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Solution-processed Polymer Tandem Cells Using Nano Crystalline $TiO_2$ Interlayer ($TiO_2$ 나노 입자의 중간 전극을 이용한 직렬 적층형 유기 태양 전지)

  • Chung, Won-Suk;Ju, Byeong-Kwon;Ko, Min-Jae;Park, Nam-Gyu;Kim, Kyung-Kon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.444-444
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    • 2008
  • For the polymer tandem cell, simple and advantaged solution-based method to electron transport intermediate layer is presented which are composed $TiO_2$ nanoparticles. Device were based on a regioregular Poly(3-hexylthiophene)(P3HT) and [6,6]-phenyl $C_{61}$ butyric acid methyl ester($PC_{60}BM$) blend as a donor and acceptor bulk-heterojunction. For the middle electrode interlayer, the $TiO_2$ nanoparticles were well dispersed in ethanol solution and formed thin layer on the P3HT:PCBM charge separation layer by spin coating. The layer serves as the electron transport layer and divides the polymer tandem solar cell. The open-circuit voltage (Voc) for the polymer tandem solar cells was closed to the sum of those of individual cells.

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Effects of Fe2O3 Addition on Optical and Electrical Properties of MgO Films as a Protective Layer for AC PDPs (Fe2O3 첨가에 따른 AC PDP 보호막용 MgO 박막의 광학적.전기적 특성)

  • Kim, Chang-II;Jeong, Young-Hun;Lee, Young-Jin;Paik, Jong-Hoo;choi, Eun-Ha;Jung, Seok;Kim, Jeong-Seok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.22 no.9
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    • pp.760-765
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    • 2009
  • The effects of $Fe_2O_3$ addition on optical and electrical properties of MgO films as a protective layer for AC plasma display panels were investigated. Doped MgO films prepared by the e-beam evaporation have a higher ${\gamma}$ (secondary electron emission coefficient) than pure MgO protective layer. Roughness increased with amount of $Fe_2O_3$ up to 100 ppm and then decreased further addition. These results showed that discharge properties and optical properties of MgO protective layers seemed to be closely related with microstructure factors such as roughness. Good optical and electrical properties of ${\gamma}$ of 0.120, surface roughness of 14.1 nm and optical transmittance of 94.55% were obtained for the MgO + 100 ppm $Fe_2O_3$ protective layer sintered at $1700^{\circ}C$ for 5 hrs.

PLASMA-SULFNITRIDING USING HOLLOW CATHODE DISCHARGE

  • Urao, Ryoichi;Hong, Sung-pill
    • Journal of Surface Science and Engineering
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    • v.29 no.5
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    • pp.443-448
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    • 1996
  • In order to plasma-sulfnitride by combining ion-nitriding of a steel and sputtering of MoS$_2$, chromium-molybdenum steel was plasma-sulfritrided using hollow cathode discharge with parallel electrodes which are a main of the steel and a subsidiary cathode of $MoS_2$. The treatment was carried out at 823K for 10.8ks under 665Pa in a 30% $N_2$-70% $H_2$ gas atmosphere. Plasma-sulfnitriding layers formed of the steel were characterized with EDX, XRD, micrographic structure observation and hardness measurement. A compound layer of 8-15$\mu\textrm{m}$ and nitrogen diffusion layer of about 400$\mu\textrm{m}$ were formed on the surface of plasma-sulfnitrided steel. The compound layer consisted of FeS containing Mo and iron nitrides. The nitrides of $\varepsilon$-$Fe_2_3N$ and $\gamma$'-$Fe_4N$ formed under the FeS. The thickness of compound layer and surface hardness were different with the gaps between main and subsidiary cathodes even in the same sulfnitriding temperature. The surface hardnesses after plasma-sulfnitriding were distributed from 640 to 830Hv. The surface hardness was higher in the plasma-sulfnitriding than the usual sulfnitriding in molten salt. This may be due to Mo in sulfnitriding layer.

