• Title/Summary/Keyword: isopropyl alcohol

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A Study on Anisotropic Etching Characteristics of Silicon in TMAH/AP/IPA Solutions for Piezoresistive Pressure Sensor Applications (압저항 압력센서 응용을 위한 TMAH/AP/IPA 용액의 실리콘 이방성 식각특성에 대한 연구)

  • 윤의중;김좌연;이태범;이석태
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.41 no.3
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    • pp.9-14
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    • 2004
  • In this study, Si anisotropic etching characteristics of tetramethylammonium hydroxide (TMAH)/ ammonium persulfate(AP)/isopropyl alcohol(IPA) solutions were investigated to realize the optimum structure of a diaphragm for the piezoresistive pressure sensor application. Due to its low toxicity and its high compatibility with the CMOS processing, TMAH was used as Si anisotropic etchants. The variations of Si etch rate on the etching temperature, TMAH concentration, and etching time were obtained. With increasing the etching temperature and decreasing TMAH concentrations, the Si etch rate is increased while a significant non-unifonnity exists on the etched surface because of formation of hillocks on the (100) surface. The addition of IPA to TMAH solution leads to smoother etched surfaces but, makes the Si etch rate lower. However, with the addition of AP to TMAH solution, the Si etch rate is increased and an improvement in flatness on the etching front is observed. The Si etch rate is also maximized with increasing the number of addition of AP to TMAH solution per one hour. The Si square membranes of 20${\mu}{\textrm}{m}$ thickness and l00-400${\mu}{\textrm}{m}$ one-side length were fabricated successfully by applying optimum Si etching conditions of TMAH/AP solutions.

Studies on the Preparation and Utilization of Filefish Protein Concentrate (FPC) -II. The Effect of Processing Conditions on the Functional Properties- (말쥐치 농축단백질(濃縮蛋白質)의 제조(製造) 및 이용(利用)에 관(關)한 연구(硏究) -제 2 보 : 제조방법(製造方法)에 의한 기능성(機能性)의 변화(變化)-)

  • Yang, Han-Chul;Lim, Seung-Taik;Son, Heung-Soo
    • Korean Journal of Food Science and Technology
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    • v.15 no.3
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    • pp.252-261
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    • 1983
  • Isopropyl alcohol extracted filefish protein concentrate (FPC) and NaOH hydrolyzed filefish protein isolate (FPI) were used for the investigation on the effect of processing conditions on the molecular distribution and functional properties. The molecular distribution of FPC on polyacrylamide gel showed a resemblance to that of fish muscle, but that of alkaline hydrolyzed FPI showed the severe degradation of protein. The content of several amino acids in FPI were lower than those of FPC. The pepsin digestibility of the FPC dried at high temperature was relatively high. FPC didn't exhibit a significant difference in nitrogen solubility at the pH range of 3.0-9.0, while FPI showed a wide difference with the pH change. FPI was more suspensible and rehydrated in water than FPC. Although the aeration capacity of FPI was very low, foam viscosity was higher than that of FPC. In contrast with aeration capacity, FPI presented higher emulsion capacity and lower emulsion viscosity than FPC. The size of fat globule in the emulsion of FPC was larger than that of FPI. In general, most functional properties decreased with the increment in drying temperature, except water holding capacity.

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Extraction of Intracellular Lipids from Recombinant E. coli for Improving Long-chain Fatty Acid Production (긴 사슬 지방산 생산을 위해 재조합된 E. coli로부터의 세포 내 지질 추출)

