• 제목/요약/키워드: kaolin mineral

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부순모래를 사용한 습식 숏크리트의 광물성 혼화재료 혼입에 따른 내구성 평가 (Durability Assessment for Crushed Sand Wet-mix Shotcrete Mixed with Mineral Admixtures)

  • 이겨레;한승연;남궁경;윤경구
    • 콘크리트학회논문집
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    • 제26권5호
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    • pp.607-614
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    • 2014
  • 본 논문에서는 품질확보를 위하여 혼합골재 입도분포를 적용한 부순모래 숏크리트에 플라이애시, 고로슬래그 미분말, 메타카올린, 실리카퓸을 종류 및 혼입률에 변동을 주어 혼입하여 숏크리트의 기초특성과 내구특성에 미치는 영향을 고찰하였다. 또한 각 혼화재료의 주요 혼입률을 선정하고 실제 숏팅을 실시 하여 숏팅 전 후의 기초특성과 내구특성을 분석하였다. 실내실험 결과 광물성 혼화재료 혼입률이 증가할수록 압축강도가 증가하는 경향을 보였다. 특히 메타카올린을 혼입한 경우 가장 우수한 강도 증진효과를 보였으며, 숏팅 후 압축강도 역시 코어링에 의한 강도감소 현상을 감안하여도 강도 발현이 우수한 혼화재료로 판단된다. 염소이온 침투저항성 시험과 황산저항성 시험 결과 광물성 혼화재료 혼입은 염소이온과 황산에 대한 저항성이 증진되는 경향을 보인다. 화상분석을 통한 공극구조 분석 결과 공기연행제를 사용하지 않아 소요의 간격계수와 비표면적을 얻는데 실패하였으며, 향후 공기연행제의 도입 후 실험이 진행될 필요성을 보이고 있다.

통가국 라우분지 TA 26 해저산의 열수변질작용 (Hydrothermal Alteration Around the TA 26 Seamounts of the Tofua Volcanic Arc in Lau Basin, Tonga)

  • 조현구;김영호;엄인권;최헌수
    • 한국광물학회지
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    • 제25권4호
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    • pp.233-247
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    • 2012
  • 통가국 라우분지(Lau Basin)의 해저열수광상 개발을 위한 해저열수광상 분포 및 산상에 관한 특성을 규명하기 위하여 X선 회절분석을 통하여 해저열수광상 해저퇴적물 및 열수변질대의 광물조성을 연구하였다. 연구에 사용된 시료는 TA 26 해저산 주변에서 채취된 코어 시료, 기반암 및 해저퇴적물 시료이고, 벌크 시료와 점토 부분을 분리한 정방위 시료를 제작하여 X선 회절분석을 실시하였다. TA 26 해저산에서 채취된 기반암은 대부분 사장석과 석영으로 이루어져 있는 데 반하여, 표층퇴적물은 대부분 카올린광물과 스멕타이트로 구성되어 있다. 열수구 퇴적물은 대부분 석고, 중정석, 섬아연석, 황철석 등 황산염광물과 황화광물로 구성된다. 기반암과 해저퇴적물의 광물조성으로 미루어 보아, TA 26 해저산의 열수광화대는 주변에 스멕타이트 또는 카올린광물을 형성시키는 정도의 이질변질작용을 일으켰음을 알 수 있다. MC08H-06 시추 코어 시료는 상부는 비변질대, 하부는 스멕타이트와 카올린광물로 구성된 이질변질대에 해당한다. 다양한 황화광물과 황산염 광물의 존재, 이질변질작용에 해당하는 열수변질대의 존재는 TA 26 해저산 내에 해저열수광상이 존재하고 있음을 지시하는 것으로 판단된다.

실리케이트 광물을 이용한 내열충격성 LAS계 세라믹스의 제조에 관한 연구: (II) Sillimanite, Kaolin 및 Pyrophyllite족 광물을 이용한 Spodumene 분말합성 (The Study on Fabrication of LAS System Ceramics for Thermal Shock Resistance from Silicate Minerals: (II) Preparation of Spodumene Powders with Sillimanite, Kaolin and Pyrophyllite Group Minerals)