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Effects of Gd2O3 Addition on Optical and Electrical Properties of MgO Films as a Protective Layer for AC PDPs (Gd2O3 첨가에 따른 AC PDP 보호막용 MgO 박막의 광학적.전기적 특성)

  • Kim, Chang-Il;Lim, Eun-Kyeong;Park, Young-Jun;Lee, Young-Jin;Paik, Jong-Hoo;Choi, Eun-Ha;Juang, Seok;Kim, Jeong-Seok
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.20 no.7
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    • pp.620-625
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    • 2007
  • The effects of $Gd_2O_3$ addition and sintering condition on optical and electrical properties of MgO films as a protective layer for AC plasma display panels were investigated. Doped MgO films prepared by the e-beam evaporation have a higher ${\Upsilon}$ (secondary electron emission coefficient) than pure MgO protective layer. Relative density and grain size increased with amount of $Gd_2O_3$ up to 100 ppm and then decreased further addition. These results showed that discharge properties and optical properties of MgO protective layers seemed to be closely related with microstructure factors such as relative density and grain size. Good optical and electrical properties of ${\Upsilon}$ of 0.138, surface roughness of 5.77 nm and optical transmittance of 95.76 % were obtained for the MgO+100 ppm $Gd_2O_3$ protective layer sintered at $1700^{\circ}C$ for 5 hrs.

Atmospheric Oxidation of Fe-16Cr-6Ni-6Mn-1.7Mo Stainless Steel between 700 and 900℃ (Fe-16Cr-6Ni-6Mn-1.7Mo 스테인리스 합금의 700~900℃에서의 대기중 산화)

  • Lee, Dong Bok
    • Korean Journal of Metals and Materials
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    • v.49 no.2
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    • pp.153-160
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    • 2011
  • The AISI 216L stainless steel with a composition of Fe-16Cr-6Ni-6Mn-1.7Mo (wt.%) was oxidized at $700{\sim}900^{\circ}C$ in air for 100 h. At $700^{\circ}C$, a thin $Mn_{1.5}Cr_{1.5}O_4$ oxide layer with a thickness of $0.4{\mu}m$ formed. At $800^{\circ}C$, an outer thin $Fe_2O_3$ oxide layer and a thick inner $FeCr_2O_4$ oxide layer with a total thickness of $30{\mu}m$ formed. The non-adherent scale formed at $800^{\circ}C$ was susceptible to cracking. At $900^{\circ}C$, an outer thin $Fe_2O_3$ oxide layer and a thick inner $Mn_{1.5}Cr_{1.5}O_4$ oxide layer formed, whose total thickness was $10{\sim}15{\mu}m$. The scales formed at $900^{\circ}C$ were non-adherent and susceptible to cracking. 216 L stainless steel oxidized faster than 316 L stainless steel, owing to the increment of the Mn content and the decrement of Ni content.

Deposition of an Intermediate Layer on an Ultrapermeable Ceramic Support by Evaporation-Driven Self-Assembly (증발유도 자기조립을 이용한 고투과도 세라믹 지지체의 중간층 제조)

  • Kwon, Hyuk Taek;Kim, Jinsoo
    • Membrane Journal
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    • v.31 no.1
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    • pp.80-85
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    • 2021
  • In this study, we developed an evaporation-driven self-assembly coating method for an ceramic intermediate layer on an ultrapermeable ��-Al2O3 support with large pore size of ~1.5 ㎛. The method led to the formation of a ceramic intermediate layer with higher surface homogeneity and less surface roughness than the conventional dip-coating method. A mesoporous ��-Al2O3 layer was deposited on the support to evaluate support quality. A supported ��-Al2O3 membrane was defect-free even without repeated coating. Furthermore, the membrane showed 2.3 times higher nitrogen permeance than one prepared on a macroporous support with pore size range of 100~200 nm, which is widely used for ceramic membrane coating.

Hafnium Carbide Protective Layer Coatings on Carbon/Carbon Composites Deposited with a Vacuum Plasma Spray Coating Method

  • Yu, Hui-Il;Kim, Ho-Seok;Hong, Bong-Geun;Sin, Ui-Seop;Mun, Se-Yeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.237.2-237.2
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    • 2016
  • A pure hafnium-carbide (HfC) coating layer was deposited onto carbon/carbon (C.C) composites using a vacuum plasma spray system. By adopting a SiC buffer layer, we successfully integrated C.C composites with a $100-{\mu}m-thick$ protective coating layer of HfC. Compared to the conventional chemical vapor deposition process, the HfC coating process by VPS showed increased growth rate, thickness, and hardness. The growth behavior and morphology of HfC coatings were investigated by FE-SEM, EDX, and XRD. From these results, it was shown that the addition of a SiC intermediate layer provided optimal surface conditions during the VPS procedure to enhance adhesion between C.C and HfC (without delamination). The thermal ablation test results shows that the HfC coating layer perfectly protected inner C.C layer from thermal ablation and oxidation. Consequently, we expect that this ultra-high temperature ceramic coating method, and the subsequent microstructure that it creates, can be widely applied to improve the thermal shock and oxidation resistance of materials under ultra-high temperature environments.

