • Lee, Ye Jin;Park, Ki Ho;Shin, Hee Dong;Lim, Jong Choo
    • Applied Chemistry for Engineering
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    • v.32 no.3
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    • pp.260-267
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    • 2021
  • In this study, a carboxylate-based anionic surfactant SLEC-3 was prepared from coconut oil and the structure was elucidated by using FT-IR, 1H-NMR and 13C-NMR analysis. Measurements of interfacial properties such as critical micelle concentration, static and dynamic surface tensions, emulsification index, and foam stability have shown that SLEC-3 is better in terms of interfacial activity and more effective in lowering interfacial free energy than those of SLES, which has been widely used as a conventional anionic surfactant in the detergent industry. Biodegradability, acute oral toxicity and dermal irritation tests also revealed that SLEC-3 surfactant possesses excellent mildness and low toxicity, indicating the potential applicability in detergents and cleaner products formulation.

Study of Improvement Life and Electrochemical Characteristics for Lithium/sulfur Battery using Porous Carbon Sphere (다공성 구형 탄소를 이용한 리튬/유황 전지의 수명개선 및 전기화학특성 연구)

  • Hur, Sung Kyu;Lim, Soo A
    • Journal of the Korean Electrochemical Society
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    • v.24 no.3
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    • pp.42-51
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    • 2021
  • Dissociation into Lithium-polysulfide electrolyte due to repeated cycles during the Lithium/Sulfur battery reaction is a major problem of reduced battery lifespan. We searched for a porous carbon with a large specific surface area that infiltrated S to prevent liquid Lithium-polysulfide from being dissolved in electrolyte, induce adsorption of Lithium-polysulfide, and further increase conductivity. In order to obtain porous carbon spheres with a large specific surface area, the carbon spheres of 1939 m2/g were raised to 2200 m2/g through additional KOH treatment. In addition, through heat treatment with S, a carbon sulfur compound containing 75 wt% of S was fabricate and material analysis was conducted on the possibility of using the cathode material. The electrochemical characteristics of the Reference (622; sulfur: 60%, conductive material: 20%, binder: 20%) pouch cell and the pouch cell made using 75wt% of carbon sulfur compound were analyzed. 75wt% of carbon sulfur pouch cell showed a 20% increase in lifespan and 10% improvement in C-rate compared to the Reference pouch cell after 50 cycles.

Effect of Channel and Gate Structures on Electrical Characteristics of Oxide Thin-Film Transistors (Channel과 gate 구조에 따른 산화물 박막트랜지스터의 전기적 특성 연구)

  • Kong, Heesung;Cho, Kyoungah;Kim, Jaybum;Lim, Junhyung;Kim, Sangsig
    • Journal of IKEEE
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    • v.26 no.3
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    • pp.500-505
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    • 2022
  • In this study, we designed oxide thin-film transistors (TFTs) with dual gate and tri layered split channels, and investigated the structural effect of the TFTs on the electrical characteristics. The dual gates played a key role in increasing the driving current, and the channel structure of tri layers and split form contributed to the increase in the carrier mobility. The tri layered channels consisting of the a-ITGZO and two ITO layers inserted between the gate dielectric and a-ITGZO led to the increase in the on-current by using ITO layers with high conductivity, and the split channels lowered series resistance of the channels. Compared with the mobility (15 cm2/V·s) of the single gate a-ITGZO TFT, the mobility (134 cm2/V·s) of the dual gate tri-layer split channel TFT was remarkably enhanced by the structural effect.

Facilitators and Barriers of Social Participation of Older Adults: Systematic Review of Qualitative Studies (노인의 사회참여에 영향을 미치는 요인에 대한 체계적 고찰 : 질적연구 중심)

  • Lee, Hamin;Park, Hae Yean;Lim, Young-Myoung
    • The Journal of the Korea Contents Association
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    • v.22 no.10
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    • pp.475-487
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    • 2022
  • The purpose of this study is to comprehensively examine the facilitators and barriers to social participation of older adults in the society through systematic review of qualitative research. Through PubMed, Embase, Cochrane, data from 2012 to 2022 were collected. The main search keywords were 'elderly', 'older adults', social participation', 'engagement', 'motiv*', 'barrier', 'facilitat*'. 7 articles that satisfy the inclusion criteria were selected for analysis. Facilitators and barriers of older adults' social participation were analyzed. The analyzed factors were assorted into 'personal/ internal factors', 'environmental factors', 'social network factors'. The results of this study emphasize not only logistical factors, but also motivation, desire, social context of older adults' as factors to social participation. To prevent older adults' social isolation, a broad understanding of what promotes and inhibits the participation of the older adults is needed.

Predicting the resting metabolic rate of young and middle-aged healthy Korean adults: A preliminary study

  • Park, Hun-Young;Jung, Won-Sang;Hwang, Hyejung;Kim, Sung-Woo;Kim, Jisu;Lim, Kiwon
    • Korean Journal of Exercise Nutrition
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    • v.24 no.1
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    • pp.9-13
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    • 2020
  • [Purpose] This preliminary study aimed to develop a regression model to estimate the resting metabolic rate (RMR) of young and middle-aged Koreans using various easy-to-measure dependent variables. [Methods] The RMR and the dependent variables for its estimation (e.g. age, height, body mass index, fat-free mass; FFM, fat mass, % body fat, systolic blood pressure, diastolic blood pressure, mean arterial pressure, pulse pressure, and resting heart rate) were measured in 53 young (male n = 18, female n = 16) and middle-aged (male n = 5, female n = 14) healthy adults. Statistical analysis was performed to develop an RMR estimation regression model using the stepwise regression method. [Results] We confirmed that FFM and age were important variables in both the regression models based on the regression coefficients. Mean explanatory power of RMR1 regression models estimated only by FFM was 66.7% (R2) and 66.0% (adjusted R2), while mean standard errors of estimates (SEE) was 219.85 kcal/day. Additionally, mean explanatory power of RMR2 regression models developed by FFM and age were 70.0% (R2) and 68.8% (adjusted R2), while the mean SEE was 210.64 kcal/day. There was no significant difference between the measured RMR by the canopy method using a metabolic gas analyzer and the predicted RMR by RMR1 and RMR2 equations. [Conclusion] This preliminary study developed a regression model to estimate the RMR of young and middle-age healthy Koreans. The regression model was as follows: RMR1 = 24.383 × FFM + 634.310, RMR2 = 23.691 × FFM - 5.745 × age + 852.341.