  • Ham, Su Mi;Yoo, In Sang;Park, Sang Joon;Kim, Ji Hyeon
    • Korean Chemical Engineering Research
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    • v.51 no.4
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    • pp.482-486
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    • 2013
  • Recently, biohydrocarbons are gathering an interest as a new bioenergy due to the versatile applicability. In the present work, a process is proposed for the recovery of lipids from Recombinant E. coli MG1655 which provides longer chain fatty acids. After the growth of the recombinant E. coli, the cells were disrupted by high pressure homogenizer for obtaining intracellular lipids and the resulting solutions were centrifuged and extracted. For the efficient cell disruption with high pressure homogenizer, the pressure higher than 5,000 psi was required. In addition, under the conditions of applied pressure 5,000 to 20,000 psi, 1~3 pass homogenizing was enough for the more than 90% cell disruption. As organic solvents for extraction of lipid, hexane/isopropyl alcohol and ethyl acetate/ethanol systems showed excellent extracting power. With these solvent systems, the 60% lipid could be recovered. Moreover it was found that the extracted lipids contained long-chain fatty acids such as $C_{12}$, $C_{14}$, $C_{16}$ and $C_{18}$.

A Study on Applicability of Hydrofluoroethers as CFC-Alternative Cleaning Agents (CFC 대체 산업세정제로의 HFEs의 적용가능성 연구)

  • Min, Hye-Jin;Shin, Jin-Ho;Bae, Jae-Heum;Kim, Hong-Gon;Lee, Hyun-Joo
    • Clean Technology
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    • v.14 no.3
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    • pp.184-192
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    • 2008
  • Fluoride-type cleaning agents such as 2,2,2-trifluoroethanol (TFEA) and hydrofluoroethers (HFEs) do not destroy ozone in the stratosphere and have low global warming potential compared to hydrofluorocarbons(HFCs) and hydrochlorofluorocarbons (HCFCs). Especially, HFEs which have no flash point are paid attention as next generation type of cleaning agents for chlorofluorocarbons (CFCs) since they are safe in handling and have excellent penetration ability compared to hydrocarbon cleaning agents with low flash point. Here, the physical properties and cleaning abilities of fluoride-type cleaning agents such as TFEA, HFE-7100, HFE-7200, HFE-476mec, HFE-449mec-f, AE-3000 and AE-3100E and silicide-type cleaning agents such as trifluoroetoxytrimethylsilane (TFES) and hexamethyldisilazane (HMDS) were measured and compared with those of ozone destruction substances such as CFC-113 and 1,1,1-trichloroethane. They were also compared with toxic methylene chloride (MC) and isopropyl alcohol (IPA) which are now being used as an alternative cleaning agents. As a result, TFEA and HFEs had lower cleaning ability for removal of various soils compared to chloride-type cleaning agents, but they showed excellent cleaning ability fur fluoride-type soils. TFES and HMDS also showed excellent cleaning ability for silicide-type soils.

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Activated Carbon Adsorption Characteristics of Multi-component Volatile Organic compounds in a Fixed Bed Adsorption Bed (고정층 흡착탑에서 다성분 휘발성 유기화합물의 활성탄 흡착 특성)

  • Cho, Jong Hoon;Lee, Sihyun;Rhee, Young Woo
    • Korean Chemical Engineering Research
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    • v.54 no.2
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    • pp.239-247
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    • 2016
  • This study aims to examine absorption characteristics of toluene, isopropyl alcohol (IPA), ethyl acetate (EA), and ternary-compounds, all of which are widely used in industrial processes, by means of four types of commercial activated carbon substances. It turned out that among the three types of volatile organic compounds, the breakthrough point of activated carbon and that of IPA, whose affinity was the lowest, were the lowest, and then that of EA and that of toluene in the order. With the breakthrough point of IPA, which was the shortest, as the standard, changes in the breakthrough points of unary-compounds, binary-compounds, and ternary-compounds were examined. As a result, it turned out that the larger the number of elements, the lower the breakthrough point. This resulted from competitive adsorption, that is, substitution of substances with a low level of affinity with those with a high level of affinity. Hence, the adsorption of toluene-IPA-EA and ternary-compounds require a design of the activated carbon bed based on the breakthrough of IPA, and in the design of activated carbon beds in actual industries as well, a substance whose level of affinity is the lowest needs to be the standard.

