• Title/Summary/Keyword: lead dust

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Environment Parameters Affecting Heavy Metal Concentration in Sand Collected from Children Playground in Seoul Metropolitan Area

  • An, Hyunsun;Kim, Juhee;Hyun, Seunghun
    • Korean Journal of Soil Science and Fertilizer
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    • v.46 no.3
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    • pp.193-202
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    • 2013
  • The concentrations of heavy metals such as cadmium (Cd), chromium (Cr), copper (Cu), lead (Pb), zinc (Zn), nickel (Ni), and arsenic (As) in sand samples collected from selected children's playground and their correlation with environmental parameters, such as concentration of particulate matter in the atmosphere ($PM_{10}$), apartment age (> 5 years), clay and organic matter contents in sand samples, were analyzed. The average heavy metal concentration in samples was 0.040 mg $kg^{-1}$ for Cd, 0.200 mg $kg^{-1}$ for Cr, 1.75 mg $kg^{-1}$ for Cu, 15.1 mg $kg^{-1}$ for Ni, 3.42 mg $kg^{-1}$ for Pb, 66.7 mg $kg^{-1}$ for Zn and 0.750 mg $kg^{-1}$ for As, all of which were below the environmental regulatory level established by Korea Ministry of Environment. However, in the consideration of direct and oral exposure by children to playground sand, the risk of the concentration range in the samples might be greatly enhanced. Heavy metal concentration in samples collected from high $PM_{10}$ (> $70{\mu}gm^{-3}$) area was slightly greater than in samples from low $PM_{10}$ (< $70{\mu}gm^{-3}$), indicating the contribution of particulate matter in air phase to heavy metal concentration in playground sand samples. The concentrations of both Cd and Pb were the highest in apartments older than 21 years (0.050 mg $kg^{-1}$ and 5.28 mg $kg^{-1}$ for Cd and Pb respectively) and showed positive correlation with apartment age (p<0.01 and p<0.001 for Cd and Pb, respectively). Clay content in playground sands ranged 3.8~11.2% and was positively correlated with heavy metal concentration. Organic matter content was negligible (mostly < 0.1%) and showed poor correlation with heavy metal concentration. In conclusion, concentration of heavy metals in playground sand was found to be predominantly influenced by the apartment age and clay content in sand samples and supplemented by dust deposition of particulate matter ($PM_{10}$) from atmosphere.

Preparation and Characterization of Polyurethane Waterproof Coatings Containing Fly Ash

  • Lee, Sung-Il;Kim, Duk-Bae;Yang, Go-Su;Kim, Wan-Young;Byoun, Youn-Seop;Lee, Youn-Sik
    • Elastomers and Composites
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    • v.38 no.3
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    • pp.243-250
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    • 2003
  • Polyurethane waterproof (PW) coatings are increasingly demanded in Korea for repairing cracks on old building roofs and construction of many sporting facilities. Calcium carbonate, a common filler, is incorporated in PW compositions. In this study, PW coatings were prepared by substituting a part of calcium carbonate with fly ash. The maximum amounts of calcium carbonate which can be substituted by fly ash obtained in the cyclone and bag filter dust collectors were 20 and 10%, respectively. It was found that the curing rate of PWs ran be controlled by varying the amount of Pb-octoate catalyst. The elongations at break as well as tensile strength and tear strength of PW coatings containing fly ash could also be adjusted such that their values were comparable to those of a standard PW coating by varying relative amounts of some components. However, the amount of cadmium, mercury, and lead leached from PW coatings containing fly ash obtained from the bag filter collector exceeded the respective allowed upper limits, mainly due to the initial high contents of them in the fly ash. On the other hand, PW coatings containing fly ash obtained from the cyclone collector exhibited better mechanical properties and did not release any significant amounts of the heavy metals. Thus, it was concluded that PW coatings containing fly ash can be utilized for practical applications as long as an appropriate fly ash is used.

