• Title/Summary/Keyword: hydrogen sulphide

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Non-randomized, one way cross-over, open label preliminary clinical trial for silk protein based oral gargling

  • Kang, Yei-Jin;Ahn, Se-Hui;Kim, Yong-Wan;Jo, You-Young;Kweon, HaeYong;Kim, Seong-Gon
    • International Journal of Industrial Entomology and Biomaterials
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    • v.38 no.1
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    • pp.14-17
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    • 2019
  • Oral gargling solution has been used for the control of halitosis. The purpose of this study was to compare the level of hydrogen sulphide concentration between silk oral gargling solution and commercially available oral gargling solution. Total 21 volunteers were included in this study. The relative level of hydrogen sulphide concentration was calculated to the baseline level. In terms of the primary endpoint of the trial, relative level of hydrogen sulphide concentration was $50.84{\pm}33.19%$ with silk group, versus $71.07{\pm}21.83%$ with Listerine group ($P_{non-inferiority}=0.003$). In conclusion, the results of oral gargling with a silk protein for healthy individual were non-inferior to oral gargling with Listerine for hydrogen sulphide concentration reduction.

Adsorptive removal of odour substances and NO and catalytic esterification using empty fruit bunch derived biochar

  • Lee, Hyung Won;Kim, Jae-Kon;Park, Young-Kwon
    • Carbon letters
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    • v.28
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    • pp.81-86
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    • 2018
  • Empty fruit bunch (EFB) char was used to remove $NO_x$ and odorous substances. The physicochemical properties of the EFB chars were altered by steam or KOH treatments. The Brunauer-Emmett-Teller surface area and porosity were measured to determine the properties of the modified EFB chars. The $deNO_x$ and adsorption test for hydrogen sulphide and acetaldehyde were performed to determine the feasibility of the modified EFB chars. The KOH-treated EFB (KEFB) char revealed higher $deNO_x$ efficiency than with commercial activated carbon. The Cu-impregnated EFB char also had high $deNO_x$ efficiency at temperatures higher than $150^{\circ}C$. The KEFB char showed the highest hydrogen sulphide and acetaldehyde adsorption ability, followed by the steam-treated EFB char and untreated EFB char. Moreover, the product prepared by sulfonation of EFB char showed excellent performance for esterification of palm fatty acid distillate for biodiesel production.

Tin Sulphide Thin Films Formed by Sulphidising D.C. Magnetron Sputtered Layers of Tin Using $H_2S$ ($H_2S$ 가스를 이용한 황화주석 박막 증착에 관한 연구)

  • Leach, M.;Jang, D.Y.;Miles, R.
    • Tribology and Lubricants
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    • v.26 no.6
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    • pp.317-321
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    • 2010
  • Thin films of tin sulphide (SnS) have been formed by a novel 2-stage process where-in D.C. magnetron sputtering was used to deposit to thin films of tin (Sn) and the layers then sulphidised using 5% hydrogen sulphide ($H_2S$) gas in Argon. Although it was not found possible to deposit high quality thin films of tin directly onto glass substrates, excellent layers of tin were produced by using molybdenum (Mo) coated glass as the substrate material. The chemical and physical properties of the SnS layers formed were determined using scanning electron microscopy, energy dispersive x-ray analysis, x-ray diffraction studies and using reflectance versus wavelength measurements and these related to the conditions of synthesis. The data shows that it should be possible to produce conventional "substrate structure" devices based on the use of this technology.

Reduction of Hydrogen Sulphide in Chicken Manure by Immobilized Sulphur Oxidising Bacteria Isolated from Hot Spring

