• Title/Summary/Keyword: interlayer characteristics

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c-axis Tunneling in Intercalated Bi$_2Sr_2CaCu_2O_{8+x}$ Single Crystals

  • Lee, Min-Hyea;Chang, Hyun-Sik;Doh, Yong-Joo;Lee, Hu-Jong;Lee, Woo;Choy, Jin-Ho
    • 한국초전도학회:학술대회논문집
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    • v.9
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    • pp.260-260
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    • 1999
  • We compared c-axis tunneling characteristics of small stacked intrinsic Josephson junctions prepared on the surface of pristine, I-, and HgI$_2$-intercalated Bi$_2Sr_2CaCu_2O_{8+x}$ (Bi2212) single crystals. The R(T) curves are almost metallic in I-Bi2212 specimens, but semiconducting in HgI$_2$-Bi2212 ones.· The transition temperatures were 82.0 K, 73.0 K, and 76.8 K for pristine Bi2212, I-Bi2212, and HgI2-Bi2212 specimens, respectively, consistent with p-T$_c$ phase diagram. Current-voltage (IV) characteristics of both kinds of specimens show multiple quasiparticle branches with well developed gap features, indicating Josephson coupling is established between neighboring CuO$_2$ planes. The critical current I$_c$ of I-Bi2212 is almost the same as of that of pristine crystals, but I$_c$ is much reduced in Hgl$_2$-Bi2212. In spite of expanded interlayer distances, the interlayer coupling is not significantly affected in I-Bi2212due to holes generated by iodine atoms. The coupling in HgI$_2$-Bi2212 is, however, weakened due to inertness of HgI$_2$ molecules and the expansion of interlayer distance. Relation between the superconducting transition temperature T$_c$ and the critical current I$_c$ seems to contradict Anderson's interlayer-pair-tunneling theory but agree with a modified version of it.

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CHARACTERISTICS OF DIAMONDLIKE CARBON COATED ALUMINA SEALS AT TEMPERATURES UP TO $400^{\circ}C$ (플라즈마 증착방식에 의해 DLC코팅된 알루미나 세라믹의 코팅박막 특성에 관한 연구)

  • Ok, Chul-Ho;Kim, Byoung-Yong;Kang, Dong-Hun
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.397-397
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    • 2007
  • Diamondlike carbon (DLC) coatings were deposited on alumina ceramic seals using a plasma immersion ion deposition technique (PIID). Then they were subjected to tribological tests using a pin-on-disc tribometer under a high load (1.3 GPa) and under elevated temperatures up to 400C. Coefficients of friction (COFs) were recorded and compared with that of the untreated alumina while the wear tracks were analyzed using SEM with EDS to characterize the DLC films. To enhance the DLC adhesion to the substrate, various interlayers including Si and Cr were deposited using the PIID process or an ion beam assisted deposition (IBAD) method. It was observed that the DLC coating, if adhering well to the substrate, reduced the COFs significantly, from 0.4-0.8 for the uncoated alumina to about 0.05-0.1, within the tested temperature range. The adhesion was determined by the interlayer type and possibly by the application method. Cr interlayer did not perform as well as the Si interlayer. This could also be due to the fact that the Cr interlayer and the subsequent DLC coating had to be done in two different processing systems, while both the Si interlayer and the subsequent DLC film were deposited in one system without breaking the chamber. The coating failure mode was found to be delamination between the Cr and the alumina substrate. In contrast, the Si interlayer with proper DLC deposition procedures resulted in very good adhesion and hence excellent tribological performance. Further study may lead to future DLC applications of ceramic seals.

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A Comparative Study on the Sound Insulation Characteristics of Laminated Glass in Accordance with Material and Composition of Interlayer Film (Interlayer film 재료 및 구성에 따른 접합유리 차음성능 비교)

  • Hong, Jiyoung;Ko, Sangwon;Koh, Hyo-In;Jang, Seungho
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2013.10a
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    • pp.501-505
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    • 2013
  • It is well known that monolithic glass has specific coincidence dip allowing transmittance of noise around the critical frequency. Laminated glass, made of a polyvinyle butyral(PVB) interlayer sandwiched by two panes of glass sheet, has long served for the advantage in noise attenuation properties as well as the safety purpose. More research on the improvement of sound insulation performance is needed, considering much of the noise is still transmitted through the glass. As a preliminary study, authors have made several test specimens, varied combinations of glass and interlayer film, to optimize the acoustic performance. Experimental investigation was carried out to study the sound transmission loss of test specimens in the reverberation chamber by using sound intensity method. Several new applications, instead of the existing PVB laminated glass, show better results in sound transmission loss and low temperature have a bad influence on the acoustic performance.

