• Title/Summary/Keyword: ion-exchange

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Study of Development of Selective Removal Adsorption Ion Exchange Resin Materials for Fabricated with Chemical-biological Cloth by QFD (QFD 기법을 이용한 특정 유해가스 노출제어 이온선택성 보호복 소재개발연구)

  • Song, Hwa Seon;Koo, Il Seob;Kim, In Sik
    • Journal of Korean Society for Quality Management
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    • v.43 no.3
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    • pp.359-372
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    • 2015
  • Purpose: Through studying the expert's and non-experts panel responses to the questions regarding the attributes of chemical-biological protection cloth quality in terms of the levels of customer demand and technical factors has been studied. We are applied to a QFD matrix with find out the relationship between the selective removal efficiency of chemical-biological cloth and the guidelines of technical approach. Methods: We fabricated several composite of ion-exchange resins with selectively permeable performance designed to facilities water vapor transport and selective adsorption of the harmful gases. With these materials, we characterized on the selectively permeable performance to identify ion-exchange resin with chemical-biological protective cloth. Results: Results showed that ion exchange materials possessed performance with selectively efficiencies as NH3, SOx, NOx and HCl gas. The selective adsorption amount of ammonia and hydrogen gases were $90-80{\mu}g/g$ with TRILITE SCR-BH sulfonated ion exchange resin. The PP non-woven/ion exchange resin adsorbent materials possessed performance with water vapor permeability were 1,100-1,350 g/m2/day, it's was two times high value compare with activated carbon. With these materials, we characterized selectively removal efficiency to identify new ion-exchange material with chemical-biological protective capability. Conclusion: This study shows that a QFD aids in deciding with of the adsorption parameters to optimized with chemical-biological protection cloth manufacturing.

Synthesis and Characterization of Ion Exchange Particles for Application of Anion Exchange Membrane (음이온교환막 적용을 위한 이온교환입자의 합성 및 특성평가)

  • Dong Jun Lee;Kwang Seop Im;Ka Yeon Ryu;Sang Yong Nam
    • Membrane Journal
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    • v.33 no.3
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    • pp.137-147
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    • 2023
  • In this study, Br-PPO was developed by applying additive organic particles through a suspension polymerization synthesis method. The anion exchange membrane fuel cell system performance was evaluated using it to an anion exchange membrane. To improve the performance, organic ion exchange particles were prepared and added to the anion exchange membrane. Chemical structure analysis and synthesis were determined through FT-IR and NMR, and tensile strength and thermal stability were measured through TGA and UTM to determine whether it could be driven. Before the anion exchange membrane fuel cell test, the performance was evaluated by measuring the ion conductivity and ion exchange capacity. Finally, the Br-PPO-TMA-SDV (0.7%) anion exchange membrane with excellent ion conductivity and ion exchange capacity was introduced into the fuel cell system. Its performance was compared with FAA-3-50, a commercial membrane, to determine whether it could be introduced into a fuel cell system.

The Fabrication of Ion Exchange Membrane and Its Application to Energy Systems (고분자 이온교환막의 제조와 이온교환막을 이용한 에너지 공정)

  • Kim, Jae-Hun;Ryu, Seungbo;Moon, Seung-Hyeon
    • Membrane Journal
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    • v.30 no.2
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    • pp.79-96
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    • 2020
  • Secondary energy conversion systems have been briskly developed owing to environmental issue and problems of fossil fuel. They are basically operated based on electro-chemical systems. In addition, ion exchange membranes are one of the significant factors to determine performance in their systems. Therefore, the ion exchange membranes in suitable conditions must be developed to improve the performance for the electro-chemical systems. These ion exchange membranes can be classified into various types such as cation exchange membrane, anion exchange membrane and bipolar membrane. Their membranes have distinct characteristics according to the chemical, physical and morphological structure. In this review, the types of ion exchange membranes and their fabrication processes are described with main characteristics. Moreover, applications of ion exchange membranes in newly developed energy conversion systems such as reverse electrodialysis, redox flow battery and water electrolysis process are described including their roles and requirements.

