• Journal of the Korean Ceramic Society
• /
• v.42 no.4
• /
• pp.292-297
• /
• 2005

$LiMO_{2}(M=Co,Ni)$ samples were synthesized with $Li_{2}CO_{3},\;Co_{3}O_{4}$, and NiO by the solid-state reaction method. In the case of $LiCoO_{2}$, at low temperature$(T=400^{\circ}C)$ spinel structure was synthesized and the obtained spinel phase was transformed to layered phase at high temperature$(T\ge600^{\circ}C)$. The phase transition behaviors of $LiCoO_{2}$ were investigated with various heating temperature and time. The rate of transition was directly proportional to the concentrations of reactant, and activation energy of reaction was around 6.76 kcal/mol. When CoO(rock salt structure) was used as a starting material instead of $Co_{3}O_{4}$(spinel structure), layered structure of $LiCoO_{2}$ was obtained at low temperature. In the case of $LiNiO_{2}$ the transition from layered structure to rock salt structure occurred easily by disordering/ordering reaction, but did not occur in $LiCoO_{2}$. The difference in metal ion radii in $LiCoO_{2}$ and $LiNiO_{2}$ results in different behaviors of phase transitions.

• Geomechanics and Engineering
• /
• v.23 no.4
• /
• pp.327-338
• /
• 2020

The role of precise prediction of subsurface fluids and discrimination among them cannot be ignored in reservoir characterization and petroleum prospecting. A suitable rock physics model should be build for the extraction of valuable information form seismic data. The main intent of current work is to present a rock physics model to analyze the characteristics of seismic wave propagating through a cracked porous rock saturated by a three phase fluid. Furthermore, the influence on wave characteristics due to variation in saturation of water, oil and gas were also analyzed for oil and water as wet cases. With this approach the objective to explore wave attenuation and dispersion due to wave induce fluid flow (WIFF) at seismic and sub-seismic frequencies can be precisely achieved. We accomplished our proposed approach by using BISQ equations and by applying appropriate boundary conditions to incorporate heterogeneity due to saturation of three immiscible fluids forming a layered system. To authenticate the proposed methodology, we compared our results with White's mesoscopic theory and with the results obtained by using Biot's poroelastic relations. The outcomes reveals that, at low frequencies seismic wave characteristics are in good agreement with White's mesoscopic theory, however a slight increase in attenuation at seismic frequencies is because of the squirt flow. Moreover, our work crop up as a practical tool for the development of rock physical theories with the intention to identify and estimate properties of different fluids from seismic data.

• Transactions of the Korean Society for Noise and Vibration Engineering
• /
• v.18 no.2
• /
• pp.247-254
• /
• 2008

Resilient materials are generally used for the floating floors to reduce the floor impact sound. Dynamic stiffness of resilient material, which has the most to do with the floor impact sound reduction. The resilient materials available in Korea include EPS(styrofoam), recycled urethane types, EVA(ethylene vinylacetate) foam rubber, foam PE(polyethylene). glass fiber & rock wool, recycled tire, foam polypropylene. compressed polyester, and other synthetic materials. In this study, we tested dynamic stiffness of resilient material and floor impact sound reduction characteristic to a lot of kinds of resilient materials. It was found that dynamic stiffness of multi-layered damping material could be estimated if know value of each layer that compose whole structure. And the test showed that the amount of the heavy-weight impact sound reduction appeared by being influenced from this dynamic stiffness of resilient material. The dynamic stiffness looked like between other resilient materials, a similar to the amount of the heavy-weight impact sound reduction was shown.

• Journal of the Korean Society for Railway
• /
• v.14 no.2
• /
• pp.160-166
• /
• 2011

It is difficult to clarify the dynamic response characteristics of trackbed because of various environmental conditions. However, track irregularity be affected by ununiformed bearing capacity and its dynamic response, study for dynamic response characteristics is required to investigate the cause of track irregularity and countermeasure. In this paper, the response variation for dominant frequency and vibration energy by trackbed structure and material stiffness are investigated. The analysis section is two layered ground structure that is comprised of trackbed and soft rock. This structure amplifies the energy of dominant range easily. It is evaluated to affect track irregularity on comparing by theoritical, analytical and empirical method for dynamic response of the trackbed.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
• /
• v.20 no.6
• /
• pp.546-549
• /
• 2007

As a rule, high temperature superconducting coated conductors have multi-layered buffers consisting of seed, diffusion barrier and cap layers. Multi-buffer layer deposition requires longer fabrication time. This is one of main reasons which increases fabrication cost. Thus, single buffer layer deposition seems to be important for practical coated conductor process. In this study, a single layered buffer deposition of $CeO_2$ for low cost coated conductors has been tried using thermal evaporation technique. 100 nm-thick $CeO_2$ layers deposited by thermal evaporation were found to act as a diffusion layer. $1\;{\mu}m-thick$ SmBCO superconducting layers were deposited by thermal co-evaporation on the $CeO_2$ buffered Ni-5%W substrate. Critical current of 90 A/cm was obtained for the SmBCO coated conductors.

