• Title/Summary/Keyword: initial setting time

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Effects of Catalytic Reaction and Natural Convection on the Hot Surface Ignition of Methane-Air Mixtures (메탄-공기 예혼합기의 열면점화에 미치는 촉매반응 및 자연대류의 영향)

  • Kim, H.M.;Jurng, J.S.
    • Journal of the Korean Society of Combustion
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    • v.2 no.1
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    • pp.29-38
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    • 1997
  • In this study, the experimental and numerical investigations of the ignition of methane-air mixtures by a electrically heated wire have been carried out. In order to define the initial condition and make the analysis simple, the following control unit was developed; which heats the wire to the setting temperature in a very short time, and maintains the wire temperature constant until ignition. Experiments with the feedback control have been performed using nickel and platinum wires in normal gravity and microgravity. From experimental results, ignition temperatures in normal gravity are higher than those in microgravity, however, the dependences of ignition temperature on equivalence ratio are not affected by natural convection. Numerical calculations, including catalytic reaction for platinum, have been performed to analyze the experimental results in microgravity. Numerical results show that reactants near platinum wire are consumed by catalytic reaction, therefore, the higher temperature is needed to ignite the mixture with platinum wire.

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An Effect of $Ca(OH)_2$ on Development of an Early Age Strength of GGBFS Cement (고로슬래그 시멘트의 초기강도 발현에 있어서 수산화칼슘의 영향)

  • 이제방;김재신;소승영;소양섭
    • Proceedings of the Korea Concrete Institute Conference
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    • 1999.04a
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    • pp.64-69
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    • 1999
  • Slags are by-products of the metallurgical industry. The most important slag from the standpoint of the quantity used as building material is iron blastfurnace slag. Slags are either crystalline stable solid used as aggregates or glassy material used as hydraulic binder. Slag cements are low heat of hydration cements. Slags react more slowly with than portland cement but they can be activated chemically. Activatiors can be either alkaline activators such as soda, lime, sodium carbonate, sodium silicate or sulphate activators such as calcium sulphate or phosphogypsum. So, in this study slaked lime was used as an activator that the compressive strength of this modified cement(M1 type) is high range in early age. And initial setting time of M1 type cement was shorter than conventional cements.

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An experimental study for improvement in physical properties on the alumino-silicate binder for wood wool ceramic board (목모 세라믹 보드용 알루미노-실리케이트계 무기 바인더의 물리적 특성 향상에 관한 실험적 연구)

  • Park, Dong-Cheal;Yang, Wan-Hee;Choi, Hae-Young;Lee, Se-Hyun;Song, Tae-Hyup;Sim, Jong-Woo
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.625-628
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    • 2006
  • It is known that cement production not only consumes large amount of energy but also contributes substantially to the green house gas emission. Therefore, there is a demand to develope a new technology to produce energy efficient and environmental conscious cements. The most recent, wood wool ceramic board is being applied in various building material field, for example thermal insulating and acoustic absorption material. This paper focused on improvement of alumino-silicate binder's physical properties for wood wool ceramic board. As the result of this experiment, what we could obtain best fitted alumino-silicate binder's properties such as initial setting time, flow and compressive strength of 3 days aged, was 58min, 110% and 66.0Mpa. This result can be applicable to commercial wood wool ceramic board.

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A Engineering Properties of High Early Strength Low Carbon Concrete Using Modified Ternary Blended Cement (개량형 3성분계 결합재를 사용한 조강형 저탄소 콘크리트의 기초적 특성)

  • Choi, Hyun-Kyu;Han, Sang-Yoon;Kim, Kyung-Min;Park, Sang-Joon;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2011.11a
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    • pp.55-56
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    • 2011
  • This study is to investigate the engineering properties of low heat concrete incorporating improved ternary blended cement by combining OPC(original portland cement), blast furnace slag and fly ash. The results were summarized as following ; For ITB(Improved Ternary Blend)mixture was that setting time proved to be accelerated, and adiabatic temperature rises were low. The use of ITB resulted in an increase of initial compressive strength.

