• 제목/요약/키워드: inflammable gas

검색결과 31건 처리시간 0.045초

가연성 가스 인식을 위한 $SnO_2$계열의 박막 가스센서 ($SnO_2$-based thin film gas sensors in array for recognizing inflammable gases)

  • 이대식;심창현;이덕동
    • 한국진공학회지
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    • 제10권3호
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    • pp.289-297
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    • 2001
  • 가연성 가스의 검지 및 인식을 위하여, SnO$_2$계열의 4가지 종류의 박막을 형성하였다. 감지막 형성을 위하여, Sn, Pt/Sn, Au/Sn 그리고 Pt, Au/Sn 막을 Sn의 열증착과 귀금속의 스퍼터링으로 증착하였다. 증착된 박막들을 $700^{\circ}C$ 정도에서 2 시간 열산화시켜 $SnO_2$계열의 감지막을 형성하였다. 제작된 박막은 tetragonal구조의 $SnO_2$이었고, 가스 흡착을 위한 가스 흡착점과 기공도를 많이 갖고 있었다. 스퍼터로 형성된 박막보다 열산화법으로 형성된 박막이 고감도를 보였다. 제작 박막들은 작업환경기준치정도의 저농도에서 측정 가연성 가스(부탄, 프로판, LPG, 일산화탄소)에 대해 고감도와 재현성을 나타내었다. 특히, 백금(30 $\AA$)을 첨가한 박막이 LPG와 부탄 가스에 대해, 순수 열산화된 $SnO_2$ 박막이 프로판과 일산화탄소에 대하여 가장 고감도를 나타내었다. 이들 센서들의 각 가스별로 차별화된 감도패턴을 이용하여 주성분 분석 기법을 통해 환경기준치(LEL, TLV) 범위에서 부탄, 프로판, LPG, 일산화탄소와 같은 가연성 가스의 종류 인식 및 정량을 인식할 수 있었다.

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플레어스택의 정량적인 복사열 분석 (Quantitative Analysis of Thermal Radiation in Flare Stack)

  • 정상용;이헌석;김범수;유진환;박철환;고재욱
    • 한국가스학회지
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    • 제14권1호
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    • pp.37-41
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    • 2010
  • 공정내의 가연성 혹은 독성가스를 연소시켜 안전한 물질로 전환시키는 것을 목적으로 플레어시스템이 설치되어 있다. 플레어시스템은 공정의 안전성 향상을 위하여 폐가스의 안전한 연소가 가장 중요한 요소이다. 연소의 복사열이 공정의 위험요인이 되지 않도록 API 521 Code에 규정되어 있다. 플레어스택에서 발생하는 화염의 형상은 방출되는 가스의 압력과 질량유속에 의하여 jet fire의 형상을 하고 있으며, 이를 API 521 Code 방식이 아닌 Chamberlain Model을 이용하여 화염의 형상을 확인하고, 이로 인한 복사열을 분석하였다.

지하철 역내 가스 검출 원격 모니터링 시스템 구현 (Development of a remote monitoring system for gas detection at the subway station)

  • 박용만;김희식;김규식;이문규
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2007년도 심포지엄 논문집 정보 및 제어부문
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    • pp.439-441
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    • 2007
  • The seoul metropolitan subway has installed 8 lines and about 500 stations to transport 5 million passengers everyday. The underground air pollution level in the subway stations is very severe status, which is very harmful to the commutators and its personals. Although subway roles as such a massive and huge transportation system, the subway doesn't adapt yet any real-time air monitoring system. They have only some hand-held type detector equipments for monitoring air pollution. Therefore subway passengers are exposed to the harmful air pollution environment. The most harmful environmental parameters among the air pollution are known as the dust and sound noise dB level in the subway station. Because the dust is consisted of very small particles, we can't see them easily in dark condition on the platform, but it is very harmful. The monitoring system for air pollution is developed using embedded system attached with 6 different environmental sensors. This system monitors air pollution of dust sound noise, gas, temperature, humidity, inflammable gas, toxic gas in the subway ?station. The sensor unit of the ARM-CPU board and sensor transmits real time environmental data to the main server using Zigbee wireless communication module and TCP/IP network. The main control server receives and displays the real-time environmental data, and it send alarms to the personals when high level value.

