• Transactions of the Korean hydrogen and new energy society
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• v.34 no.5
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• pp.505-513
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• 2023

Hydrogen infrastructure is expanding. High-capacity hydrogen refueling stations offer advantages because they can refuel a variety of light and heavy-duty vehicles, and multi-port refueling technology is developing to reduce charging time for heavy-duty vehicles. In this study, we suggest directions to lower the risk by analyzing the risk factors for each process involved in the installation of a high-capacity multi-port hydrogen refueling station in Changwon city. We conducted both qualitative and quantitative risk assessments of the equipment to evaluate the station. A hazard and operability study was performed for qualitative risk assessment, and PHAST/SAFETI were used for quantitative risk assessment. Quantitative risk assessment was used to calculate the consequence analysis of the facility to ensure secure design prior to station development and to predict individual and societal risks in various scenarios. As a result, the station's risk level was determined to be as low as reasonably practicable.

• Proceedings of the Korean Vacuum Society Conference
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• 2011.02a
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• pp.319-319
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• 2011

Hydrolysis of sodium borohydride provides a safe and clean approach to hydrogen generation. Having the proper catalytic support for controlling this reaction is therefore a valuable technology. Here we demonstrate the capability of hydroxyapatite as a novel catalytic support material for hydrogen generation. Aside from being inexpensive and durable, we reveal that Ru ion exchange on the HAP surface provides a highly active support for sodium borohydride hydrolysis, exemplifying a high total turnover number of nearly 24,000 mol $H_2$/ mol Ru. Moreover, we observe that the RuHAP support exhibits a high catalytic lifetime of approximately one month upon repeated exposure to $NaBH_4$ solutions. In addition to examining surface area effects, we also identified the role of complex surface morphology in enhancing hydrolysis by the catalytic transition metal covered surface. Particularly, we found that a polycrystalline RuHAP catalytic support exhibits shorter induction times for the initial bubble formation as well as increased hydrogen generation rates as compared to a single crystal supports. The independent factor of a complex surface morphology is believed to provide enhanced sites for gas release during the initial stages of the reaction. By demonstrating the ability to shorten induction time and enhance catalytic activity through changes in surface morphology and Ru content, we find it feasible to further explore this catalyst support in the construction of a practical hydrogen generator.

• Journal of the Korean Institute of Gas
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• v.27 no.4
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• pp.110-115
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• 2023

According to the Off-Gas Generation and Use Status Report (2015), Off-gas from the steel industry is estimated to be 80 million tons per year in Korea. If this is purified, large amounts of hydrogen can be produced, so active research and development related to hydrogen purification facilities is underway. In this study, a quantitative risk assessment (QRA) was conducted by analyzing the components of a off-gas based hydrogen purification facility and investigating risk factors. The risk analysis results were determined to be at an acceptable level and will be used as basic data to improve the safety of facilities considering the risks of hydrogen.

• Journal of the Korean Society of Safety
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• v.39 no.1
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• pp.9-15
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• 2024

Hydrogen-based electricity and transportation systems are widely recognized as sustainable power sources. However, the low ignition energy of hydrogen, only 1/10th that of conventional fossil fuels, poses a safety concern involving the risk of ignition due to electrostatic discharge from facility workers. Therefore, anti-static systems are imperative for hydrogen-based electricity facilities. To address this, we propose a reliable conductive rubber mat (CRM) to ensure the safety of these facilities. Unlike conventional anti-static floors that utilize conductive paint (CP), the CRM features a uniform distribution of conductive components in chemically and mechanically stable rubber. As a result, the CRM is unyielding to polar solvents (such as ethanol and hydrosulfuric acid) and non-polar solvents (like mineral oil) without increasing its resistance. Moreover, the CRM can withstand mechanical stress. Consequently, the human-body voltage of workers on the CRM would be sufficiently low enough to protect them from hydrogen explosions, thereby enhancing overall safety.

