• Title/Summary/Keyword: ionic concentration

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A Study on the Adsorption of Anionic Surfactant by Various Textile Fibers and Rinsing Efficiency in Washing Process (세척시 섬유의 음이온계 계면활성제 흡착과 헹구기 효과에 관한 연구)

  • Park, Son Kyeong;Kim, Sung Reon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.17 no.1
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    • pp.129-136
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    • 1993
  • Authors have studied the adsorption of anionic surfactant from detergent solutions on cotton fabric during washing process and have measured the concentration of the residual surfactant in rinsing solution. The relations with temperature and pre-soaking time to rinsing process have been studied. The adsorption of sodium dodecylbenzene sulfonate by various textile fibers has also been investigated. The results of this study are; 1. Three times rinsing is sufficient as, without pre-soaking, the concentration of the surfactant on fabric is stable from that time on. 2. The rinsing efficiency increases with temperature; at $25^{\circ}C$, $40^{\circ}C$, and $55^{\circ}C$, the concentrations of surfactant on the fabric after-rinsing are 68, 59, 51 mg/100 g of fiber respectively. 3. The longer the pre-soaking time, the lower the rinsing efficiency is; the 4hrs presoaked fabric shows increased surfactant concentration than the one without-soaking. And the increment is 35.8%. 4. The adsorption of sodium dodecylbenzene sulfonate on fabrics differs greatly with the chemical nature of the fiber; wool, silk and nylon which are thought to be ionic-adsorbants shows greater adsorption. 5. The adsorption of surfactant is more affected by the ionic character than the physical one, and the one with higher crystallinity such as cotton and polyester shows lower value than rayon or acetate.

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Temperature and Salinity Tolerance and Haemolymph Osmotic and ionic Concentration of the Snow Crab, Chionoecetes opilio (대게, Chionoecetes opilio의 수온 및 염분변화에 따른 생존내성과 Haemolymph의 삼투질과 이온 농도변화)

  • 임영수;이종관;이복규;장영진;허준옥;문승현;허성범
    • Journal of Aquaculture
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    • v.14 no.3
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    • pp.165-171
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    • 2001
  • Tolerance limits of the adult crab were determined by exposing them to different temperatures (5~2$0^{\circ}C$) and salinities(12~32$\textperthousand$). The tolerance limit for high temperature was determined at 14$^{\circ}C$ and 16$^{\circ}C$ for male and female snow crab, respectively and that for salinity was 21 $\textperthousand$ at 5 $^{\circ}C$. Osmolality concentration, Na$^{+}$ and $K^{+}$ ions in the haemolymph of especially, the females was positively related to the salinity changes. Increased water temperature resulted in a marked decreased in ionic and osmolality concentrations near the limit of tolerance in male, however, such a clear pattern was not apparent for the females. The concentration of glucose in the haemolymph was positively related to water temperature but negatively to salinity.ity.

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Studies on the Myofibrilar Protein from Korean Duck Muscle (오리고기의 근원섬유 단백질에 관한 연구)

  • Chang, In-Yae;Nam, Hyun-Keun
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.9 no.1
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    • pp.45-50
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    • 1980
  • Myofibrilar Protein from Korean Duck Muscle was extracted and ATPase activities were studied. The results were as follows: 1. Mg-activated ATPase activity of Myofibril from Korean Duck, muscle exhibited a biphasic response, ATPase activity was high at a low ionic strength and low activity was showed at high ionic strength. 2. Effect of EDTA on the Myofibrillar protein ATPase activity was studied, it was investigated that the EDTA inhibition was showed at the concentration of $6.9{\mu}g$ and it above. 3. It showed that the effect of Ca++ on ATPase activity was decreased at the lower than $3{\mu}g$. Inhibition showed at the concentration of $6.9{\mu}g$ and it above. 4. It showed that the effect of Mg++ on ATPase activity was decreased at the lower than $3.6{\mu}g$. Inhibition showed at the concentration of $3.9{\mu}g$ and it above.

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Solvent Extraction Equilibria of Gd with PC88A from Chloride Solution (염산용액에서 PC88A에 의한 Gd 용매추출의 평형)

  • Lee Gwang-Seop;Lee Jin-Young;Kim Sung-Don;Kim Joon-Soo;Park Jang-Hyun;Lee Man-Seung
    • Resources Recycling
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    • v.13 no.2
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    • pp.24-32
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    • 2004
  • Solvent extraction equilibria of Gd with PC88A from chloride solutions were analyzed by considering chemical equilibria. phase equilibria, mass and charge balance equations. The following solvent extraction reaction and equilibrium constant were evaluated from the experimental data performed in this study. $Gd^{3+}$ $+2H_2$$A_2$,$or=GdA_3$HA.or+3 $H^{+}$ , K=3.3 A procedure was suggested to calculate the initial concentration of chloride ion from initial pH and initial concentration of Gd. By applying ionic equilibria, the distribution of Gd complexes with Gd and HCl concentration was obtained. The predicted distribution coefficients of Gd agreed well with the experimental results.

