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EFFECTS OF SMEAR LAYER AND DENTIN PRIMERS ON THE SEALING ABILITY OF ROOT CANAL (근관 밀폐도에 미치는 도말층 및 상아질 접착강화제의 영향)

  • Yang, Jin-Suck;Hwang, In-Nam;Kim, Won-Jae;Oh, Won-Mann
    • Restorative Dentistry and Endodontics
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    • v.25 no.4
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    • pp.527-535
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    • 2000
  • The purpose of this study was to evaluate effects of smear layer and dentin primers on the sealing ability of root canals. 126 extracted human teeth with single, straight canals and mature apices were used. The Samples were first classified into six groups as follows: presence of smear layer; absence of smear layer; Scotchbond Bond Multi-Purpose; All Bond 2; Mac Bond 2; Clearfil Liner Bond 2. A Positive control was also established. All teeth except the control group were then obturated with thermoplasticized gutta-percha and AH26. Electrochemical and dye penetration technique were later used to evaluate the degree of micro leakage through the root canal. Seventy teeth were then immersed in a 1% potassium chloride solution and An external power supply(DC 10 V) was then applied to the circuit for the electrochemical microleakage test. The degree of Microleakage was determined over period of 28 days before being evaluated. In total, 48 teeth were submitted to the dye infiltration technique. All specimen were suspended in 2% methylene blue dye for 1 week before being longitudinally split. The degree of dye infiltration was measured under a stereo microscope at ${\times}10$ magnification and evaluated. The results were as follows: 1. Apical microleakage increased throughout the test period in all group and one group having a smear layer showed a dramatic increase under electrochemical test (p<0.05). In the group having smear layer, the degree of apical microleakage was the highest, and the micro leakage was much higher than in the smear layer removed group in electrochemical test (p<0.05). Scotchbond Multi-Purpose, All Bond 2, Mac Bond 2 and Clearfil Liner Bond 2 showed lower micro leakage than one group having smear layer. The All Bond 2 and Clearfil Liner Bond 2 treated groups showed the lowest microleakage in electrochemical test (p<0.05). 2. There was no significant difference between the experimental groups in dye penetration technique. These results suggested that the removal of the smear layer from root canal and concomitantly the application of dentin primer into root canal could improve the sealing ability of root canal obturation.

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Low-Voltage Driving of Indium Zinc Oxide Transistors with Atomic Layer Deposited High-k Al2O3 as Gate Dielectric (원자층 증착을 이용한 고 유전율 Al2O3 절연 박막 기반 Indium Zinc 산화물 트랜지스터의 저전압 구동)

  • Eom, Ju-Song;Kim, Sung-Jin
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.30 no.7
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    • pp.432-436
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    • 2017
  • IZO transistors with $Al_2O_3$ as gate dielectrics have been investigated. To improve permittivity in an ambient dielectric layer, we grew $Al_2O_3$ by atomic layer deposition directly onto the substrates. Then, we prepared IZO semiconductor solutions with 0.1 M indium nitrate hydrate [$In(NO_3)_3{\cdot}xH_2O$] and 0.1 M zinc acetate dehydrate [$Zn(CH_3COO)_2{\cdot}2H_2O$] as precursor solutions; the IZO solution made with a molar ratio of 7:3 was then prepared. It has been found that these oxide transistors exhibit low operating voltage, good turn-on voltage, and an average field-effect mobility of $0.90cm^2/Vs$ in ambient conditions. Studies of low-voltage driving of IZO transistors with atomic layer-deposited high-k $Al_2O_3$ as gate dielectric provide data of relevance for the potential use of these materials and this technology in transparent display devices and displays.

