• Title/Summary/Keyword: inter-particle

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THE MICROSTRUCTURE OF Pb-DOPED SOLIDIFIED WASTE FORMS USING PORTLAND CEMENT AND CALCITE

  • Yoo, Hee-Chan;Lee, Dong-Jin
    • Environmental Engineering Research
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    • v.11 no.1
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    • pp.54-61
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    • 2006
  • An electron probe microanalysis (EPMA) investigation can provide quantitative and qualitative insight into the nature of the surface and bulk chemistry on solidified waste forms(SWF). The proportion of Pb in grain areas is below 0.3 wt. %, and the proportion near the border of the grain slightly increases to 0.98 wt. % but in the inter-particle areas farther from the grain, the concentration of Pb markedly increases. It is apparent that very little Pb diffuses into the tricalcium silicate($C_3S$) particles and most of the Pb exists as precipitates of sulfate, hydroxide, and carbonate in the cavity areas between $C_3S$ grains. Calcite additions on Pb-doped SWF are also observed to induce deeper incorporation of lead into the cement grains with EPMA line-analysis of cross-sections of cement grains. The line-analysis reveals the presence of $0.2{\sim}5$ weight % Pb over $5\;{\mu}m$ from cement grain boundaries. In the inter-particle areas, the ratio of Ca, Si, Al and S to Pb is relatively similar even at some distance from the grain border and the Pb (wt. %) ratio is reasonably constant throughout the whole inter-particles area. It is apparent that the enhanced development of C-S-H on addition of calcite can increasingly absorbs lead species within the silica matrix.

Validity of Inter-Particle Models for the Mass-Transfer Kinetics of a Fin-Tube-Type Adsorption Bed (핀-튜브형 흡착탑 해석시 입자간 물질전달 모델의 타당성 검증)

  • Ahn, Sang Hyeok;Hong, Sang Woo;Kwon, Oh Kyung;Chung, Jae Dong
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.25 no.12
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    • pp.660-667
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    • 2013
  • This study presents a numerical investigation of the heat and mass transfer kinetics of a fin-tube-type adsorption bed using a two-dimensional numerical model with silica-gel and water as the adsorbent and refrigerant pair. The performance is strongly affected by the heat and mass transfer in the adsorption bed, but the details of the mass transfer kinetics remain unclear. The validity of inter-particle models used to simulate mass-transfer kinetics were examined, such as a constant pressure model and non-constant pressure model, and the valid ranges of the diffusion ratio for each model are proposed. The COP and SCP have been numerically calculated as the performance indexes according to the diffusion ratio. The constant pressure model, which is commonly used in previous research, was found to be valid only in a limited range of diffusion ratio.

Caking in Food Powders

  • Ruan, Roger;Choi, Young-Jin;Chung, Myong-Soo
    • Food Science and Biotechnology
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    • v.16 no.3
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    • pp.329-336
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    • 2007
  • Caking has been a serious problem in food, feed, pharmaceutical, and related industries, where dry powdered materials are produced and/or utilized. Caking of dry food powders occurs when water is redistributed or absorbed by the powders during processing and storage. The powders become sticky when their surfaces are mobilized by water, resulting in inter-particle binding, formation of clusters, and inter-particle fusion, which lead to caking. As a result of caking, the solubility of the powdered materials may decrease, lipid oxidation and enzymatic activity may increase, and sensory qualities such as flavor and crispness may deteriorate. Caking may also lead to microbial growth. For consumers, caking of powder products is a sign of poor quality and possible food safety problems. This paper provides a review of factors affecting caking, caking mechanisms, and analysis of caking based on previous studies.

Analysis of drawing process of the Al-Si wire using FEM (유한요소해석을 이용한 Al-Si 선재의 인발 공정해석)

  • Hwang W. H.;Kim B. M.;Kim W. Y.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.10a
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    • pp.89-92
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    • 2004
  • This paper is concerned with the drawing process of Al-Si wire. In this study, the finite-element model established in previous work was used to analyze the effects of various forming parameters, which included the reduction in area, the semi-die angle, the aspect ratio and the inter-particle spacing of the Si in drawing processes. The finite-element results gave the consolidation condition. From the results of analysis, the effects of each forming parameter were determined. It is possible to obtain the important basic data which can be guaranteed in the fracture prevention of Al-Si wire by using FEM simulation.

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Two-dimensional Assembly of Organically Functionalized Ag Nanoparticles at Air-water Interface (공기와 물이 형성하는 계면에서 발생하는 유기적으로 기능화된 은 나노 입자들의 2차원 조립)

  • Chung, Sungwook
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.125-131
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    • 2017
  • We report organically functionalized Ag nanoparticles spontaneously form two-dimensional (2D) novel superstructures at the air-water interface. Analysis of the superstructures suggests that the 2D assembly of Ag nanoparticles originates from a subtle interplay between characteristic inter-particle interactions that can be readily controlled by changing the sizes of nanoparticle metal core and surfactants. Such structures have potential uses in nanostructured functional materials, catalysis, and device applications.