Aggregation Behavior of Silver and TiO2 Nanoparticles in Aqueous Environment (수환경 특성에 따른 은과 이산화티탄 나노입자의 응집 특성 연구)

  • Lim, Myunghee;Bae, Sujin;Lee, Yong-Ju;Lee, Sung-Kyu;Hwang, Yu Sik
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.5
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    • pp.571-579
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    • 2013
  • The aggregation behaviors of silver nanoparticles (AgNPs) and titanium dioxide ($TiO_2$) nanoparticles were investigated. Time-resolved dynamic light scattering (DLS) was used to study the initial aggregation of AgNPs and $TiO_2$ over a range of mono (NaCl) and divalent ($CaCl_2$) electrolyte concentrations. The effects of pH, initial concentration of NPs and natural organic matters (NOM) on the aggregation of NPs were also investigated. The aggregation of both nanoparticles showed classical Derjaguin-Landau-Verwey-Overbeek (DLVO) type behavior. Divalent electrolyte was more efficient in destabilize the AgNPs and $TiO_2$ than monovalent electrolyte. The effect of pH on the aggregation of AgNPs was not significant. But the aggregation rate of $TiO_2$ was much higher with increasing pH. Higher NPs concentration leads to faster aggregation. Natural organic matter (NOM) was found to substantially hinder the aggregation of both AgNPs and $TiO_2$. This study found that the aggregation behavior of AgNPs and $TiO_2$ are closely associated with environmental factors such as ionic strength, pH, initial concentration of NPs and NOM.

Analysis of Groundwater quality and Contamination factors in Livestock Region, South Korea (국내 농축산단지 내 지하수 수질특성 및 오염인자 상관관계 분석)

  • Yoon, JongHyun;Park, Sunhwa;Choi, HyoJung;Kim, Deok Hyun;Kim, Moonsu;Yun, Seong-Taek;Kim, Young;Kim, Hyun-Koo
    • Journal of Soil and Groundwater Environment
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    • v.25 no.4
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    • pp.98-105
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    • 2020
  • In this study, the concentrations of some of the important ionic contaminants in groundwaters of national monitoring network in Korea were identified, and their correlation to nitrate concentration was investigated. Approximately 80% of the groundwater samples were found to be as Ca2+-(Cl-+NO3-) type groundwater with the concentration ranges [minimum to maximum values, median (mg/L)] of Ca2+[0.1~228.2, 19.7], Mg2+[0.1~53.2, 5.1], K+[0.1~50.8, 1.9], Na+[1.5~130.5, 18.1], NO3--N[0.1~73.4, 9.3], NH4+-N[0.0~53.9, 0.3], Cl-[3.1~482.6, 24.0], and SO42-[2.8~101.6, 7.0]. The prevalence of Ca2+-(Cl-+NO3-) type suggest that the composition of groundwaters were greatly influcenced by chemical fertilizers and animal manure, Correlation analyses indicated threre was positive correlation between NO3--N concentration and ionic species including Cl-, Ca2+, Mg2+, and Na+. In particular, the correlation was strongest for Cl- and NO3--N, suggesting that groundwaters largely impacted by agricultural and livestock breeding activities tend to contain high levels of Cl-.

An Experimental Study on the Sorption of Uranium(VI) onto a Bentonite Colloid (벤토나이트 콜로이드로의 우라늄(VI) 수착에 대한 실험적 연구)

  • Baik Min-Hoon;Cho Won-Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.4 no.3
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    • pp.235-243
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    • 2006
  • In this study, an experimental study on the sorption properties of uranium(VI) onto a bentonite colloid generated from Gyeongju bentonite which is a potential buffer material in a high-level radioactive waste repository was performed as a function of the pH and the ionic strength. The bentonite colloid prepared by separating a colloidal fraction was mainly composed of montmorillonite. The concentration and the size fraction of the prepared bentonite colloid measured using a gravitational filtration method was about 5100 ppm and 200-450 nm in diameter, respectively. The amount of uranium removed by the sorption reaction bottle walls, by precipitation, and by ultrafiltration was analyzed by carrying out some blank tests. The removed amount of uranium was found not to be significant except the case of ultrafiltration at 0.001 M $NaClO_4$. The ultrafiltration was significant in the lower ionic strength of 0.001 M $NaClO_4$ due to the cationic sorption onto the ultrafilter by a surface charge reversion. The distribution coefficient $K_d$ (or pseudo-colloid formation constant) of uranium(VI) for the bentonite colloid was about $10^4{\sim}10^7mL/g$ depending upon pH and ionic strength of $NaClO_4$ and the $K_d$ was highest in the neutral pH around 6.5. It is noted that the sorption of uranium(VI) onto the bentonite colloid is closely related with aqueous species of uranium depending upon geochemical parameters such as pH, ionic strength, and carbonate concentration. As a consequence, the bentonite colloids generated from a bentonite buffer can mobilize the uranium(VI) as a colloidal form through geological media due to their high sorption capacity.