Conservation of Chungmugong's Artifacts (보물 제326호 이충무공유물의 과학적 보존)

  • Kwon, Hyuk Nam;Seo, Jung Eun;Ha, Eun Ha;Lee, Han Hyoung;Lee, Eun Woo
    • Korean Journal of Heritage: History & Science
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    • v.44 no.3
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    • pp.62-77
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    • 2011
  • Yi Sunsin's artifacts had been exhibited at Hyeonchungsa in Asan-si, Chungchungnam-do. These artifacts include Janggeom(Long swords), Okno(Jade ornament of Korea traditional hat), Yodae(Waist belt) and Dobae(Peach shaped wine cups) Gudae(Yodae's saucers). These were covered with dust and corroded due to long term display. Condition of these artifacts was examined for a re-opening of Yi Chungmugong Memorial Pavilion on 28 March 2011. Before conservation treatment of the artifacts, scientific analysis was conducted to identify the material of the artifacts. The result showed that the red paint on the hilt of the sword is composed of two layers. Pigments of two layers were found to be hematite and cinnabar mixed with red lead respectively. Mixed layer was assumed to have been applied recently. Also it was found that the blade of the sword was repainted using chrome yellow($PbCrO_4$). Considering the time limit, conservation treatment focused on stabilization of damaged area and prevention of futher risk during display.

Development of Skin Health Promoting Materials Using Leuconostoc mesenteroides (중금속 흡착능 Leuconostoc mesenteroides CJNU 0705 균주를 활용한 피부 건강기능성 소재 개발)

  • Han, Min-Hui;Moon, Gi-Seong
    • Microbiology and Biotechnology Letters
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    • v.48 no.4
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    • pp.455-462
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    • 2020
  • Leuconostoc mesenteroides CJNU 0705 was isolated from a breast milk sample and identified by 16S rRNA gene sequencing and confirmed by its ability to produce dextran from tryptic soy agar plates supplemented with 2% sucrose. This strain can absorb various heavy metals including lead (Pb) and cadmium (Cd) which are both found in fine dust and have been shown to be harmful to human skin. In addition, Leu. mesenteroides CJNU 0705 has demonstrated antimicrobial activity against Propionibacterium acnes, the primary causative agent of acne. Given these traits it was natural to evaluate the use of this strain in the fermentation of several natural extracts from green tea, carrot, annual wormwood, parsley, broccoli, and corn silk, which are known to improve skin health, to see if it could increase their dextran content when supplemented with no sucrose, 2% sucrose, or 2% sucrose and 3% yeast extract. The extracts supplemented with both yeast and sucrose were found to produce the most dextran, which was confirmed by the scanning electron microscope (SEM) images. These results suggest that Leu. mesenteroides CJNU 0705 and its fermented natural extracts could be used as functional materials for improving human skin health.

A Study on the Legal Issues on the Payment of Renewable Energy Subsidies (신재생에너지 보조금 지급에 관한 법적쟁점 고찰)

  • Park, Ji-Eun;Lee, Yang-Kee
    • Korea Trade Review
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    • v.43 no.4
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    • pp.111-130
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    • 2018
  • In December 2015, the Paris Agreement was adopted to cope with global warming caused by greenhouse gas emission and to prevent the average temperature of the Earth from rising. Renewable energy sources have become important to address environmental problems such as rising sea levels, depletion of forests and fine dust. In order to grow renewable energy, government support is needed. However, excessive government support for the renewable energy industry could pose problems that include undermining fair competition and raising costs. The WTO already has heard cases involving renewable energy subsidies. This article focuses on subsidies and countervailing tariffs as well as examines WTO disputes related to renewable subsidies, and also analyze legal issues that are problematic in granting subsidies for the development of new renewable energy industries. In WTO dispute involving renewable energy subsidies, legal issues are SCM Agreement article 2 Specificity, article 3 (b) import substitution subsidy and GATT article 20. This paper proposes improvement measures such as the reintroduction of article 8 Non-Actionable Subsidies or special provisions on energy subsidy. In addition, it is necessary to clarify the interpretation of Article 3 of the subsidy agreement. However, excessive government subsidies can lead to trade friction, so the WTO rules should be improved in line with the WTO goals of environmental protection, equity in free trade, and sustainable development.

