• Title/Summary/Keyword: interfacial change

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Surface Modification of Glass Fiber for Polymer Insulator by Plasma Surface Treatment (플라즈마 표면처리에 따른 고분자절연재료용 유리섬유의 표면개질)

  • 임경범;이덕출
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.5
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    • pp.206-212
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    • 2003
  • It is hard to expect excellent electrical, mechanical and chemical properties from most of the composite materials presently used as insulators due to insufficient wettability property caused by the difference of interfacial properties between the matrix material and the reinforcer. Therefore, various interfacial coupling agents have been developed to improve the interfacial properties of composite materials. But if the wettable coupling agents are used outdoor for a long time, change in quality takes place in the coupling agents themselves, bringing about deterioration of the properties of the composite materials. In this study, glass surface was treated by plasma to examine the effect of dry interface treatment without coupling agent. It was identified that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system pressure, 100 W of discharge power, and 3 minutes of discharge time. Also, the surface resistance rate and dielectric property were improved.

Surface Modification of Polymer Insulator by Plasma Surface Treatment (플라즈마 표면처리에 따른 고분자절연재료의 표면개질)

  • Lim, K.B.;Hwang, M.W.;Lee, B.S.;You, D.H.;Yuk, J.H.;Kim, H.G.;Lim, H.C.;Park, K.S.;Lee, D.C.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05c
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    • pp.31-35
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    • 2002
  • It is hard to expect excellent electrical, mechanical and chemical properties from most of the composite materials presently used as insulators due to insufficient wettability property caused by the difference of interfacial properties between the matrix material and the reinforcer. Therefore, various interfacial coupling agents have been developed to improve the interfacial properties of composite materials. But if the wettable coupling agents are used outdoor for a long time, change in quality takes place in the coupling agents themselves, bringing about deterioration of the properties of the composite materials. In this study, composite materials were put to dry interfacial treatment by use of plasma technology. It has been presented that the optimum parameters for the best wettability of the samples at the time of generation of plasma were oxygen atmosphere, 0.1 torr of system pressure, 100 W of discharge power, and 3 minutes of discharge time. Also, the surface resistance rate and dielectric property were improved.

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A Study on Wetting, Interfacial Reaction and Mechanical Properties between Sn-Bi-Ag System Solders and Cu Substrate (Sn-Bi-Ag계 땜납과 Cu기판과의 젖음성, 계면 반응 및 기계적 성질에 관한 연구)

  • Seo, Youn-Jong;Lee, Kyung-Ku;Lee, Doh-Jae
    • Journal of Korea Foundry Society
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    • v.17 no.3
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    • pp.245-251
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    • 1997
  • Solderability, interfacial reaction and mechanical properties of joint between Sn-Bi-Ag base solder and Cu-substrate were studied. Solders were subjected to aging treatments to see the change of mechanical properties for up to 30 days at $100^{\circ}C$, and then also examined the changes of microstructure and morphology of interfacial compound. Sn-Bi-Ag base solder showed about double tensile strength comparing to Pb-Sn eutectic solder. Addition of 0.7wt%Al in the Sn-Bi-Ag alloy increase spread area on Cu substrate under R-flux and helps to reduce the growth of intermetallic compound during heat-treatment. According to the aging experiments of Cu/solder joint, interfacial intermetallic compound layer was exhibited a parabolic growth to aging time. The result of EDS, it is supposed that the soldered interfacial zone was composed of $Cu_6Sn_5$.

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A Study on Improvement of Interfacial Adhesion Energy of Inkjet-printed Ag Thin film on Polyimide by CF4 Plasma Treatment (CF4플라즈마 처리에 의한 잉크젯 프린팅 Ag박막과 폴리이미드 사이의 계면파괴에너지 향상에 관한 연구)

  • Park, Sung-Cheol;Cho, Su-Hwan;Jung, Hyun-Cheol;Joung, Jae-Woo;Park, Young-Bae
    • Korean Journal of Materials Research
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    • v.17 no.4
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    • pp.215-221
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    • 2007
  • The effect of $CF_4$ plasma treatment condition on the interfacial adhesion energy of inkjet printed Ag/polyimide system is evaluated from $180^{\circ}$ peel test by calculating the plastic deformation energy of peeled metal films. Interfacial fracture energy between Ag and as-received polyimide was 5.5 g/mm. $CF_4$ plasma treatment on the polyimide surface enhanced the interfacial fracture energy up to 17.6 g/mm. This is caused by the increase in the surface roughness as well as the change in functional group of the polyimide film due to $CF_4$ plasma treatment on the polyimide surface. Therefore, both the mechanical interlocking effect and the chemical bonding effect are responsible for interfacial adhesion improvement in ink jet printed Ag/polyimide systems.

Characteristics of Gas-liquid Mass Transfer and Interfacial Area in a Bubble Column

  • Lim, Dae Ho;Yoo, Dong Jun;Kang, Yong
    • Korean Chemical Engineering Research
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    • v.53 no.3
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    • pp.315-320
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    • 2015
  • Characteristics of gas-liquid mass transfer and interfacial area were investigated in a bubble column of diameter and height of 0.102 m and 2.5 m, respectively. Effects of gas and liquid velocities on the volumetric gas-liquid mass transfer coefficient ($k_La$), interfacial area (a) and liquid side true mass transfer coefficient ($k_L$) were examined. The interfacial area and volumetric gas-liquid mass transfer coefficient were determined directly by adopting the simultaneous physical desorption of $O_2$ and chemical absorption of $CO_2$ in the column. The values of $k_La$ and a increased with increasing gas velocity but decreased with increasing liquid velocity in the bubble column which was operated in the churn turbulent flow regime. The value of $k_L$ increased with increasing gas velocity but did not change considerably with increasing liquid velocity. The liquid side mass transfer was found to be related closely to the liquid circulation as well as the effective contacting frequency between the bubbles and liquid phases.