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Broadband Microstrip Antenna (광대역 마이크로스트립 안테나)

  • 홍재표
    • Journal of Korea Society of Industrial Information Systems
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    • v.4 no.4
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    • pp.111-116
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    • 1999
  • In this paper, the electromagnetically coupled microstrip dipole antenna by adapting one parasitic metal-strip(dipole) between the microstrip transmission line open end and the radiating microstrip dipole antenna is presented for the bandwidth improvement The microstrip dipole antenna is simulated using Ensemble 51 simulation package The effects of varying several physical parameters, such as the lengths of radiating dipole and parasitic dipole and the width of parasitic dipole are investigated The bandwidth behavior of the 3-layer optimum antenna is compared with that of 2-layer antenna without the parasitic dipole. Experimental result for the obtained broadband performance is presented and discussed.

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Effect of MWCNTs/PSf support layer on the performance of polyamide reverse osmosis membrane (탄소나노튜브가 첨가된 폴리술폰 지지체가 폴리아미드 역삼투막의 성능에 미치는 영향)

  • Min, Choong-Sik;Kim, Seung-Hyun
    • Journal of Korean Society of Water and Wastewater
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    • v.34 no.2
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    • pp.127-137
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    • 2020
  • In this study, a MWCNT(multi-wall carbon nanotube) was added to polysulfone(PSf) support layer to improve flux of TFC(thin film composite) RO(reverse osmosis) membrane. Two different kinds of MWCNT were used. Surfaces of some MWCNTs were modified hydrophilically through acid treatment, while those of other MWCNTs were modified through heat treatment to maintain their hydrophobicity. MWCNT/PSf support layer was prepared by adding PSf to the NMP mixed solvent containing 0.1 wt% MWCNTs using a phase inversion method. The surface porosity of the MWCNT/PSf support increased by 42~46% while its surface pore size being maintained. The TFC RO membrane made of MWCNT/PSf support layer showed a 20% flux increase while its salt rejection characteristics is sustained. In addition, the MWCNT/PSf support layer has better mechanical stability than the PSf support layer, there resulting in an increased resistance of flux reduction due to physical pressure.

Digital X-ray Detector에 적용을 위한 Polycrystalline CdTe 구조에 따른 전기적 신호 연구

  • Kim, Jin-Seon;O, Gyeong-Min;Jo, Gyu-Seok;Song, Yong-Geun;Hong, Ju-Yeon;Heo, Seung-Uk;Nam, Sang-Hui
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.484-484
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    • 2013
  • 기존 진단용 Digital X-ray Detector이 직접방식에서는 a-Se (Amorphous Selenium)이 대중화되었지만 고전압을 인가하여야한다는 점과 그로 인한 물질 자체의 Life time 감소 등 여러 단점들 때문에 기타 후보물질들로 HgI2, PbI2, PbO, CdTe, CdZnTe가 연구 되고 있다. 이러한 후보 물질들 중 본 연구에서는 PVD (Physical Vapor Deposition)방식을 이용하여 Polycrystalline CdTe 박막을 제작하고 특성 향상을 위해 유전물질을 Passive layer와 Protect layer로써 증착하였다. 또한 유전체층의 위치에 따른 특성 분석을 위해 제작된 박막은 FE-SEM (Field Emission Scanning Electron Microscope), XRD (X-ray Diffraction)을 통해 구조적인 특성을 확인하였다. 그리고 입사되는 X-ray 선량에 의해 생성되는 전기적 특성을 분석하였다, 그 결과 박막의 Grain Size는 약 $5{\mu}M$이며 (111)방향의 주 peak를 띄는 Poly CdTe형태로 증착된 것을 확인하였다. 전기적인 신호 결과 Passive layer와 Protect layer를 증착한 박막 모두 Darkcurrent가 감소된 것을 확인하였다. 또한 Sensitivity 측정 결과 Passive layer를 삽입한 경우 신호 값이 감소하였으며 Protect layer를 삽입한 경우 신호 값의 변화가 일어나지 않았다. 그러므로 Protect layer를 등착한 박막의 경우 SNR이 현저히 높아지는 결과를 낳았다.

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