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The Consideration about Heavy Metal Contamination of Room and Worker in a Workshop (공작실에서 실내 및 작업종사자의 중금속 오염도에 관한 고찰)

  • Kim Jeong-Ho;Kim Gha-Jung;Kim Sung-Ki;Bea Suk-Hwan
    • The Journal of Korean Society for Radiation Therapy
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    • v.17 no.2
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    • pp.87-94
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    • 2005
  • Purpose : Heavy metal use when producing the block from the workshop. At this time, production of heavy metal dust and fume gives risk in human. This like heavy metal to improve seriousness through measurement and analysis. And by the quest in solution is purpose of this thesis. Materials and Methods : Organization is Inductively Coupled Plasma Atomic Emission Spectrometer, and the object is Deajeon city 4 workshops in university hospital radiation oncology (Bismuth, Lead, Tin and cadmium). Method is the ppb the pumping it does at unit, comparison analysis. And the Calculation heavy metal standard level in air through heavy metal standard level in body and blood, so Heavy metal temporary standard set. Results : Subterranean existence room air quality the administration laws appointed Lead and Cadmium's exposure recommend that it is $3{\mu}g/m^3\;and\;2{\mu}g/m^3$. And Bismuth and Tin decides $7{\mu}g/m^3\;and\;6{\mu}g/m^3$ through standard level in air heavy metal and standard level in body and blood. Heavy metal measurement level of workshops in 4 university hospital Daejeon city compares with work existence and nonexistence. On work nonexistence almost measurement level is below the recommend level. But work existence case express high level. Also consequently in composition ratio of the block is continuous with the detection ratio. Conclusion : Worker's heavy metal contamination imbrued serious for solution founds basic part. In hospital may operation on local air exhauster and periodical efficiency check, protector offer, et al. And worker have a correct understanding part of heavy metal contamination, and have continuous interest, health control. Finally, learned society sphere administer to establishment standard level and periodical measurement. And it founds basic solution plan of periodical special health checkup.

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Effects of Rearing Densities on Behavior Characteristics in Korean Native Broilers (사육밀도가 토종육계의 행동특성에 미치는 영향)

  • Ha, Jae-Jung;Rhee, Yong-Joon;Kim, Byong-Chon;Ohh, Sang-Jip;Song, Young-Han
    • Journal of Animal Science and Technology
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    • v.53 no.5
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    • pp.481-487
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    • 2011
  • Rearing density is a major factor in welfare production and health of broiler chicks. An experiment was conducted to investigate the effect of rearing density on the behavioral characteristics of Korean native chicks. In the study, 20, 30, and 40 chicks per pen (3.17 $m^2$) were used in each treatment and randomly allotted to 6.3 bird/$m^2$, 9.5 bird/$m^2$, and 12.6 bird/$m^2$ density, respectively. The broilers' behavior was recorded for 12 hours continuously during 1 to 8 weeks of age. The time budgets (standing, sitting, and walking) and frequencies of certain behaviors (drinking, feeding, preening, scratching, dust bathing, flapping, aggressive pecking, and pecking) in the broilers were checked during the day. The behavioral characteristics in the early period (1 to 4 weeks) were compared to the later period (5 to 8 weeks) to know the changes in each behavior as the chicks matured. It was observed that 40 chicks per pen showed significant decrease in feed intake and body weight. Corticosterone hormone was higher in the order of 12.6 bird/$m^2$ > 9.5 bird/$m^2$ > 6.3 bird/$m^2$ (p<0.05). The behaviors of standing and sitting were the highest in groups of 30 and 40 respectively. The walking behavior was gradually decreased as rearing density increased. The frequencies of the other behaviors also decreased in a high density treatment; especially for feeding, drinking, preening, and pecking. These tendencies widened the gaps of behaviors as time passed. It was concluded that a group of 20 chicks (6.3 bird/$m^2$) was the proper rearing density among these three treatments. Broilers in the lower rearing density showed more activity than that with higher density and therefore this environment may lead to better welfare condition.

