• 제목/요약/키워드: hydrogen sulphide

검색결과 13건 처리시간 0.02초

Non-randomized, one way cross-over, open label preliminary clinical trial for silk protein based oral gargling

  • Kang, Yei-Jin;Ahn, Se-Hui;Kim, Yong-Wan;Jo, You-Young;Kweon, HaeYong;Kim, Seong-Gon
    • International Journal of Industrial Entomology and Biomaterials
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    • 제38권1호
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    • pp.14-17
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    • 2019
  • Oral gargling solution has been used for the control of halitosis. The purpose of this study was to compare the level of hydrogen sulphide concentration between silk oral gargling solution and commercially available oral gargling solution. Total 21 volunteers were included in this study. The relative level of hydrogen sulphide concentration was calculated to the baseline level. In terms of the primary endpoint of the trial, relative level of hydrogen sulphide concentration was $50.84{\pm}33.19%$ with silk group, versus $71.07{\pm}21.83%$ with Listerine group ($P_{non-inferiority}=0.003$). In conclusion, the results of oral gargling with a silk protein for healthy individual were non-inferior to oral gargling with Listerine for hydrogen sulphide concentration reduction.

Adsorptive removal of odour substances and NO and catalytic esterification using empty fruit bunch derived biochar

  • Lee, Hyung Won;Kim, Jae-Kon;Park, Young-Kwon
    • Carbon letters
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    • 제28권
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    • pp.81-86
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    • 2018
  • Empty fruit bunch (EFB) char was used to remove $NO_x$ and odorous substances. The physicochemical properties of the EFB chars were altered by steam or KOH treatments. The Brunauer-Emmett-Teller surface area and porosity were measured to determine the properties of the modified EFB chars. The $deNO_x$ and adsorption test for hydrogen sulphide and acetaldehyde were performed to determine the feasibility of the modified EFB chars. The KOH-treated EFB (KEFB) char revealed higher $deNO_x$ efficiency than with commercial activated carbon. The Cu-impregnated EFB char also had high $deNO_x$ efficiency at temperatures higher than $150^{\circ}C$. The KEFB char showed the highest hydrogen sulphide and acetaldehyde adsorption ability, followed by the steam-treated EFB char and untreated EFB char. Moreover, the product prepared by sulfonation of EFB char showed excellent performance for esterification of palm fatty acid distillate for biodiesel production.

$H_2S$ 가스를 이용한 황화주석 박막 증착에 관한 연구 (Tin Sulphide Thin Films Formed by Sulphidising D.C. Magnetron Sputtered Layers of Tin Using $H_2S$)

  • 마크리치;장동영;로저 마일즈
    • Tribology and Lubricants
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    • 제26권6호
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    • pp.317-321
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    • 2010
  • 황화주석 박막을 만들기 위해 마그네트론 스퍼터 박막증착 공정을 통해 몰리브텐 유리판위에 주석박막을 만들고, 95% 알곤 +5% 황화수소 가스 혼합물을 사용하여 아닐링 공정을 통해 황화주석 박막을 형성하위에 증착하는것이 좋은 결과를 보여주고있다. 박막면의 화학적 물리적 특성을 전자현미경, X선 분석, X 선회절을 통해 실험하였으며, 아닐링 조건에 따른황화주석 박막의 파장대 반사율의 관계를 측정하였다.

Reduction of Hydrogen Sulphide in Chicken Manure by Immobilized Sulphur Oxidising Bacteria Isolated from Hot Spring

  • Hidayat, M.Y.;Saud, H.M.;Samsudin, A.A.
    • 한국미생물·생명공학회지
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    • 제47권1호
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    • pp.116-124
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    • 2019
  • The rapid development of the poultry industry has led to the production of large amounts of manure, which produce substances like hydrogen sulfide ($H_2S$) that contribute to odor pollution. $H_2S$ is a highly undesirable gas component and its removal from the environment is therefore necessary. Sulfur-oxidizing bacteria (SOB) are widely known to remove contaminating $H_2S$ due to their ability to oxidize reduced sulfur compounds. In this study, three potential SOB (designated AH18, AH25, and AH28) that were previously isolated from a hot spring in Malaysia were identified by 16S rRNA gene analysis. Laboratory-scale biological deodorization experiments were conducted to test the performance of the three isolates-in the form of pure or mixed cultures, with the cells immobilized onto alginate as a carrier-in reducing the $H_2S$ from chicken manure. On the basis of 16S rRNA phylogenetic analysis, isolate AH18 was identified as Pseudomonas sp., whereas isolates AH25 and AH28 were identified as Achromobacter sp. The most active deodorizing isolate was AH18, with an $H_2S$ reduction rate of 74.7% (p < 0.05). Meanwhile, the reduction rates for isolates AH25 and AH28 were 54.2% and 60.8% (p > 0.05), respectively. However, the $H_2S$ removal performance was enhanced in the mixed culture, with a reduction rate of 81.9% (p < 0.05). In conclusion, the three potential SOB isolates were capable of reducing the $H_2S$ from chicken manure in the form of a pure culture immobilized on alginate, and the reduction performance was enhanced in the mixed culture.