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열처리 효과에 따른 SnO2 기반 수소가스 센서의 특성 최적화 (Optimization of SnO2 Based H2 Gas Sensor Along with Thermal Treatment Effect)

  • 정동건;이준엽;권진범;맹보희;김영삼;양이준;정대웅
    • 센서학회지
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    • 제31권5호
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    • pp.348-352
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    • 2022
  • Hydrogen gas (H2) which is odorless, colorless is attracting attention as a renewable energy source in varions applications but its leakage can lead to disastrous disasters, such as inflammable, explosive, and narcotic disasters at high concentrations. Therefore, it is necessary to develop H2 gas sensor with high performance. In this paper, we confirmed that H2 gas detection ability of SnO2 based H2 gas sensor along with thermal treatment effect of SnO2. Proposed SnO2 based H2 gas sensor is fabricated by MEMS technologies such as photolithgraphy, sputtering and lift-off process, etc. Deposited SnO2 thin films are thermally treated in various thermal treatement temperature in range of 500-900 ℃ and their H2 gas detection ability is estimatied by measuring output current of H2 gas sensor. Based on experimental results, fabricated H2 gas sensor with SnO2 thin film which is thermally treated at 700 ℃ has a superior H2 gas detection ability, and it can be expected to utilize at the practical applications.

화재안전성을 위한 도시철도 차량의 구조개선 (A Study on the Structural Reform of Urban Transit Vehicle Considering Elevation of Fire Safety)

  • 이근오;김규중
    • 한국안전학회지
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    • 제21권5호
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    • pp.22-27
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    • 2006
  • Even though the interior of urban transit vehicle has been changed as a preventing measure against fire to make it inflammable, there remains a possibility of fire breaking out in case of gasoline etc being brought in the subway. However, there is also the possibility that in case if fire toxic gas is generated and hot air spreads in carriage it will prove very dangerous for people sitting inside. This is a comparative study where we compare simulation results with model examining the time and direction the fire spreads when it breaks out. Also there is vertical distribution of temperature in carriage where the fire spreads out. This study is about demonstrating how to establish smokeless system in urban vehicle, about its necessity, and about vehicle system restructuring. This study also makes an effort to find more advanced method for efficient fire safety in trains. In existing vehicles, in case of fire, the smoke can't go out when doors are closed and hence it spreads in whole train. Even though the method of using ventilation or exhaust established inside the carriage to throw smoke out is much better than the way of opening end doors in each carriage, this study is trying to do research on second way. Through simulation we see that in second case, even though not as good as the first one, smoke can exit through gates. Even though the first method is better, the second can also be uses to let fire out. We can know that in the first case as the smoke can exit out faster, it provides more safety for people. So this system provides better fire safety condition.

공기보다 가벼운 가스 사용시설의 폭발위험장소 설정방안에 대한 연구 (A Study on Classification of Explosion Hazardous Area for Facilities using Lighter-than-Air Gases)

  • 임지표;정창복
    • 한국안전학회지
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    • 제29권2호
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    • pp.24-30
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    • 2014
  • There have been controversies over whether explosion hazardous area(EHA) should be classified for facilities which use lighter-than-air gases such as city gas, hydrogen and ammonia. Two view points are confronting each other: an economic piont of view that these gases are lighter than air and disperse rapidly, hence do not form EHA upon release into the atmosphere, and a safety point of view that they are also inflammable gases, hence can form EHA although the extent is limited compared to heavy gases. But various standards such as KS, IEC, API, NFPA do not exclude light gases when classifying EHA and present examples of EHA for light gas facilities. This study calculates EHA using the hypothetical volume in the IEC code where the hole sizes required for the calculation were selected according to various nominal pipe sizes in such a way to conform to the EHA data in the API code and HSL. Then, 25 leakage scenarios were suggested for 5 different pipe sizes and 5 operating pressures that cover typical operating conditions of light gas facilities. The EHA for the minimum leakage scenario(25 mm pipe, 0.01MPa pressure) was found to correspond to a hypothetical volume larger than 0.1 $m^3$(medium-level ventilation). This confirms the validity of classifying EHA for facilities using lighter-than-air gases. Finally, a computer program called HACPL was developed for easy use by light gas facilities that classifies EHA according to operating pressures and pipe sizes.