Effect of Solvents Washing on Chemical and Physical Properties of Dried Soymilk Residue (용매처리에 의해 건조(乾燥)된 두유(豆乳)비지의 이화학적 성질(性質)에 관한 연구(硏究))

  • Kim, W.J.;Kim, D.H.;Oh, H.I.
    • Korean Journal of Food Science and Technology
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    • v.16 no.3
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    • pp.261-266
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    • 1984
  • Soymilk residue was washed separately with acetone, ethanol, isopropyl alcohol and n-hexane, and then dried at $45^{\circ}C$. The dried residues were evaluated for drying rate, color and chemical and functional properties. Washing with acetone resulted in the shortest drying time (1hr) and the highest in protein content (48.8%) and in Hunter 'L' value. The dried residues after treatment with acetone and alcohols showed relatively high values of 4.3-4.7g/g and 8.5-8.7g/g in oil and water absorption, respectively. Addition of the acetone treated residue to wheat flour at a level of 10% affected little in Amylograph viscosity while those treated with other solvents caused a significant decrease in the viscosity.

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Research on ANIOS Disinfection Efficiency to Prevent Infection in Radiography Room (방사선촬영실 감염 방지를 위한 에니오설프의 소독효율 연구)

  • Jung, Woo-Chan;Ahn, Ki-Song;Yang, Eun-Ju;Kim, Young-Jae
    • Journal of the Korean Society of Radiology
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    • v.15 no.1
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    • pp.55-61
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    • 2021
  • In this study, microbes were collected before and after disinfection using ANIOS(ANIOSURF Premium NPC) and compared the areas where the radiological technologist and the patient frequently contacted the chest X-ray. From September 1st to September 7th, 2020. in P Hospital in Deagu, 4 region were collected in a 10×10 size using a sterile cotton swab of the transport medium, and before and after disinfection results were obtained through the colorimetric method. As a result, n the X-ray tube handle Proteus mirabilis, Staphylococcus epidermidis, Bacillus spp., Candida spp., and in the Chin region Proteus mirabilis, Enterococcu faecium, Pseudomonas aeruginosa, NTM, and in the Chest region Proteus mirabilis, Enterococcu faecium, Pseudomonas aeruginosa, and in the Palm region NTM, Candida spp. were detected, and 103 CFU(Colony Forming Unit) or more were measured. After disinfection, only X-ray tube handle was detect Bacillus spp. and more than 102 CFU was measured. Microorganisms found prior to disinfection can cause opportunistic infections, Experimental results showed that Aniosulf(0.25%) is more economical and disinfectant than ethanol(70-90%) and isopropyl alcohol(70-90%). However, further research is needed on the detection of Bacillus spp. resultingly this research is useful basic data of infection control in Radiography room and prevention secondary infections.

A Study on the Applicability of $C_5$ Hydrofluoroether-based Formulated Cleaning Agents as CFC-Alternatives ($C_5$계 수소불화에테르를 기반으로 하는 배합 세정제의 CFC 대체세정제 적용 연구)

  • Min, Hye-Jin;Bae, Jae-Heum;Chang, Yoon-Sang
    • Clean Technology
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    • v.16 no.3
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    • pp.172-181
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    • 2010
  • Hydrofluoroethers (HFEs) with fluoride molecules in their structure which are evaluated as the third generation replacement alternatives to chlorofluorocarbons (CFCs) are known to be excellent for removal of nanoparticles and fluoride-type soils due to their low surface tension and high wetting index. In addition, HFEs have good physical properties with no flash point and excellent drying characteristics. But, HFEs also have shortcomings in that they are not effective for removal of organic soils due to their poor solubility in soil. In this study, $C_5$ HFE-based cleaning agents were formulated through addition of solvents such as isopropyl alcohol (IPA), ethyleneglycol monoether (EG), propyleneglycol monoethylether (PM) to HFE-7100 [$CF_3CF_2CF_2CF_2OCH_3$] or HFE-mec-f [$CF_3CHF=CF_2OCH_2CF_3$] with its maximum amount, respectively, in order to have no flash point for the safety in the working environment. These solvents are known to be excellent for dissolving organics in soil. Their physical properties and cleaning abilities for fluxes, water-insoluble cutting oils, and fluoride-type oils were evaluated and compared with those of other cleaning agents with single components. The experimental results show that the HFE-based formulated cleaning agents have various good physical properties which are almost similar to those of a single type of HFE cleaner. They show excellent cleaning ability for fluxes, water-insoluble cutting oils, and fluoride-type oils. These results indicate that the HFE-based formulated cleaning agents can be applicable to various industrial cleaning fields because of their good physical properties and cleaning abilities for various soils.