• Polymer(Korea)
• /
• v.31 no.4
• /
• pp.297-301
• /
• 2007

In this work, polymer/(layered silicate) nanocomposites (PLSN) based on poly (ethylene oxide) (PEO), ethylene carbonate (EC) as a plasticizer, lithium salt ($LiClO_4$), and sodium montmorillonite ($Na^+-MMT$) or organic montmorillonite (organic MMT) clay were fabricated. And the effects of organic MMT on the polymer matrix were investigated as a function of ionic conductivity. For the application to electrolytes an Li batteries, polymer electrolytes containing the organic nanoclays were used in this work. As a result, the spacing between layers and hydrophobicity of the organic nanoclays were increased, affecting on the exfoliation behaviors of the MMT layers in clay/PEO nanocomposites. From ion-conductivity results, the organic-MMT showed higher values than those of $Na^+-MMT$, and the MMT-20A sample that was treated by methyl dihydrogenated tallow ammonium, showed the highest conductivity in this system.

• Nuclear Engineering and Technology
• /
• v.25 no.4
• /
• pp.529-538
• /
• 1993

A stochastic way using continuous time Markov process is presented to model the one-dimensional nuclide transport in fractured rock matrix as an extended study for previous work ［1］. A nuclide migration model by the continuous time Markov process for single planar fractured rock matrix, which is considered as a transient system where a process by which the nuclide is diffused into the rock matrix from the fracture may be no more time homogeneous, is compared with a conventional deterministic analytical solution. The primary desired quantities from a stochastic model are the expected values and variance of the state variables as a function of time. The time-dependent probability distributions of nuclides are presented for each discretized compartment of the medium given intensities of transition. Since this model is discrete in medium space, parameters which affect nuclide transport could be easily incorporated for such heterogeneous media as the fractured rock matrix and the layered porous media. Even though the model developed in this study was shown to be sensitive to the number of discretized compartment showing numerical dispersion as the number of compartments are decreased, with small compensating of dispersion coefficient, the model agrees well to analytical solution.

• Proceedings of the Korean Geotechical Society Conference
• /
• 1994.09a
• /
• pp.139-148
• /
• 1994

Rapid industrialization and urbanization caused by the high economic growth of the country requires optimization of land usage as well as the expansion of underground space. Therefore the construction of large and deep basements is inevitable in built up areas where the braced excavation for earth retaining structures may create many problems such as settlement and damages of nearby buildings and underground utilities. In this work, some of major influential factors concerning the stability of braced excavation are investigated and the results are compared with the field observation results. The ground water table, applied strut forces, horezontal wall displacement, infilling materials in the rock joints were found to be the most critical factors influencing the stability of braced walls constructed in the layered ground. Magnituide and type of the wall deformation was closely related to the pattern of the surface settlement. The stability of braced walls are described in terms of strut forces.

• Proceedings of the Computational Structural Engineering Institute Conference
• /
• 1996.10a
• /
• pp.202-209
• /
• 1996

In this paper, two dimensional vertical and comer infinite elements which can include multiple wave components to model underlying half space are developed. These elements are natural and economical to model underlying stiff half space or rock. To verify the behavior of these infinite elements, vertical, horizontal, and rocking compliances of a rigid strip foundation on a viscoelastic soil profile are analyzed and compared with those of Tzong and Penzien who used the boundary solution method. Good agreements are noticed between the two methods. The influence of material properties like Poisson's ratio, material damping, and stiffness ratio of layers as well as the influence of geometrical properties such as layer thicknesses and depth of foundation embedment are studied. Example analysis is carried out for the shaking table which is located in KIMM(Korea Institute of Machinery and Materials), and the vertical and horizontal displacements of the analysis are compared with the measured, and show good results and demonstrate the efficiency of the proposed method.

• Structural Engineering and Mechanics
• /
• v.57 no.4
• /
• pp.703-716
• /
• 2016

In this paper, we have investigated shear horizontal wave propagation in a layered structure, consisting of granular macromorphic rock (Dionysos Marble) substrate underlying a viscoelastic layer of finite thickness. SH waves characteristics are affected by the material properties of both substrate and the coating. The effects of microstructural parameter "characteristic length" of the substrate, along with heterogeneity, internal friction and thickness of viscoelastic layer are studied on the dispersion curves. Dispersion equation for SH wave is derived. Real and damping phase velocities of SH waves are studied against dimensionless wave number, for different combinations of various parameters involved in the problem.