  • 박한수;조경식;문종수
    • 한국세라믹학회지
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    • 제31권7호
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    • pp.784-794
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    • 1994
  • Though spodumene have a law theraml expension and good thermal shock resistance, its sintering temperature is too close to its melting point in the application for industral purpose. Solving the problems, impurities within the silicate minerals act as a frit during firing, so its densification is expected through enlargement of sintering temperature range. By the heat treatment of starting materials, mixtures of silicate mineral, lithium carbonate, if necessary SiO2 or Al2O3 were added for stoichiometric correction, in the range of 1000~125$0^{\circ}C$ for 10 hrs, $\beta$-spodumene single phase was synthesized. Mixtures with sillimanite group minerals, $\beta$-spodumene was formed at 120$0^{\circ}C$ or 125$0^{\circ}C$ via intermediate phases of petalite, Li2SiO3 and LiAlO2. For the case of kaolin group minerals, synthesis were completed at 110$0^{\circ}C$ for Hadon pink kaolin, 120$0^{\circ}C$ for New Zealand white kaolin, When pyrophyllite group minerals were used, those were at the range of 1000~125$0^{\circ}C$. Spodumene was completed at lowest temperature, 100$0^{\circ}C$ from the mixture of Wando pyrophyllite among them. Microstructure of synthesized powders showed the inrregular lump shape such as densed crystallines.

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수륜 고령토광산에서 산출되는 각섬석의 표성 변질작용: 광물학적 및 형태적 연구 (Supergene Alteration of Amphibole in Suryun Kaolin Deposits: Mineralogical and morphological Studies)

  • 김수진;아비드무타자칸;이동진
    • 한국광물학회지
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    • 제2권1호
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    • pp.37-46
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    • 1989
  • X-ray, optical and electron microscope studies exhibit that the amphiboles in anorthositic saprolite from kaolin deposits, located in Suryun-myeon, Seongju-gun, Kyungsangbuk-do, have altered under weathering conditions to smectite, mixed-layer mineral, vermiculite and goethite. In early supergene alteration stage when rock structure is still preserved, smectite occurs as initial weathering product of amphibole. Further weathering leads to the formation of mixed-layer mineral, vermiculite and goethite as indicated by XRD and SEM studies. Scanning electron microscopy studies of amphibole show that the dissolution of amphibole proceeds by selective etching at the surface along weaker zones producing distinct etch pattern, The calcic amphiboles according to electron microprobe analyses, show leaching of the most mobile elements (Mg, Ca and Fe) during alteration.

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한국공업화과정(韓國工業化過程)에서의 광물자원(鑛物資源)의 수급구조변화(需給構造變化)와 경제성장(經濟成長)에 있어서의 역할(役割) (The Changing Patterns of Demand-Supply and Role of Mineral Resources in Economic Growth during Industrialization of the Republic of Korea)