Effect of Ultrathin Al2O3 Layer on TiO2 Surface in CdS/CdSe Co-Sensitized Quantum Dot Solar Cells

  • Sung, Sang Do;Lim, Iseul;Kim, Myung Soo;Lee, Wan In
    • Bulletin of the Korean Chemical Society
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    • v.34 no.2
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    • pp.411-414
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    • 2013
  • In order to enhance the photovoltaic property of the CdS/CdSe co-sensitized quantum dot sensitized solar cells (QDSSCs), the surface of nanoporous $TiO_2$ photoanode was modified by ultrathin $Al_2O_3$ layer before the deposition of quantum dots (QDs). The $Al_2O_3$ layer, dip-coated by 0.10 M Al precursor solution, exhibited the optimized performance in blocking the back-reaction of the photo-injected electrons from $TiO_2$ conduction band (CB) to polysulfide electrolyte. Transient photocurrent spectra revealed that the electron lifetime (${\tau}_e$) increased significantly by introducing the ultrathin $Al_2O_3$ layer on $TiO_2$ surface, whereas the electron diffusion coefficient ($D_e$) was not varied. As a result, the $V_{oc}$ increased from 0.487 to 0.545 V, without appreciable change in short circuit current ($J_{sc}$), thus inducing the enhancement of photovoltaic conversion efficiency (${\eta}$) from 3.01% to 3.38%.

Study on Frequency Characteristics for Double-Layer Symmetric Spiral Inductor (2층 대칭 나선형 인덕터에 대한 주파수 특성 연구)

  • Kim, Jae-Wook
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.15 no.5
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    • pp.315-320
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    • 2022
  • In the case of a general spiral inductor, the orientation of the port is affected as it has an asymmetric structure. In this paper, double-layer spiral inductor that can have a symmetrical structure is proposed, and the simulation and frequency characteristics are analyzed. Compared to the conventional single-layer symmetrical inductor having an inductance of 3.9~4.2nH, the proposed double-layer symmetric spiral inductor has an inductance of 11~12nH in 0.3~1.2GHz frequency range, a quality factor of about 4.4 in 800MHz, and a self-resonant frequency of about 2.7~2.8GHz without changing the port. Compared to the general spiral inductor having a large difference depending on the port, it was confirmed that the influence on the port direction was small.

Photoconductive Property and Its Application of $Sb_2S_3$ Thin film ($Sb_2S_3$ 박막의 광도전특성 및 그 응용)

  • Yun, Young Hoon;Park, Ki Cheol;Choi, Gyu Man;Kim, Ki Wan
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.23 no.5
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    • pp.699-705
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    • 1986
  • Sb2S3 thin films were fabricated by vacuum evaporation of compound Sb2S3 at a pressure of 10**-5 torr. and in argon ambient. Then, their electrical and photoconductive properties were investigated. The Sb2S3 glass-layer showed maximum photosensitivity at the deposition rate of 250\ulcornersec, and Sb2S3 porous layer had mininum dielectric constant of 1.5 at the deposition rate of 0.3 um/sec and argon partial pressure of 0.2torr. Sb2S3 multi-layers were prepared at the different thickness ratio (B/A) to find the proper structural property suited for camera pick-up tube. Here, A is the sum of the thickness of Sb2S3 porous layer and Sb2S3 fine grain layer, and B is the thickness of Sb2S3 fine grain layer. As a result, photosensitivity had a peak value at the thickness ratio (B/A) of 60%.

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High performance of inverted polymer solar cells

