Preparation of Sols by Carbon-arc

炭素아-크 (arc)에 依한 Sol의 生成

  • Chang, Sei-Hun (Dept. of Chem., Coll. of Lib. Arts & Sci., Seoul National University) ;
  • Kim, Tai-Lin (Dept. of Chem., Coll. of Lib. Arts & Sci., Korea University)
  • Published : 19571100

Abstract

On sparking carbon-arc in water we found that a inflammable gas was generated. The object of this experiment is to prepare sols of metals by applying the gas mentioned to a solution of metallic salts. As the result of this experiment we found that : 1) By this method we can prepare easily some kinds of Ag-sol from $AgNO_3$ solution in about 30 sec. by adjusting the temperature, the quantity of stabilizer and the concentration of metallic salt. 2) The appropriate concentration of $AgNO_3$ is about 0.01% by volume, that of the stabilizer, 0.9104 N-NaOH is 0.03-2 cc/100 cc of 0.01% $AgNO_3$ solution. And the lower the temperature, the more concentrated the Ag-sol. But to check the possibility of applying this method to metals other than Au and Ag, measurement of the particle size and properties of a sol prepared by this method, should be studied. Especially, we must study what kinds of gases are generated by sparking the carbon-arc in water.

Keywords

References

  1. Z. angew. chem. v.11 Bredig
  2. Z. phyik. chem. v.32 Bredig
  3. Das Kolloid Gold Zsigmondy-Thieren
  4. 大工試 v.9 Weimarn
  5. Bull. C.S.J. v.4 Weimarn
  6. Kolloid Z. v.53 Weimarn
  7. Z. Electrochem. v.14 Kohlschutter
  8. Kolloid-Z v.12 Kohlschutter
  9. 日化 v.55 宮本進
  10. 日化 v.56 宮本進
  11. Kolloid-Z v.67 宮本進
  12. Bull, C.S.J. v.9 佐野과
  13. Bull, C.S.J. v.15 佐野과