  • 윤석규
    • 자원환경지질
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    • 제18권1호
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    • pp.65-92
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    • 1985
  • A total of 12 mineral commodities significant in domestic output, economy and/or strategy of the Republic of Korea are chosen to examine the structural changes in production and demand-supply of these minerals during the last two decades of her industrialization. These include iron and manganese ores as the raw materials for iron and steel making, copper, zinc and tungsten ores among other non-ferrous metallic minerals, limestone (cement), kaolin, talc, pyrophyllite and graphite among other non-metallic minerals, and anthracite coal as the only domestic source of fossil energy. These are reviewed historically in time-series based on the statistical data which are tabulated and graphed in terms of domestic output, export, import, apparent demand-supply, its increasing rate, and self-sufficiency rate of each commodity. The increasing rates of demand-supply (IRDS) of some more important commodities are compared with those of Gross Domestic Production (GDP) and Economic Growth Rate (EGR) to evaluate how the IRDS contributed to the GDP and EGR. The major results revealed are as follows: Among the 12 commodities, the domestic output of 8 commodities appeared to have grown with steady upward trends: they are ores of lead, zinc and tungsten, limestone (cement), kaolin, talc, pyrophyllite and anthracite coal. Two commodities, ores of iron and copper, continued with unchanging or slightly declining trends and varied fluctuations, in spite of their cardinal importance to the heavy industry and strategy of Korea. The remaining two, graphite and manganese ore, have gradualy declined in domestic output in which the former has still enough resource potential but the latter has not and virtually ceased its domestic output. Trade patterns for mineral commodities in the Republic of Korea during the last two decades have changed greatly, being marked by a shift from mineral-exporting to mineral importing, mainly because of increasing consumption of mineral raw materials for industrialization rather than beceuse of decreasing output of domestic mineral commodities in quantity. In terms of trade patterns, the 12 commodities concerned in this study can be classified into the following four groups. The 1st group - ores of lead and tungsten have only been exported without imports. The 2nd group - amorphous graphite, and pyrophyllite have mainly been exported but partly been imported. The 3rd group - kaolin, talc and crystalline graphite have equally been exported and imported, but quantity of imports have rapidly been increased with time. The 4th group - ores of iron, manganese and zinc have shifted from exports to imports during the industrialization, particularly owing to the initiation of iron and steel making by the Pohang Iron and Steel Company in the middle 1970' s and the new establishment of the Onsan Zinc Refinery in the late 1970' s. All of the 12 commodities under considerations were far above 100% in self-sufficiency rate before or in the early 1960' s. Recently, however, most of them have been declined to below 100% except for those of limestone (cement) and pyrophyllite. It is particularly serious to identify that the self-sufficiency rates of the three important metallic minerals, iron, copper and manganese ores in 1982 appeared to be 5.1%, 0.5%, and 0.01%, respectively. The average self-sufficiency rate of the total domestic minerals produced in 1982 was 14.4% (in value) for that year. Mining industry appeared to be extremely high in its intermediate demand rate whereas its intermediate input rate to be quite low indicating that mineral raw materials have been exerted strong forward linkage effects upon the other industries rather than backward linkage effects. In comparing the curves of increasing rates of demand-supply of several major minerals - iron ore, manganese ore, copper ore, limestone (cement), kaolin, and anthracite coal - with those of Gross Domestic Production and Economic Growth Rate drawn on every graph, it is clearly shown that the curves of increasing rates of demand-supply comprise around 6 to 7 periods of cycles which roughly harmonious with those of the curves of GDP and EGR, except for the curve of anthracite coal of which the configuration seems to have resulted from the (artificial) government's mineral policy rather than from economic free market mechanism. The harmonic feature of these curves well suggests that the increasing rates of demand-supply of major minerals have been significantly contributed to the GDP and EGR. In addition, the wider amplitudes of the iron, manganese and copper curves than those of the limestone (cement) and kaolin curves indicate that the contribution of the former, metallic commodities, has been greater than that of the latter, non-metallic commodities.

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고령토 미립자의 수중 응집 특성 (Flocculation of Fine Particles of Kaolin in Water)

  • Shin, Hong-Jun;Shin, Kang-Ho;Cho, Dong-Sung
    • 자원리싸이클링
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    • 제5권3호
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    • pp.3-8
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    • 1996
  • 경남 단성의 대명광산 고령토의 전기영동에 의한 표면전위를 조사하였다. 고분자응집제, 수소이온 및 전해질의 농도변화에 따른 응집 정도를 알아보기 위하여 현탁상등액의 빛 투과율을 측정하였다. 수용액에서 고령토 미립자의 등전위점이 pH 3.2 부근으로 나타났으며, 등전위점 근처에서 최고의 응집효과가 나타났다. 고령토 미립자에 대한 Accofloc 고분자응집제의 응집효과는 음이온(A-110)<비이온(N-100)<양이온(C-482)순으로 높았으며, 4ppm 정도로도 충분한 효과를 나타냈다. 양이온 고분자응집제의 응집효과는 Superfloc(C-577)에 비하여 Accofloc(C-482)이 더 좋은 결과를 보였다. NaCl 만으로는 응집효과가 없었으나, 고분자응집제와 병용시에는 고분자응집제 만을 사용할 때보다 더 향상된 응집효과를 나타냈다.

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Removal of Arsenic(V) from Aqueous Solutions by Using Natural Minerals

  • Mohapatra Debasish;Mishra Debaraj;Chaudhury G. Roy;Das R.P.;Park, Kyung-Ho
    • 자원리싸이클링
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    • 제15권5호
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    • pp.38-46
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    • 2006
  • The removal of arsenic(V) using four different natural minerals were evaluated. Parameters like contact time, pH, adsorbent dosages, and As(V) concentration were optimized. The kinetics of adsorption was observed to be fast and reached equilibrium within 2h. As(V) adsorption on studied minerals was dependent on pH and followed a pseudo-second-order reaction model. For kaolin, maximum adsorption was found at pH 5.0. Whereas, in case of other three minerals, a pH range of 6.0-7.0 was found to be the best for As(V) adsorption. The maximum adsorption capacity (Q) was calculated by fitting Langmuir equation to the adsorption isotherms obtained under a specified condition. From the slope of best fit, the Q values were calculated to be 2.07, 2.15, 1.95 and 0.86 mg As(V)/g of bauxite, wad, iron ore and kaolin, respectively. Desorption of As(V) from loaded materials was dependent on the type of leaching reagents used. Based on the results, it was found that among the studied natural minerals, wad was the best As(V) adsorbent.

