• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2016년도 추계학술대회 논문집
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• pp.153-153
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• 2016

Aluminum alloys have poor corrosion resistance compared to the pure aluminum due to the additive elements. Thus, anodizing technology artificially generating thick oxide films are widely applied nowadays in order to improve corrosion resistance. Anodizing is one of the surface modification techniques, which is commercially applicable to a large surface at a low price. However, most studies up to now have focused on its commercialization with hardly any research on the assessment and improvement of the physical characteristics of the anodized films. Therefore, this study aims to select the optimum temperature of sulfuric electrolyte to perform excellent corrosion resistance in the harsh marine environment through electrochemical experiment in the sea water upon generating porous films by variating the temperatures of sulfuric electrolyte. To fabricate uniform porous film of 5083 aluminum alloy, we conducted electro-polishing under the 25 V at $5^{\circ}C$ condition for three minutes using mixed solution of ethanol (95 %) and perchloric (70 %) acid with volume ratio of 4:1. Afterward, the first step surface modification was performed using sulfuric acid as an electrolyte where the electrolyte concentration was maintained at 10 vol.% by using a jacketed beaker. For anode, 5083 aluminum alloy with thickness of 5 mm and size of $2cm{\times}2cm$ was used, while platinum electrode was used for cathode. The distance between the two was maintained at 3 cm. Afterward, the irregular oxide film that was created in the first step surface modification was removed. For the second step surface modification process (identical to the step 1), etching was performed using mixture of chromic acid (1.8 wt.%) and phosphoric acid (6 wt.%) at $60^{\circ}C$ temperature for 30 minutes. Anodic polarization test was performed at scan rate of 2 mV/s up to +3.0 V vs open circuit potential in natural seawater. Surface morphology was compared using 3D analysis microscope to observe the damage behavior. As a result, the case of surface modification presented a significantly lower corrosion current density than that without modification, indicating excellent corrosion resistance.

• 대한금속재료학회지
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• 제56권12호
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• pp.900-909
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• 2018

A $ZnO/TiO_2$ photocatalyst decorated with PbS quantum dots (QDs) was synthesized to achieve high photocatalytic efficiency for the decomposition of dye in aqueous media. A $TiO_2$ porous layer, as a precursor photocatalyst, was fabricated using micro-arc oxidation, and exhibited irregular porous cells with anatase and rutile crystalline structures. Then, a ZnO-deposited $TiO_2$ catalyst was fabricated using a zinc acetate solution, and PbS QDs were uniformly deposited on the surface of the $ZnO/TiO_2$ photocatalyst using the successive ionic layer adsorption and reaction (SILAR) technique. For the PbS $QDs/ZnO/TiO_2$ photocatalyst, ZnO and PbS nanoparticles are uniformly precipitated on the $TiO_2$ surface. However, the diameters of the PbS particles were very fine, and their shape and distribution were relatively more homogeneous compared to the ZnO particles on the $TiO_2$ surface. The PbS QDs on the $TiO_2$ surface can induce changes in band gap energy due to the quantum confinement effect. The effective band gap of the PbS QDs was calculated to be 1.43 eV. To evaluate their photocatalytic properties, Aniline blue decomposition tests were performed. The presence of ZnO and PbS nanoparticles on the $TiO_2$ catalysts enhanced photoactivity by improving the absorption of visible light. The PbS $QDs/ZnO/TiO_2$ heterojunction photocatalyst showed a higher Aniline blue decomposition rate and photocatalytic activity, due to the quantum size effect of the PbS nanoparticles, and the more efficient transport of charge carriers.

• 한국해안·해양공학회논문집
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• 제29권6호
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• pp.286-304
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• 2017

본 연구에서는 어항 등과 같은 소규모 항에서 적용 가능한 격자블록결속에 의한 신형식의 원형유공케이슨을 제안하고, 이러한 방파제의 수리특성을 수치적으로 검토하였다. 본 연구에서 적용한 수치해석 코드는 최근들어 다양한 분야에서 공학적 문제해결을 위해 그 사용예가 급증하고 있는 공중사용허가서(오픈소스 기반) 라이선스 기반의 OpenFOAM(Open Field Operation and Manipulation)에 조파모듈, 투과층 해석모듈, 및 반사파 제어기능 등을 추가한 OLAFOAM을 적용하였다. 본 연구는 먼저, 1) 규칙파 하 3차원슬리트케이슨 방파제에서 파의 파압변동에 대해 기존의 실험 결과와 비교 검토하고, 2) 불규칙파를 조파하여 목표한 파의 재현과 주파수스펙트럼을 비교 검토하여 OLAFOAM의 타당성을 검증하였다. 이로부터 슬리트케이슨과 유사한 원형유공케이슨이 설치된 일정수심의 3차원수치파동수조에 불규칙파를 조파하여 유수실 폭과 유의파고 및 유의주기의 변화에 따른 원형유공케이슨 방파제에서 월파량, 반사율, 파압분포 및 그들의 상호연관성을 면밀히 검토 분석하였다. 이로부터 파압분포는 불투과연직벽체에 대한 Goda 식의 결과보다 매우 작은 결과를 나타내었으며, 반사율은 기존의 슬리트케이슨에서 반사율의 변동범위 내에 존재하는 것을 알 수 있었다.