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Strength Characteristics in 3D-printed Concrete with Interlayer Reinforcements (층간 보강재로 보강한 3D 프린팅 콘크리트의 강도 특성)

  • Lee, Jung Woo;Park, Ji-Hun;Bui, The Quang;Jo, Changbin;Yang, In-Hwan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.3
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    • pp.338-347
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    • 2021
  • This paper aims to evaluating the interlayer strength of 3D-printed concrete with interlayer reinforcement. According to lap splices, two reinforcement methods were considered. One method did not include lap splices of interlayer reinforcement, but the other method included lap splices with length of 40mm. In addition, two different curing conditions were applied: air curing conditions and water curing conditions. The compressive, splitting tensile, and flexural tensile strengths of 3D-printed concrete specimens were measured in three loading directions with different reinforcement methods and curing conditions. Splitting and flexural tensile strengths decreased considerably when tensile stresses acted over the interlayers of 3D-printed concrete specimens. However, the flexural tensile strength or interlayer bonding strength of the printed specimens increased significantly at the interlayers when the longitudinal interlayer reinforcement penetrated printed layers. Interlayer bonding strength of printed concrete decreased after air curing treatment was applied because interlayers of printed concrete with more pores formed by the air cu ring conditions are more vulnerable to the load.

Solution processed inverted organic solar cells with hybrid inorganic/organic cathode interlayers

  • Lee, Jung Suk;Cha, Myoung Joo;Park, Yu Jung;Kim, Jin Young;Seo, Jung Hwa;Walker, Bright
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.154.2-154.2
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    • 2016
  • In this work, we introduce a solution-processed CdS interlayer for use in inverted bulk heterojunction (BHJ) solar cells, and compare this material to a series of standard organic and inorganic cathode interlayers. Different combinations of solution-processed CdS, ZnO and conjugated polyelectrolyte (CPE) layers were compared as cathode interlayers on ITO substrates to construct inverted solar cells based on $PTB7:PC_{71}BM$ and a $P3HT:PC_{61}BM$ as photoactive layers. Introduction of a CdS interlayer significantly improved the power conversion efficiency (PCE) of inverted $PTB7:PC_{71}BM$ devices from 2.0% to 4.9%, however, this efficiency was still fairly low compared to benchmark ZnO or CPE interlayers due to a low open circuit voltage ($V_{OC}$), stemming from the deep conduction band energy of CdS. The $V_{OC}$ was greatly improved by introducing an interfacial dipole (CPE) layer on top of the CdS layer, yielding outstanding diode characteristics and a PCE of 6.8%. The best performing interlayer, however, was a single CPE layer alone, which yielded a $V_{OC}$ of 0.727 V, a FF of 63.2%, and a PCE of 7.89%. Using $P3HT:PC_{61}BM$ as an active layer, similar trends were observed. Solar cells without the cathode interlayer yielded a PCE of 0.46% with a poor $V_{OC}$ of 0.197 V and FF of 34.3%. In contrast, the use of hybrid ZnO/CPE layer as the cathode interlayer considerably improved the $V_{OC}$ of 0.599 V and FF of 53.3%, resulting the PCE of 2.99%. Our results indicate that the CdS layer yields excellent diode characteristics, however, performs slightly worse than benchmark ZnO and CPE layers in solar cell devices due to parasitic absorption below 550 nm. These results suggest that the hybrid inorganic/organic interlayer materials are promising candidates as cathode interlayers for high efficiency inverted solar cells through the modification of interface contacts.

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Characteristics of Gate Oxides with Cobalt Silicide Process (복합 코발트 실리사이드 공정에 따른 게이트 산화막의 특성변화)

  • Song, Oh-sung;Cheong, Seong-hwee;Yi, Sang-don;Lee, Ki-yung;Ryu, Ji-ho
    • Korean Journal of Materials Research
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    • v.13 no.11
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    • pp.711-716
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    • 2003
  • Gate length, height, and silicide thickness have all been shrinking linearly as device density has progressively increased over the years. We investigated the effect of the cobalt diffusion during the silicide formation process on the 60$\AA$-thick gate oxide lying underneath the Ti/Co and Co/Ti bilayers. We prepared four different cobalt silicides, which have similar sheet resistance, made from the film structure of Co/Ti(interlayer), and Ti(capping layer)/Co, and peformed the current-voltage, time-to-break down, and capacitance-voltage measurements. Our result revealed that the cobalt silicide process without the Ti capping layer allowed cobalt atoms to diffuse into the upper interface of gate oxides. We propose that 100$\AA$-thick titanium interlayer may lessen the diffusion of cobalt to gate oxides in 1500-$\AA$ height polysilicon gates.

