• 한국세라믹학회지
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• 제28권6호
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• pp.429-436
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• 1991

Silicon carbide has been grown by a chemical vapor deposition (CVD) technique using CH3SiCl3 and H2 gaseous mixture onto a graphite substrate. Based on the thermodynamic equilibrium studies and the suggestion that the deposition rate of SiC is controlled by surface reaction theoretical kinetic equation for CVD of silicon carbide has been proposed. The proposed theoretical kinetic equation for CVD of silicon carbide agreed well with the experimental results for the variation of the deposition rate as a function of the partial pressure of reactant gases. The Vikers microhardness of the SiC layer was about 3000∼3400 kg/$\textrm{mm}^2$ at room temperature.

• 한국전산유체공학회지
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• 제3권2호
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• pp.65-72
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• 1998

From the Boltzmann equation with BGK approximation, a gas-kinetic BGK scheme is developed and methods for its efficient calculation, using the convergence acceleration techniques, are presented in a framework of an implicit time integration. The characteristics of the original gas-kinetic BGK scheme are improved in order for the accurate calculation of viscous and heat convection problems by considering Osher's linear subpath solutions and Prandtl number correction. Present scheme applied to various numerical tests reveals a high level of accuracy and robustness and shows advantages over flux vector splittings and Riemann solver approaches from Euler equations.

• Bulletin of the Korean Chemical Society
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• 제34권10호
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• pp.2989-2994
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• 2013

The solvolysis rate constants of 3,4- (1) and 3,5-dimethoxybenzoyl (2) chlorides were measured in various pure and binary solvents at $25.0^{\circ}C$, and studied by application of the extended Grunwald-Winstein (G-W) equation, kinetic solvent isotope effect in methanolysis and activation parameters. The solvolysis of 1 was interpreted as the unimolecular pathway due to a predominant resonance effect from para-methoxy substituent like 4-methoxybenzoyl chloride (3), while that of 2 was evaluated as the dual mechanism, with unimolecular or bimolecular reaction pathway according to the character of solvent systems (high electrophilic/nucleophilic) chosen, caused by the inductive effect by two meta-methoxy substituents, no resonance one. In the solvolyses of 1 and 2 with two $-OCH_3$ groups, the resonance effect of para-methoxy substituent is more important to decide the mechanism than the inductive effect with other corresponding evidences.

• 한국자동차공학회논문집
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• 제7권7호
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• pp.1-14
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• 1999

In the present study, the flame factor which primarily influence the simulation accuracy of the combustion process in a gasoline engine was modeled as a nonlinear function of turbulent intensity to laminar flame speed ratio. Multi-length-scale production rate model for turbulent kinetic energy equation was introduced to consider the different length scales of the swirling and tumbling motions in cylinder on the production rte of turbulent kinetic energy. By7 introducing the multi-length-scale production rate model for the turbulent kinetic energy equation, the predictions of turbulent burning velocity , cylinder pressure, mass burning rate and engine performance of a gasoline engine can much be improved.

• Bulletin of the Korean Chemical Society
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• 제30권10호
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• pp.2437-2439
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• 2009

• Bulletin of the Korean Chemical Society
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• 제32권10호
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• pp.3799-3801
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• 2011

• Wind and Structures
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• 제19권6호
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• pp.687-708
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• 2014

The performance of the $k-{\varepsilon}$ and $k-{\omega}$ two-equation turbulence models was investigated in computational simulations of the neutrally stratified atmospheric boundary layer developing above various terrain types. This was achieved by using a proposed methodology that mimics the experimental setup in the boundary layer wind tunnel and accounts for a decrease in turbulence parameters with height, as observed in the atmosphere. An important feature of this approach is pressure regulation along the computational domain that is additionally supported by the nearly constant turbulent kinetic energy to Reynolds shear stress ratio at all heights. In addition to the mean velocity and turbulent kinetic energy commonly simulated in previous relevant studies, this approach focuses on the appropriate prediction of Reynolds shear stress as well. The computational results agree very well with experimental results. In particular, the difference between the calculated and measured mean velocity, turbulent kinetic energy and Reynolds shear stress profiles is less than ${\pm}10%$ in most parts of the computational domain.