사워가스 학술정보 동향 (Global Trends of Sciences Information on the Sour Gas)

  • 조진동
    • 자원환경지질
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    • 제48권1호
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    • pp.89-101
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    • 2015
  • '사워(sour)'는 종종 게르만 단어 "sauer 혹은 acidic" 어원에서 유래되었다. 사워가스는 물과 혼합되었을 때 산을 형성하는 황화수소($H_2S$)와 이산화탄소($CO_2$)와 같은 구성요소를 포함하고 있는 천연가스를 의미하며, 이는 부식, 연소와 폭발이 심하게 만드는 상당한 량의 황화수소를 포함하고 있으므로 사워가스 처리에 있어서 소요경비가 많아 들며 위험성이 따른다. 즉 특별한 취급과 기반시설을 요구하는 사워가스 사업은 가스의 경제적 가치와 생산 방법에 의한 요인으로 부터 영향을 받으므로 사워가스 개발생산은 안전하고 환경 친화적인 방법을 유지할 수 있는 진정한 과제들을 가지고 있다. 사워가스 에너지는 천연가스 중에서 황화수소 농도가 4 ppm 이상의 농도를 포함하고 있는 가스에 사용되는 용어로서 지하 심부의 돌로마이트 및 석회암 내에 부존하고 있다. 한편 황화수소는 부식될 수 있으며, 아주 낮은 농도에서도 사람에게 해롭기 때문에 특별한 주의가 필요한 위험한 가스이다. 계속적인 기술진보, 에너지 수요 급상승 및 유가강세는 미개발된 천연가스 중에서 40% 정도로 추정되는 사워가스 계획이 개선된 경제를 주도한다. 세계에서 사워가스 부존국가는 중국, 러시아, 캐나다, 미국 등등으로서 최대 부존지역인 중동지역으로서 부존된 천연가스 중에서 60%가 사워가스이고 다음은 최대 천연가스 생산국인 러시아로서 총 매장량의 34%가 사워가스이다. 세계 최대의 사워 가스전의 대부분 개발은 중동지역에 있는 오만, 쿠웨이트, 사우디아라비아와 아랍 에미리트 연방에서 착수를 하였다. 따라서 사워가스 자원 현황과 'Web of science' 데이터베이스에 등록된 학술문헌지에 발표된 사워가스 연구 활동(2000~2014)을 분석한 결과, 145편이 확인되었으며, 선도적으로 협력관계를 유지하는 기관은 미국지질조사소, 캐나다 지질조사소 및 중국 탐사개발 기술연구소이며, 국제적인 국가협력관계 측면에서는 중국, 미국 및 캐나다가 강세를 보여주고 있다.

고장력강 용접열영향부의 지연균열에 미치는 개재물의 영향 (Effect of Non-metallic Inclusions on Heat Affected Zone Delayed Cracking of High Strength Steels by Hydrogen)

  • 엄동석;정호신;익본공
    • Journal of Welding and Joining
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    • 제7권2호
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    • pp.49-59
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    • 1989
  • The effect of non-metallic inclusions on the HAZ hydrogen induced cracking was investigated. Quench and temper high tensile strength steels containing various sulphur contents were employed. The sulphur contents range between 0.007% and 0.040%. Non-metallic inclusions were mainly MnS type sylphide and Mn-Al-Si type. The sensitivity of HAZ delayed cracking was evaluated by implant testing. Diffusible hydrogen content was varied by controlling the moisture absorbing condition of manual arc welding electrodes. The one was asreceived condition, the other was dipping the electrodes in the water for ten minutes. The main results obtained were as follows; 1) The results of implant test showed that critical stress increased with increasing S content up to 0.013%. But steel containing 0.040%S showed lower critical stress than that of 0.013% S. These result suggest that there will be optimum S content to prevent HAZ delayed cracking of high strength steels. 2) Under the lower D.H.C. level, critical stress was increased with rolling reduction, but higher D.H.C. level, effect of rolling reduction was not recognized.