첨가제 및 패턴인식에 의한 후막 SnO2 가스센서의 선택성 향상 (The Enhancement of Selectivity in Thick Film SnO2 Gas Sensors by Additives and Pattern Recognition)

  • 정해원;김종명;박희숙;윤기현
    • 한국세라믹학회지
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    • 제40권11호
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    • pp.1073-1077
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    • 2003
  • Sn $O_2$ 가스센서는 낮은 농도의 가연성 가스 및 유독 가스를 표면 저항의 변화로부터 탐지할 수 있으나, 가스 선택성이 부족하다는 단점을 가지고 있다. 이러한 단점을 보완하기 위해서는 가스반응기구의 규명과 같은 기초이론 연구와 함께 선택성이 우수한 센서재료의 개발 및 적절한 신호처리방법의 적용이 필요하다. 본 논문에서는 Sn $O_2$ 표면에서 일어나는 에탄올 (C$_2$ $H_{5}$OH)과 아세토니트릴($CH_3$CN)의 촉매산화반응을 가스크로마토그래피 분석을 통해 확인하였다. PdCl$_2$가 첨가된 Sn $O_2$ 센서는 에탄올과 아세토니트릴에 대하여 높은 감도를 보였고, 반면에 La$_2$ $O_3$가 첨가된 Sn $O_2$ 센서는 에탄올에 대해서는 높은 감도를, 그리고 아세토니트릴에 대해서는 낮은 감도를 보였다. 이들 두 센서재료 개발 및 패턴인식기법적용을 통하여 아세토니트릴에 대한 선택성을 크게 증가시킬 수 있었다. 아세토니트릴에 대한 최소 탐지농도는, 공기 중에서는 15 ppm이었고, 다른 방해가스와 함께 존재할 경우에는 20 ppm에서 100 ppm 정도로 나타났다.

유·무기섬유 혼입비 및 혼입율 변화에 따른 HPFRCC의 기초물성 변화 (Changing Fundamental Properties of HPFRCC Depending on Combination and Content of Organic and Inorganic Fibers)

  • 이제현;문병룡;박용준;조성준;김종;한천구
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2016년도 춘계 학술논문 발표대회
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    • pp.28-29
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    • 2016
  • Recently, the attention on high tensile, and high performance cementitious composite (HPFRCC) which can minimize the damage from explosion of inflammable gas and chemicals has been increased. In spite of outstanding tensile performance, HPFRCC has the drawbacks of fiber ball, undesirable cost, and high autogenous shrinkage. therefore, in this research, to develop the optimum HPFRCC, the fundamental properties and autogenous shrinkage of HPFRCC was analyzed depending on various combination and content of organic and inorganic fibers.

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炭素아-크 (arc)에 依한 Sol의 生成 (Preparation of Sols by Carbon-arc)

  • 장세헌;김태린
    • 대한화학회지
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    • 제4권1호
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    • pp.7-9
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    • 1957
  • On sparking carbon-arc in water we found that a inflammable gas was generated. The object of this experiment is to prepare sols of metals by applying the gas mentioned to a solution of metallic salts. As the result of this experiment we found that : 1) By this method we can prepare easily some kinds of Ag-sol from $AgNO_3$ solution in about 30 sec. by adjusting the temperature, the quantity of stabilizer and the concentration of metallic salt. 2) The appropriate concentration of $AgNO_3$ is about 0.01% by volume, that of the stabilizer, 0.9104 N-NaOH is 0.03-2 cc/100 cc of 0.01% $AgNO_3$ solution. And the lower the temperature, the more concentrated the Ag-sol. But to check the possibility of applying this method to metals other than Au and Ag, measurement of the particle size and properties of a sol prepared by this method, should be studied. Especially, we must study what kinds of gases are generated by sparking the carbon-arc in water.

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열매체 가열기 설비에서의 폭발위험관리에 관한 연구 (A Study on Explosion Risk Management for Hot Oil Heater)

  • 장철;권진욱;황명환
    • 대한안전경영과학회지
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    • 제19권3호
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    • pp.1-9
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    • 2017
  • In the industrial field, various type of fuel have been used for product processing facilities. Recent for 10 years, the usage of natural gas (NG) was gradually increased. Because it has many merits; clean fuel, no transportation, storage facility and so on. There are common safety concept that strict explosion protection approaches are needed for facilities where explosive materials such as flammable liquid, vapor and gases exist. But some has an optimistic point of view that the lighter than air gases such as NG disperse rapidly, hence do not form explosion environment upon release into the atmosphere, many parts has a conventional safety point of view that those gases are also inflammable gases, hence can form explosion environment although the extent is limited and present. In this paper, the heating equipments (Hot Oil Heater) was reviewed and some risk management measures were proposed. These measures include hazardous area classification and explosion-proof provisions of electric apparatus, an early gas leak detection and isolation, ventilation system reliability, emergency response plan and training and so on. This study calculates Hazardous Area Classification using the hypothetical volume in the KS C IEC code.