• 대한토목학회논문집
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• 제9권3호
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• pp.97-106
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• 1989

본(本) 연구(硏究)는 유한요소법(有限要素法)(FEM)을 이용(利用)하여 2차원(次元) 지하수(地下水) 흐름모형(模型)을 확립(確立)한 것으로 지하수계(地下水界)에서의 오염물질이동(汚染物質移動)에 관한 종합적(綜合的)인 동적(動的)시스템 모형(模型)을 개발(開發)하는 연구(硏究)의 첫 단계(段階)이다. 이 흐름모형(模型)은 보다 많은 실재문제(實在問題)를 다를 수 있는 융통성(融通性)과 유연성(柔軟性)을 가지도록 하고 있다. 시간(時間)의 함수(函數)로 나타나는 Sources/Sinks, Dirichlet 형(形)의 경계조건(境界條件), Neumann 형(形) 혹은 Cauchy 형(形)의 유동(流動) 경계조건(境界條件), 누수성피압상(漏水性被壓床) (leaky confining beds) 등(等)의 조건(條件)을 가진 지하수(地下水)흐름을 모의발생(模擬發生 수 있으며, 또 복잡(複雜)한 경계조건(境界條件)을 잘 나타내기 위하여 삼각형요소(三角形要素)와 사각형요소(四角形要素)를 혼합(混合)하여 쓸 수 있는 지하수(地下水)흐름 FEM 모형(模型)을 확립(確立)한 것이다.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2004년도 하계학술대회 논문집 C
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• pp.1573-1575
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• 2004

An alumina membrane with nano-sized pores was fabricated by anodic oxidation. The shape and structure of the pore on alumina membrane were changed according to the roughness of aluminum surface. The shape and structure of the nano-sized pre were investigated according to purity of aluminum substrate for the anodization process. The aluminum substrates with 99.5% and 99.999% purities were used. The aluminum substrate(99.5%) was anodized after the processes of pressing, mechanical polishing, chemical polishing, and electrochemical polishing. The nano-sized pores with the pore size of 50 - 100nm, the cell size of 20-50nm and the thickness of $10{\mu}m{\sim}45{\mu}m$ were obtained. Even though the electrochemical polishing was used for the aluminum substrate (99.999%), the same characteristics as the aluminum substrate (99.5%) was obtained. The alumina membrane prepared by anodization for 5 min using fixed voltage method shows the pore with irregular shape. The pore shape was changed to regular shape after pore widening process.

• 한국도로학회논문집
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• 제16권2호
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• pp.11-18
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• 2014

PURPOSES : This study aims to develop a strength test method for irregularly shaped concrete block paver. METHODS : Ten (10) different types of concrete block pavers including porous and dense blocks were tested for strength capacities. Destructive and non-destructive methods were used to develop a strength test method for irregularly shaped concrete block paver. The flexural strength evaluation was conducted in accordance to KS F 4419, while compressive strength was conducted with a 45.7mm-diameter core specimen. The impact echo test method was used to evaluate the elastic modulus. Finally, regression analysis was used to investigate the relationship between flexural strength, compressive strength and elastic modulus based on their corresponding test results. RESULTS : The flexural strength of the tested block pavers ranged from 4MPa to 10MPa. At 95% confidence level, the coefficients of determination between compressive-flexural strength relationship and compressive strength-elastic modulus relationship were 0.94 and 0.84, respectively. These coefficients signified high correlation. CONCLUSIONS : Using the test method proposed in this study, it will be easier to evaluate the strength of irregularly shaped concrete block pavers through impact echo test and compressive test, instead of the flexural test. Relative to the flexural strength requirement of 5MPa, the minimum values of compressive strength and elastic modulus, as proposed, are 13.0MPa and 25.0GPa, respectively.