Efficiency enhancement of Organic Light Emitting Diodes by the AlON interfacial Layer (산소질화알루미늄 계면층에 의한 유기발광 소자의 효율 향상)

  • Park, Hyung-Jun;Hai, Jin Zheng;Nam, Eun-Kyoung;Jung, Dong-Geun;Yi, Jun-Sin
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.388-389
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    • 2007
  • In this work, Organic Light Emitting Diodes using Aluminum-Oxynitride as a hole-injecting interfacial have been fabricated. This interfacial layer is inserted at the ITO/N,NV-diphenyl-N, NV-bis(3-methylphenyl)-1,1V-diphenyl-4,4V-diamine (TPD) interface. The brightness and efficiency of the device with the AION film is higher than that of the device without it. The enhancements are attributed to an improved balance of hole and electron injections due to the energy level realignment and the change in carrier tunneling probability by the interfacial layer.

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Thermal Stresses in a Bimaterial Axisymmetric Disk-Approximate and Exact Solutions (복합 재료로 구성된 축대칭 원판에서의 열응력)

  • 정철섭;김기석
    • Computational Structural Engineering
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    • v.8 no.1
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    • pp.173-186
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    • 1995
  • It is well known that structures constructed by bonding two or more materials and then subjected to temperature change experience thermal stress. This stress results from thermal expansion mismatch of materials. The present paper derives formulas for the stresses in a bimaterial axisymmetric disk which is subjected to a uniform temperature change. First, an approximate solution following strength-of-materials principles is developed. However, the strength-of-materials solution has difficulty in predicting both the peak value of interfacial stresses and its associated distribution. Next, a solution consistent with the theory of elasticity is developed by way of an eigenfunction expansion approach. The eigenfunction analysis is compared with finite element stress analysis results for a specific numerical example. Finite element analysis results show that the interfacial stresses are adequately predicted by eigenfunction solution. Therefore, the method developed in this paper will be useful in determination of the interfacial stress state.

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Positive Exchange Bias in Thin Film Multilayers Produced with Nano-oxide Layer

  • Jeon, Byeong-Seon;Hwang, Chan-Yong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.304-305
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    • 2013
  • We report a positive exchange bias (HE) in thinmultilayered filmscontaining nano-oxide layer. The positive HE, obtained for our system results from an antiferromagnetic coupling between the ferromagnetic (FM) CoFe and the antiferromagnetic (AFM) CoO layers, which spontaneously form on top of the nano-oxide layer (NOL). The shift in the hysteresis loop along the direction of thecooling field and the change in the sign of exchange bias are evidence of antiferromagnetic interfacial exchange coupling between the CoO and CoFe layers. Our calculation indicates that uncompensated oxygen moments in the NOL results in antiferromagnetic interfacial exchange coupling between the CoO and CoFe layers. One of the interesting features observed with our system is that it displays the positive HE even above the bulk Neel temperature (TN) of CoO. Although the positive HEsystem has a different AFM/FM interfacial spin structure compare to that of the negative HE one, the results of the angular dependence measurements show that the magnetization reversal mechanism can be considered within the framework of the coherent rotation model.

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The effect of interfacial layer thickness on the interface dipole energy in $O_2$ plasma treated metal/organic interface

  • Kim, Soo-Young;Lee, Jong-Lam
    • 한국정보디스플레이학회:학술대회논문집
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    • 2009.10a
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    • pp.115-117
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    • 2009
  • Interface dipole energies between interfacial layers with different thicknesses coated on indium tin oxides (ITOs) and 4,4'-bis[N-(1-naphtyl)-N-phenyl-amino]biphenyl are determined. After $O_2$ plasma treatment on thick-metal (>4 nm) coated ITO, the work function and interface dipole energy increased. In thin-metal (< 2 nm) coated ITO, no change in the interface dipole energy was found though the work function increased. Thus, the $O_2$ plasma treated thin (< 2 nm) interfacial layer reduced the hole injection barrier.

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Interfacial Elemental Change When Soldering the Nico-crally and Fe-Cr-Ni Alloy (국소의치금속상과 Fe-Cr계 wire를 soldering 할때 발생한 계면의 성분변화)

  • Cho, Sung-Am;Ko, Hyun-Kwon
    • The Journal of Korean Academy of Prosthodontics
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    • v.27 no.1
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    • pp.49-54
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    • 1989
  • The purpose of this study was to investigate the interfacial elemental change when solding the Ni-Co-Cr dental removable partial denture alloy and Fe-Cr-Ni wrought wire alloy with Ag-Cu-Zu Silver solder, by EDXA, EPMA, to investigate the appropriateness of clinical usefullness for repair the fractured clasps of removable partial dentive. The result of this study was as follows: 1. The Ni element of major component of Ticonium penetrate into the silver solder 2. The movement Age element of silver solder into Fe-Cr-Ni wire was not significant, by EDXA and EPMA.

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