• Title/Summary/Keyword: insulating performance

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Strategic design for oxide-based anode materials and the dependence of their electrochemical properties on morphology and architecture

  • 강용묵
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2012년도 춘계학술발표대회
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    • pp.73-73
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    • 2012
  • Modern technology-driven society largely relies on hybrid electric vehicles or electric vehicles for eco-friendly transportation and the use of high technology devices. Lithium rechargeable batteries are the most promising power sources because of its high energy density but still have a challenge. Graphite is the most widely used anode material in the field of lithium rechargeable batteries due to its many advantages such as good cyclic performances, and high charge/discharge efficiency in the initial cycle. However, it has an important safety issue associated with the dendritic lithium growth on the anode surface at high charging current because the conventional graphite approaches almost 0 V vs $Li/Li^+$ at the end of lithium insertion. Therefore, a fundamental solution is to use an electrochemical redox couple with higher equilibrium potentials, which suppresses lithium metal formation on the anode surface. Among the candidates, $Li_4Ti_5O_{12}$ is a very interesting intercalation compound with safe operation, high rate capability, no volume change, and excellent cycleability. But the insulating character of $Li_4Ti_5O_{12}$ has raised concerns about its electrochemical performance. The initial insulating character associated with Ti4+ in $Li_4Ti_5O_{12}$ limits the electronic transfer between particles and to the external circuit, thereby worsening its high rate performance. In order to overcome these weak points, several alternative synthetic methods are highly required. Hence, in this presentation, novel ways using a synergetic strategy based on 1D architecture and surface coating will be introduced to enhance the kinetic property of Ti-based electrode. In addition, first-principle calculation will prove its significance to design Ti-based electrode for the most optimized electrochemical performance.

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β-Ga2O3/4H-SiC MESFETs에서의 Self-Heating (Self-Heating Effects in β-Ga2O3/4H-SiC MESFETs)

  • 김민영;서현수;서지우;정승우;이희재;변동욱;신명철;;구상모
    • 한국전기전자재료학회논문지
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    • 제35권1호
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    • pp.86-92
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    • 2022
  • Despite otherwise advantageous properties, the performance and reliability of devices manufactured in β-Ga2O3 on semi-insulating Ga2O3 substrates may degrade because of poorly mitigated self-heating, which results from the low thermal conductivity of Ga2O3 substrates. In this work, we investigate and compare self-heating and device performance of β-Ga2O3 MESFETs on substrates of semi-insulating Ga2O3 and 4H-SiC. Electron mobility in β-Ga2O3 is negatively affected by increasing lattice temperature, which consequently also negatively influences device conductance. The superior thermal conductivity of 4H-SiC substrates resulted in reduced β-Ga2O3 lattice temperatures and, thus, mitigates MESFET drain current degradation. This, in turn, allows practically reduced device dimensions without deteriorating the performance and improved device reliability.

잔골재를 바이오차로 치환한 콘크리트의 강도와 열적 특성 (Strength and Thermal Properties of Concrete for Replacement Fine Aggregate with Biochar)

  • 김경철;임광모;손민수;김영석;고경택
    • 한국건설순환자원학회논문집
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    • 제11권4호
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    • pp.425-432
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    • 2023
  • 본 연구에서는 바이오차를 혼입한 탄소 저감형 콘크리트 기술을 개발하고자 한다. 주요 인프라 분야인 건축과 터널에 단열성능과 탄소 포집이 가능한 바이오차를 혼입시킨 콘크리트의 성능 평가 실험을 수행하였다. 콘크리트 배합은 바이오차 혼입률 0, 5, 10, 15 및 20 %와 물-바인더 비를 0.25, 0.30, 0.35 및 0.40으로 선정하여 배합조건을 구성하였다. 각 배합별 물리적 특성을 평가하기 위해 단위중량, 총 공극률 및 투수계수를 측정하였고, 역학적 특성을 파악하기 위해 콘크리트 압축강도, 휨강도를 측정하였다. 바이오차를 혼입한 탄소 저감형 콘크리트의 단열 효과를 향상 시키기 위한 주요 인자는 회귀분석을 통해 바이오차 혼입률, 단위중량, 콘크리트 강도 및 열전도율은 서로 밀접한 상관관계를 갖는 것으로 나타났다. 향후 혹한기후 특성을 갖는 북방지역에 단열성능을 높이기 위한 단열재료로 활용될 것으로 판단된다.