Investigation on the Removal of Dissolved Aluminum Ion in Drinking Water (정수중(淨水中)의 용존(溶存)알루미늄 제어방안(制御方案)의 조사(調査))

  • Choi, Suing-Il;Kim, Moon-Jeong
    • Journal of Korean Society of Water and Wastewater
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    • v.11 no.1
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    • pp.42-52
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    • 1997
  • The affection of activated carbon on the dissolved aluminum ion in drinking water has been observed. In addition, the aluminum ion removal capability of activated, alumina, chitosan, and ion exchange resin have been investigated. Experimental results indicated that the coal based activated carbon released considerable amount of aluminum ion to the water while coconut shell based activated carbon didn't. However the release was not continuous. Activated alumina didn't show any recognizable removal capability for aluminum ion in water. Particulate chitosan has removed aluminum ion although dissolved chitosan has not. However it need to development a regeneration process for chitosan to be an effective mean for aluminum ion removal. Ion exchange resin showed a reliable aluminum ion removal capability. The ion exchange capacity was 2.63 meq/g resin for the aluminum ion in drinking water.

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The Limiting Current Density and the Regeneration of a Heterogeneous Ion Exchange Membrane in a Nickel Plating Rinse Waters Treatment Process by Electrodialysis (전기투석에 의한 니켈도금 폐수처리 공정에서 한계전류밀도와 불균질 이온교환막의 재생)

  • 윤용수
    • Journal of environmental and Sanitary engineering
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    • v.16 no.2
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    • pp.38-46
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    • 2001
  • In this work, the heterogeneous ion exchange membrane was used in a electrodialysis apparatus to treat a Ni planting rinse water because the heterogeneous ion exchange membrane was excellent efficiency as compared with low manufacturing cost, was easy to make, and had a good mechanical properties. For a regeneration of membrane and to obtain the optimal condition for a scale-up of apparatus after treating Ni plating rinse water, we would find about the limiting current density and the concentration polarization. When the Ni plating rinse water 150mg/L was treated with the electrodialysis apparatus using the heterogeneous ion exchange membrane, the limiting current density was about $1.49{\;}mA/\textrm{cm}^2$. And the limiting current density increased with the flow rate and concentration of Ni plating rinse water. We recognized that the used membrane could be reused by periodic backwashing because efficiency was constant when the membrane was backwashed after treating wastewater.

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The guided field distribution characteristics in the ion-exchange channel glass waveguide (이온 교환 채널 유리 도파로의 도파광 분포특성)

  • 박정일;박태성;천석표;정홍배
    • Electrical & Electronic Materials
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    • v.8 no.3
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    • pp.332-339
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    • 1995
  • In this paper, it was investigated the guided field intensity distribution of the channel in the silver & potassium ion-exchange glass-waveguide. The guided field intensity distribution analysis of ion-exchange glass-waveguide was based on the combination of the WKB dispersion relationship method with a Gaussian distribution function of refractive index profile and the Field Shadow method to the modeling of the channel waveguide. As the results of the channel waveguide modeling, it was represented 2-dimensional and 3-dimensional field distribution of ion-exchange glass waveguide.

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Ion Exchange Property of the Synthesized Ion Exchange Resins

  • Lee, Dong-Hwan;Lee, Yong-Hee;Lee, Kook-Eui;Lee, Min-Gyu;Suh, Jung-Ho
    • Proceedings of the Korean Environmental Health Society Conference
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    • 2004.06a
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    • pp.155-159
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    • 2004
  • We synthesized ion exchange resin that can remove $NO_3\;^-$ selectively rather than $SO_4\;^{2-}$. Ion exchange property of the synthesized ion exchange resin occurred like the following process, $NO_3\;^-$ > $SO_4\;^{2-}$, the efficiency of functional group to remove $NO_3\;^-$ occurred in the process of $NPr_3$ > $NBu_3$ > $NEt_3$ > $NMe_3$ > $NPe_3$ > $N(EtOH)_3$, and the efficiency of functional group to remove $SO_4\;^{2-}$ occurred in the process of $NMe_3$ > $NEt_3$ > $NPr_3$ > $NBu_3$ > $NPe_3$.