Effects of Strain Rate and Temperature on Fracture Strength of Ceramic/Metal Joint Brazed with Ti-Ag-Cu Alloy

  • Seo, Do-Won;Lim, Jae-Kyoo
    • Journal of Mechanical Science and Technology
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    • v.16 no.9
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    • pp.1078-1083
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    • 2002
  • Ceramics are significantly used in many industrial applications due to their excellent mechanical and thermal properties such as high temperature strength, low density, high hardness, low thermal expansion, and good corrosion resistive properties, while their disadvantages are brittleness, poor formability and high manufacturing cost. To combine advantages of ceramics with those of metals, they are often used together as one composite component, which necessiates reliable joining methods between metal and ceramic. Direct brazing using an active filler metal has been found to be a reliable and simple technique, producing strong and reliable joints. In this study, the fracture characteristics of Si$_3$N$_4$ ceramic joined to ANSI 304L stainless steel with a Ti-Ag-Cu filler and a Cu (0.25-0.3 mm) interlayer are investigated as a function of strain rate and temperature. In order to evaluate a local strain a couple of strain gages are pasted at the ceramic and metal sides near joint interface. As a result the 4-point bending strength and the deflection of interlayer increased at room temperature with increasing strain rate. However bending strength decreased with temperature while deflection of interlayer was almost same. The fracture shapes were classified into three groups ; cracks grow into the metal-brazing filler line, the ceramic-brazing filler line or the ceramic inside.

Pseudogap behavior in interlayer tunneling spectroscopy in $Bi_{2}Sr_{2}CaCu_{2}O_{8+x}$

  • Bae Myung-Ho;Choi Jae-Hyun;Lee Hu-Jong
    • Progress in Superconductivity
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    • v.7 no.1
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    • pp.1-5
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    • 2005
  • A pseudogap in the normal-state quasiparticle density of states of $high-T_c$ superconductors has been revealed in many different kinds of experiments. The existence of the pseudogap and the superconducting gap, and the correlation between them has attracted considerable attention because they are believed to be a key to understanding the mechanism of the $high-T_c$ superconductivity. The interlayer tunneling spectroscopy, excluding the surface-dependent effect, is one of the most accurate means to examine the electron spectral characteristics both in the superconducting and the normal states. In this study, a new constant-temperature intrinsic tunneling spectroscopic technique, excluding the overheating effect using the in-situ temperature monitoring combined with the digital proportional-integral-derivative control, is introduced. The implication on the $high-T_c$ superconductivity of the detailed temperature dependencies of the observed spectral weight in $Bi_{2}Sr_{2}CaCu_{2}O_{8+x}\;high-T_c$ material for overdoped and underdoped levels is discussed.

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The formation of diamond films on high speed steel with a titanium inter- layer by electron-assisted CVD process (화학증착법에 의한 티타늄 피복된 고속도강에의 다이아몬드 박막 형성)

  • 정연진;이건영;이호진;최진일
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.14 no.1
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    • pp.6-11
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    • 2004
  • The characteristics of interface layer and the effect of bias voltages on the nucleation density and heteroepitaxial growth of diamond films were studied in the hot filament CVD diamond process. Diamond films were deposited on a high speed steel (SKH-51) substrate by bias-assisted hot filament CVD technique with a titanium interlayer. The bias applied for enhancing the emission of electrons from the filament increased the nucleation density and achieving heteroepitaxial growth of CVD diamond. Diamond films obtained at a gas pressure of 20 torr; a bias voltage of 200 V and a substrate temperature of $700^{\circ}C$. Titanium was a suitable element as an interlayer for the diamond deposition on steel because it has high diffusivity of Fe and C as a carbide forming element.

A Study on the Dispersion Characteristics of PP/MMT Composites (PP/MMT 복합체의 분산특성에 관한 연구)

  • 김규남;김형수
    • Polymer(Korea)
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    • v.24 no.3
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    • pp.374-381
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    • 2000
  • Composites of polypropylene (PP) and organically modified montmorillonite (org-MMT) were prepared by melt mixing in an intensive mixer. Three grades of PP's having different melt viscosities were employed to investigate the dispersion characteristics of the composites with various org-MMT's. Depending on the matrix viscosity and nature of the interlayer in org-MMT significant variations of the phase structure were found. Under the constant mixing condition and matrix viscosity, intercalation of PP chains into the interlayer of org-MMT was possible when initial interlayer distance and packing density were maintained in the optimum range; by which the loss in entropy associated with the confinement of polymer chains was compensated. The state of org-MMT particle dispersion was improved by increasing the matrix viscosity only in the case that dispersed phase is suitable for intercalation process thermodynamically, otherwise little variation was occurred regardless of the matrix viscosity. Due to the lack of specific interaction between PP and erg-MMT considered here, although the intercalation was possible for an appropriate org-MMT, the composites revealed unstable phase structure upon increasing the mixing time, which was characterized by agglomeration of the org-MMT domains.

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