  • Hidayat, M.Y.;Saud, H.M.;Samsudin, A.A.
    • Microbiology and Biotechnology Letters
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    • v.47 no.1
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    • pp.116-124
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    • 2019
  • The rapid development of the poultry industry has led to the production of large amounts of manure, which produce substances like hydrogen sulfide ($H_2S$) that contribute to odor pollution. $H_2S$ is a highly undesirable gas component and its removal from the environment is therefore necessary. Sulfur-oxidizing bacteria (SOB) are widely known to remove contaminating $H_2S$ due to their ability to oxidize reduced sulfur compounds. In this study, three potential SOB (designated AH18, AH25, and AH28) that were previously isolated from a hot spring in Malaysia were identified by 16S rRNA gene analysis. Laboratory-scale biological deodorization experiments were conducted to test the performance of the three isolates-in the form of pure or mixed cultures, with the cells immobilized onto alginate as a carrier-in reducing the $H_2S$ from chicken manure. On the basis of 16S rRNA phylogenetic analysis, isolate AH18 was identified as Pseudomonas sp., whereas isolates AH25 and AH28 were identified as Achromobacter sp. The most active deodorizing isolate was AH18, with an $H_2S$ reduction rate of 74.7% (p < 0.05). Meanwhile, the reduction rates for isolates AH25 and AH28 were 54.2% and 60.8% (p > 0.05), respectively. However, the $H_2S$ removal performance was enhanced in the mixed culture, with a reduction rate of 81.9% (p < 0.05). In conclusion, the three potential SOB isolates were capable of reducing the $H_2S$ from chicken manure in the form of a pure culture immobilized on alginate, and the reduction performance was enhanced in the mixed culture.

Global Trends of Sciences Information on the Sour Gas (사워가스 학술정보 동향)

  • Cho, Jin Dong
    • Economic and Environmental Geology
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    • v.48 no.1
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    • pp.89-101
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    • 2015
  • The sour gas is natural gas containing components such as hydrogen sulphide and carbon dioxide that form acids when mixed with water. Element sulfur precipitates from sour gas when reservoir pressure and temperature decrease. According to the International Energy Agency, about 43% of the world's natural gas reserves(2,580 tcf or 73.057 tcm), excluding North America, are sour. The sour gas is often derived from the Germanic word 'sauer or acidic' and the etymology referred to as 'sour'. Sour gas requires special handling and infrastructure because it contains significant amounts of hydrogen sulphide, making it highly corrosive, flammable and explosive, and there fore more costly and dangerous to process. So the business of sour gas is affected by two important factors: the economic value of the gas, and the methods used in its production. According to be analyzed in the academic literature to sour gas(2000~2014) by the program of 'web of science', the research activities 145 papers in sour gas.

Effect of Non-metallic Inclusions on Heat Affected Zone Delayed Cracking of High Strength Steels by Hydrogen (고장력강 용접열영향부의 지연균열에 미치는 개재물의 영향)

  • 엄동석;정호신;익본공
    • Journal of Welding and Joining
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    • v.7 no.2
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    • pp.49-59
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    • 1989
  • The effect of non-metallic inclusions on the HAZ hydrogen induced cracking was investigated. Quench and temper high tensile strength steels containing various sulphur contents were employed. The sulphur contents range between 0.007% and 0.040%. Non-metallic inclusions were mainly MnS type sylphide and Mn-Al-Si type. The sensitivity of HAZ delayed cracking was evaluated by implant testing. Diffusible hydrogen content was varied by controlling the moisture absorbing condition of manual arc welding electrodes. The one was asreceived condition, the other was dipping the electrodes in the water for ten minutes. The main results obtained were as follows; 1) The results of implant test showed that critical stress increased with increasing S content up to 0.013%. But steel containing 0.040%S showed lower critical stress than that of 0.013% S. These result suggest that there will be optimum S content to prevent HAZ delayed cracking of high strength steels. 2) Under the lower D.H.C. level, critical stress was increased with rolling reduction, but higher D.H.C. level, effect of rolling reduction was not recognized.

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H2S Gas Sensing Properties of SnO2:CuO Thin Film Sensors Prepared by E-beam Evaporation

  • Sohn, Jae-Cheon;Kim, Sung-Eun;Kim, Zee-Won;Yu, Yun-Sik
    • Transactions on Electrical and Electronic Materials
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    • v.10 no.4
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    • pp.135-139
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    • 2009
  • $H_2S$ micro-gas sensors have been developed employing $SnO_2$:CuO composite thin films. The films were prepared by e-beam evaporation of Sn and Cu metals on silicon substrates, followed by oxidation at high temperatures. Results of various studies, such as scanning electron microscopy (SEM), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) reveal that $SnO_2$ and CuO are mutually non-reactive. The CuO grains, which in turn reside in the inter-granular regions of $SnO_2$, inhibit grain growth of $SnO_2$ as well as forming a network of p-n junctions. The film showed more than a 90% relative resistance change when exposed to $H_2S$ gas at 1 ppm in air at an operating temperature of $350^{\circ}C$ and had a short response time of 8 sec.