Simplified Synthetic Testing Facility with Modified TRV Circuit

  • Chong, Jin-Kyo;Lee, Kyung Seob;Lee, Chang-Hoon;Kim, Gyu-Tak
    • Journal of Electrical Engineering and Technology
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    • 제13권2호
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    • pp.881-885
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    • 2018
  • In order to develop a gas circuit breaker (GCB), the breaking performance of the short line fault (SLF) should be prioritized over that of the breaker terminal fault (BTF). In brief, it is necessary to evaluate the thermal characteristics of the insulating gas that is filled in a GCB. In the process of developing a GCB, many companies use the simplified synthetic testing facility (SSTF).In order to evaluate the SLF breaking performance of a GCB with a long minimum arcing time, a modifications to the conventional SSTF was proposed. In this study, we developed the SSTF with a modified transient recovery voltage circuit. The performance of the newly developed SSTF was verified by an $L_{90}$ breaking performance test on a rating combination of 170 kV, 50 kA, and 60 Hz.

Renewable Low-viscosity Dielectrics Based on Vegetable Oil Methyl Esters

  • Yu, Hui;Yu, Ping;Luo, Yunbai
    • Journal of Electrical Engineering and Technology
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    • 제12권2호
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    • pp.820-829
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    • 2017
  • Vegetable oil dielectrics have been used in transformers as green alternatives to mineral insulating oils for about twenty years, because of their advantages of non-toxic, biodegradability, and renewability. However, the viscosity of vegetable oils is more than 3 times of mineral oils, which means a poor heat dissipation capacity. To get low-viscosity dielectrics, transesterification and purification were performed to prepare vegetable oil methyl esters in this study. Electrical and physical properties were determined to investigate their potential as dielectrics. The results showed that the methyl ester products had good dielectric strengths, high water saturation and enough fire resistance. The viscosities (at $40^{\circ}C$) were 0.2 times less than FR3 fluid, and 0.7 times less than mineral oil, which indicated superior cooling capacity as we expected. With the assistance of 0.5 wt% pour point depressants, canola oil methyl ester exhibited the lowest pour point ($-26^{\circ}C$) among the products which was lower than FR3 fluid ($-21^{\circ}C$) and 25# mineral oil ($-23^{\circ}C$). Thus, canola oil methyl ester was the best candidate as a low-viscosity vegetable oil-based dielectric. The low-viscosity fluid could extend the service life of transformers by its better cooling capacity compared with nature ester dielectrics.

Rotating Wheel Dip Test에 의한 에폭시 절연재료의 내트래킹성과 열화 특성 (Tracking Resistance and Aging Characteristics of Epoxy Insulating Materials by the Rotating Wheel Dip Test)

  • 조한구
    • 한국전기전자재료학회논문지
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    • 제21권6호
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    • pp.530-537
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    • 2008
  • This paper describes the results of a study on the tracking performance of outdoor insulating materials based on the rotating wheel dip test(RWDT). And, the influence of surface degradation was evaluated through such as measurement of the flashover voltage after and before tracking test, also aspects of surface degradation using scanning electron microscopy. The time to tracking breakdown of treated filled specimen is longer than untreated filled specimen. And, after the RWDT, the surface of specimen by adding untreated filler appeared heavy erosion. It was found that the addition to surface treated filler, the better tracking resistance. In the RWDT, the breakdown specimen is not affected by the dry flashover voltage, despite the fact that the surface degradation of tracking test has different state on each specimen. This suggests that wet flashover voltage play an important role in evaluating of tracking and erosion on the surface degradation in tracking test. And, the flashover voltage of specimen under wet conditions are greatly affected by the salt concentration and degree of degradation by the RWDT Because of hydrophobicity and degree of degradation by the RWDT, the flashover voltage of treated filled specimen is higher than that of untreated filled specimen. Different types of specimen may have different hydrophobicity and their surface state under contaminated conditions may not be the same.