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Effect of Lithium Ion Concentration on Electrochemical Properties of BF3LiMA-based Self-doping Gel Polymer Electrolytes (BF3LiMA기반 자기-도핑형 겔 고분자 전해질의 전기화학적 특성에 미치는 리튬이온 농도의 영향)

  • Kang, Wan-Chul;Ryu, Sang-Woog
    • Journal of the Korean Electrochemical Society
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    • v.13 no.3
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    • pp.211-216
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    • 2010
  • Boron trifluoride lithium methacrylate ($BF_3$LiMA)-based gel polymer electrolytes (GPEs) were synthesized with various $BF_3$LiMA concentration to elucidate the effect on ionic conductivity and electrochemical stability by a AC impedance and linear sweep voltammetry (LSV). As a result, the highest ionic conductivity reached $5.3{\times}10^{-4}Scm^{-1}$ at $25^{\circ}C$ was obtained for 4 wt% of $BF_3$LiMA. Furthermore, high electrochemical stability up to 4.3 V of the $BF_3$LiMA-based GPE was observed in LSV measurement since the counter anion was immobilized in this self-doped system. On the other hand, it was assumed that there was a rapid decomposition of electrolytes on a lithium metal electrode which results in a high solid electrolyte interface (SEI) resistance. However, a high stability toward graphite or lithium cobalt oxide (LCO) electrode thereby a low SEI resistance was observed from the AC impedance measurement as a function of storage time at $25^{\circ}C$. Consequently, the high ionic conductivity, good electrochemical stability and the good interfacial compatibility with graphite and LCO were achieved in $BF_3$LiMA-based GPE.

Enhancement of Membrane Performance through Surface Hydrophilization of Hydrophobic Porous Flat-sheet Membranes (소수성 다공성 평막의 표면 친수화를 통한 막성능 향상)

  • Kim, Baek-Ahm;Lee, Hak-Min;Lee, Bo-Seong;Kim, Sung-Pyo;Cheong, Seong-Ihl;Rhim, Ji-Won
    • Polymer(Korea)
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    • v.35 no.5
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    • pp.438-443
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    • 2011
  • In order to enhance water permeability through the improvement of fouling phenomena and wettability of hydrophobic porous membranes, various adsorption materials, i.e., poly(vinyl amine), poly (styrene sulfonic acid), poly(vinyl sulfonic acid), and poly(acrylamide-co-acrylic acid) were adsorbed onto the surface of polyethylene (PE) porous membrane. The concentration of adsorption solutions, adsorption time, the sort of salts and their ionic strength were varied, and the pure water permeability of their resulting adsorbed membranes was measured. In general, water permeability increased with an initial increase in the concentration of adsorption solution, adsorption time, and ionic strength and then decreased with a further increase. The pure water permeability of 375 $L/m^2h$(LMH), 35% enhancement, was obtained at a condition of poly(vinyl sulfonic acid) 1000 ppm, $Mg(NO_3)_2$ ionic strength(IS) 0.1, and adsorption time 150 sec, while the 50% (411 LMH) and 35% (374 LMH) enhancements were obtained at conditions of poly(styrene sulfonic acid) 1000 ppm, adsorption time 60 sec, and NaCl IS 0.1 and 0.2, respectively.

Seasonal variation of concentration and size distribution of Ionic species on aerosol in urban air (도시대기 입자상물질중 수용성 성분의 농도와 입경분로의 계절적 변동)

  • 이승일;황경철;조기철;신영조;김희강
    • Journal of Environmental Health Sciences
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    • v.22 no.3
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    • pp.64-71
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    • 1996
  • Measurement of concentration and size distribution of TSP, ammonium, nitrate and sulfate were made from Mar., 1991. to June., 1992 in Seoul. The seasonal variation of concentration and size distribution of aerosols has been investiated. Aerosol were collected and size frationated by Andersen air sampler. Size classified samples were extrated with deionized water and analyzed for ammonium, nitrate and sulfate by ion chromatography. As the results of measurement, the average of concentration and MMAD(mass median aerodynamic diameter) were $118.58 \mu g/m^3$, and $2.77 \mu m$ for TSP, $1.92 \mu g/m^3$ and $1.35 \mu m$ for ammonium, $1.34 \mu g/m^3$ and $1.58 \mu m$ for nitrate, $8.52 \mu g/m^3$ and $2.15 \mu m$ for sulfate. The Seasonal variation of concentration and size distribution was observed for ammonium, nitrate and sulfate. The concentration peak of TSP was observed in coarse particles in spring and observed in fine particles in winter. The concentration's distribution of TSP, ammonium, nitrate and sulfate was observed bimodal type during all season.

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