Enhanced Performance Characteristics of Polymer Photovoltaics by Adding an Additive-incorporated Active Layer

  • Lee, Hye-Hyeon;Hwang, Jong-Won;Jo, Yeong-Ran;Gang, Yong-Su;Park, Seong-Hui;Choe, Yeong-Seon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.316-316
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    • 2010
  • Thin films spin-coated from solvent solutions are characterized by solution parameters and spin-coating process. In this study, performance characteristics of polymer solar cells were investigated with changing solution parameters such as solvent and additives. The phase-separation between polymer and fullerene is needed to make the percolation pathway for better transportation of hole and electron in polymer solar cells. For this reason, cooperative effects of solvent mixtures adding additives with distinct solubility have been studied recently. In this study, chlorobezene, 1, 2-dichlorbenzene, and chloroform were used as solvent. 1, 8-diiodoctaned and 1, 8-octanedithiol were used as additives and were added into poly(3-hexylthiophene-2, 5-diyl)/[6, 6]-phenyl C61 butyric acid methyl ester (P3HT/PCBM) blends. Pre-patterned ITO glass was cleaned using ultrasonication in mixed solvent with ethyl alcohol, isopropyl alcohol and acetone. PEDOT:PSS was spin-coated on to the ITO substrate at 3000rpm and was baked at $120^{\circ}C$ for 10min on the hotplate. The prepared solution was spin-coated at 1000rpm and the spin-coated thin film was dried in the Petri dishes. Al electrode was deposited on the thin film by thermal evaporation. The devices were annealed at $120^{\circ}C$ for 30min. By adding 2.5 volume percent of additives into the chlorobenzene from that bulk heterojunction films consisting of P3HT/PCBM, the power efficiency (AM 1.5G conditions) was increased from 2.16% to 2.69% and 3.12% respectively. We have investigated the effect of additives in P3HT/PCBM blends and the film characteristics and the film characteristics including J-V characteristics, absorption, photoluminescence, X-ray diffraction, and atomic force microscopy to mainly depict the morphology control by doping additives.

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Solvent Effects on the Solvolysis of cis-$[Co(en)_2ClNO_2]^+$ Ion and Its Mechanism (cis-$[Co(en)_2ClNO_2]^+$ 착이온의 가용매 분해반응에 미치는 용매의 영향과 그 반응 메카니즘)

  • Jong-Jae Chung;Young-Ho Park
    • Journal of the Korean Chemical Society
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    • v.30 no.1
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    • pp.3-8
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    • 1986
  • The investigation of the effect of solvent structure on the first-order solvolysis of cis-$[Co(en)_2ClNO_2]^+$ion has been extended to water + co-solvent mixtures where the co-solvents are glycerol, ethylene glycol, isopropyl alcohol and t-butyl alcohol. Rates of solvolysis have been evaluated by spectrophotometric method at temperature 25∼30$^{\circ}$C. The polarity of solvent has influence on the variation of rate constant. The non-linear plot of the rate constant in log scale versus $\frac{D-1}{2D+1}$ implies that change in solvent structure with composition plays an important role in determining the variation of rate constant. The linearity of the plot of the rate constant in log scale versus the Grundwald-Winstein Y factor confirms that the solvolysis is an Id-type process with considerable extension of the metal chloride bond in the transition state. In the Kivinen equation the slope of the plot of log k versus $log(H_2O)$ suggests that the solvolysis is also an Id-type process. The application of free energy cycle shows that the effect of solvent structure is greater in the transition state than in the initial state.

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