Air Pollution and Its Effects on E.N.T. Field (대기오염과 이비인후과)

  • 박인용
    • Proceedings of the KOR-BRONCHOESO Conference
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    • 1972.03a
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    • pp.6-7
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    • 1972
  • The air pollutants can be classified into the irritant gas and the asphixation gas, and the irritant gas is closely related to the otorhinolaryngological diseases. The common irritant gases are nitrogen oxides, sulfur oxides, hydrogen carbon compounds, and the potent and irritating PAN (peroxy acyl nitrate) which is secondarily liberated from photosynthesis. Those gases adhers to the mucous membrane to result in ulceration and secondary infection due to their potent oxidizing power. 1. Sulfur dioxide gas Sulfur dioxide gas has the typical characteristics of the air pollutants. Because of its high solubility it gets easily absorbed in the respiratory tract, when the symptoms and signs by irritation become manifested initially and later the resistance in the respiratory tract brings central about pulmonary edema and respiratory paralysis of origin. Chronic exposure to the gas leads to rhinitis, pharyngitis, laryngitis, and olfactory or gustatory disturbances. 2. Carbon monoxide Toxicity of carbon monoxide is due to its deprivation of the oxygen carrying capacity of the hemoglobin. The degree of the carbon monoxide intoxication varies according to its concentration and the duration of inhalation. It starts with headache, vertigo, nausea, vomiting and tinnitus, which can progress to respiratory difficulty, muscular laxity, syncope, and coma leading to death. 3. Nitrogen dioxide Nitrogen dioxide causes respiratory disturbances by formation of methemoglobin. In acute poisoning, it can cause pulmonary congestion, pulmonary edema, bronchitis, and pneumonia due to its strong irritation on the eyes and the nose. In chronic poisoning, it causes chronic pulmonary fibrosis and pulmonary edema. 4. Ozone It has offending irritating odor, and causes dryness of na sopharyngolaryngeal mucosa, headache and depressed pulmonary function which may eventually lead to pulmonary congestion or edema. 5. Smog The most outstanding incident of the smog occurred in London from December 5 through 8, 1952, because of which the mortality of the respiratory diseases increased fourfold. The smog was thought to be due to the smoke produced by incomplete combustion and its byproduct the sulfur oxides, and the dust was thought to play the secondary role. In new sense, hazardous is the photochemical smog which is produced by combination of light energy and the hydrocarbons and oxidant in the air. The Yonsei University Institute for Environmental :pollution Research launched a project to determine the relationship between the pollution and the medical, ophthalmological and rhinopharyngological disorders. The students (469) of the "S" Technical School in the most heavily polluted area in Pusan (Uham Dong district) were compared with those (345) of "K" High School in the less polluted area. The investigated group had those with subjective symptoms twice as much as the control group, 22.6% (106) in investigated group and 11.3% (39) in the control group. Among those symptomatic students of the investigated group. There were 29 with respiratory symptoms (29%), 22 with eye symptoms (21%), 50 with stuffy nose and rhinorrhea (47%), and 5 with sore thorat (5%), which revealed that more than half the students (52%) had subjective symptoms of the rhinopharyngological aspects. Physical examination revealed that the investigated group had more number of students with signs than those of the control group by 10%, 180 (38.4%) versus 99 (28.8%). Among the preceding 180 students of the investigated group, there were 8 with eye diseases (44%), 1 with respiratory disease (0.6%), 97 with rhinitis (54%), and 74 with pharyngotonsillitis (41%) which means that 95% of them had rharygoical diseases. The preceding data revealed that the otolaryngological diseases are conspicuously outnumbered in the heavily polluted area, and that there must be very close relationship between the air pollution and the otolaryngological diseases, and the anti-pollution measure is urgently needed.

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