• 한국경제지리학회지
• /
• 제5권1호
• /
• pp.5-24
• /
• 2002

본 연구는 경질제품의 유통구조와 물류체계를 공간적 관점에서 분석하였다. 석유제품은 정유사, 대리점, 주유소의 유통기관들을 통해서 공급되지만, 제품의 특성과 용도별로 상이한 유통경로를 갖고 있다. 석유제품의 수송은 정유공장에서 주요 소비지역에 입지하고 있는 저유소까지의 1차 수송과 주유소로부터 주유소나 중소수요처까지의 2차 수송으로 이루어진다. 1차 수송에는 유조선, 유조화차, 송유관, 유조차가 이용되고, 대리점이나 수송용역 업체가 담당하는 2차 수송은 대부분 유조차가 수송을 전담하고 있다. 본 논문에서는 SK와 LG 정유사의 저유소 분포와 저유소 유형별 공급권역을 분석하였다. 또한 하나의 저유소가 관할하는 공급권역내에 포함된 인구수와 자동차수, 주유소수를 도출하였고, 이를 바탕으로 하나의 주유소가 공급을 담당하는 최소요구치 수요인 인구수와 자동차수를 산출하였다.

• Bulletin of the Korean Chemical Society
• /
• 제20권9호
• /
• pp.1021-1025
• /
• 1999

Near-infrared (NIR) spectroscopy has been successfully utilized for the rapid identification of six typical petroleum products such as light straight-run (LSR), naphtha, kerosine, light gas oil (LGO), gasoline, and diesel. The spectral features of each product were reasonably differentiated in the NIR region, and the spectral differences provided enough qualitative spectral information for discrimination. For discrimination, principal component analysis (PCA) combined with Mahalanobis distance was used to identify each petroleum product from NIR spectra. The results showed that each product was accurately identified with an accuracy over 95%. Most noticeably, LSR, kerosine, gasoline, and diesel samples were predicted with identification accuracy of 99%. The overall results ensure that a portable NIR instrument combined with a multivariate qualitative discrimination method can be efficiently utilized for rapid and simple identification of petroleum products. This is especially important when local at-site measurements are necessary, such as accidental petroleum leakage and regulation of illegal product blending.

• 공업화학
• /
• 제27권5호
• /
• pp.546-550
• /
• 2016

국내 토양오염의 60~70% 이상이 석유제품에 의한 오염이며, 석유제품에 의해 토양오염이 발생될 경우, 토양환경보전법 상 B T E X와 total petroleum hydrocarbon (TPH)를 분석하도록 명시하고 있다. 본 연구에서는 국내 유통 중인 석유제품에 대한 구간별 TPH 패턴을 분석하였다. 또한 $C_8{\sim}C_{40}$ 구간만을 분석하는 현행 토양오염공정시험기준의 문제점을 보완하여 석유제품 내 TPH를 정량분석 하였다. 분석결과, 토양오염공정시험기준 분석조건으로 분석한 결과값과 보완된 분석방법을 이용했을 시, 휘발유와 용제 1호 같은 저비점 유류의 경우, 최대 85%의 차이가 발생하는 것을 확인하였다.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2014년도 제49회 KOSCO SYMPOSIUM 초록집
• /
• pp.255-257
• /
• 2014

The installation of light oil facilities or delayed cokers seems to be inevitable in the oil refinery industry due to the heavy crude oil reserves and the increased use of light fuels as petroleum products. Petroleum coke is a byproduct of oil refineries and it has higher fixed carbon content, higher calorific value, and lower ash content than coal. However, its sulfur content and heavy metal content are higher than coal. In spite of disadvantages, petroleum coke might be one of promising resources due to gasification processes. The gasification of petroleum coke can improve economic value of oil refinery industries by handling cheap, toxic wastes in an environment-friendly way. In this study, $CO_2$ gasification reaction kinetics of petroleum coke, various coals and mixing coal with petroleum coke have investigated and been compared by using TGA. The kinetics of $CO_2$ gasification has been performed with petroleum coke, 3 kinds of bituminous coal [BENGALLA, White Haven, TALDINSKY], and 3 kinds of sub-bituminous coal [KPU, LG, MSJ] at various temperature[$1100-1400^{\circ}C$].

• 한국지하수토양환경학회지:지하수토양환경
• /
• 제22권1호
• /
• pp.13-17
• /
• 2017

Over 30% of domestic soil contamination has occurred via petroleum products and complex oil. Moreover, contamination by complex oil is more intense than it is by a single petroleum product species. In this study, we analyzed sectional TPH (total petroleum hydrocarbon) pattern and sectional ratio of current domestically distributed petroleum products, such as kerosene, diesel, bunker C, and lubricant and complex oils, to determine pollution characteristics of the soil. In the TPH pattern, kerosene, which is a light distillate, had an early retention time, and lubricant oil, which is a heavy distillate, had a late retention time in the gas chromatogram. In addition, we obtained a complexly contaminated soil via diesel and lubricant oil from the Navy and inspected it for its ratio of complex oil species. The inspection results showed that this soil was contaminated with 85% diesel and 15% lubricant oil. The method developed in this study could be used to determine complex petroleum sources and ratios at sites with accidentally contaminated soil.

