• 제목/요약/키워드: improving reaction

검색결과 444건 처리시간 0.028초

나노입자 혼합 복합슬러리를 이용한 반응소결 SiC 재료의 제조 (Fabrication of Reaction Sintered SiC Materials by Complex Slurry with Nano Size Particles)

  • 이상필
    • 대한기계학회논문집A
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    • 제29권3호
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    • pp.425-431
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    • 2005
  • The efficiency of complex slurry preparation route for developing the high performance SiC matrix of $RS-SiC_{f}/SiC$ composites has been investigated. The green bodies for RS-SiC materials prior to the infiltration of molten silicon were prepared with various C/SiC complex slurries, which associated with both the sizes of starting SiC particles and the blending conditions of starting SiC and C particles. The characterization of Rs-SiC materials was examined by means of SEM, EDS and three point bending test. Based on the mechanical property-microstructure correlation, the process optimization is also discussed. The flexural strength of Rs-SiC materials greatly depended on the content of residual Si. The decrease of starting SiC particle size in the C/SiC complex slurry was effective for improving the flexural strength of RS-SiC materials.

The Synthesis of Chlorin-based Photosensitizers for using in Photodynamics Therapy by Modification of Methyl Pyropheophorbide-a

  • Wang, Jin-Jun;Han, Guang-Fan;Shim, Young-Key
    • Journal of Photoscience
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    • 제8권2호
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    • pp.75-77
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    • 2001
  • The Grignard reaction of methyl pyropheophorbide-a (MPP-a) was performed to introduce lengthy alkyl chain for improving lipophilicity. After the introduction of alkyl chain to the both of carbonyls, peripheral aldehyde and cyclopentanone, the obtained diol 3 was subjected to dehydration to give monodehydrate product 4 selectively. The Qy band of prepared compounds were affected by the substituents on the Qy axis (N$\sub$21/-N$\sub$23/).

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Polarization Behavior of Li4Ti5O12 Negative Electrode for Lithiumion Batteries

  • Ryu, Ji-Heon
    • Journal of Electrochemical Science and Technology
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    • 제2권3호
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    • pp.136-142
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    • 2011
  • $Li_4Ti_5O_{12}$ is prepared through a solid-state reaction between $Li_2CO_3$ and anatase $TiO_2$ for applications in lithium-ion batteries. The rate capability is measured and the electrode polarization is analyzed through the galvanostatic intermittent titration technique (GITT). The rate characteristics and electrode polarization are highly sensitive to the amount of carbon loading. Polarization of the $Li_4Ti_5O_{12}$ electrode continuously increases as the reaction proceeds in both the charge and discharge processes. This relation indicates that both electron conduction and lithium diffusion are significant factors in the polarization of the electrode. The transition metal (Cu, Ni, Fe) ion added during the synthesis of $Li_4Ti_5O_{12}$ for improving the electrical conductivity also greatly enhances the rate capability.

고령운전자를 위한 자동긴급제동시스템 기술 개발 (Proactive Autonomous Emergency Braking System for the Elderly Driver)

  • 신동훈
    • 자동차안전학회지
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    • 제16권2호
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    • pp.14-19
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    • 2024
  • This paper describes autonomous emergency braking systems (AEB) for elderly drivers designed to consider their driving characteristics. With aging, perception-reaction time, and decision-making time increase accordingly. Without being aware of these performance degradations, however, changes in driving patterns due to increased alertness while driving lead to vehicle crashes. Therefore, it is necessary to develop an autonomous emergency braking system by incorporating the characteristics of the elderly driver. In order to enhance the driver acceptance of older people, perception-reaction time, alertness, and ride comfort need to be considered for conventional autonomous emergency braking systems (C-AEB). Proactive AEB(P-AEB) algorithm has been proposed to reflect human factor of elderly driver above. The performance of the proposed algorithm has been evaluated through MATLAB simulink simulation studies. It has been shown from the computer simulations that the proposed P-AEB algorithm enhances the driver acceptance of older people by improving ride comfort while ensuring safety of vehicle.

Effect of Urea-Formaldehyde Resin Adhesive Viscosity on Plywood Adhesion

  • Hong, Min-Kug;Park, Byung-Dae
    • Journal of the Korean Wood Science and Technology
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    • 제45권2호
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    • pp.223-231
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    • 2017
  • This work was conducted to investigate on the effect of urea-formaldehyde (UF) resin viscosity on plywood adhesion. The viscosity of UF resin was controlled either by adjusting the condensation reaction during its synthesis to obtain different target viscosities (100, 200 and 300 mPa.s) at two levels of formaldehyde/urea (F/U) mole ratios (1.0 and 1.2) or by adding different amounts (10, 20 and 30%) of wheat flour into the resins for the manufacture of plywood. When the viscosity of UF resin increased by the condensation reaction, the adhesion strength of plywood bonded with UF resin of 1.2 F/U mole ratio consistently increased, while those bonded with the 1.0 F/U mole ratio resin slightly decreased, suggesting a difference in the adhesion in plywood. However, the adhesion strength of plywood decreased as the viscosity increased by adding wheat flour, regardless of F/U mole ratio. The manipulation of UF resin viscosity by adjusting the condensation reaction was much more efficient than by adding wheat flour in improving the adhesion performance of plywood. These results indicated that a way of controlling the viscosity of UF resin adhesives has a great influence to their adhesion in plywood.