광물질 혼화재 종류에 따른 초고강도 콘크리트의 공학적 특성에 관한 실험적 연구 (An Experimental Study on the Engineering Properties of Ultra-High Strength Concrete according to Types of Mineral Admixtures)

  • 정현웅;강훈;이상수;송하영;김을용
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 봄학술 발표회 논문집(II)
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    • pp.29-32
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    • 2005
  • In this study, the experiment was carried out to investigate and analyze the strenth properties and flowability of ultra-high strength concrete accroding to types of mineral admixtures. The main experimental variables were water/binder ratio 25.0, 27.5 and 30.0$\%$, water content 155, 160, 165, and 170kg/$m^{3}$ and mineral admixtures such as fly ash, silica fume and meta kaolin. According to the test results, the principle conclusions are summarized as follows. 1) In case of using admixtures, superplasticizer amount need more than plain concrete. 2) According to kinds of admixtures, the viscosity of concrete show much difference. 3) The compressive strength of concrete that use admixtures becomes low in early-age strength, but appeared by higher than plain concrete in long-term strength. 4) Meta kaolin is excellent in side but has viscosity enlargement efficiency a little. But, problem estimates that is not to make design strength 600 and 700kgf/$cm^{2}$ if use mixing condition with water-binder ratio properly.

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Control of phosphoric acid induced volume change in clays using fly ash

  • Chavali, Rama Vara Prasad;Reddy, P. Hari Prasad
    • Geomechanics and Engineering
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    • 제15권6호
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    • pp.1135-1141
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    • 2018
  • Volume changes of soils induced by inorganic acids cause severe foundation and superstructure failures in industrial buildings. This study aimed to assess the potential of fly ash to control volume changes in soils under acidic environment. Two soils such as black cotton soil predominant with montmorillonite and kaolin clay predominant with kaolinite were used for the present investigation. Both soils exhibited an increase in swelling subjected to phosphoric acid contamination. Ion exchange reactions and mineralogical transformations lead to an increase in swelling and a decrease in compressibility in black cotton soil, whereas phosphate adsorption and mineral dissolution lead to an increase in swelling and compressibility in case of kaolin clay. Different percentages of Class F fly ash obtained from Ramagundam national thermal power station were used for soil treatment. Fly ash treatment leads to significant reduction in swelling and compressibility, which is attributed to the formation of aluminum phosphate cements in the presence of phosphoric acid.

카올린으로부터 Si-Al 탄화물의 합성 및 Si$_3$N$_4$ 결합 소결 특성 (Synthesis of Si-Al Carbonates from Kaolin and Sintering Characteristics by Reaction Bonding Si3N4)

  • 백용혁;김영구;한창;권양호
    • 한국세라믹학회지
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    • 제28권9호
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    • pp.667-674
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    • 1991
  • In this study, Kaolin was carbonized at 1300~175$0^{\circ}C$ and its constituent mineral change was investigated. Carbonized kaolin at 1$650^{\circ}C$ was mixed with metallic silicon, formed and nitrified at 135$0^{\circ}C$ in N2-NH3 atmosphere. Properties of this product such as porosity, bulk density, MOR, nitrization rate and oxidation resistence were measured, and its mineralogical changes were investigated by XRD. The results were as follows; 1) $\beta$-SiC was initially synthesized at 150$0^{\circ}C$, and its amount was continuously increased with reaction temperature to 1$700^{\circ}C$. 2) At 1$600^{\circ}C$, mullite was rapidly decomposed and the amounts of $\beta$-SiC and $\alpha$-Al2O3 were increased simultaneously. 3) By adding alkali to kaolin, the decomposition temperature of mullite was dropped approximately 10$0^{\circ}C$, but the amount of $\alpha$-SiC was increased. 4) The highest values of their nitrization rate and MOR were obtained at the specimen of 35 wt% metallic silicon in nitrization reaction. 5) It seems that increment of $\alpha$-Si3N4 and $\alpha$-Al2O3 phase during nitrization was due to the decomposition of Al4SiC4 existed in carbonized kaolin. 6) Si3N4 bonded SiC-Al2O3 composite were fabricated from kaolin at relatively low temperature (135$0^{\circ}C$).

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