선형회귀법을 이용한 절연유에 용존된 furfural과 CO, CO2 가스 함유량 간의 상관관계 분석 (Analysis for Correlation Between Furfural and CO, CO2 Gas Dissolved Inside Insulating Oil using Linear Regression Method)

  • 김재훈;박두기;한상옥
    • 전기학회논문지P
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    • 제59권2호
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    • pp.212-217
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    • 2010
  • When paper which was applied as insulation in oil-filled transformer was aged by thermal, its electrical, mechanical and chemical characteristics were changed and deteriorated. Therefore operating temperature was more higher, damage of paper was more quicker. Insulating paper which was generally made with cellulose was degraded, polymer of long length chain was decomposed as a monomer and CO, $CO_2$ gas and/or by-product such as furfural was produced from paper at the same time. In according with detection these gas and furfural by dissolved gas analysis(DGA) and high performance liquid chromatography(HPLC), we have investigated effects of CO, $CO_2$ gas and furfural on insulation of paper. Also we have analyzed for correlation between furfural and CO, $CO_2$ gas using linear regression method that was known as useful, credible statistical analysis.

천장구조를 이용한 공동주택 바닥충격음 차단성능 개선에 관한 실험적 연구 (An Experimental Study on the Improvement Floor Impact Sound Insulation by Ceiling Structure in Apartment Houses)

  • 백은선
    • KIEAE Journal
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    • 제7권1호
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    • pp.95-100
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    • 2007
  • In apartment houses, said to be similar to a typical housing form, every household share the walls and floors. Many problems inevitably accompany such as an arrangement, as noise and vibration are shared among households. When investigating the percentage of apartment resident's dissatisfaction with housing environments, discontent due to noise ranks the highest. Among many different kinds of noises, noise such as floor crashing sounds show the highest indication rate in the residents' comparison of discontent. Therefore, it is the practice of insulating against noises such as floor crashing sounds that improves the apartment house environments. The factors influencing the floor impact sound insulation include floor finishing materials, shock absorbing floors (slabs included), and ceiling structures. The ceilings of the apartment houses, currently built in Korea, are set up with lower parts of slabs and paper finishing, or with double floors for protecting against floor impact sounds in order to improve the sound insulating performance. The most common the method of ceiling structure construction consists of 'wood boarded frames +Gypsum boards + ceiling papers', which is called the wood boarded frame method. This study aimed to measures and evaluates floor impact sound insulation by which the ceiling space are widened according to suppression system is added in apartment house ceiling structure.

Thermal stabilities and dynamic mechanical properties of dielectric materials for next generation PCB

  • 조재춘;이화영;임성택;박문수;이근용;오준록
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.253-253
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    • 2008
  • Recently, high performance microelectronic devices are designed in multi-layer structure in order to make dense wiring of metal conductors in compact size. For making dense wiring of metal conductors, we investigated CTE and peel strength of dielectric materials for next generation PCB. It is an object of this research to develop an epoxy resin composition for an interlayer insulating material exhibiting low CTE and high peel strengnth and making an insulating layer thinner.

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변압기에 용존된 Furan계 물질 분석 (Analysis of Furanic Compounds Dissolved in Transformer Oil)

  • 김재훈;이병성;이세현;구경완;한상옥
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2005년도 제36회 하계학술대회 논문집 C
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    • pp.1909-1911
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    • 2005
  • The electrical and chemical characteristics in transformer insulations are changed due to thermal stress. In the chemical property, as the Kraft paper ages, the cellulose polymer chains breakdown into shorter lengths with a corresponding decrease in both tensile strength and degree of polymerization(DP). Furthermore, cellulous chains breakdown is accompanied by an increase in the content of various furanic compounds within the dielectric liquid. It is known that furanic components in transformer oil come only from the decomposition of insulating paper rather than from the oil itself. Therefore the analysis of furan products provides a complementary technique to dissolved gas analysis for monitoring transformers when we evaluate the aging of insulating paper by the total concentration of carbon monoxide and carbon dioxide dissolved in oil only. In this paper the accelerated aging process of oil--paper samples have been investigated at a temperature up to $140^{\circ}C$ for 500 hours. The oil-paper insulation samples have been measured at intervals of 100 hours. For analysis we used high performance liquid chromatography(HPLC) in accordance with IEC 61198 method.

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