환원-산화 연계처리를 통한 니트로벤젠의 반응성 향상 및 무해화 연구 (Improving the Reactivity and Harmlessness of Recalcitrant Contaminants by Reduction-oxidation-linked Process)

  • 권희원;황인성;김영훈
    • 한국환경과학회지
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    • 제29권12호
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    • pp.1205-1211
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    • 2020
  • In this study, the applicability of reduction-oxidation-linked treatment was evaluated for nitrobenzene and a by-product by analyzing the reaction kinetics. Nitrobenzene showed very low reactivity to persulfate that was activated using various methods. Nitrobenzene effectively reacted through the reduction process using Zero-Valent Iron (ZVI). However, aniline, a toxic substance, was produced as a by-product. Reduction-oxidation-linked treatment is a method that can allow the oxidative degradation of aniline after reducing nitrobenzene to aniline. The experimental results show improved reactivity and complete decomposition of the by-product. Improved reactivity and decomposition of the by-product were observed even under conditions in which the reduction-oxidation reaction was induced simultaneously. No activator was injected for persulfate activation in the process of reducing oxidant linkage, and the activation reaction was induced by ferrous iron eluted from the ZVI. This indicates that this method can be implemented relatively simply.

알칼리 활성화 플라이애쉬를 사용한 비소성 무기결합재의 제조기술 개발 (Development of Manufacturing Technology of Non-Sintered Inorganic Using Alkali-activated Fly-ash)

  • 정석조;추용식;이종규
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2005년도 추계 학술발표회 제17권2호
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    • pp.753-756
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    • 2005
  • Recently, the alkali activation of Fly-ash has become a significant field of research because it is possible to use these materials having highly chemical reaction property. Also, the product does not generate CO2 gas, unlike ordinary Portland cement(O.P.C). Therefore, the purpose of this paper is to design for improving mechanical and chemical properties using Fly-ash and Meta-kaolin. And additive(CaO) affected to control the strength behaviors and shrinkage rate.

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오행체질론에 의한 안전직무 설계 (Job Design for Safety Based on Five Elements Constitution)

  • 이동형;김재두
    • 대한안전경영과학회지
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    • 제5권3호
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    • pp.31-43
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    • 2003
  • In the Oriental Medicine, the physical constitution of a human being can be classified into five characteristic elements. The remedy based on the five elements constitution has revealed excellent clinical effects so far. Therefore, it may be worthwhile to conduct job design researches considering the five elements constitution for improving the efficiency and safety of job. In this study, we examine whether the theory can be applied for job design through the experiment by ‘Digital-type Speed Anticipation Reaction Tester’ or not and suggest the desirable direction of job design.

방전여기 엑시머 레이저의 고효율화 방안 (Improving the efficiency in discharge pumped excimer laser)

  • 이영우
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2006년도 춘계종합학술대회
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    • pp.368-370
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    • 2006
  • 자외선영역에서 발진하는 엑시머 레이저 장치의 가스 장수명화에 의한 고효율화 방안을 제안하였다. 가스수명에 대하여 불소$(F_2)$의 감소와 불순물 발생에 의한 출력 변화의 이론적 해석 결과를 보고한다.

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ECH 생산공정 개선을 위한 Hypochlorination 반응에 관한 연구 : 부반응 억제 (A Study on the Hypochlorination Reaction for Improvement of Epichlorohlydrin Production Process : Reduction of Side Reacion)

  • 이철행;전상준;이태용;홍원희;윤창한;김영섭;조병남;김연석
    • 청정기술
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    • 제9권1호
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    • pp.29-35
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    • 2003
  • 기존의 Epichlorohydrin의 생산 공정을 개선하기 위해 중간 생성물인 dichlorohydrin생성 반응인 hypochlorination 반응에 대한 실험을 통해 개선방안을 조사하였다. 첫 번째로 이 반응에서 사용되고 있는 공업용수를 PVC 공장으로부터 방출된 폐수를 재활용하여 사용하였을 경우 반응 수율에 미치는 영향에 대해 실험하였고 실제적인 반응 생성물 조성에는 크게 영향을 미치지 않는 것으로 나타났다. 부반응물 중 거의 대부분을 차지하고 있는 TCPA를 정제공정 이전에 "추출제 A"를 사용하여 제거할 수 있다. 이를 이용하여 TCPA에 의한 부가적인 부반응을 억제하고 후단의 정제공정에서 분리하는데 소요되는 에너지를 절감할 수 있을 것이다. 또한 Allyl chloride와 반응하는 염소기체의 양을 감소시키면서 생성물의 조성변화를 관찰하였다. 주반응 생성물의 수율에 는 거의 영향을 미치지 않으면서 부반응물의 비율이 다소 감소하는 경향을 확인할 수 있었다.

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