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Improvement of Mechanical Property by Single Ion Exchange Process in Substrate Glass

  • Lee, Hoi-Kwan;Kang, Won-Ho;Green, David J.
    • Journal of Information Display
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    • v.4 no.3
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    • pp.12-16
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    • 2003
  • In connection with the ion exchange strengthening on soda-lime-silicate, substrate glass for display use was investigated. In the processing, the temperature was varied during the ion exchange in order to make stress profile and to determine optimum condition. In the present work, we found that the maximum value of strength was 617.8 MPa after an ion exchange process at 470 $^{\circ}C$ for 1h, and then, at 450 $^{\circ}C$ for 24h. Also, the effect of residual stress placed on the near surface was measured by analyzing the number of crack branches and brittleness. This approach allowed us the residual stress profile to be engineered to improve mechanical reliability.

Decontamination of spent ion exchange resins contaminated with iron-oxide deposits using mineral acid solutions

  • Tokar, E.A.;Matskevich, A.I.;Palamarchuk, M.S.;Parotkina, Yu.A.;Egorin, A.M.
    • Nuclear Engineering and Technology
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    • v.53 no.9
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    • pp.2918-2925
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    • 2021
  • The efficiency of decontamination of model spent ion exchange resins, contaminated with magnetite and hematite, with mineral acid solutions, and using electro-decontamination, was evaluated. It has been shown that effective hematite dissolution occurs in concentrated mineral acid solutions. However, the use of direct current increases the decontamination efficiency of spent ion exchange resins contaminated with hematite. It is determined that with increasing voltage and acid concentration, the dissolution efficiency of hematite deposits increases and can exceed 99%. It has been shown that hematite dissolution is accompanied by secondary adsorption of radionuclides due to ion exchange, which can be removed with sodium nitrate solutions.

The Calcium and Magnesium Ion-Exchange Properties of Snythetic δ-Na2Si2O5 from Water Glass (Water Glass로부터 합성한 δ-Na2Si2O5의 Ca2+, Mg2+ 이온교환성)

  • Jeong, Soon-Yong;Suh, Jeong-Kwon;Park, Jeong-Hwan;Doh, Myung-Ki;Koh, Jae-Cheon;Lee, Jung-Min
    • Applied Chemistry for Engineering
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    • v.5 no.3
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    • pp.406-412
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    • 1994
  • The ion-exchange properties of $Ca^{2+}$ and $Mg^{2+}$ ions have been studied in ${\delta}-Na_2Si_2O_5$ synthesized from water glass. Results show that optimum temperature for synthesis of ${\delta}-Na_2Si_2O_5$ was $725^{\circ}C$. Ion-exchange isotherms for $Ca^{2+}$ and $Mg^{2+}$ exchange for $Na^+$ in the synthetic ${\delta}-Na_2Si_2O_5$ show that the ion-exchange capacity of magnesium is better than that of calcium, and the ion-exchange of magnesium is less sensitive for temperature than that of calcium. When initial pH of solution is increased between 2 and 6, the ion-exchange capacities of magnesium and calcium decrease a little. However, they are almost constant above pH 6 because of alkali buffer effect of ${\delta}-Na_2Si_2O_5$. In the thermodynamic studies, it was found that Gibbs free energies of reaction of calcium ion-exchange are larger than those of magnesium ion-exchange with inverse order of selectivity. The standard enthalpy and entropy of reaction of calcium ion-exchange are larger than those of magnesium ion-exchange.

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