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A Study on the Quality Properties for Using Tailings from the Sangdong Tungsten Mine as Admixture for Concrete. (상동광산 광미를 콘크리트용 혼화재료로 사용하기 위한 품질특성 연구)

  • 최연왕;정문영;정명채;구기정
    • Proceedings of the Korea Concrete Institute Conference
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    • 2003.05a
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    • pp.781-786
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    • 2003
  • This study has focused on the possibility for recycling tailings from the Sangdong tungsten mine as admixture for concrete. The XRD(X-ray diffraction analysis) and PSA(Particle size analysis) were performed to find mineralogical characteristics. As a result of XRD analysis, the tailings were composed of quartz, feldspars and muscovites, and C-S-H and quartz were found in cement mortar. As a result of KSLT for cement mortar mixed with tailings, most of heavy metals were determined as below the guide line for waste material. In addition, the setting time and compressive strength of cement mortar mixed with tailings were investigated. It was indicated that the initial and final set were retarded according to increasing replacement. The compressive strength of mortar was decreased with increasing replacement.

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A Study on the Alkali Application of Recycled Aggregates as a Solution to Reduced Intial Intensity of Blast Furnace Slags (고로슬래그의 초기강도 저하 해결방안으로써 순환 잔골재의 알칼리 활용가치에 대한 연구)

  • Kwak, Yong-Jin;Zhao, Yang;Jung, sang-woon;Heo, Young-sun;Han, Min-Cheol;Han, Cheon-Goo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2013.05a
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    • pp.85-86
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    • 2013
  • Weakness of fine powder of blast furnace slags includes the decrease of initial intensity and delay of setting time. To solve this problem, there has been research on the alkali activation to induce hardening using alkaline chemical. However, the use of chemicals is dangerous and not cost effective, which can be solved by using recycled aggregates, one of construction wastes. The role of alkali activator can be substituted by alkali of non-hydrated cement included in recycled aggregates. In this study, the alkaline value of recycled aggregates will be evaluated through the comparison of molarity of sodium hydroxide (NaOH).

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Characteristics of Mortar Mixed Nitric Acid Neutralized Red Mud by Cement Type (시멘트 종류별 질산 중화 레드머드 혼입 모르타르의 특성)

  • Kang, Suk-Pyo;Hong, Seong Uk;Kim, Sang-Jin;Hong, Seok-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.23 no.6
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    • pp.693-702
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    • 2023
  • This research explores the potential application of Liquid Red Mud(LRM), a byproduct of industrial processes, in the construction sector. We neutralized LRM(pH 10-12) using nitric acid, aiming to understand its viability in construction applications. The study involved substituting LRM(pH 7-8) in mortar formulations, varying by cement type. We assessed the properties of these mixtures by measuring flow, setting time, and compressive strength. Additionally, X-ray Diffraction(XRD) and Scanning Electron Microscopy(SEM) analyses were conducted to examine the chemical properties. Results indicated a reduction in flow value for LRM and LN(neutralized LRM) compared to the control (Plain ) across different cement types. The setting times(initial and final) for LRM and LN were notably shorter than Plain. In compressive strength tests, LRM replaced with slag cement showed enhanced initial strength, though long-term strength gains were marginal across different cement types. SEM analysis revealed distinct voids in Plain and LN, with LRM exhibiting a fibrous microstructure. XRD patterns in SN(slag neutralized) resembled those in OR(original red mud) and ON(original neutralized), with a notable peak at a 2θ value of 22°. The study concludes that unneutralized LRM, when substituted for slag cement in mortar, yields superior initial strength compared to its neutralized counterpart.