• 한국재료학회지
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• 제21권2호
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• pp.106-110
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• 2011

A high thermal conductive AlN composite coating is attractive in thermal management applications. In this study, AlN-YAG composite coatings were manufactured by atmospheric plasma spraying from two different powders: spray-dried and plasma-treated. The mixture of both AlN and YAG was first mechanically alloyed and then spray-dried to obtain an agglomerated powder. The spray-dried powder was primarily spherical in shape and composed of an agglomerate of primary particles. The decomposition of AlN was pronounced at elevated temperatures due to the porous nature of the spray-dried powder, and was completely eliminated in nitrogen environment. A highly spherical, dense AlN-YAG composite powder was synthesized by plasma alloying and spheroidization (PAS) in an inert gas environment. The AlN-YAG coatings consisted of irregular-shaped, crystalline AlN particles embedded in amorphous YAG phase, indicating solid deposition of AlN and liquid deposition of YAG. The PAS-processed powder produced a lower-porosity and higher-hardness AlN-YAG coating due to a greater degree of melting in the plasma jet, compared to that of the spray-dried powder. The amorphization of the YAG matrix was evidence of melting degree of feedstock powder in flight because a fully molten YAG droplet formed an amorphous phase during splat quenching.

• 한국주조공학회지
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• 제10권5호
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• pp.435-443
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• 1990

By using the centrifugal atomization, which is one of the rapid solidification processes, Al-5,10wt%Pb alloys which are monotectic alloys were melted at 150K over two liquid phase line in the phase diagram. The melted alloy was poured on the rotating disk, being made into atomized powders, and then the solidified microstructure and morphology of the powder were investigated. This study converted the produced powders into strips by strained powder rolling. According to sintering temperature, the microstructure and hardness were investigated. The solidified structure of the powders were almost cellular dendritic structure. Pb particles ($2.0-3.0{\mu}m$) were fairl distributed in the Al matrix. Powder shapes were irregular. Rolling property and the compacting was good, respectively, because of increasing mechanical interlocking and surface area in the small size powders. With increasing temperature, the boundarys of powders were in porous form due to the diffusion. Pb particles which were surrounding the pores were inverse-segregated at the surface of the powders. With increasing of sintering temperature, the hardness of the powders and the strips decreased. In particular rolling-strip, the hardness abruptly decreased due to the release of work-hardening.

• 한국결정성장학회지
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• 제33권2호
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• pp.78-82
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• 2023

The oxygen evolution reaction (OER) is the primary challenge in renewable energy storage technologies, specifically electrochemical water splitting for hydrogen generation. We report effects of Mo doping into Ni layered double hydroxide (Ni-LDH) microcrystal on electrocatalytic activities. In this study, Mo doped Ni-LDH were grown on three-dimensional porous nicekl foam (NF) by a facile solvothermal method. Homogeneous LDH structure on the NF was clearly observed. However, the surface microstructure of the nickel foam began to be irregular and collapsed when Mo precursor is doped. Electrocatalytic OER properties were analyzed by Linear sweep voltammetry (LSV) and Electrochemical impedance spectroscopy (EIS). The amount of Mo doping used in the electrocatalytic reaction was found to play a crucial role in improving catalytic activity. The optimum Mo amount introduced into the Ni LDH was discussed with respect to their OER performance.

• 한국결정성장학회지
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• 제18권6호
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• pp.258-263
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• 2008

입자를 부유 상태에서 소성할 수 있는 수직로를 이용하여 2 mm 이하 크기의 경량 세골재를 제조하고 그 물리적 특성을 고찰하였다. $1200{\sim}1300^{\circ}C$에서 소성된 대부분 시편은 표면에 다량의 액상이 발달하였고 따라서 내부의 가스가 팽창하여 다공성의 중앙부와 상대적으로 치밀한 표피층이 형성되었다. 특히 압출 성형체를 파쇄시켜 얻은 부정형의 C 계열 시편은 $1300^{\circ}C$ 이상으로 소결하면 내부에 가스가 팽창하여 시편 전체가 부풀어져서 구형으로 되었다. 본 부유 수직로에서 소성된 시편의 겉보기 비중은 $0.68{\sim}1.08$ 범위로 대부분 물에 뜰 정도의 경량이었다. 제조된 경량 세골재의 흡수율은 기공율과 비례하였고, 따라서 내부 기공들이 완전 고립된 폐쇄기공은 아님을 나타내었다. 부유소성로에서 제조된 세골재는 전기 머플로에서 소성된 시편과 비슷한 물성을 나타내었으나, 전기로에서 나타나는 골재 간 융착 현상이 발생하지 않았다. 수직로에서 부유소성된 세골재의 내충격성은 자연골재보다 다소 낮았으나, 단위용적중량은 KS 규격 기준을 만족하였다.