• 한국전산유체공학회지
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• 제20권3호
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• pp.54-61
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• 2015

In the present study, a flow solver using a kinetic BGK scheme was developed for the compressible Navier-Stokes equation. The kinetic BGK scheme was used to simulate flow field from the continuum up to the transitional regime, because the kinetic BGK scheme can take into account the statistical properties of the gas particles in a non-equilibrium state. Various numerical simulations were conducted by the present flow solver. The laminar flow around flat plate and the hypersonic flow around hollow cylinder of flare shape in the continuum regime were numerically simulated. The numerical results showed that the flow solver using the kinetic BGK scheme can obtain accurate and robust numerical solutions. Also, the present flow solver was applied to the hypersonic flow problems around circular cylinder in the transitional regime and the results were validated against available numerical results of other researchers. It was found that the kinetic BGK scheme can similarly predict a tendency of the flow variables in the transitional regime.

• Carbon letters
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• 제22권
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• pp.14-24
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• 2017

Carboxylated multi-wall carbon nanotubes (MWCNTs-COOH) have been used as efficient adsorbents for the removal of picric acid from aqueous solutions under stirring and ultrasound conditions. Batch experiments were conducted to study the influence of the different parameters such as pH, amount of adsorbents, contact time and concentration of picric acid on the adsorption process. The kinetic data were fitted with pseudo-first order, pseudo-second-order, Elovich and intra-particle diffusion models. The kinetic studies were well described by the pseudo-second-order kinetic model for both methods. In addition, the adsorption isotherms of picric acid from aqueous solutions on the MWCNTs were investigated using six two-parameter models (Langmuir, Freundlich, Tempkin, Halsey, Harkins-Jura, Fowler-Guggenheim), four three-parameter models (Redlich-Peterson, Khan, Radke-Prausnitz, and Toth), two four-parameter equations (Fritz-Schlunder and Baudu) and one five-parameter equation (Fritz-Schlunder). Three error analysis methods, correlation coefficient, chi-square test and average relative errors, were applied to determine the best fit isotherm. The error analysis showed that the models with more than two parameters better described the picric acid sorption data compared to the two-parameter models. In particular, the Baudu equation provided the best model for the picric acid sorption data for both methods.

• 한국지반환경공학회 논문집
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• 제19권12호
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• pp.15-23
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• 2018

우리나라에서 발생하는 대부분의 토양침식은 물에 의한 토양침식이며 강우와 밀접한 관계를 가진다. 강우로부터 발생하는 토양침식은 토지자원의 손실을 발생시키고 이후 하천에 유입되고 퇴적되어 하천수자원의 관리 및 이용에 많은 어려움을 주고 있다. 최근 기후변화의 영향으로 우리나라에서는 30mm/hr 이상의 집중호우의 발생횟수가 증가하고 있어 단기간에 토양침식이 발생할 가능성이 높아지고 있다. 본 연구에서는 강우의 물리적인 특성을 고려하기 위하여 누적분포함수를 이용하여 강우강도별 강우입자의 분포를 추정하고 단일 호우사상이 가지는 강우에너지를 계산하는 방법을 제안하고자 하였다. 강우에너지 산정공식을 개발하기 위하여 강우강도 0.254~152.4mm/hr에서 측정된 강우입자 자료를 이용하였다. 누적분포함수를 적용하여 산정된 강우에너지는 강우강도의 관계에서 멱함수형태로 증가하는 경향으로 나타났으며, 이 관계로 얻어진 식을 바탕으로 1~80mm/hr 강우강도의 강우 운동에너지를 산정한 결과 $0.03{\sim}48.26Jm^{-2}mm^{-1}$로 나타났다. 강우강도와 강우에너지의 관계를 바탕으로 강우에너지 식을 멱함수로 제시하였다. 본 연구에서 제안된 공식은 한시적으로 설치하는 침사지와 같은 시설물의 규모를 결정하는 계획의 토양침식량을 예측에 활용될 수 있을 것으로 판단된다.