Determination Method of TTL for Improving Energy Efficiency of Wormhole Attack Defense Mechanism in WSN (무선 센서 네트워크에서 웜홀 공격 방어기법의 에너지 효율향상을 위한 TTL 결정 기법)

  • Lee, Sun-Ho;Cho, Tae-Ho
    • Journal of the Korea Society for Simulation
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    • v.18 no.4
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    • pp.149-155
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    • 2009
  • Attacks in wireless sensor networks (WSN), are similar to the attacks in ad-hoc networks because there are deployed on a wireless environment. However existing security mechanism cannot apply to WSN, because it has limited resource and hostile environment. One of the typical attack in WSN is setting up wrong route that using wormhole. To overcome this threat, Ji-Hoon Yun et al. proposed WODEM (WOrmhole attack DEfense Mechanism) which can detect and counter with wormhole. In this scheme, it can detect and counter with wormhole attacks by comparing hop count and initial TTL (Time To Live) which is pre-defined. The selection of a initial TTL is important since it can provide a tradeoff between detection ability ratio and energy consumption. In this paper, we proposed a fuzzy rule-based system for TTL determination that can conserve energy, while it provides sufficient detection ratio in wormhole attack.

Fluidity and Hydration Properties of Cement Paste Added Zinc Fluosilicate(ZnSiF6, aq.) (규불화아연(ZnSiF6, aq)이 첨가된 시멘트의 유동성과 수화특성)

  • Kim, Do-Su;Khil, Bae-Su;Lim, Heon-Seong;Nam, Jae-Hyun;Rho, Jae-Seong
    • Journal of the Korean Ceramic Society
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    • v.39 no.2
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    • pp.178-183
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    • 2002
  • Zinc fluosilicate ($ZnSiF_6$, 15% aqueous solution) was prepared using zinc oxide (ZnO) and fluosilicic acid ($H_2SiF_6$) by soluiton synthetic method. The fluidity and hydration properties of cement which was added $ZnSiF_6$ (aq.) as an additive for cement were studied. At water to cement ratio (W/C) equals to 0.45, the initial fluidity and slump loss of cement paste which the addition of $ZnSiF_6$ (aq.) was increased from 1.0% to 4.0% based on cement weight were investigated. Initial fluidity of cement paste was measured by mini-slump test and slump loss was examined by measuring the fluidity variation of cement paste with time elapsed from 0 min to 120 min at intervals 30 min. Also, the effect of $ZnSiF_6$ addition on the setting and hydration of cement paste when $ZnSiF_6$ increased in the addition range 1.0% to 3.0% were investigated. The fluidity of cement paste which was added 2.1% $ZnSiF_6$ (aq.) presented the highest value among all addition ranges. The setting time of cement paste was retarded gradually and the heat evolution of hydrated cement was reduced with the increasing of $ZnSiF_6$ addition.

Phase Changes of Soil-Cement Mixture Using Fall Cone and Heat of Hydration (Fall cone과 수화열을 이용한 흙-시멘트 혼합물의 상 변화 연구)

  • Kim Jae-Hyung;Won Jeong-Yun;Kim Sung-Pil;Chang Pyoung-Wuck
    • Journal of the Korean Geotechnical Society
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    • v.20 no.9
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    • pp.25-32
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    • 2004
  • Some amount of cements can be added into the soil with high water content to improve the engineering properties. In such a case, it is difficult to predict and figure out the phase changes of the soil-cement mixture which is closely associated with workability of the soil-cement mixture. Changes in heat of hydration and hardness of the cement pastes are known to provide the useful information about the phase changes of the soil-cement mixtures. In this study, heat of hydration and cone penetration depth were measured from the specimens of cement paste and 3 soil-cement mixtures. From the experimental results, it was found that the phase changes of the soil-cement mixtures are the same as those of cement paste, and that shear strength of the mixtures abruptly increases when the heat of hydration is minimum. Initial setting time of the mixtures coincides with the state when fall cone penetration depth was 1.0 mm and it is defined as plastic limit of the mixtures. Initial setting time of the mixtures is retarded as soil/cement ratio is increased. Measurements of heat of hydration and fall cone apparatus could be the useful tools to predict the phase changes of tile soil-cement mixtures.