Biogas-Microturbine Distributed Generation Developement at Gong-Ju Public Livestock Wastewater Treatment Facility (공주 축산폐수공공처리장에서의 바이오가스-마이크로터빈 분산발전시스템 개발)

  • Park, Jung-Keuk;Hur, Kwang-Beom;Lee, Ki-Chul;Kang, Ho;Rhim, Sang-Gyu
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.229-234
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    • 2008
  • Korea Electric Power Corporation (KEPCO) has started the nation's first biogas-microturbine project in the city of Gongju as an effort to encourage the utilization of wasted biogas containing useful energy source in the form of $CH_4$. The goal of the project is to set up the biogas microturbine co-generation system for utilizing biogas as an energy source and improving the economics of the wastewater treatment plant. Wastewater treatment processes were investigated in depth to find improvement possibility. Changes in internal recirculation ratio and pre-treatment degree are needed to optimize plant operation and biogas production. Biogas pre-treatment system satisfies Capstone's fuel condition requirement with the test result of 99.9% and 90.2% of hydrogen sulphide and ammonia is removal performance. Installation of microturbine and manufacture of heat exchanger to warm anaerobic digester has been done successfully. Expected economic profit produced by the system is coming from energy saving including electricity 115,871kWh/year and heat contained in exhaust gas 579GJ/year.

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Services of Algae to the Environment

  • Rai, Lal-Chand;Har Darshan Kumar;Frieder Helmut Mohn;Carl Johannas Soeder
    • Journal of Microbiology and Biotechnology
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    • v.10 no.2
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    • pp.119-136
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    • 2000
  • Being autotrophic, algae occupy a trategic place in the biosphere. They produce oxygen both directly and indirectly through the chloroplasts of all green plants. The chloroplasts are believed to have originated from archaic prokaryotic algae through endosymbiosis with primitive eukaryotic cells. Phytoplankton and other algae regulate the global environment not only by releasing oxygen but also by fixing carbon dioxide. They affect water quality, help in the treatment of sewage, and produce biomass. They can be used to produce hydrogen which is a clean fuel, and biodiesel, and fix $N_2$ for use as a biofertilizer. Some other services of algae to the environment include restoration of metal damaged ecosystems, reducing the atmospheric $CO_2$ load and citigating global warming, reclamation of saline-alkaline unfertile lands, and production of dimethyl sulphide (DMS) and oxides of nitrogen (NOx) involved in the regulation of UV radiation. ozone concentration, and global warming. Algae can be valuable in understanding and resolving certain environmental issues.

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A Study on the Improvement of Comfortable Living Environment by Using real-time Sensors

  • KIM, Chang-Mo;KIM, Ik-Soo;SHIN, Deok-Young;LEE, Hee-Sun;KWON, Seung-Mi;SHIN, Jin-Ho;SHIN, YongSeung
    • Journal of Wellbeing Management and Applied Psychology
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    • v.5 no.4
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    • pp.19-31
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    • 2022
  • Purpose: This study was conducted to identify indoor air quality in various living spaces using sensors that can measure noise, vibration, fine dust, and odor in real time and to propose optimal indoor air quality maintenance management using Internet of Things(IoT). Research design, data and methodology: Using real-time sensors to monitor physical factors and environmental air pollutants that affect the comfort of the residential environment, Noise, Vibration, Atmospheric Pressure, Blue Light, Formaldehyde, Hydrogen Sulfide, Illumination, Temperature, Ozone, PM10, Aldehyde, Amine, LVOCs and TVOCs were measured. It were measured every 1 seconds from 4 offices and 4 stores on a small scale from November 2018 to January 2019. Results: The difference between illuminance and blue light for each measuring point was found to depend on lighting time, and the ratio of blue light in total illumination was 0.358 ~ 0.393. Formaldehyde and hydrogen sulphide were found to be higher than those that temporarily attract people in an indoor office space that is constantly active, requiring office air ventilation. The noise was found to be 50dB higher than the office WHO recommendation noise level of 35 ~ 40dB. The most important factors for indoor environmental quality were temperature> humidity> illumination> blue light in turn. Conclusions: Various factors that determine the comfort of indoor living space can be measured with real-time sensors. Further, it is judged that the use of IoT can help maintain indoor air quality comfortably.