• 폴리머
• /
• 제27권1호
• /
• pp.84-89
• /
• 2003

열분해 온도 및 열분해 시간이 HDPE의 열분해에 미치는 영향을 해석하였다. HDPE 열분해의 시작온도와 활성화에너지는 가열속도가 증가함에 따라 증가하였다. 전환율과 액체수율은 열분해 온도와 시간이 증가함에 따라 계속 증가하였고, 특히 45$0^{\circ}C$에서 열분해 시간에 매우 민감하게 변하였다. 전환율에 있어 열분해 온도가 열분해 시간보다 더 큰 영향을 주었다. 열분해 과정에서 생성된 각각의 액체성분을 한국석유품질검사소 석유제품 품질기준에 기초하여 증류온도에 따라 가솔린, 등유, 경유, 왁스로 분류하여 본 결과, 450 $^{\circ}C$에서는 경유 > 왁스 > 등유 > 가솔린 순이었고, 475$^{\circ}C$와 50$0^{\circ}C$에서는 왁스 > 경유 > 등유 > 가솔린 순이었다.

• 한국응용과학기술학회지
• /
• 제19권4호
• /
• pp.258-264
• /
• 2002

Pyrolysis of polypropylene(PP) Was performed to find the effects of the pyrolysis temperature(425, 450, 475 and $500^{\circ}C$) and the pyrolysis time(35, 50 and 65minutes), respectively. Conversion and liquid yield obtained during PP pyrolysis continuously increased with the pyrolysis temperature( up to $500^{\circ}C$) and the pyrolysis time(up to 65minutes), especially these were more sensitive to the pyrolysis time at $425^{\circ}C$ than other pyrolysis temperatures. Each liquid product formed during the pyrolysis was classified into gasoline, kerosene, light oil and wax according to the distillation temperature based on the petroleum product quality standard of Korea Petroleum Quality Inspection Institute. The liquid products of PP pyrolysis up to $450^{\circ}C$ were almost same fractions($26{\pm}3$wt.% gasoline, $20{\pm}2$wt.% kerosene and $23{\pm}2$wt.% light oil) except wax($3{\sim}13$wt.%). On the other hand, the pyrolysis of PP from $475^{\circ}C$ to $500^{\circ}C$ produced $26{\pm}3$wt.% wax, $24{\pm}1$wt.% gasoline, $18{\pm}1$wt.% kerosene and $16{\pm}1$wt.% light oil. After all, the main liquid product changed from gasoline to wax with increasing pyrolysis temperature.

• 폴리머
• /
• 제32권2호
• /
• pp.157-162
• /
• 2008

LDPE, LLDPE 및 HDPE의 반응온도 및 반응시간에 따른 저온 열분해 특성을 연구하였다. 실험범위는 반응온도에 대하여 $425^{\circ}C$에서 $500^{\circ}C$이었고 반응시간은 35분에서 65분이었다. 열분해 생성물들은 한국석유품질검사소의 석유제품 품질기준에 따라 휘발유, 등유, 경유 및 왁스로 분류하였다. TGA분석결과, 3종류의 시료 모두가 가열속도를 증가시킴에 따라 열분해 개시온도가 증가하는 것으로 나타났으며, 일정한 가열속도에서 열분해 개시온도는 LDFE$475^{\circ}C$ 이상에서는 모든 폴리에틸렌 시료의 전환율이 90 wt% 이상이었다. 휘발유와 등유의 수율은 $450^{\circ}C$, 65분에서 최대이었으며 $475^{\circ}C$ 이상에서는 약간 감소하는 것으로 나타났다.

• 한국자동차공학회논문집
• /
• 제22권4호
• /
• pp.1-9
• /
• 2014

The vast stores of biomass available in the worldwide have the potential to displace significant amounts of petroleum fuels. Fast pyrolysis of biomass is one of several paths by which we can convert biomass to higher value products. The wood pyrolysis oil (WPO) has been regarded as an alternative fuel for petroleum fuels to be used in diesel engine. However, the use of WPO in a diesel engine requires modifications due to low energy density, high water contents, high acidity, high viscosity, and low cetane number of the WPO. One possible method by which the shortcomings may be circumvented is to co-fire WPO with other petroleum fuels. WPO has poor miscibility with light petroleum fuel oils; the most suitable candidates fuels for direct fuel mixing are methanol or ethanol. Early mixing with methanol or ethanol has the added benefit of significantly improving the storage and handling properties of the WPO. For separate injection co-firing, a WPO-ethanol blended fuel can be fired through diesel pilot injection in a dual-injection dieel engine. In this study, the performance and emission characteristics of a dual-injection diesel engine fuelled with diesel (pilot injection) and WPO-ethanol blend (main injection) were experimentally investigated. Results showed that although stable engine operation was possible with separate injection co-firing, the fuel conversion efficiency was slightly decreased due to high water contents of WPO compare to diesel combustion.

• 폴리머
• /
• 제29권1호
• /
• pp.64-68
• /
• 2005

폐플라스틱으로 수거되는 내충격 폴리스티렌의 액상연료로서의 재활용을 위해 열분해에 의한 HIPS 해중합 특성을 연구하였다. 열분해 온도 및 열분해 시간이 HIPS의 열분해에 미치는 영향을 조사하였다. HIPS의 열분해 반응 시작온도와 활성화에너지는 가열속도가 증가함에 따라 증가하였다. 전환율과 액체수율은 열분해 온도와 시간이 증가함에 따라 점진적으로 증가하였다. 열분해 과정에서 생성된 각각의 액체성분을 한국석유품질검사소 석유제품 품질기준에 기초하여 증류온도에 따라 가솔린, 등유, 경유, 중유로 분류하여 본 결과, 가솔린 > 중유 > 등유 > 경유 순이었다. 특히 가솔린 성분은 열분해된 HIPS의 51${\pm}$6 wt%를 차지하였다.