• Applied Chemistry for Engineering
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• v.31 no.2
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• pp.153-163
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• 2020

Compared to gaeous hydrogen, liquid hydrogen has approximately 1/800 volume, 800 times higher volumetric energy density at the same pressure, and the advantage of lower explosion risk and easier transportation than gaseous hydrogen. However, hydrogen liquefaction requires larger scale facility investment than simple compression storage method. Therefore, the research on energy-saving hydrogen liquefaction processes is highly necessary. In this study, helium/neon (mole ratio 80 : 20) refrigeration cycle was investigated as the main refrigeration process for hydrogen liquefaction. Process simulation for less energy consumption were carried out using PRO/II with PROVISION V10.2 of AVEVA. For hydrogen liquefaction, energy consumption was compared in three cases: Using a helium/neon refrigerant cycle, a SMR+helium/neon refrigerant cycle, and a C3-MR+helium/neon refrigerant cycle. As a result, the total power consumptions of compressors required to liquefy 1 kg of hydrogen are 16.3, 7.03 and 6.64 kWh, respectively. Therefore, it can be deduced that energy usage is greatly reduced in the hydrogen liquefaction process when the pre-cooling is performed using the SMR process or the C3MR process, which have already been commercialized, rather than using only the helium/neon refrigeration cycle for the hydrogen liquefaction process.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• v.y2005m4
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• pp.159-167
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• 2005

Considering the increase of interest in $H_{2}O_2$ as a rocket propellant, a test facility and a rocket engine have been developed to research in areas of $H_{2}O_2$ mono-propellant propulsion. A detailed design-study of a $H_{2}O_2$ mono-propellant rocket engine of 100-N thrust is presented. Several firings attempted in early stage had some problems with misfire and chamber pressure decrease. Low environmental temperature and impurities included in hydrogen peroxide were considered to be the reasons. Addressing these points resulted in successful firing of the rocket engine and obtained thrust about $100\sim107-N.$

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2006.05a
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• pp.110-117
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• 2006

Considering the increase of interest in $H_2O_2$ as a rocket propellant, a test facility and a rocket engine have been developed to research in areas of $H_2O_2$ mono-propellant propulsion. A detailed design-study of a $H_2O_2$ mono-propellant rocket engine of 100-N thrust is presented. Several firings attempted in early stage had some problems with misfire and chamber pressure decrease. Low environmental temperature and impurities included in hydrogen peroxide were considered to be the reasons. Addressing these points resulted in successful firing of the rocket engine and obtained thrust about $100\sim107-N$.

• Nuclear Engineering and Technology
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• v.30 no.2
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• pp.140-147
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• 1998

Basic concept of a cold neutron source for a 30 MW heavy water moderated reactor (HANARO) is developed. The source is a cold bottle located in a vertical hole near the reactor core. Since the bottle does not have sufficient volume for cooling, the optimum liquid mixture ratio is studied between liquid hydrogen and liquid deuterium. We also studied the variation of the gain depending on the volume of the bottle. The calculation is performed by a coupled MCNP model and by a semi-analytic approach. For the current geometry, 80% liquid deuterium mixture with liquid hydrogen gives the highest gain at 10 A neutron wave.

• Transactions of the Korean hydrogen and new energy society
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• v.32 no.1
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• pp.63-67
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• 2021

Accurate measurements of the heat transfer coefficients of concentric annular space for the test section is important to measure the tube-side heat transfer coefficients of working fluids. This paper presents the annular side heat transfer coefficients of concentric annuli with variation of tube diameter ratios using Wilson plot method. The test facility has a straight, horizontal test section with an active length of 3.0 m. Inner/outer diameters of test tubes are 7.0/7.5 and 8.0/8.56 mm, respectively. An outer diameter of annulus side is 16.0 mm. The test results show that convective heat transfer coefficients in annuli increase with annular diameter ratio. The correlations for convective heat transfer coefficients in annuli are also developed.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2004.03a
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• pp.34-40
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• 2004

Two different type scramjet models with side-wall compression and top-wall compression inlets have been tested in HPTF (Hypersonic Propulsion Test Facility) under the experimental conditions of Mach number 5.8, total temperature 1700K, total pressure 4.5㎫ and mass flow rate 3.5kg/s. The liquid kerosene was used as main fuel for the scramjets. In order to get fast ignition in the combustor, a small amount of hydrogen was used as a pilot. A strut with alternative tail was employed for increasing the compression ratio and for mixing enhancement in the side-wall compression case. Recessed cavities were used as a flameholder for combustion stability. The combustion efficiency was estimated by one dimensional theory. The uniformity of the facility nozzle flow was verified by a scanning pitot rake. The experimental results showed that the kerosene fuel was successfully ignited and stable combustion was achieved for both scramjet models. However the thrusts were still less than the model drags due to the low combustion efficiencies.