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H2S Gas Sensing Properties of SnO2:CuO Thin Film Sensors Prepared by E-beam Evaporation

  • Sohn, Jae-Cheon;Kim, Sung-Eun;Kim, Zee-Won;Yu, Yun-Sik
    • Transactions on Electrical and Electronic Materials
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    • 제10권4호
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    • pp.135-139
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    • 2009
  • $H_2S$ micro-gas sensors have been developed employing $SnO_2$:CuO composite thin films. The films were prepared by e-beam evaporation of Sn and Cu metals on silicon substrates, followed by oxidation at high temperatures. Results of various studies, such as scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) reveal that $SnO_2$ and CuO are mutually non-reactive. The CuO grains, which in turn reside in the inter-granular regions of $SnO_2$, inhibit grain growth of $SnO_2$ as well as forming a network of p-n junctions. The film showed more than a 90% relative resistance change when exposed to $H_2S$ gas at 1 ppm in air at an operating temperature of $350^{\circ}C$ and had a short response time of 8 sec.

공주 축산폐수공공처리장에서의 바이오가스-마이크로터빈 분산발전시스템 개발 (Biogas-Microturbine Distributed Generation Developement at Gong-Ju Public Livestock Wastewater Treatment Facility)

  • 박정극;허광범;이기철;강호;임상규
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2008년도 춘계학술대회 논문집
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    • pp.229-234
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    • 2008
  • Korea Electric Power Corporation (KEPCO) has started the nation's first biogas-microturbine project in the city of Gongju as an effort to encourage the utilization of wasted biogas containing useful energy source in the form of $CH_4$. The goal of the project is to set up the biogas microturbine co-generation system for utilizing biogas as an energy source and improving the economics of the wastewater treatment plant. Wastewater treatment processes were investigated in depth to find improvement possibility. Changes in internal recirculation ratio and pre-treatment degree are needed to optimize plant operation and biogas production. Biogas pre-treatment system satisfies Capstone's fuel condition requirement with the test result of 99.9% and 90.2% of hydrogen sulphide and ammonia is removal performance. Installation of microturbine and manufacture of heat exchanger to warm anaerobic digester has been done successfully. Expected economic profit produced by the system is coming from energy saving including electricity 115,871kWh/year and heat contained in exhaust gas 579GJ/year.

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Services of Algae to the Environment

  • Rai, Lal-Chand;Har Darshan Kumar;Frieder Helmut Mohn;Carl Johannas Soeder
    • Journal of Microbiology and Biotechnology
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    • 제10권2호
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    • pp.119-136
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    • 2000
  • Being autotrophic, algae occupy a trategic place in the biosphere. They produce oxygen both directly and indirectly through the chloroplasts of all green plants. The chloroplasts are believed to have originated from archaic prokaryotic algae through endosymbiosis with primitive eukaryotic cells. Phytoplankton and other algae regulate the global environment not only by releasing oxygen but also by fixing carbon dioxide. They affect water quality, help in the treatment of sewage, and produce biomass. They can be used to produce hydrogen which is a clean fuel, and biodiesel, and fix $N_2$ for use as a biofertilizer. Some other services of algae to the environment include restoration of metal damaged ecosystems, reducing the atmospheric $CO_2$ load and citigating global warming, reclamation of saline-alkaline unfertile lands, and production of dimethyl sulphide (DMS) and oxides of nitrogen (NOx) involved in the regulation of UV radiation. ozone concentration, and global warming. Algae can be valuable in understanding and resolving certain environmental issues.

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A Study on the Improvement of Comfortable Living Environment by Using real-time Sensors

  • KIM, Chang-Mo;KIM, Ik-Soo;SHIN, Deok-Young;LEE, Hee-Sun;KWON, Seung-Mi;SHIN, Jin-Ho;SHIN, YongSeung
    • 웰빙융합연구
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    • 제5권4호
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    • pp.19-31
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    • 2022
  • Purpose: This study was conducted to identify indoor air quality in various living spaces using sensors that can measure noise, vibration, fine dust, and odor in real time and to propose optimal indoor air quality maintenance management using Internet of Things(IoT). Research design, data and methodology: Using real-time sensors to monitor physical factors and environmental air pollutants that affect the comfort of the residential environment, Noise, Vibration, Atmospheric Pressure, Blue Light, Formaldehyde, Hydrogen Sulfide, Illumination, Temperature, Ozone, PM10, Aldehyde, Amine, LVOCs and TVOCs were measured. It were measured every 1 seconds from 4 offices and 4 stores on a small scale from November 2018 to January 2019. Results: The difference between illuminance and blue light for each measuring point was found to depend on lighting time, and the ratio of blue light in total illumination was 0.358 ~ 0.393. Formaldehyde and hydrogen sulphide were found to be higher than those that temporarily attract people in an indoor office space that is constantly active, requiring office air ventilation. The noise was found to be 50dB higher than the office WHO recommendation noise level of 35 ~ 40dB. The most important factors for indoor environmental quality were temperature> humidity> illumination> blue light in turn. Conclusions: Various factors that determine the comfort of indoor living space can be measured with real-time sensors. Further, it is judged that the use of IoT can help maintain indoor air quality comfortably.