  • Lee, Hsin-Ying;Lee, Ching-Ting;Huang, Hung-Lin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.61.2-61.2
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    • 2015
  • In the past decades, green energy, such as solar energy, wind power, hydropower, biomass energy, geothermal energy, and so on, has been widely investigated and developed to solve energy shortage. Recently, organic solar cells have attracted much attention, because they have many advantages, including low-cost, flexibility, light weight, and easy fabrication [1-3]. Organic solar cells are as a potential candidate of the next generation solar cells. In this abstract, to improve the power conversion efficiency and the stability, the inverted polymer solar cells with various structures were developed [4-6]. The novel cell structures included the P3HT:PCBM inverted polymer solar cells with AZO nanorods array, with pentacene-doped active layer, and with extra P3HT interfacial layer and PCBM interfacial layer. These three difference structures could respectively improve the performance of the P3HT:PCBM inverted polymer solar cells. For the inverted polymer solar cells with AZO nanorods array as the electronic transportation layer, by using the nanorod structure, the improvement of carrier collection and carrier extraction capabilities could be expected due to an increase in contact area between the nanorod array and the active layer. For the inverted polymer solar cells with pentacene-doped active layer, the hole-electron mobility in the active layer could be balanced by doping pentacene contents. The active layer with the balanced hole-electron mobility could reduce the carrier recombination in the active layers to enhance the photocurrent of the resulting inverted polymer solar cells. For the inverted polymer solar cells with extra P3HT and PCBM interfacial layers, the extra PCBM and P3HT interfacial layers could respectively improve the electron transport and hole transport. The extra PCBM interfacial layer served another function was that led more P3HT moving to the top side of the absorption layer, which reduced the non-continuous pathways of P3HT. It indicated that the recombination centers could be further reduced in the absorption layer. The extra P3HT interfacial layer could let the hole be more easily transported to the MoO3 hole transport layer. The high performance of the novel P3HT:PCBM inverted polymer solar cells with various structures were obtained.

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Numerical Simulations of Diurnal Variations of Air Temperature and Relative Humidity in the Urban Canopy Layer (도시 캐노피 층 기온과 상대습도의 일변화에 관한 수치 모의)

  • Park, Kyeongjoo;Han, Beom-Soon;Jin, Han-Gyul
    • Atmosphere
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    • v.31 no.3
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    • pp.295-309
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    • 2021
  • Diurnal variations of air temperature and relative humidity in the Urban Canopy Layer (UCL) of the Seoul metropolitan area are examined using the Weather Research and Forecasting model coupled with the Seoul National University Urban Canopy Model. The canopy layer air temperature is higher than 2-m air temperature and exhibits a more rapid rise and an earlier peak in the daytime. These result from the multiple reflections of shortwave radiation and longwave radiation trapping due to the urban geometry. Because of the absence of vegetation in the UCL and the higher canopy layer air temperature, the canopy layer relative humidity is lower than 2-m relative humidity. Additional simulations with building height changes are conducted to examine the sensitivities of the canopy layer meteorological variables to the urban canyon aspect ratio. As the aspect ratio increases, net sensible heat flux entering the UCL increases (decreases) in the daytime (nighttime). However, the increase in the volume of the UCL reduces the magnitude of change rate of the canopy layer air temperature. As a result, the canopy layer air temperature generally decreases in the daytime and increases in the nighttime as the aspect ratio increases. The changes in the canopy layer relative humidity due to the aspect ratio change are largely determined by the canopy layer air temperature. As the aspect ratio increases, the canopy layer relative humidity is generally increased in the daytime and decreased in the nighttime, contrary to the canopy layer air temperature.