Effect of Process Parameters and Kraft Lignin Additive on The Mechanical Properties of Miscanthus Pellets

  • Min, Chang Ha;Um, Byung Hwan
    • Journal of the Korean Wood Science and Technology
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    • v.45 no.6
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    • pp.703-719
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    • 2017
  • Miscanthus had a higher lignin content (19.5 wt%) and carbohydrate (67.6 wt%) than other herbaceous crops, resulting in higher pellet strength and positive effect on combustion. However, miscanthus also contains a high amount of hydrophobic waxes on its outer surface, cuticula, which limits the pellet quality. The glass transition of lignin and cuticula were related to forming inter-particle bonding, which determined mechanical properties of pellet. To determine the effects of surface waxes, both on the pelletizing process and the pellet strength were compared with raw and extracted samples through solvent extraction. In addition, to clarify the relationship between pellet process parameters and bonding mechanisms, the particle size and temperature are varied while maintaining the moisture content of the materials and the die pressure at constant values. Furthermore, kraft lignin was employed to determine the effect of kraft lignin as an additive in the pellets. As results, the removal of cuticula through ethanol extractions improved the mechanical properties of the pellet by the formation of strong inter-particle interactions. Interestingly, the presence of lignin in miscanthus improves its mechanical properties and decreases friction against the inner die at temperatures above the glass transition temperature ($T_g$) of lignin. Consequently, it could found that the use of kraft lignin as an additive in pellet reduced friction in the inner die upon reaching its glass transition temperature.

Nano-scale Inter-lamellar Structure of Metal Powder Composites for High Performance Power Inductor and Motor Applications

  • Kim, Hakkwan;An, Sung Yong
    • Journal of Magnetics
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    • v.20 no.2
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    • pp.138-147
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    • 2015
  • The unique nano-scale inter-lamellar microstructure and unparalleled heat treatment process give our developed metal powder composite its outstanding magnetic property for power inductor & motor applications. Compared to the conventional polycrystalline Fe or amorphous Fe-Cr-Si-B alloys, our unique designed inter-lamellar microstructure strongly decreases the intra-particle eddy current loss at high frequencies by blocking the mutual eddy currents. The combination of optimum permeability, magnetic flux and extremely low core loss makes this powder composite suitable for high frequency applications well above 10 MHz. Moreover, it can be also possible to SMC core for high speed motor applications in order to increase the motor efficiency by decreasing the core loss.

Thermophoresis in Dense Gases: a Study by Born-Green- Yvon Equation

  • Han Minsub
    • Journal of Mechanical Science and Technology
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    • v.19 no.4
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    • pp.1027-1035
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    • 2005
  • Thermophoresis in dense gases is studied by using a multi-scale approach and Born- Yvon­Green (BYG) equation. The problem of a particle movement in an ambient dense gas under temperature gradient is divided into inter and outer ones. The pressure gradient in the inner region is obtained from the solutions of BYG equation. The velocity profile is derived from the conservation equations and calculated using the pressure gradient, which provides the particle velocity in the outer problem. It is shown that the temperature gradient applied to the quiescent ambient gas induces some pressure gradient and thus flow tangential to the particle surface in the interfacial region. The mechanism that induces the flow may be the dominant source of the thermophretic particle movement in dense gases. It is also shown that the particle velocity has a nonlinear relationship with the applied temperature gradient and decreases with increasing temperature.

Fatigue Crack Growth Behavior of Short fiber/Particle Hybrid Metal Matrix Composites (단섬유/입자 혼합 금속복합재료의 피로균열진전 거동)

  • Oh K.H.;Jang J. H.;Han K. S.
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.219-222
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    • 2004
  • The effects of short fiber and particle hybrid reinforcement on fatigue crack propagation behaviors in aluminum matrix composites have been investigated. Single and hybrid reinforced 6061 aluminum containing same 20 $Al_2O_3\;volume\%$ with four different constituent ratios of short fibers and particles were prepared by squeeze casting method and tested to check the near-threshold and stable crack growth behavior. The fatigue threshold of the composites increased with portion of particle contents and showed the improved crack resistance especially in low stress intensity range. Addition of particle instead of short fiber also increased fracture toughness due to increase of inter-reinforcement distance. These increase in both fatigue threshold and fracture toughness eventually affected the fatigue crack growth behavior such that the crack growth curve shift low to high stress intensity factor value. Overall experimental results were shown that particle reinforcement was enhanced the fatigue crack resistance over the whole stress intensity factor range.

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The Properties of Inter-Locking Block with the Variation of Particle Grading and Shape of Aggregate (골재의 입도와 입형 변화에 따른 인터로킹 블록의 특성)

  • 이상태;김기철;신병철;김진선;권상준;한천구
    • Proceedings of the Korea Concrete Institute Conference
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    • 1998.04b
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    • pp.661-664
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    • 1998
  • In this paper, the properties of inter-lacking block by the kind of aggregate and fineness modulus are investigated. According to the experimental results, compressive strength and flexural strength increase and absorption ratio decrease with larger fineness modulus in the range of 2.15~4.20. Flexural strength with river sand is higher than that with crushed sand by about 19%, compressive strength with river sand, that with crushed sand by about 11% and absorption ratio with river sand is smaller than that with crushed sand by abort 2%.

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