CIGS 박막태양전지용 Cd free형 ZnS(O, OH) 버퍼층 제조 및 특성평가

  • Kim, Hye-Jin;Kim, Jae-Ung;Kim, Gi-Rim;Jeong, Deok-Yeong;Jeong, Chae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.257.1-257.1
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    • 2015
  • Cu(In,Ga)Se2 (CIGS) 박막 태양 전지에서 buffer layer는 CIGS 흡수층과 TCO 사이의 밴드갭 차이에 대한 문제점과 lattice mismatch를 해결하기 위해 필수적이다. 흔히 buffer layer 물질로는 CdS가 가장 많이 사용되고 있으나 Cd의 독성에 관한 문제가 야기되고 있다. 따라서 ZnS(O, OH) buffer layer가 친환경 물질로 기존의 CdS 버퍼 층의 대체 물질로 각광 받고 있으며, 단파장 범위에서 높은 투과율로 인해 wide band gap의 Chalcopyrite 태양 전지에 응용되는 buffer layer로 많은 연구가 이루어지고 있다. 또한 buffer layer를 최적화 하여 carrier lifetime과 양자 효율이 증가시킬 수 있는 특성을 가지고 있다. 이 연구에서는 Cu(In,Ga)Se2 (CIGS) 박막에 화학습식공정 (CBD) 방법을 이용하여 최적화된 ZnS(O, OH)의 증착 조건을 찾고, 고품질의 buffer layer를 제조하기 위한 실험에 초점을 맞췄다. 또한, buffer layer의 막질을 개선하고 균일한 막을 제조하기 위해 processing parameters인 시약의 농도, 제조 시간 및 온도 등의 다양한 변화를 통해 실험을 진행하였다. 그 후 최적화된 ZnS(O, OH) buffer layer의 특성 분석을 위해 X-ray diffraction(XRD), photoluminescence (PL), scanning electron microscope (SEM) and GD-OES을 이용하였고, 이를 통해 제조된 CIGS 박막 태양전지는 light induced current-voltage (LIV) and external quantum efficiency (EQE)를 통해 특성 분석을 실시 하였다. 결과적으로, 제조된 ZnS(O, OH) buffer layer의 $ZnSO4{\cdot}7H2O$의 농도는 0.16 M, Thiourea는 0.5 M, NH4OH는 7.5 M, 그리고 반응 온도는 77.5 oC의 조건 하에 CIGS 기판 위에 균일하고 균열이 없는 ZnS(O, OH) 박막을 제조하였으며 이때 제조된 태양전지의 소자 특성은 Voc = 0.478 V, Jsc = 35.79 mA/cm2, FF = 47.77%, ${\eta}=8,18 %$이다.

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Stratum Division Effect of Consolidation Settlement Formula Using Compression Index (압축지수를 이용한 압밀침하량 계산식의 압밀층 두께 분할효과)

  • Kim, Khi-Woong
    • Journal of the Korean Geosynthetics Society
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    • v.11 no.2
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    • pp.49-54
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    • 2012
  • The final consolidation settlement is important factor in soft ground improvement because of settlement management and completion time. The compression index, which is slope of primary consolidation curve, is commonly used for the calculation of final consolidation settlement in clay layer. The existing final consolidation settlement is calculated in total consolidation layer that is assumed as one layer. This paper describes analysis result of the acquired settlement, when the consolidation layer is divided as several layer. The consolidation settlement increased according to increase of the divided layer and then it is converged. This result was unrelated to surcharge load. The division effect of layer is very high when the surcharge load is less than the consolidation layer thickness. The division effect of layer is 1.2 to 1.4 in the general surcharge load, and this value can be apply as safety factor in the calculation of final consolidation settlement.

Antioxidative and Hepatoprotective Activity of Colured-Scented and Korean Native Rice Varieties Based on Different Layers (특수 유색미, 향류미 및 한국 재래종 벼 종자의 층위별 항산화 및 간보호 활성)

  • 박희준;곽태순;정원태;최종원
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.1
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    • pp.191-198
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    • 1999
  • Fifteen varieties of Oryza sativa mainly including those of Korean native rice were exactly cutted into three layers such as L1 layer(the outer part of 92% from rice center), L2 layer(the part of 81∼91% from the rice center) and L3 layer(the inner part of 80% from the rice center) We biologically evaluated the antioxidative effect on the every layer(L1, L2 and L3) of all the varieties, by observing malondialdehyde (MDA) produced by galactosamine in the mouse. L1 layer of some varieties showed significant antiox idative effect, while L2 and L3 layer didn't show the activity. It was also suggested that coloured rice(Suwon 425 and Sanggaehangbyeolna) showed stronger activity than other general rices, probably due to high contents of anthocyanins. Successively, we evaluated antihepatotoxic effect, based on the determination of serum ALT and AST activity. Some varieties of only L1 layer, except for L2 and L3 layer, significantly decreased the serum ALT and AST activity. This finding indicate that oral diet of some raw rice are able to protect hepatotoxicities. Among all the samples tested, L1 layer of Suwon 425 showed the strongest antihepatotoxic effect. From quantitative analysis on ferulic acid derivatives, it was found that the more it enters from the surface into the rice center, the more those secondary metabolites contents were highly reduced. These findings above suggested that Suwon 425 could be a promising candidate for the development of health rice food.

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